High Levels Of Radioactivity Research Articles

Foreword: Selected papers from the 2022 International High-Level Radioactive Waste Management Conference

Foreword: Selected papers from the 2022 International High-Level Radioactive Waste Management Conference

Geochemical evaluation and hazard indices due to radioactive minerals associated with granitic areas

The present study employed statistical methods to evaluate the possible radiological hazards linked to granitic rocks-bearing mineralization in the ELgarra region of Egypt. The geological structures influence the occurrence of uranium mineralization in this area and are primarily associated with altered granites. Gamma-ray spectrometry was utilized to examine the quantities of 238U, 232Th, and 40K in granitic rock samples. The recorded levels of radioisotope activity concentrations in the analyzed regions ranged from 374 to 1740 Bq.kg−1238U, with an average of 1018 Bq.kg−1. For 232Th, the range was between 71 and 163 Bq.kg−1, with an average of 119 Bq.kg−1. Lastly, for 40K, the range was 756–1789 Bq.kg−1, with an average of 1212 Bq.kg−1. The detected levels of 238U, 232Th, and 40K in the examined rock samples were observed to exceed the permissible limits of 35, 45, and 412 Bq.kg−1, respectively. The primary radiological risks linked to these granitic rocks were attributed to the gamma rays released by the radioactive elements. Estimations of the radiological hazards in the granitic rocks were made, and statistical approaches were utilized to demonstrate the associations among radionuclides and radiological factors. The assessment confirmed that uranium, potassium, and their respective minerals in the granitic rocks were the key factors contributing to the radiological risks. As a result, the study determined that the granite rocks found in the study area needed precautions to be taken due to their high levels of radioactivity.

Radiological Analyses of 226Ra and 238U in Surface Water and Sediments from the Jackpile Member of the Morrison Formation, Pueblo of Laguna, New Mexico.

Surface water and sediments from the Jackpile mine, St. Anthony mine, Rio Paguate, Rio Moquino, and Mesita Dam areas near Pueblo of Laguna, New Mexico, were analyzed for 226Ra and U using gamma (γ) spectroscopy and inductively coupled plasma mass spectroscopy, respectively. Activity ratios for 226Ra/238U for solid samples range from 0.34 ± 0.13 to 16 ± 2.9, which reflect uranium transport and accumulation (<1), relatively pristine material in secular equilibrium (1), and removal of uranium by weathering (>1). Concentrations ranging from 80 to 225 μg L-1 U were detected in unfiltered water samples near the Jackpile mine. Water samples upstream and downstream from the mine contained concentrations ranging from 12 to 15 μg L-1 U. Water samples collected from the North Pit standing pond in the Jackpile mine contained as much as 1560 pCi L-1 of 226Ra, and passing the water through a 0.2 μM filter did not substantially reduce the activity of 226Ra in the water. 234Th and 226Ra are in secular equilibrium in this water, while radon gas was lost from the water. The results of the current study provide insight into the distribution of U-series radionuclides in the Pueblo of Laguna area, including detection of high levels of radioactivity in water at some locations within the Jackpile mine.

Radioactivity as a driver of bacterial community composition in naturally radioactive mineral springs in the French Massif Central.

Some natural environments on Earth are characterised by high levels of radiation, including naturally radioelement enriched mineral springs in the French Massif Central. Therefore, naturally radioactive mineral springs are interesting ecosystems for understanding how bacterial populations in these springs have adapted to high levels of natural and chronic radioactivity over the very long term. The aim of this study was to analyse the bacterial communities of sediments from five naturally radioactive mineral springs in the French Massif Central, sampled in autumn 2019 and spring 2020, and to observe whether radionuclides, compared to other physicochemical parameters, are drivers of the bacterial community structuring in these extreme environments. Physicochemical measurements showed that two springs, Dourioux and Montagne had high radioelement concentrations/activities (uranium, thorium and radon). Analysis of the structure of the bacterial communities, by next generation sequencing based on 16S rRNA gene sequencing, showed that the presence of radionuclides in Dourioux and Montagne, did not lead to a reduction in bacterial diversity and richness compared to the other springs. However, Dourioux and Montagne were characterised by specific bacterial populations, whose presence correlates with the radioelement concentrations/activities measured in these springs. This suggests that radioelements could partly explain the structuring of bacterial communities in these springs. In addition, several of these operational taxonomic units (OTUs) specific to Dourioux and Montagne, mainly affiliated to Proteobacteria, Firmicutes, Acidobacteria, Actinobacteria, and Bacteroidetes, could be involved in the biogeochemistry of radionuclides through different mechanisms (biosorption, biomineralisation, bioaccumulation, and bioreduction), which would allow the development of other bacterial species sensitive to these metals/radioelements. In particular, the co-occurrence of sulphate and/or iron-reducing bacteria, capable of bioreducing uranium, with fermentative bacteria, releasing sources of organic carbons, reflects associations of bacteria with complementary functions that allow them to grow in this peculiar environment and maintain a high diversity in these extreme environments. This study has provided a better understanding of the structuring of bacterial communities exposed to ionising radiation for thousands of years in naturally radioactive environments.

