Higher Short-circuit Current Research Articles

Charge Transfer and Retention in 2D Passivated Perovskite-C60 Systems.

2D perovskites and organic ligands are often implemented as passivating interlayers in perovskite solar cells. Herein, five such passivates are evaluated by using time-resolved spectroscopy to study the carrier dynamics at the perovskite-C60 interface. The impact of passivation on factors such as charge transfer rate, charge retention in the acceptor layers, surface recombination, and uniformity are mapped onto the solar cell performance. The charge transfer was found to take place in tens of nanoseconds, and the charge retention without any passivate lasted a few hundred nanoseconds. The passivate that produced the best solar cells, ethylenediammonium iodide, extended the charge retention time up to one microsecond, which significantly increased the open-circuit voltage. It also had the best uniformity and hence least variance in power conversion efficiency. Curiously, it did not merely adjust surface energy states to enhance charge transfer but also extracted charges by itself without the C60, resulting in higher short-circuit current.

Metal coordination bond and rough interface enhanced triboelectric nanogenerator aiming for multiple complex conditions

Triboelectric nanogenerator (TENG) is widely used in the fields of sustainable green energy harvesting, self-powered motion parameter and tactile sensing, However, it still fails to meet the requirements under various complex conditions, such as low temperatures, self healing after destruction, punching, long-term placement, soaking in acid or alkali solution, scorch, continuous work. Herein, based on metal coordination, Zr4+ ions are introduced to enhance the first network k-carrageenan (k-CG) for achieving double enhancement in mechanics and electricity of the gel electrode layer, poly (N-hydroxyl acrylamide)/k-CG (PKZ) double network organic conductive gel enhanced by multiple hydrogen bonds and metal coordination bond is designed, and the gel exhibits high tensile strength, high conductivity, fast self-recovery, excellent self-repairing and low-temperature resistance. Based on simple sandpaper templates with different mesh numbers Ecoflex film with rough surfaces is designed for efficient triboelectric contact interface, and TENG with PKZ double network organic conductive gel as electrode layer is constructed, and possesses excellent resistant to multiple complex conditions. With high short-circuit current, open-circuit voltage and output power, the TENG is capable of powering electronic devices, and it can also be sensitive and stable sensing in writing recognition, real-time monitoring of motion parameters involving acceleration, speed and distance. The TENG is stable and reliable for sustainable green energy harvesting, motion parameter and tactile sensing in multiple complex environments. Thus, we provide novel ideas for designing energy harvesting and sensing for future wearable electronics under multiple complex conditions.

Modulating Aggregation Behavior by Ternary Strategies for Efficient and Stable Thick-Film Organic Solar Cells.

Functional third components targeted to improve a specific property of organic solar cells is an effective strategy. However, introducing a third component to simultaneously improve efficiency and stability and achieve good performance in thick-film devices has rarely been reported. Herein, low diffusion third components IDCN and ID2CN are reported to achieve a power conversion efficiency (PCE)of 18.08% and a high short-circuit current (J SC)of 27.82mAcm-2, one of the highest values based on PM6:Y6. They increase light harvesting in the range of 400-500nm while enhancing energy transfer via Förster resonance energy transfer (FRET). A tightly ordered molecular arrangement is achieved by modulating the preaggregation and film formation kinetics of Y6, which enhance exciton dissociation and charge transport. Moreover, the low-diffusion third component can effectively restrict the diffusion of Y6 to improve the morphology stability, and the T90 lifetime is increased from 689 to 1545h. In 300nm thick-film devices, PM6:ID2CN:Y6 achieves a PCE of 15.01%, much higher than PM6:Y6's 12.83%, demonstrating the great potential of ID2CN in thick-film devices.

Highly efficient 2D transition metal Dichalcogenides/SnSe solar cells using Sb2S3 as a back surface field and interfacial layer engineering

