High Hardness Research Articles

Obtaining of WC–Co- and WC–TiC–Co-Based Ultradispersive Alloys Modified with B<sub>4</sub>C–TiB<sub>2</sub> Quasieutetic

Tungsten carbide WC-based materials characterized by high hardness and wear resistance have long been widely used in manufacturing cutting and mining tools. They are alloyed or modified with different ceramic phases to improve operational characteristics further. There are obtained the hard tungsten carbide–cobalt WC–Co and tungsten carbide–titanium carbide–cobalt WC–TiC–Co metal-ceramic alloys ultradispersed powders modified with quasieutectic ceramic alloy B<sub>4</sub>C–30wt.%TiB<sub>2</sub> and complex samples compacted from them. The quasieutectic alloy used as a modifier has almost as high hardness as pure boron carbide. Still, it is characterized by higher electrical and thermal conductivities of several orders of magnitude. Two groups of hard alloys modified with B<sub>4</sub>C–30wt.%TiB<sub>2</sub> were studied: ВK8 grade WC–Co and T30K4 and T15K6 grades WC–TiC–Co. Metal-ceramic composite powders of different concentrations are obtained by chemical synthesis and mechanical dispersion in an attritor. The particle size of chemically synthesized composite powders is ≤0.3 μm, and those obtained by mechanical dispersion are ≤0.8 μm. SPS (Spark-Plasma Sintering) and HTS (High-Temperature Sintering) methods compact these powder materials. Phase composition of the obtained materials, distribution of chemical elements in them, and structural features are investigated by the XRD (X-Ray Diffraction) method and EDX (Energy Dispersive (micro)X-ray) spectrometry and optical and electron microscopies, respectively. Key physical-mechanical characteristics of the received samples, such as hardness, microhardness, and bending strength, are studied. Ultradispersed (≤0.8 μm) metal-ceramic alloys of the WC–Co–B<sub>4</sub>C–TiB<sub>2</sub> system with interesting characteristics have been obtained using the WC–Co hard alloy of BK8 grade as the matrix. A SPS-compacted sample's hardness, microhardness, and bending strength are 93.0 HRA, 3350 kgf/mm<sup>2</sup>, and 100 kgf/mm<sup>2</sup>, respectively. Among the WC–TiC–Co system materials, the Т15K6 grade-based hard alloy modified with 15wt.%(B<sub>4</sub>C–30wt.%TiB<sub>2</sub>) has the best characteristics with hardness, microhardness, and bending strength of 91.5 HRA, 2900, and 117 kgf/mm<sup>2</sup>, respectively. A preliminary study of the problem of environmentally safe utilization of tungsten-containing scrap and tungsten waste is also carried out as part of the work. In particular, the tungsten heater waste is treated in hydrogen peroxide, and by adding specific liquid components to the tungsten-containing proper solution in a single utilization–synthesis cycle, the target product – ultradispersed WC–Co hard alloy is obtained.

Effect of Laser Power on Microstructure and Properties of WC-12Co Composite Coatings Deposited by Laser-Based Directed Energy Deposition.

During the laser-based directed energy deposition (DED-LB) processing, a WC-12Co composite coating with high hardness and strong wear resistance was successfully prepared on a 316L stainless steel substrate by adopting a high-precision coaxial powder feeding system using a spherical WC-12Co composite powder, which showed a large number of dendritic carbides and herringbone planar crystals on the substrate-binding interface. The influences of laser power on microstructural and mechanical properties (e.g., hardness, friction resistance) of WC-12Co composite surfaces were investigated. The results show that laser power has a significant effect on determining the degree of Co phase melting around the WC particles and the adhesion strength between the matrix and the coating. Lower laser power does not meet the melting requirements of WC particles, thus weakening the molding quality of the composite coating. At high laser power, it is possible to dissolve the WC particles and melt the metal powder between the particles, thus improving the material properties. The laser power increased from 700 W to 1000 W and the average hardness of the coating surface gradually increased from 1166.33 HV to 1395.70 HV, which is about 4-5 times higher than the average hardness of the substrate (about 281.76 HV). In addition, the coatings deposited at 1000 W showed better wear resistance. This work shows that the processing parameters during laser-directed energy deposition can be optimized to prepare WC-12Co composite coatings with excellent mechanical properties.

