This paper presents a backbone curve estimation method for the stiffness nonlinearity of a nonlinear vibration absorber consisting of a circular brass plate with geometric imperfections. The backbone curves of an asymmetric system are estimated from the free vibration signal using the Hilbert vibration decomposition method, where only a single resonant frequency is excited. The Helmholtz-Duffing oscillator is applied to illustrate the proposed approach. Experimental data obtained from the free vibration of the nonlinear vibration absorber are measured, and the stiffness parameters are estimated using the current methods. The results compare reasonably well with those obtained using the restoring force surface method. The estimated backbone curves are qualitatively similar to those obtained using the Hilbert vibration decomposition. The proposed methods can be successfully applied to estimate the stiffness parameters of asymmetric engineering structures.