Boosting the performance of solar cells is crucial for advancing photovoltaic technology. This study investigates the integration of alternative 2D materials to enhance the performance of solar cells. Three solar cell configurations sample 1 with CdS, sample 2 with MoS2, and sample 3 with SnS2 are systematically investigated via numerical simulation. The simulation framework is validated against experimental data, demonstrating good agreement. Alternative 2D materials are explored to replace toxic CdS and improve the Voc through suitable band alignment with the absorber material, SnSe. Additionally, Sb2S3 is introduced as a back surface field (BSF) for the first time, resulting in increased efficiencies across all three samples. Further performance enhancements involve the insertion of 2D interfacial layers between the electron transport layer (ETL) and absorber to mitigate interface defects. Thirteen materials are evaluated as interfacial layers and nine metals as back contacts, revealing Ni as the optimal back contact for all samples, while MoS2, SnS2, and WS2 are identified as suitable interfacial layers for samples 1, 2, and 3, respectively. Analysis of the solar cells reveals that sample 2, incorporating MoS2 and SnS2, achieves the highest efficiency at 13.58 %. This outperforms sample 3 at 13.55 % and sample 1 at 13.13 %. Sample 2′s superior performance is attributed to the effective utilization of 2D transition metal dichalcogenide (TMDC) materials, which enhance charge carrier transport and minimize recombination losses within the cell structure. Optimized solar cell configurations are modeled using a one-diode approach to build corresponding modules. These modules, created by connecting solar cells in series and parallel, are evaluated through simulated I-V characteristics and power output under standard test conditions. Analysis reveals that Module 2 exhibits superior performance, with higher short-circuit current (ISC) and open-circuit voltage (VOC) compared to Modules 1 and 3. Overall, this study demonstrates the significant role of 2D TMC materials in advancing solar cell performance, providing valuable insights for future solar energy applications.

Enhancing electricity generation from water evaporation through cellulose-based multiscale fibers network

Harvesting energy from the water − solid interface through natural water evaporation provides a promising approach for generating sustainable electricity to power self-powered electronics. Advancing the bio-based hydrovoltaic materials enhances sustainability, with wood as a viable candidate due to the inherent hydrophilic and charged properties. However, current wood-based water evaporation-induced electricity generators (WEIGs) mainly depend on the “top-down” construction strategies. Wherein, the improvement of power density is constrained by the limited structural regulation, nondiverse building blocks, and monolithic enhancement mechanisms. Here, the high-performance wood-based WEIGs based on multiscale fibers network (MFN) are reported by embedding the Ti4O7 nanofibers (T4NF) inside the assemblies of TEMPO-oxidized cellulose nanofibrils (TOCNF) through a “bottom-up” route. Benefiting from the large specific surface area, high surface potential, and photothermal effect of conductive T4NF, the WEIG achieves a high short-circuit current of ∼13.7 μA while delivering ∼0.94 V open-circuit voltage. This work presents an efficient method to boost performance while understanding the impact of functional MFN on water evaporation.

The effect of applying lead ion to the surface of TiO2 on dye-adsorption rate and photovoltaic properties of solar cells

Lead ion was incorporated into TiO2 layers prepared on an F-doped tin oxide (FTO) substrate. The resulting electrodes (Pb2+-TiO2/FTO) were sensitized with N719 dye and put to use in dye-sensitized solar cells (DSCs). Owing to the electrostatic attraction between the positively charged TiO2 and the carboxylate anions (–COO−) in the N719 dye, more dye was adsorbed into the Pb2+-TiO2/FTO, which required only 2 h for sensitization, than in a reference TiO2/FTO electrode that was sensitized for 8 h. The power conversion efficiency of a DSC with the Pb2+-TiO2/FTO rose to 10.01 % over the efficiency (9.29 %) of the reference device. It was found that the increased dye adsorption in the Pb2+-TiO2/FTO allowed the cells to more efficiently harvest light and collect electrons, resulting in a higher short-circuit current in the DSC. The larger amount of dye also induced a higher open-circuit voltage in the cell by increasing the total number of photoinjected electrons and prolonging their lifetime.

Tailored Band Alignment for Improved Carrier Transport in Composition-Controlled Sb2(S,Se)3.

Sb2(S,Se)3 is a highly available energy material with a tunable bandgap by adjusting the S/Se ratio. Increasing the Se ratio can enhance the efficiency of Sb2(S,Se)3 solar cells, with a higher short-circuit current (JSC). However, the accompanying decrease in the open-circuit voltage (VOC) restricts further improvement. The defect passivation is important, since it can reduce carrier recombination, enhancing the VOC. In this study, the relevance of the S/Se ratio, defect concentration, and VOC was investigated. The samples with or without the deposition of Se-rich Sb2(S,Se)3 onto S-rich Sb2(S,Se)3 were used for defect characterization. Different surface compositions were confirmed by Raman spectroscopy. The complicated subdefect states of S-rich Sb2(S,Se)3 were shown through photoluminescence and conductive atomic force microscopy, and a decrease in the defect concentration was observed through surface photovoltage. The improvement of JSC via bandgap grading and the simultaneous VOC improvement by defect passivation resulted in efficient cell performance.