Characteristics of radioactive aerosols during the pre-decommission phase of the experimental shielding reactor

The decommissioning of nuclear reactors is a global concern, in part because of the generation of radioactive aerosols that can lead to internal radiation exposure. At present, radioactive aerosols generated during nuclear decommissioning have not been actively studied, and data collected from the actual decommissioning are limited. This paper presents a study of radioactive aerosols generated during the pre-decommission phase of an experimental shielding reactor. Among all the on-site operations, cutting resulted in the highest levels of radioactivity. Plasma arc cutting, in particular, had a maximum gross α and β radioactivity over 0.10 and 0.14 Bq/m3, respectively. Assumed AMAD (activity median aerodynamic diameter) values are employed to assess the impact of particle size on the internal exposure dose resulting from the inhalation of 137Cs aerosols. This assessment is based on the Human Respiratory Tract Model of International Commission on Radiological Protection. When cutting stainless steel by plasma arc, the internal exposure dose caused by 137Cs aerosols with an AMAD of 0.1 µm is estimated to be nearly four times as that of aerosols with an AMAD of 10 µm. Results show that the internal exposure dose is highly dependent on the AMAD, implying the importance of measuring size-related parameters of radioactive aerosols in the future nuclear decommissioning. This study has revealed some characteristics of radioactive aerosols released in decommissioning operations, which can serve as a valuable reference for controlling and removing aerosols during the decommissioning of nuclear facilities.

Natural radioactivity level in Yemen: A systematic review of radiological studies

This paper aimed to conduct a systematic review of 26 published articles from 13 different regions in the Republic of Yemen related to the study of natural radioactivity (NORM) and enhanced artificial radioactivity (TENORM). The study relied on the analysis of various sample types, including air, groundwater, surface water, hot spring water, soil, sand, rocks, building materials, and oil field samples. It also analyzed the study areas, the types of detectors employed, and the study's timeframe. The analytical results raised significant concerns regarding the high levels of radioactivity observed in many of the studied regions. Moreover, some regions indicated the absence of any prior radiological study, despite apparent effects on the population and the environment, which suggest the presence of potential radionuclide concentration. Based on this study, it is strongly recommended that researchers conduct further radiological studies in regions previously studied over extended periods and in areas where no prior radiological studies have been conducted to assess potential radionuclide concentration.

High temperature nanoindentation of (U,Ce)O2 compounds

Continuing to refine our knowledge of the evolving mechanical properties of nuclear fuel over the entire fuel service cycle is necessary to understand the pellet-clad mechanical interaction that occurs in the fuel rods during the operation. A challenge with measuring the mechanical properties of irradiated fuels is their high levels of radioactivity that usually require the use of hot cells making testing time consuming and expensive. Nanoindentation based techniques can be employed on minute volumes of material to measure mechanical properties, including Young’s modulus, hardness, and creep stress exponents. Increasing the mixed oxide fuels mechanical properties database through a variety of testing techniques should enhance modelers’ abilities to predict failure mechanisms in the fuel/clad interface. A current challenge to testing mixed oxide fuels is the plutonium component in the fuel. Mixed fluorite type oxides with ceria (CeO2) can be used as a surrogate for mixed oxide fuels. In this study, (U,Ce)O2 solid solutions samples are used to develop elevated temperature nanoindentation and nanoindentation creep testing methods for use on mixed oxide fuels. Nanoindentation testing was performed on 3 separate (Ux-1,Cex)O2 compounds ranging from x equals 0.1 to 0.3 in equal steps at temperatures up to 800 °C: their Young’s modulus, hardness, and creep stress exponents were evaluated. The Young’s modulus decreases in the expected linear manner while the hardness decreases in the expected exponential manner. The nanoindentation creep experiments at 800 °C give stress exponent values, n = 4.7–6.9, that suggests dislocation motion as the deformation mechanism.