Study on emulsion-filled gels with oxidation stability: Structure, rheology, and baking applications

Specialty oils and fats play a crucial role in enhancing the texture and flavor of foods. The findings revealed that the emulsion-filled gels containing sinapine exhibited a more uniform and consistent distribution of oil droplets and proteins, with an average particle size that was better aligned across the samples. These emulsion-filled gels also exhibited higher stability, up to 95 % oil binding capacity, 3 N higher hardness and 0.2 mJ higher adhesion compared to proanthocyanidins (PC) and catechins (EC). Additionally, they demonstrated better spread-ability. In terms of the rheological properties of the oleogel prepared with sinapine, the apparent viscosity was high and the thixotropy was good. However, the softness was poor. The groups involved in the binding of various species of polyphenols are essentially identical, and the primary non-covalent driving force in this system is hydrogen bonding along with double bonding. With a thiobarbituric acid reactant (TBARS) value of 4.5 µg/mL, sinapine is more effective at maintaining the stability of emulsion-filled gels. It also enhances the oleogel’s oil-holding capacity and antioxidant capacity. In addition, the cookies with increased levels of SPI and sinapine exhibited greater hardness and were more well-received by the public. This information will help expand the application of polyphenol-modified protein-based emulsion-filled gels in food systems.

Effects of prefabricated arch-support insole hardness on foot pressure and muscle activity in mountaineer porters during load-bearing tasks in mountainous terrain

BackgroundThe study aimed to compare the effects of medium hardness and high hardness arch-support insoles, with the latter modified by a soft forefoot pad, on foot pressure distribution and muscle activation during high-load carrying tasks in authentic mountainous trail environments. MethodsSixteen male mountaineer porters with experience in high-load carrying tasks participated in the experiments. They wore commercially available prefabricated arch-support insoles, specifically referred to as medium hardness arch-support material (MH) and high hardness arch-support material attached a 1-mm soft sponge pad to the forefoot area (HHSF) during uphill and downhill walking tasks with a 25-kg load. Foot pressure and muscle activation were measured using wireless pressure distribution insoles and a wireless surface electromyography system, respectively. ResultsThe HHSF showed significantly higher perceived comfort scores and reduced foot pressure in specific regions during downhill walking (p < 0.05). It exhibited increased peak foot pressure in the forefoot during uphill walking (p < 0.05). The MH showed greater foot pressure in the second metatarsal during downhill walking and a larger contact area in the midfoot during uphill walking (p < 0.05). Muscle activation did not differ significantly between the two insoles (p > 0.05). ConclusionThe study indicates that combining a high hardness arch-support insole with a soft forefoot pad may enhance comfort and potentially reduce foot injury risks, and improves foot propulsion and pressure distribution.

Investigation on rock-breaking characteristics of hard sandstone by non-planar PDC cutters under high confining pressure