Self-powered online practical machine condition monitoring and wireless communication achieved on integrated, efficient, and durable triboelectric nanogenerator

Triboelectric nanogenerator (TENG) can effectively scavenge ambient mechanical energy with cost, weight, and effectiveness advantages despite critical issues of TENG such as integration to complex components, low current output, and durability. In this work, we designed an adaptive TENG on a mechanical shaft for harvesting rotational energy which can easily assemble and disassemble. The proposed TENG presents an excellent performance for a wide range of rotational speeds (0–2000rpm) and delivers a high power of up to about 80mW (a high short circuit current of 3mA) for a size of 216 cm3, which is high enough for many types of machine condition monitoring purposes. The designed TENG has been evaluated under the noncontact mode of operation within a 0–0.5mm gap between TENG films. The TENG demonstrates excellent electrical stability of 99% without surface wear under noncontact mode within the whole test period for continuous operation of 420,000 cycles. The contact mode with a contact pressure of 0.76 Pa results in 90% electrical stability and apparent surface degradation. Moreover, it is demonstrated that the proposed TENG can power a wireless vibration sensor (60 mW) within 10 minutes energy harvesting for 9 seconds to send data via Bluetooth to a smartphone at up to 30 m, and a wireless temperature sensor (1.2 mW) in real-time for machine condition monitoring.

Enhanced Performance of Dye Sensitized Solar Cells Through the Incorporation of Al2O3 Nanofillers in Polymer Electrolytes

In recent advancements in dye sensitized solar cell (DSSC) technology, the integration of inorganic nanofillers into polymer electrolytes has emerged as a promising strategy to enhance the structural stability and electrochemical performance of the devices. This study investigates the impact of various inorganic nanofillers, including TiO2, SiO2, and Al2O3, on the properties of polymer composite electrolytes employed in solid-state DSSCs sensitized with N719 dye. Among the considered nanofillers, the incorporation of Al2O3 into the polymer composite electrolyte demonstrated superior results, exhibiting heightened ionic conductivity and photo-current density attributed to increased amorphicity and reduced crystallinity. The Al2O3-enhanced DSSCs achieved notable photovoltaic parameters, including a conversion efficiency (η) of 5.61%, a high short circuit current (JSC) of approximately 13.17 mA/cm2, and an open circuit voltage (VOC) of approximately 0.707 V. Comparative analysis with other polymer composite electrolytes revealed that the Al2O3-based system surpassed in terms of photovoltaic performance. This study underscores the pivotal role of diverse nanofillers in polymer composite electrolytes for augmenting photocurrent density, conversion efficiency, and overall device stability.

Modelling and Analysis of Electromechanical Stress in Transformers Caused by Short-Circuits

A common reason for internal faults in transformers windings is the weakness insulation caused by vibration / deformation related to electromechanical forces produced by high short circuit currents. This phenomenon significantly reduces the transformer life expectancy and may even lead to its instantaneous or timing destruction. Focusing this subject this paper is aimed at presenting the performance of a time domain model inserted in a finite element program i.e. the 3D software package and the investigation of the relationship between high current levels occurring at transformer windings and the internal mechanical stresses. To highlight the overall model and the software performance, a laboratory 15 kVA transformer is utilized to show the programme facilities and potentially. The transformer has been built with concentric double-layer windings and ferromagnetic core with three columns and this equipment has been submitted to a balanced three-phase short- circuit. In addition, the computational simulations were carried out using distinct geometries to the windings i.e. with and without deformation.

