Higher Fracture Energy Research Articles

Fracture process zone and fracture energy of heterogeneous soft materials

Bio-inspired heterogeneous soft materials are under rapid development due to their superior fracture and fatigue resistance. In the last few years, several kinds of fibrous soft composites in different length scales have been fabricated. However, the fracture behavior and toughening mechanism of this class of materials are still elusive. Here we develop a theoretical model for the crack tip field of fiber reinforced soft composites. The distribution of deformation around the crack tip and released elastic energy during crack propagation are obtained. The fracture process zone and fracture energy are quantified. There is a critical sample height, below which the fracture process zone size and fracture energy are size-dependent, above which they approach material-specific constants: steady-state fracture process zone size and steady-state fracture energy. A formula is derived to relate the steady-state fracture process zone size and parameters of the composite. It is found that both the steady-state fracture process zone size and the critical sample height scale with the fractocohesive length of the composite. The steady-state fracture energy of the composite can be enhanced either by enlarging the fracture process zone size through tuning fiber geometry or by increasing the work to rupture of the fiber through chemical treatment. This work reveals the toughening mechanism of heterogeneous soft materials and paves the way to design soft materials of high fracture energy, high fatigue threshold, and low hysteresis. It also provides a practical guideline for determining the sample size to measure the steady-state fracture energy of heterogeneous soft materials.

Flexural post-cracking performance of macro synthetic fiber reinforced super workable concrete influenced by shrinkage-reducing admixture

Most literature has focused on the effect of shrinkage-reducing admixture (SRA) in shrinkage mitigation resistance of concrete. This study aims to examine the impact of SRA on the efficiency of macro synthetic fibers (MSF) in enhancing the flexural post-cracking behavior of fiber-reinforced super workable concrete (FR-SWC). A comparative analysis of the influence of fiber combinations on the flexural post-cracking behavior of beams is also included. Results showed that a higher dosage of SRA, particularly at 5 % by mass of binder, had a noticeable negative impact on flexural post-cracking performance of beams while exhibiting positive effect on workability and shrinkage reduction. However, incorporating low dosages of SRA (1.25 % by mass of binder) did not have a significant impact on the ability of MSF. This was attributed to the reduction of the MSF-matrix bond strength caused by a significant delay in cement hydration. The characteristics of selected MSF type, including length and surface roughness had a positive effect on the post-cracking performance of FR-SWC, regardless of SRA dosage. The notched beams made with 100 % MSFA outperformed those made with fiber combination of 25 % MSFA and 75 % MSFB. Beams made with 100 % MSFA showed 55 % higher residual flexural tensile strength, 49 % higher equivalent flexural tensile strength, 50 % higher fracture energy, and 35 % higher equivalent flexural strength ratio compared to beams made with fiber combination of 25 % MSFA and 75 % MSFB. Therefore, the negative effect of SRA on the flexural-post cracking behavior can be partial compensated by adjusting MSF content and combinations.

Squid-Inspired Anti-Salt Skin-Like Elastomers With Superhigh Damage Resistance for Aquatic Soft Robots.

Cephalopod skins evolve multiple functions in response to environmental adaptation, encompassing nonlinear mechanoreponse, damage tolerance property, and resistance to seawater. Despite tremendous progress in skin-mimicking materials, the integration of these desirable properties into a single material system remains an ongoing challenge. Here, drawing inspiration from the structure of reflectin proteins in cephalopod skins, a long-term anti-salt elastomer with skin-like nonlinear mechanical properties and extraordinary damage resistance properties is presented. Cation-π interaction is incorporated to induce the geometrically confined nanophases of hydrogen bond domains, resulting in elastomers with exceptional true tensile strength (456.5 ± 68.9MPa) and unprecedently high fracture energy (103.7 ± 45.7kJ m-2). Furthermore, the cation-π interaction effectively protects the hydrogen bond domains from corrosion by high-concentration saline solution. The utilization of the resultant skin-like elastomer has been demonstrated by aquatic soft robotics capable of grasping sharp objects. The combined advantages render the present elastomer highly promising for salt enviroment applications, particularly in addressing the challenges posed by sweat, in vivo, and harsh oceanic environments.