Due to high hardness, strong heterogeneity, and low drillability in deep formations, conventional Polycrystalline Diamond Compact (PDC) bits with planar cutters usually get bit worn, short drilling footage, and low rate of penetration (ROP) when drilling into such formations. To improve the aggression and the impact resistance of PDC bit, a series of non-planar PDC cutters have been proposed and developed by scholars and oil & gas industries. However, the in-situ stress and hydrostatic pressure significantly weaken the rock-breaking performance of PDC cutters, which is a paucity in related studies. Consequently, this paper conducts rock-cutting experiments in hard sandstones by planar cutters and three types of ridged cutters under confining pressure and atmospheric conditions. The influences of cutting parameters on the rock-breaking performances of different cutters are investigated, focused on the changes in cutting force, mechanical specific energy, and rock cuttings distribution. Additionally, visual cutting experiments are conducted to compare the differences in the rock-breaking mechanisms of different cutters. The results indicate that in-situ stress and hydrostatic pressure exert a noticeable inhibitory effect on rock fragmentation, resulting in smaller cuttings and lower rock-breaking efficiency than those under atmospheric conditions. Furthermore, compared to the three types of ridge cutters, planar cutters exhibit a lower rock-breaking efficiency. Ridged cutters, which leverage the efficient stress concentration caused by their ridges, demonstrate a higher rock-breaking performance by effective and efficient rock failure near the ridges. Additionally, under different cutting parameter conditions, each cutter have a corresponding optimal rock-breaking efficiency range. Specifically, for the triple-ridged concave cutters, the highest rock-breaking efficiency is achieved when the cutting angle is approaching 20°. As the cutting angle increases, the axe-shaped cutter exhibits the highest rock-breaking efficiency. In addition, the triple-ridged concave cutter and the axe-shaped cutter possess unique rock-breaking advantages, with the former being more stable and the latter producing larger volumes of cuttings. The selection of appropriate cutter parameters can enhance the service life and the drilling speed of PDC bits. The experimental results and optimization charts have significant implications for selection on cutter shapes and the design of hybrid-cutter parameters in deep hard formation drilling.

Wear performance of CoCrFeMnNi and CoCrFeMnNi-SiC coatings on 0Cr18Ni9Ti stainless steel fabricated by plasma transfer arc cladding

To enhance the wear resistance of stainless steel, CoCrFeMnNi and CoCrFeMnNi-SiC coatings were deposited on 0Cr18Ni9Ti via plasma transfer arc cladding. Effects of SiC particles on microstructure, microhardness and tribological properties of the CoCrFeMnNi coating were investigated. Results demonstrate that, in addition to the FCC solid solution and a small amount of oxide, the CoCrFeMnNi-SiC coating contains M23C6 and M7C3 phases, which exhibit an average hardness approximately 2.3 times that of the CoCrFeMnNi coating. Meanwhile, the wear resistance of the composite coating under different loads was improved, which was attributed to the fact that the high hardness SiC reduced the shear and adhesion between the coating and the mill ball, and the composite coating received abrasive and oxidative wear.

Growth mechanism and performance of MAO-AO composite coating obtained by two-stage process

Titanium alloys, with the high specific strength and low elastic modulus, are currently the research focus of many applications. Various surface treatments have been applied with the intention of improving their wear and corrosion resistance. Micro-arc oxidation (MAO) technology originated from anodic oxidation (AO) technology, which has the advantages of simple process, high efficiency and environmentally friendly electrolyte. However, due to the micro-arc discharge effect, MAO coatings inevitably show the characteristic of high porosity. In this study, post-treatment of MAO coatings using AO was proposed to obtain a composite coating with both high hardness and low roughness and porosity thereby compensating for the defects of MAO coatings. After preparation, each sample was analyzed and characterized. The results indicated that AO was main conducted in the discharge channel of MAO coating and an amorphous phase coating with the matrix oxide as main component was grown in situ. The composite coating showed a slight increase in thickness and significant reduction in roughness than MAO coating and with superior wear and corrosion resistance. In conclusion, this study provides new idea and data support for improving the performance of MAO coatings, which is expected to be widely used in the field of surface treatment.

Investigation of the Surface Characteristics of GCr15 in Electrochemical Machining.