Radiological safety assessment for transportation of reactor pressure vessel during decommissioning of a nuclear power plant in Korea

In Korea, decommissioning of nuclear power plants and transportation of the decommissioning waste are expected to expand in the near future. It is necessary to confirm that radiological risks to the public and workers are not significant through radiological safety assessment. The objective of this study is to assess the radiological safety for transportation of RPV waste, which is a major decommissioning waste with relatively high level of radioactivity. It was assumed that the waste would be transported to the Gyeongju disposal facility by land transportation. First, the source term and transportation method of the RPV waste were determined, and the external dose rates from the waste were calculated using MCNP. Then, transportation scenarios were assumed under both normal and accident conditions. Under the scenarios, radiation doses were calculated using the RADTRAN. Under normal operation scenarios without a transportation accident, assuming 40 shipments per year, the average individual doses for the public ranged from 6.56 × 10−6 to 2.18 × 10−2 mSv yr−1. The maximum individual doses for only a single shipment ranged from 2.43 × 10−6 to 3.14 × 10−1 mSv. For cargo handlers and vehicle crew members, the average doses were 2.26 × 101 mSv yr−1 and 2.95 mSv yr−1, respectively. Under transportation accident scenarios, average individual radiological risks which are product of the radiation doses and the annual accident rates ranged from 1.14 × 10−11 to 1.61 × 10−10 mSv yr−1 by transportation route segment when considering the transportation accident rate. Average individual doses assuming transportation accident occurrence ranged from 2.62 × 10−4 to 1.42 × 10−3 mSv. The maximum individual dose under accident conditions was 7.99 × 10−2 mSv. The calculated doses were below the regulatory limits in Korea. However, relatively high doses were observed for cargo handlers and vehicle crew members because of conservative assumptions. This study results can be used as basic data for the radiological safety assessment for the decommissioning waste transportation in the future.

Improvement of the knowledge of diatom ecology by coupling geochemistry, radioactivity and taxa inventory in thermo-mineral springs of a volcanic and upland area in south-central France, the Massif Central

ABSTRACT In connection with its geological history, many thermo-mineral springs are present in the Massif Central (France). The physicochemical characteristics of these springs (temperature, mineralization, gas content) result both from their deep circulation and from the geological formations or surface waters with which they interact during their ascent. In mineral springs, diatoms are well represented. To date, no study has focused on coupling the origin of water with diatom communities, whether in the Massif Central or in other parts of the world. The purpose of this study is to cross the information obtained on the water and the diatoms in order to analyse the biodiversity and improve knowledge of the species autecology. Twelve mineral springs with some of which have high levels of radioactivity were studied in the Massif Central. As results, the geochemical facies, the origin of the water and the Total Dissolved Solids influence the taxonomic composition but not the specific richness, Shannon index and Evenness. Furthermore, 222Rn influences diatom richness and community structure. Planothidium frequentissimum, Crenotia angustior and Sellaphora labernardierei were associated with high values of 222Rn activity. The water temperature was a factor that influences diatom species distribution. Some species appears to be more sensitive to the composition of water, such as Planothidium frequentissimum which attests to a mixing between deep and surface waters.