Top cell design and optimization of all-chalcopyrite CuGaSe<sub>2</sub>/CuInSe<sub>2</sub> two-terminal tandem solar cells

Solar cells have attracted much attention, for they can convert solar energy directly into electric energy, and have been widely utilized in manufacturing industry and people’s daily life. Although the power conversion efficiency (PCE) of single-junction solar cells has gradually improved in recent years, its maximum efficiency is still limited by the Shockley-Queisser (SQ) limit of single-junction solar cells. To exceed the SQ limit and further obtain high-efficiency solar cells, the concept of tandem solar cells has been proposed. In this work, the chalcopyrite CuGaSe<sub>2</sub>/CuInSe<sub>2</sub> tandem solar cells are studied systematically in theory by combining first-principle calculations and SCAPS-1D device simulations. Firstly, the electronic structure, defect properties and corresponding macroscopic performance parameters of CuGaSe<sub>2</sub> (CGS) are obtained by first-principles calculations, and are used as input parameters for subsequent device simulations of CGS solar cells. Then, the single-junction CGS and CuInSe<sub>2</sub> (CIS) solar cells are simulated by using SCAPS-1D software, respectively. The simulation results for the single junction CIS solar cells are in good agreement with the experimental values. For single-junction CGS cells, the device simulations reveal that the CGS single-junction solar cells have the highest short-circuit current (<i>J</i><sub>sc</sub>) and PCE under the Cu-rich, Ga-rich and Se-poor chemical growth condition. Further optimization in the growth environment with the highest short circuit current (<i>J</i><sub>sc</sub>) shows that the open-circuit voltage (<i>V</i><sub>oc</sub>) and PCE of CGS solar cells can be improved by replacing the electron transport layer (ETL) with ZnSe. Finally, after the optimized CGS and CIS solar cells are connected in series with two-terminal (2T) monolithic tandem solar cell, the device simulation results show that under the growth temperature of 700 K and the growth environment of Cu-rich, Ga-rich, and Se-poor, with ZnSe serving as the ETL, the CGS thickness of 2000 nm and the CIS thickness of 1336 nm, the PCE of 2T monolithic CGS/CIS tandem solar cell can reach 28.91%, which is higher than the ever-recorded efficiency of the current single-junction solar cells, and shows that this solar cell has a good application prospect.

14C diamond as energy converting material in betavoltaic battery: A first principles study

The application of radioactive semiconductors is a potential way to improve the performance of betavoltaic battery. The stability and band structure of decayed 14C diamond are investigated by density functional theory. After the decay, the 14C atoms are substituted by nitrogen atoms, and it can be seen that the corresponding C63N1 and C62N2 structures have larger lattice constants and become more unstable. The C63N1 structure is a metallic system instead of an indirect bandgap semiconductor. Different C62N2 configurations have either metallic or indirect bandgap semiconductor properties, and the bandgaps are significantly lower than those of pure diamond. The 14C diamond–12C diamond betavoltaic battery switches between a pn-junction and p-type Schottky diode with higher short-circuit current.

Recent progress in nanocomposite-oriented triboelectric and piezoelectric energy generators: An overview

The demand for alternative energy is increasing globally, leading to the increased importance of energy harvesting technologies. Research is being conducted on the manufacture of piezoelectric (PENG), triboelectric (TENG) and electromagnetic nanogenerators (EMG), pyroelectric nanogenerators, electrochemical cells and solar cells, which transform thermal, mechanical, magnetic, chemical and solar energy into electrical energy. Furthermore, work is being done to create advanced hybrid systems that can convert multiple forms of energy into electrical energy simultaneously and adapt to different electronic devices and work environments. It is evident that advances in technology are essential for the development of TENGs, whose performance is influenced by the properties of their constituent elements. Fifty-five percent of the published literature focuses on TENGs, with 34.5% focusing on nanocomposites, owing to their improved properties and potential use in the fabrication of TENGs. However, piezoelectric nanogenerators (PENGs) can also enable low-power electronic devices to collect energy from the motions of biological systems. They demonstrate extraordinary piezoelectric capabilities and a higher power density, conversion efficiency and durability than earlier published prototype nanogenerators. Together, the high open circuit voltage (120 V) and low short circuit current (1.95 A) of PENGs result in a high-power density (7091 Vq).

Construction of efficient silicon solar cells through polymetallic oxidation-reduction triggered by thermite reaction

Optimal metal-semiconductor contact interface is crucial for semiconductor devices, particularly for silicon solar cells aluminum-silicon contact is a key to improve the efficiency of the cell. In this work, a new type of Sb2O3-MoO3-B2O3 glass frits that can trigger a thermite reaction was utilized to improve the Al-Si interface. The low melting temperatures of these glass frits enhance the effect of thermite reaction by providing solid-liquid contact, which enables gradient distribution of the elements and leads to differences in the valence states of the Al-Si layer at the inner and surface regions. The valence states of Al and Sb at the inner layer are higher than those at the surface, while Mo is the opposite. Metallic Mo with a matched work function can lower the potential barrier, thereby improving hole selectivity and enhancing the potential skip-step. As a result, the fabricated solar cell achieved a high open-circuit voltage, a high short-circuit current, and a low series resistance. Consequently, a power conversion efficiency of 19.94% was obtained for a monocrystalline silicon solar cell with full Al-BSF. This work not only presents a new hole-selective contact for silicon solar cells, but also introduces a new approach for regulating the distribution and valence states of interface elements for enhanced efficiency.