Bearing steel (GCr15) is widely used in key parts of mechanical transmission for its excellent mechanical properties. Electrochemical machining (ECM) is a potential method for machining GCr15, as the machining process is the electrochemical dissolution of GCr15 regardless of its high hardness (>50 HRC). In ECM, NaNO3 solution is a popular electrolyte, as it has the ability to help in the nonlinear dissolution of many metallic alloy materials, making it useful for precision machining. However, due to high carbon content of GCr15, the electrochemical dissolution of GCr15 is unique, and there is always a black layer with high roughness on the machined surface, reducing the surface quality. In order to improve the electrochemical machining of GCr15 with a high surface quality, the surface characteristics of GCr15 in ECM were investigated. The anodic polarisation curve in the NaNO3 electrolyte was measured and electrochemical dissolution experiments were conducted with different current densities. SEM, XRD, and XPS were employed to analyse the surface morphology and composition formed on the machined surface at different current densities. The initial results showed that there were two parts (black part and bright part) formed on the machined surface when a short circuit occurred, and the test results suggested that the black part contained a mass of Fe3O4 while the bright part was composed of mainly Fe and Fe3C. Further investigation uncovered that a black flocculent layer (Fe3O4) always formed in a low current density (32 A/cm2) with high roughness. With the current density increased, the amount of black flocculent layer was reduced, and Fe3C particles appeared on the machined surface. When the current density reached 81 A/cm2, the entire flocculent oxide layer was removed, only some spherical Fe3C particles were inserted on the machined surface, and the roughness was reduced from Ra7.743 μm to Ra1.783 μm. In addition, due to exposed Fe3C particles on the machined surface, the corrosion resistance of the machined surface was significantly improved. Finally, circular arc grooves of high quality were well manufactured with current density of 81 A/cm2 in NaNO3 electrolyte.

Evaluation of zirconia ceramics fabricated through DLP 3d printing process for dental applications

Zirconia ceramics are versatile materials with remarkable properties such as a high thermal resistance, high fracture strength, and low thermal conductivity. They are chemically inert and highly wear- and corrosion-resistant, making them ideal for a wide range of applications in the aerospace, automotive, and biomedical fields. In dentistry, zirconia ceramics are used for veneers, crowns, bridges, and implants because of their biocompatibility. Despite the various benefits of zirconia ceramics, they are difficult to process because of their high hardness and brittleness. Additive manufacturing (AM) has proven to be a viable alternative to conventional fabrication processes, particularly for the processing of difficult-to-cut materials. AM of ceramics has gained significant attention in recent years because of its flexibility and ability to produce customized geometries rapidly and economically. In this study, the digital light processing (DLP) technique was employed to 3D print yttria-stabilized zirconia. The fabricated zirconia was evaluated and characterized for use in dental applications. Thermogravimetric analysis (TGA) and differential thermogravimetry (DTG) were performed on the green body to assess the decomposition of the additives in the slurry and determine the debinding temperatures. The as-built parts were subjected to debinding and sintering to obtain fully dense zirconia parts. The parts tended to shrink after sintering; therefore, the shrinkage ratios were evaluated and found to be 1.2817, 1.2900, and 1.3388 in the x-, y-, and z-directions, respectively. The average density after sintering was 6.031 g/cc. The flexural strength determined using four-point bending tests was 451.876 MPa, and the tensile and compressive strengths were 143 MPa and 298.4 MPa, respectively.

Tuning the adhesion of diamond/copper interfaces through surface chemical modifications and reconstruction

Diamond and diamond-like carbon (DLC) coatings are well-known for their exceptional combination of tribological and mechanical properties, such as low friction coefficients and wear rates, together with high hardness and elastic modulus. A significant limitation in their employment concerns their spallation from the substrate; it is thus interesting to explore how DLCs adhesion can be tuned through chemical modifications of its surfaces. We employ ab initio simulations to study the effect of surface reconstruction and chemical species intercalation (B, P, O, F, N, S, H) on the adhesion of non-reconstructed and Pandey-reconstructed C(111)/Cu(111) interfaces. We found that the increment of graphitization at the diamond surface decreases the adhesion. Moreover, when a high degree of surface graphitization is present the best way to increase adhesion is to select atoms able to act as chemical bridges (e.g., B and N), compensating for the lack of interaction between the surfaces. Conversely, adhesion reduction of ∼100% can be achieved, regardless of the degree of surface graphitization, by intercalating an atomic species that does not bond with the countersurface and prevents the interaction between the slabs, i.e. F and S.