Romanian students’ knowledge on radiation protection

Abstract Since March 2022, Romania has become a country in the vicinity of a military conflict (there are 649 km border between Romania and Ukraine). As the Russian Federation threatens with using its nuclear arsenal against Ukraine or NATO member states, the risk the Romanian population to be exposed to high radioactivity levels (including radioactive iodine) has to be taken into consideration. In this context, in April 2022 the Romanian Ministry of Health decided to provide iodine tablets to all people under the age of 40; it also launched a public information campaign aimed to advise people on how to avoid radiation exposure, including how to take iodine tablets. One year after this campaign, we evaluated the students’ knowledge on potassium iodide (KI) administration. A number of 828 students (in Medicine, Dentistry, Nursing, Pharmacy, Sciences, Electronics, and Philology), 68% females, aged 20-24 years, answered a 12-item questionnaire on KI administration. The results show 78.3% of the subjects associated KI administration with a nuclear accident/use of nuclear weapons; about 70% knew they can have KI from the pharmacist's using a prescription from the general practitioner. Only 38.6 % of the students correctly mentioned the age of KI administration; 41.1% knew a single dose administration is necessary. About 63% of the respondents knew KI is necessary to protect the thyroid; 53.1% mentioned thyroid cancer as the risk of KI non-administration. As expected, most correct answers were given by students in health-care specialties, while the less correct - by students in Philology (p &amp;lt; 0.001). Surprisingly, best informed medical students were respondents from Nursing, followed by those in Medicine, Pharmacy, and Dentistry (p &amp;lt; 0.01). Even students are considered a well-informed population group, the results indicate more than half of the subjects miss important information concerning radiation exposure attitude. Key messages • Nowadays nuclear weapons use is a threat everybody should be aware of. • Information is an essential tool to make people able to protect themselves against radiation exposure.

Irradiated and radioactively contaminated foods: Analysis of EU RASFF notifications from 1997 to 2022

Food irradiation technique is an authorized tool used on a commercial scale in many countries to preserve different types of foodstuffs from deterioration caused by microorganisms, insects, and metabolic activity to prolong their shelf life without leaving any residual effect on processed foods, unlike preservatives and pesticides. This study was carried out to analyse the EU Rapid Alert System for Food and Feed (RASFF) notifications on food radiation from 1997 to 2022 in order to identify the most frequently reported products, their origin countries and associated reasons for notification, as well as the most notifying countries, product categories, notification classification, risk decisions, and actions taken. A total of 488 notifications were recorded during this time period. China was the most frequently notified origin country, accounting for 19.88% of all notifications, followed by the United States (11.68%), Russia (7.99%), Vietnam (7.17%), and Poland (5.53%). The top notified product categories were “dietetic foods, food supplements, and fortified foods” (37.09%), followed by fruits and vegetables (23.16%), herbs and spices (8.81%), and prepared dishes and snacks (5.53%). The top 5 notified products were food supplements (25.00%), mushrooms (20.70%), noodles (7.58%), tea (4.51%), and spices (3.69%). The four main reasons for food radiation notifications were unauthorized irradiation (57.58%), too high levels of radioactivity (22.34%), unlabeled irradiation (19.47%), and unauthorized facilities (14.96%). Too many notifications included more than one reason for the notification. Out of 109 notifications related to too-high levels of radioactivity (up to 10755 Bq/kg), 101 were due to the presence of 137Cs, 134Cs, 60Co, and 48Cd in mushrooms, mainly originating from Poland (25), Bulgaria (24), Ukraine (15), and Belarus (12). Such studies provide the necessary data to ensure food safety and encourage countries to implement comprehensive procedures to protect consumers health.

11C]Paraoxon: Radiosynthesis, Biodistribution and In Vivo Positron Emission Tomography Imaging in Rat.

Synthesis of the acetylcholinesterase inhibitor paraoxon (POX) as a carbon-11 positron emission tomography tracer ([11C]POX) and profiling in live rats is reported. Naïve rats intravenously injected with [11C]POX showed a rapid decrease in parent tracer to ∼1%, with an increase in radiolabeled serum proteins to 87% and red blood cells (RBCs) to 9%. Protein and RBC leveled over 60 minutes, reflecting covalent modification of proteins by [11C]POX. Ex vivo biodistribution and imaging profiles in naïve rats had the highest radioactivity levels in lung followed by heart and kidney, and brain and liver the lowest. Brain radioactivity levels were low but observed immediately after injection and persisted over the 60-minute experiment. This showed for the first time that even low POX exposures (∼200 ng tracer) can rapidly enter brain. Rats given an LD50 dose of nonradioactive paraoxon at the LD50 20 or 60 minutes prior to [11C]POX tracer revealed that protein pools were blocked. Blood radioactivity at 20 minutes was markedly lower than naïve levels due to rapid protein modification by nonradioactive POX; however, by 60 minutes the blood radioactivity returned to near naïve levels. Live rat tissue imaging-derived radioactivity values were 10%-37% of naïve levels in nonradioactive POX pretreated rats at 20 minutes, but by 60 minutes the area under the curve (AUC) values had recovered to 25%-80% of naïve. The live rat imaging supported blockade by nonradioactive POX pretreatment at 20 minutes and recovery of proteins by 60 minutes. SIGNIFICANCE STATEMENT: Paraoxon (POX) is an organophosphorus (OP) compound and a powerful prototype and substitute for OP chemical warfare agents (CWAs) such as sarin, VX, etc. To study the distribution and penetration of POX into the central nervous system (CNS) and other tissues, a positron emission tomography (PET) tracer analog, carbon-11-labeled paraoxon ([11C]POX), was prepared. Blood and tissue radioactivity levels in live rats demonstrated immediate penetration into the CNS and persistent radioactivity levels in tissues indicative of covalent target modification.