On the Problems of Current Limitations in Networks Based on Power Semiconductor Devices

The presence of high short-circuit currents (200–300 kA) in autonomous and generator power systems of low and medium voltage classes, causing a decrease in the switching resource of switching facilities, necessitates the search for ways of limiting the current. The paper proposes a solution to this problem: a semiconductor current-limiting device based on a DC chopper, a DC-to-DC converter. This devices’ features are its low dimensions and losses during typical operation. Semiconductor elements can be arranged quite compactly due to the lack of radiators for cooling, since the cooling process—taking into account the short duration of the current limitation process—is not efficient. The choice of semiconductor devices takes into account the short duration of the current load, as a result of which the temperature of the semiconductor structure does not exceed its permissible value. This paper presents a method for calculating the parameters of semiconductor devices, taking into account the current load as well as adjusting the magnitude of current limitation to a value that can be disconnected by switching devices. The short-term mode of operation of the power semiconductor device with current regulated by the frequency and duty cycle of its operation makes it possible to facilitate the required current limitation in the circuit for the subsequent fault clearance with a typical electrical device. The problem of overcurrent of one of the elements of the limiter is noted, which requires special attention to ensure that the semiconductor device is not overheated. This paper also presents the principle of current limitation, summarizes the results of experimental studies, and analyzes the presented capabilities of a semiconductor current limiter.

Biselenophene Imide: Enabling Polymer Acceptor with High Electron Mobility for High-Performance All-Polymer Solar Cells.

The shortage of narrow band gap polymer acceptors with high electron mobility is the major bottleneck for developing efficient all-polymer solar cells (all-PSCs). Herein, we synthesize a distannylated electron-deficient biselenophene imide monomer (BSeI-Tin) with high purity/reactivity, affording an excellent chance to access acceptor-acceptor (A-A) type polymer acceptors. Copolymerizing BSeI-Tin with dibrominated monomer Y5-Br, the resulting A-A polymer PY5-BSeI shows a higher molecular weight, narrower band gap, deeper-lying frontier molecular orbital levels and larger electron mobility than the donor-acceptor type counterpart PY5-BSe. Consequently, the PY5-BSeI-based all-PSCs deliver a remarkable efficiency of 17.77 % with a high short-circuit current of 24.93 mA cm-2 and fill factor of 75.83 %. This efficiency is much higher than that (10.70 %) of the PY5-BSe-based devices. Our study demonstrates that BSeI is a promising building block for constructing high-performance polymer acceptors and stannylation of electron-deficient building blocks offers an excellent approach to developing A-A type polymers for all-PSCs and even beyond.

Construction of Flexible Piezoceramic Array with Ultrahigh Piezoelectricity via a Hierarchical Design Strategy

AbstractThe µW‐level power density of flexible piezoelectric energy harvesters (FPEHs) restricts their potential in applications related to high‐power multifunctional wearable devices. To overcome this challenge, a hierarchical design strategy is proposed by forming porous piezoceramics with an optimum microstructure into an ordered macroscopic array structure to enable the construction of high performance FPEHs. The porous piezoceramic elements allows optimization of the sensing and harvesting Figure of merit, and the array structure causes a high level of effective strain under a mechanical load. The introduction of a network of polymer channels between the piezoceramic array also provides increased device flexibility, thereby allowing the device to attach and conform to the curved contours of the human body. The unique hierarchical piezoceramic array architecture exhibits superior flexibility, a high open circuit voltage (618 V), high short circuit current (188 µA), and ultrahigh power density (19.1 mW cm−2). This energy density value surpasses previously reported high‐performance FPEHs. The ultrahigh power flexible harvesting can charge a 0.1 F supercapacitor at 2.5 Hz to power high‐power electronic devices. Finally, the FPEH is employed in two novel applications related to fracture healing monitoring and self‐powered wireless position tracking in extreme environments.