Ultra-high hard and fracture-resistant multi-phase nanocrystalline AlCrFeMoNbNi multi-principal element alloy

Multi-phase nanocrystalline AlCrFeMoNbNi multi-principal element alloy was developed using mechanical alloying followed by spark plasma sintering. Mechanical alloying resulted in a two-phase microstructure (BCC and FCC), whereas subsequent sintering resulted in a multi-phase microstructure consisting of FCC, Rhombohedral and B2 phases. Extremely high hardness values in the range of 35.79–16.05 GPa were measured as a function of indentation load between 25 and 5000 g. A highly pronounced indentation size effect was observed. From classic Nix-Gao analysis, a load independent hardness of 13.82 GPa was estimated. The high hardness arises from a combination of finer grain size and solid solution strengthening (FCC phase) and multi-phase structure consisting of B2 and Rhombohedral phases. The major phase being FCC (83%) offers nearly 85% of the total flow stress realized for this MPEA and the remaining 15% of the flow stress must be arising from both the B2 and Rhombohedral phases. It is to be noted that the phase fractions of B2 and Rhombohedral phases are 10% and 7% respectively. Indentation fracture toughness, evaluated using the cracks developed during Vickers indentation, yielded encouraging numbers in the range 12.28–13.85 MPam. The excellent combination of ultra-high hardness and indentation fracture toughness of this AlCrFeMoNbNi MPEA surpasses the reported data on several related harder materials, including silicides, nitrides, carbides, etc.

Insights into the microstructural evolution and strengthening mechanisms of friction stir spot welded advanced high strength ultrafine bainitic steel

Unlocking the full potential of advanced high-strength bainitic steels in spot-welding is a pivotal endeavor for harnessing their extraordinary mechanical properties in the automotive industry. This study suggests a shift in paradigm to address the inferior fusion weldability of this type of steel because of the formation of coarse martensite within the welded zone of weldments obtained by liquid-state welding, through the strategy of refining the martensite within the weld zone using the solid-state friction stir spot welding (FSSW) process. This paper delves into an in-depth investigation of the microstructural evolution and load-bearing capacity of a Fe-0.25C-3Cr-1.63Mn-1.5Si (wt%) ultrafine bainitic steel, having a remarkable tensile strength of 1.7 GPa, during the intriguing process of FSSW at rotational speeds of 600 to 2000 rpm. The research uncovers that the stir zone (SZ) undergoes dynamic recrystallization, resulting in a significantly refined microstructure. Regardless of the rotational speed employed, the high hardenability of the steel and rapid cooling during the process inevitably results in martensite formation within this region. However, a comprehensive microstructural characterization conducted by the electron backscatter diffraction (EBSD) analysis proves that the different thermal cycles induced by different rotational speeds lead into various prior austenite grain sizes, martensitic/bainitic packets and blocks attributes, and density of high-angle grain boundaries (HAGBs). Through the evaluation of strengthening mechanisms in different weld zones, the study sheds light on the key factors influencing strength. Block boundaries emerge as the primary contributor to SZ hardening, surpassing the role of geometrically necessary dislocations (GNDs) and solid solution strengthening. The load-bearing capacity observed during the tensile-shear test is governed by a delicate interplay between bonding width and crystallographic features (block size and HAGBs density) of the martensite formed within the SZ. The highest peak load was achieved under optimal welding conditions (rotational speed of 1000 rpm), which enabled the production of a sufficiently large bonding width, providing ample bonding area for load-bearing, along with an abundance of blocks and HAGBs to effectively impeding crack propagation.