Toward Stability Enhancement of NTS1R-Targeted Radioligands: Structural Interventions on [99mTc]Tc-DT1.

The neurotensin subtype 1 receptor (NTS1R) is overexpressed in a number of human tumors, thereby representing a valid target for cancer theranostics with radiolabeled neurotensin (NT) analogs like [99mTc]Tc-DT1 (DT1, N4-Gly7-NT(8-13)). Thus far, the fast degradation of intravenously injected NT-radioligands by neprilysin (NEP) and angiotensin-converting enzyme (ACE) has compromised their clinical applicability. Aiming at metabolic stability enhancements, we herein introduce (i) DT7 ([DAsn14]DT1) and (ii) DT8 ([β-Homoleucine13]DT1), modified at the C-terminus, along with (iii) DT9 ([(palmitoyl)Lys7]DT1), carrying an albumin-binding domain (ABD) at Lys7. The biological profiles of the new [99mTc]Tc-radioligands were compared with [99mTc]Tc-DT1, using NTS1R-expressing AsPC-1 cells and mice models without or during NEP/ACE inhibition. The radioligands showed enhanced in vivo stability vs. [99mTc]Tc-DT1, with [99mTc]Tc-DT9 displaying full resistance to both peptidases. Furthermore, [99mTc]Tc-DT9 achieved the highest cell internalization and tumor uptake even without NEP/ACE-inhibition but with unfavorably high background radioactivity levels. Hence, unlike C-terminal modification, the introduction of a pendant ABD group in the linker turned out to be the most promising strategy toward metabolic stability, cell uptake, and tumor accumulation of [99mTc]Tc-DT1 mimics. To improve the observed suboptimal pharmacokinetics of [99mTc]Tc-DT9, the replacement of palmitoyl on Lys7 by other ABD groups is currently being pursued.

The Glutaminase-1 Inhibitor [11C-carbony]BPTES: Synthesis and Positron Emission Tomography Study in Mice.

Bis-2-(5-phenylacetamido-1,3,4-thiadiazol-2-yl)ethyl sulfide (BPTES) is a selective inhibitor of glutaminase-1 (GLS1), consequently inhibiting glutaminolysis. BPTES is known for its potent antitumor activity and plays a significant role in senescent cell removal. In this study, we synthesized [11C-carbonyl]BPTES ([11C]BPTES) as a positron emission tomography (PET) probe for the first time and assessed its biodistribution in mice using PET. [11C]BPTES was synthesized by the reaction of an amine precursor () with [11C-carbonyl]phenylacetyl acid anhydride ([11C]2), which was prepared from [11C]CO2 and benzyl magnesium chloride, followed by in situ treatment with isobutyl chloroformate. The decay-corrected isolated radiochemical yield of [11C]BPTES was 9.5% (based on [11C]CO2) during a synthesis time of 40 min. A PET study with [11C]BPTES showed high uptake levels of radioactivity in the liver, kidney, and small intestine of mice.

Decontamination of uranium-containing radioactive waste from stainless steel surfaces using NaOH-based molten salts.