Voltage Drop Estimation during Shore Connection with the Use of Motor Drives Modified as Static Frequency Converters

Ship-to-shore connection is an important technological element that reduces air pollution in ports. Therefore, ports install facilities that allow mooring ships to connect to the port distribution network. By 2025, this will be mandatory for all ports in Europe. This can be a challenging task in most ports due to the different frequency of the network and ship frequency. This problem can be solved by the use of grid-forming static frequency converters. This solution also brings some other advantages: The ship is not threatened by high shore short-circuit currents, and the port distribution network is not affected by the character of the ship load. However, frequency converter software must include a droop control algorithm to ensure that voltage deviations do not exceed the allowed limits during transients. Typical frequency converters used for shore connection are those developed as static frequency converters (SFCs). However, those converters were not developed for large power outputs, which are needed to power large vessels, such as ferries or cruise ships. This paper proposes motor drives that were modified to operate as SFCs. This approach has quite a lot of advantages which are described in this article. This paper describes both a standard shore connection system without a frequency converter and a solution that includes static frequency converters. The paper then focusses on voltage deviation estimations during connection/disconnection of large load (ferry or cruise ship) to static frequency converters. In this work, a high-voltage shore connection (HVSC) simulation model is developed, including a frequency converter, a shoreside transformer, medium-voltage (MV) connection cables, and a power system of the ship, to analyze in detail the behavior of the system in the case of connection or disconnection of the ship load. The model was made in DIgSILENT PowerFactory for the case of a commercial port in southern France. The model gives credible estimations of voltage drops/surges during transient and steady states.

Investigation on Preparation and Performance of High Ga CIGS Absorbers and Their Solar Cells.

Tandem solar cells usually use a wide band gap absorber for top cell. The band gap of CuIn(1-x)GaxSe2 can be changed from 1.04 eV to 1.68 eV with the ratio of Ga/(In+Ga) from 0 to 1. When the ratio of Ga/(In+Ga) is over 0.7, the band gap of CIGS absorber is over 1.48 eV. CIGS absorber with a high Ga content is a possible candidate one for the top cell. In this work, CuInGa precursors were prepared by magnetron sputtering with CuIn and CuGa targets, and CIGS absorbers were prepared by selenization annealing. The Ga/(In+Ga) is changed by changing the thickness of CuIn and CuGa layers. Additionally, CIGS solar cells were prepared using CdS buffer layer. The effects of Ga content on CIGS thin film and CIGS solar cell were studied. The band gap was measured by PL and EQE. The results show that using structure of CuIn/CuGa precursors can make the band gap of CIGS present a gradient band gap, which can obtain a high open circuit voltage and high short circuit current of the device. With the decrease in Ga content, the efficiency of the solar cell increases gradually. Additionally, the highest efficiency of the CIGS solar cells is 11.58% when the ratio of Ga/(In+Ga) is 0.72. The value of Voc is 702 mV. CIGS with high Ga content shows a great potential for the top cell of the tandem solar cell.

Towards improved efficiency of SnS solar cells using back grooves and strained-SnO2 buffer layer: FDTD and DFT calculations

In this work, a novel SnS thin-film solar cell (TFSC) based on strained-SnO2 electron transport layer (ETL) combined with back grooves aspect is proposed. The density functional theory (DFT) is used to assess the influence of the unit cell volume engineering on the electronic and optical properties of SnO2 material. Simulated results demonstrate the potential of strained-SnO2 material as a junction partner of p-type SnS absorber, showing a favorable conduction band offset and thereby reduced recombination effects. Moreover, the role of back grooves texture in enhancing light-scattering effects is investigated using FDTD technique. It is revealed that the proposed SnS TFSC based on combined strained-SnO2/SnS heterostructure and optimized back grooves paradigm offers the possibility for bridging the gap between improved absorption capabilities and enhanced photo-induced carrier extraction characteristics. It is demonstrated that the optimized SnS TFSC exhibits superior performances compared to the conventional one in terms of photovoltaic parameters, offering a high short-circuit current of Isc = 28 mA/cm2, a superior open-circuit voltage of Voc = 0.47 V, a high fill factor of FF = 68.4% and over than 9% of PCE. Therefore, our work paves the way to use the strained-SnO2 buffer layer and back grooves to boost the poor performances of SnS-based TFSCs.