Structural-phase state and properties of heat and wear resistant cast irons of Cr–Mn–Ni–Ti system additionally alloyed with Al and Nb

The paper presents the data on phase composition and structure forming for the alloys, on distribution of elements among the alloy structural components, on variation of wear resistance, scale resistance, growing stability and mechanical properties of cast iron of Cr–Mn–Ni–Ti–Al–Nb system depending on different aluminium and niobium content and thermal ac-cumulating capacity of a casting mould. Complex carbides (Nb, Ti)C are forming in white cast iron during niobium alloying. Quantitative metallographic analysis of (Nb, Ti)C carbides and (Cr, Fe, Mn)7C3 complex carbides was carried out on the samples with examined composition. Aluminium provides favourable influence on forming of the thin protective spinel-type films with minimal amount of defects; diffusion through such oxide film is very difficult. Joint alloying by aluminium and niobium leads to simultaneous increase of heat resistance and wear resistance. Wear resistance increased as a result of enlargement of the part of primary carbides (Nb, Ti)C with high hardness in the structure of cast iron. Composition of oxide films includes aluminium, which strengthens their protective properties and rises of the alloy scale resistance. It is found for the first time that niobium doping leads to secondary solidification during cooling in the casting mold. Dispersion particles of М7С3 carbides are forming in solid state, thereby no structure degradation occurs during testing at increased temperatures, and growing stability rises. On the basis of the complex of the conducted researches the rational composition of heat and wear resistant cast iron is offered at the following ratio of components, wt. %: 2.1–2.2 C; 4.5–5.0 Mn; 18.0–19.0 Cr; 1.0–1.2 Ni; 0.4–0.6 Ti, 2.0 Nb; 2.0 Al. Wear resistance increased 1.2 times compared to cast irons before the introduction of aluminum and niobium, and scale resistance – 2.4–4.5 times depending on the type of casting mold, the index of growth resistance is equal to zero for cast irons cast in dry SLM

Influence of SiO2 Nanoparticles Extracted from Biomass on the Properties of Electrodeposited Ni Matrix Composite Films on Si(100) Substrate.

Lab-made biosilica (SiO2) nanoparticles were obtained from waste biomass (rice husks) and used as eco-friendly fillers in the production of nickel matrix composite films via the co-electrodeposition technique. The produced biosilica nanoparticles were characterized using XRD, FTIR, and FE-SEM/EDS. Amorphous nano-sized biosilica particles with a high SiO2 content were obtained. Various current regimes of electrodeposition, such as direct current (DC), pulsating current (PC), and reversing current (RC) regimes, were applied for the fabrication of Ni and Ni/SiO2 films from a sulfamate electrolyte. Ni films electrodeposited with or without 1.0 wt.% biosilica nanoparticles in the electrolyte were characterized using FE-SEM/EDS (morphology/elemental analyses, roundness), AFM (roughness), Vickers microindentation (microhardness), and sheet resistance. Due to the incorporation of SiO2 nanoparticles, the Ni/SiO2 films were coarser than those obtained from the pure sulfamate electrolyte. The addition of SiO2 to the sulfamate electrolyte also caused an increase in the roughness and electrical conductivity of the Ni films. The surface roughness values of the Ni/SiO2 films were approximately 44.0%, 48.8%, and 68.3% larger than those obtained for the pure Ni films produced using the DC, PC, and RC regimes, respectively. The microhardness of the Ni and Ni/SiO2 films was assessed using the Chen-Gao (C-G) composite hardness model, and it was shown that the obtained Ni/SiO2 films had a higher hardness than the pure Ni films. Depending on the applied electrodeposition regime, the hardness of the Ni films increased from 29.1% for the Ni/SiO2 films obtained using the PC regime to 95.5% for those obtained using the RC regime, reaching the maximal value of 6.880 GPa for the Ni/SiO2 films produced using the RC regime.

Influence of nozzle temperatures on the microstructures and physical properties of 316L stainless steel parts additively manufactured by material extrusion