Herein, we report a new strategy for the rapid removal of uranium-containing contaminants from metal surfaces, and it relies on decontaminants made of NaOH-based molten salts. The addition of Na2CO3 and NaCl to NaOH exhibited superior decontamination performance, with a decontamination rate of 93.8% within 12 min, outdoing the performance of the single NaOH molten salt. The experimental results demonstrated that the synergistic effects between CO32- and Cl- promoted the corrosion efficiency of the molten salt on the substrate, which accelerated the decontamination rate. Additionally, benefiting from the optimization of the experimental conditions by the response surface method (RSM), the decontamination efficiency was improved to 94.9%. Notably, it also showed remarkable results in the decontamination of specimens containing different uranium oxides at low and high levels of radioactivity. This technology is promising for broadening the path in rapid decontamination of radioactive contaminants on metal surfaces.

Transmutation of MAs and LLFPs with a lead-cooled fast reactor

The management of nuclear wastes has long been a problem that hinders the sustainable and clean utilization of nuclear energy since the advent of nuclear power. These nuclear wastes include minor actinides (MAs: 237Np, 241Am, 243Am, 244Cm and 245Cm) and long-lived fission products (LLFPs: 79Se, 93Zr, 99Tc, 107Pd, 129I and 135Cs), and yet are hard to be handled. In this work, we propose a scheme that can transmute almost all the MAs and LLFPs with a lead-cooled fast reactor (LFR). In this scheme, the MAs and the LLFPs are loaded to the fuel assembly and the blanket assembly for transmutation, respectively. In order to study the effect of MAs loading on the operation of the core, the neutron flux distribution, spectra, and the keff are further compared with and without MAs loading. Then the LLFPs composition is optimized and the support ratio is obtained to be 1.22 for 237Np, 1.63 for 241Am, 1.27 for 243Am, 1.32 for 79Se, 1.53 for 99Tc, 1.02 for 107Pd, and 1.12 for 129I, respectively, indicating that a self-sustained transmutation can be achieved. Accordingly, the transmutation rate of these nuclides was 13.07%/y for 237Np, 15.18%/y for 241Am, 13.34%/y for 243Am, 0.58%/y for 79Se, 0.92%/y for 99Tc, 1.17%/y for 107Pd, 0.56%/y for 129I. Our results show that a lead-cooled fast reactor can be potentially used to manage nuclear wastes with high levels of long-lived radioactivity.

Synthesis and evaluation of a para-carboxylated benzyl-DOTA for labeling peptides and polypeptides

IntroductionRadiolabeled peptides and low-molecular-weight (LMW) polypeptides show high and persistent radioactivity levels in the kidney. To develop a DOTA-based bifunctional chelating agent that provides a radiometabolite with a rapid elimination rate from the kidney, a para-carboxyl Bn-DOTA (p-COOH-Bn-DOTA) was designed, synthesized, and evaluated. MethodsA precursor compound, p-COOH-Bn-DOTA(tBu)4, was synthesized in 9 steps using N-Boc-p-iodo-L-phenylalanine as the starting material. A synthetic somatostatin analog (TOC) was used as a representative peptide metabolized in the renal lysosomes. p-COOH-Bn-DOTA-conjugated TOC (DOTA-Bn-TOC) was synthesized by the conventional solid-phase peptide synthesis using p-COOH-Bn-DOTA(tBu)4. DOTA-tris(tBu ester) was also conjugated with TOC to prepare DOTATOC. 111In-labeling of the peptides was conducted under similar conditions. The radiochemical conversions, stability against apo-transferrin (apoTf), and in vivo behaviors were compared. Results[111In]In-DOTA-Bn-TOC was obtained with higher radiochemical conversions than [111In]In-DOTATOC. Both 111In-labeled TOC derivatives remained stable against apoTf. In biodistribution studies, [111In]In-DOTA-Bn-TOC exhibited higher initial uptake in the kidney, followed by a faster elimination rate of radioactivity into the urine than [111In]In-DOTATOC. The metabolic studies showed that the shorter residence time of the radiometabolite from [111In]In-DOTA-Bn-TOC was responsible for the renal radioactivity decline. Conclusionp-COOH-Bn-DOTA provides stable 111In-labeled peptides in high yields at low peptide concentrations. p-COOH-Bn-DOTA also provides a radiometabolite with a short residence time in the kidney. Such characteristics would render p-COOH-Bn-DOTA useful to the future application to radiolabeled LMW polypeptides with low renal radioactivity levels.