Purpose Material extrusion (ME) is a low-cost additive manufacturing (AM) technique that is capable of producing metallic components using desktop 3D printers through a three-step printing, debinding and sintering process to obtain fully dense metallic parts. However, research on ME AM, specifically fused filament fabrication (FFF) of 316L SS, has mainly focused on improving densification and mechanical properties during the post-printing stage; sintering parameters. Therefore, this study aims to investigate the effect of varying processing parameters during the initial printing stage, specifically nozzle temperatures, Tn (190°C–300°C) on the relative density, porosity, microstructures and microhardness of FFF 3D printed 316L SS. Design/methodology/approach Cube samples (25 x 25 x 25 mm) are printed via a low-cost Artillery Sidewinder X1 3D printer using a 316L SS filament comprising of metal-polymer binder mix by varying nozzle temperatures from 190 to 300°C. All samples are subjected to thermal debinding and sintering processes. The relative density of the sintered parts is determined based on the Archimedes Principle. Microscopy and analytical methods are conducted to evaluate the microstructures and phase compositions. Vickers microhardness (HV) measurements are used to assess the mechanical property. Finally, the correlation between relative density, microstructures and hardness is also reported. Findings The results from this study suggest a suitable temperature range of 195°C–205°C for the successful printing of 316L SS green parts with high dimensional accuracy. On the other hand, Tn = 200°C yields the highest relative density (97.6%) and highest hardness (292HV) in the sintered part, owing to the lowest porosity content (&lt;3%) and the combination of the finest average grain size (∼47 µm) and the presence of Cr23C6 precipitates. However, increasing Tn = 205°C results in increased porosity percentage and grain coarsening, thereby reducing the HV values. Overall, these outcomes suggest that the microstructures and properties of sintered 316L SS parts fabricated by FFF AM could be significantly influenced even by adjusting the processing parameters during the initial printing stage only. Originality/value This paper addresses the gap by investigating the impact of initial FFF 3D printing parameters, particularly nozzle temperature, on the microstructures and physical characteristics of sintered FFF 316L SS parts. This study provides an understanding of the correlation between nozzle temperature and various factors such as dimensional integrity, densification level, microstructure and hardness of the fabricated parts.

Effects of Autogenous Gas Tungsten Arc Welding (GTAW) on Corrosion Resistance of Stainless Steel 316L

The autogenous manual gas tungsten arc welding (GTAW) process was used for cladding austenitic stainless steel 316L using a single pass with various contact tip-to-work distances (CTWDs). Immersion and electrochemical tests were used to evaluate the corrosion resistance of the welded specimens, and a microstructural analysis was conducted to investigate the chemical composition of the molten pool and the heat-affected zone of welding. The key findings of this study indicate that the corrosion resistance improved under a CTWD of 5 mm due to the optimal distribution of ferrite and a refined microstructure. Additionally, the highest hardness was observed in specimens with a CTWD of 3 mm, attributed to the increased ferrite content in the weld metal. As the CTWD increased, the ferrite fraction decreased, and the hardness also diminished. However, in the CTWD 7 mm case, the higher heat input influenced the microstructure and molten pool shape significantly through the Marangoni effect, resulting in a lower corrosion resistance. These results suggest that optimizing the CTWD can enhance the corrosion resistance of welded 316L stainless steel.

Enabling Invar to Ti6Al4V transitions through copper in functionally graded laser powder bed fused components

This study examines the microstructural evolution, elemental distribution, phase composition, and hardness variations in multi-material samples fabricated using Laser Powder Bed Fusion (LPBF) with Invar and Ti6Al4V with compositional gradients mediated by copper. A range of compositional transitions from Invar to Ti6Al4V with different copper fractions are reported. Defects such as gas and keyhole pores were detected in well-deep keyhole mode areas, while lack of fusion defects were observed in samples with pure Cu interlayers due to poor wettability and processing parameter variations. Crack formation between interlayer gradient zones and Invar regions was linked to FeNi and CuNi intermetallic phases. Intermetallic compounds (e.g., FeNi, CuNi, TiFe, TiNi) significantly influenced the microstructure and mechanical performance. Vickers hardness testing shows varying hardness across different builds, with the highest hardness being observed in the gradient zone enabled by pure copper (approximately 620 HV). This study also underscores the need for tailored component design linking build processing parameters and compositional transitions in multi-material LPBF to achieve desired properties and component structural behaviour.