An Extended Investigation of High-Level Natural Radioactivity and Geochemistry of Neoproterozoic Dokhan Volcanics: A Case Study of Wadi Gebeiy, Southwestern Sinai, Egypt

High-level natural radioactivity, geochemical, geological, and radiological hazard assessment of the poorly investigated Wadi Gebeiy Dokhan volcanics rocks are discussed. Wadi Gebeiy Dokhan volcanics are located in Southwestern Sinai, Egypt, covering an area of ~1.3 km2. Dokhan volcanics rocks are represented by porphyritic dacite. Geochemically, they have medium-k characters and originate from calc-alkaline magma within a volcanics arc environment. Along the fault plane striking NNE-SSW, and at its intersection with the NW-SE fault plane, altered Dokhan volcanics occur with high radioactive anomalies. Radiological parameters (absorbed dose rate, radium equivalent, activity annual effective dose, external and internal hazard indices) are used to evaluate their suitability as an ornamental stone. Except for the absorbed dose rate, all the radiological hazard indices show that unaltered Dokhan volcanics can be used as an ornamental stone. Controversially, the applied radiological indices reveal that altered Dokhan volcanics have a higher content than the recommended values of UNSCEAR, reflecting their risk on human organs.

Potential REE-Li resources in lateritic granite in Indonesian granitoid formations: A review

The long-term growth trajectory of numerous industries remains dependent on rare- earth elements and lithium (REE-Li) resources, even if China began restricting the supply of REE. As critical raw minerals, REE-Li resources have become a sensitive issue, with the preservation of reserves framed are concerns over protecting the country's sovereignty. REE-Li bearing minerals are surmised to have originated from granite parent rocks. The granite belt in Indonesia is extensive on the Bangka Belitung Islands, West Kalimantan, and West Sulawesi, areas associated with high levels of radioactivity. This study discusses a conceptual analysis on the presence of REE-Li in granitic rock and lateritic granite based on previous studies both in general and in the given area. The region is mineralized with REE-Li bearing minerals in granite, which are absorbed onto clay minerals from weathered granite.

Factors controlling groundwater radioactivity in arid environments: An automated machine learning approach

Groundwater resources in the Kingdom of Saudi Arabia (KSA) have high levels of natural radioactivity. Within the northwestern KSA, gross alpha (α) and gross beta (β) levels exceed national and international drinking-water limits. In this study, we developed and used an automated machine learning (AML) approach to quantify relationships between gross α and gross β activities and different geological, hydrogeological, and geochemical conditions. Two AML model groups (group I for gross α; group II for gross β) were constructed, using water samples collected from 360 irrigation and water supply wells, to define a robust model that explains the spatial variability in gross α and gross β activities, as well as variables that control the gross activities. Each group contained four model families: deep neural network (DNN), gradient boosting machine (GBM), generalized linear model (GLM), and distributed random forest (DRF). Model inputs include chemical compositions as well as geological and hydrogeological conditions. Three performance metrics were used to evaluate the models during training and testing: normalized root mean square error (NRMSE), Pearson's correlation coefficient (r), and Nash-Sutcliff efficiency (NSE) coefficient. Results indicate that (1) the GBM model outperformed (training: NRMSE: 0.37 ± 0.10; r: 0.92 ± 0.05; NSE: 0.85 ± 0.09; testing: NRMSE: 0.71 ± 0.08; r: 0.72 ± 0.08; NSE: 0.49 ± 0.12) the DNN, DRF, and GLM models when modelling gross α activities; (2) gross α activities are controlled by pH, stream density, nitrate, manganese, and vegetation index; (3) the DRF model outperformed (training: NRMSE: 0.41 ± 0.05; r: 0.92 ± 0.02; NSE: 0.83 ± 0.04; testing: NRMSE: 0.67 ± 0.09; r: 0.77 ± 0.07; NSE: 0.54 ± 0.12) the GBM, DNN, and GLM models when modelling gross β activities; (4) input variables that affect the gross β actives are pH, temperature, stream density, lithology, and nitrate; and (5) no single model could be used to model both gross α and gross β activities—instead, a combination of AML models should be used. Our computationally efficient approach provides a framework and insights for using AML techniques in water quality investigations and promotes more and improved use of different geological, hydrogeological, and geochemical datasets by the scientific community and decision makers to develop guidelines for mitigation.