Effect of temperature-deformation regimes of equal channel angular pressing in core-shell mode on the structure and properties of near-equiatomic titanium nickelide shape memory alloy

Near-equiatomic titanium nickelide (TiNi) shape memory alloy is subjected to thermomechanical treatment by quasi-continuous equal channel angular pressing (ECAP) in core-shell mode at temperatures of 250, 300, and 400°С at the highest possible accumulated true strain. TiNi bulk samples are successfully deformed for the first time at 300°С – the temperature threshold for dynamic polygonization – at an accumulated true strain e of 2.4. Deformation at low temperatures leads to the premature destruction of TiNi samples in the second pass (e = 1.6), providing high deformation hardening and corresponding strength characteristics. An increase in the deformation temperature to 400°С allows an accumulated true strain of 5.6, while the mechanical and functional properties are inferior to those that occur after deformation at low temperatures. The most balanced combination of properties is achieved after quasi-continuous ECAP in core-shell mode at 300°С and subsequent post-deformation annealing at 400°С for 1 h: dislocation yield stress σy = 1040 MPa, ultimate tensile strength σв = 1166 MPa, and total recoverable strain Ɛrt = 10.3 %.

Construction of hard BCC phases FeCrVMnTix wear-resistant high-entropy alloy coatings enhanced by solid solution of Ti elements

To address the complex working conditions encountered by 1Cr13 ferritic/martensitic steel during operation, it is imperative to develop high-entropy alloys (HEAs) protective coatings with enhanced friction resistance. In this work, guided by the valence electron concentration criterion, we constructed a single-phase body-centered cubic (BCC) structure with high hardness. This was achieved through the introduction of titanium (Ti), which has a significantly different atomic radius compared to other elements. FeCrVMnTix (x = 0, 0.5, 1.0, 1.5, and 2.0) coatings were fabricated on 1Cr13 steel surfaces using laser cladding techniques, and the microstructure, mechanical properties, and wear-resistance properties of Ti-doped HEA coatings were investigated. The results reveal that the FeCrVMnTix coatings are comprised of a BCC solid solution. Increasing Ti content refined the dendritic structure of the coatings, enhancing the Vickers hardness from 4.35 GPa to 8.27 GPa and the Young's modulus from 232.6 GPa to 273.2 GPa. Additionally, the wear rate decreased from 3.07 × 10−5 mm3·N−1·m−1 to 4.94 × 10−6 mm3·N−1·m−1. Notably, the FeCrVMnTi2.0 coating demonstrated excellent wear resistance that can be attributed to the solid solution strengthening effect of Ti. These findings underscore the pivotal role of Ti in enhancing the wear resistance of the coatings.

The Effect of 3D Printing Layer Thickness and Post-Polymerization Time on the Flexural Strength and Hardness of Denture Base Resins

Purpose: This study evaluates and compares the effect of printing layer thickness (LT) and post-polymerization time (PPT) on the flexural strength and hardness of three 3D-printed resins after thermal aging. Methods: A bar shape (64 × 10 × 3.3 mm) and a disc shape (15 × 2 mm) were designed for flexural strength and hardness testing, respectively. ASIGA, NextDent, and FormLabs 3D-printed resins were used to print specimens with different LTs (25 µm, 50 µm, and 100 µm). Each thickness group was post-polymerized (PP) for different times (15, 30, 60, and 90 min). All printed specimens were thermally cycled (5000 cycles) and then tested, measuring the flexural strength and hardness using a universal testing machine and Vickers hardness tester, respectively. The data were analyzed using ANOVA and a post hoc Tukey’s test (α = 0.05). Results: A PPT of 90 min showed the highest flexural strength. In comparisons of the LTs, 25 µm and 50 µm significantly increased flexural strength compared with 100 µm, which showed the lowest value for each PPT. The hardness increased as the PPT increased for all materials. In our LT comparison, 25 µm and 50 µm significantly increased the hardness for NextDent and FormLabs resins, while only 25 µm showed high hardness compared with 50 µm and 100 µm for ASIGA. Conclusion: Both parameters (LT and PPT) impact flexural strength and hardness. Increased PPT with the minimum LT is recommended.