Bioinspired Bouligand-Structured Cellulose Nanocrystals/Poly(vinyl alcohol) Composite Hydrogel for Enhanced Impact Resistance.

Impact-protective materials are gaining importance because of the widespread occurrence of impact damage. Hydrogels have emerged as promising candidates owing to their lightweight and flexible nature. However, achieving soft impact-resistant hydrogels with exceptional stiffness, strength, and toughness remains a challenge. Inspired by the Bouligand structure found in the smasher dactyl club of stomatopods, we propose a straightforward multiscale hierarchical structural design strategy. This strategy integrates self-assembly and salting-out techniques to enhance the impact resistance of soft hydrogels. Rigid cellulose nanocrystals (CNCs) self-assemble into Bouligand-like structures within soft poly(vinyl alcohol) (PVA) matrix via supramolecular interactions. This rational structural design combines the CNC Bouligand structure with a cross-linked network of soft PVA crystalline domains, resulting in a composite hydrogel with impressive mechanical properties: high tensile fracture strength (30.2 MPa), elastic modulus (62.7 MPa), and fracture energy (75.6 kJ m-2), surpassing those of other tough hydrogels. Moreover, the multiscale hierarchical structure facilitates various energy dissipation mechanisms, including crack twisting, tortuous crack paths, and PVA chain orientation, resulting in notable force attenuation (80.4%) in the composite hydrogel. This biomimetic design strategy opens new avenues for developing soft and lightweight impact-resistant materials.

A robust bio-based polyurethane employed as surgical suture with help to promote skin wound healing

Designing bio-based polyurethane materials with excellent mechanical, biocompatibility, and self-healing properties simultaneously is currently a significant challenge due to the increasing demands for high-performance materials. In this study, we propose an asymmetric backbone strategy utilizing bio-based polycarbonate as the soft segment, equimolar ratios of lysine diisocyanate and isophorone diisocyanate as asymmetric hard segments, and isophorone diamine as the chain extender. The resulting polyurethane elastomers exhibit excellent mechanical properties, including high tensile stress (46.1 MPa), toughness (213.9 MJ/m3), and fracture energy (98.47 kJ/m3). The polyurethane elastomers demonstrate good self-healing and recyclable properties under simple heat treatment. Furthermore, biological experiments confirm the degradability and bio-safety of the bio-based polyurethane elastomers, which have shown potential in accelerating wound healing in mice when used as surgical sutures. These findings highlight the promising prospects of the obtained polyurethane elastomers in various applications, including biomedicine, flexible sensing, and electronic components.

Multi-Modal Sensing Ionogels with Tunable Mechanical Properties and Environmental Stability for Aquatic and Atmospheric Environments.

Ionogels have garnered significant interest due to their great potential in flexible iontronic devices. However, their limited mechanical tunability and environmental intolerance have posed significant challenges for their integration into next-generation flexible electronics in different scenarios. Herein, the synergistic effect of cation-oxygen coordination interaction and hydrogen bonding is leveraged to construct a 3D supramolecular network, resulting in ionogels with tunable modulus, stretchability, and strength, achieving an unprecedented elongation at break of 10800%. Moreover, the supramolecular network endows the ionogels with extremely high fracture energy, crack insensitivity, and high elasticity. Meanwhile, the high environmental stability and hydrophobic network of the ionogels further shield them from the unfavorable effects of temperature variations and water molecules, enabling them to operate within a broad temperature range and exhibit robust underwater adhesion. Then, the ionogel is assembled into a wearable sensor, demonstrating its great potential in flexible sensing (temperature, pressure, and strain) and underwater signal transmission. This work can inspire the applications of ionogels in multifunctional sensing and wearable fields.

Soft, Tough, Antifatigue Fracture Elastomer Composites with Low Thermal Resistance through Synergistic Crack Pinning and Interfacial Slippage.

Soft elastomer composites are promising functional materials for engineer interfaces, where the miniaturized electronic devices have triggered increasing demand for effective heat dissipation, high fracture energy, and antifatigue fracture. However, such a combination of these properties can be rarely met in the same elastomer composites simultaneously. Here a strategy is presented to fabricate a soft, extreme fracture tough (3316J m-2) and antifatigue fracture (1052.56J m⁻2) polydimethylsiloxane/aluminum elastomer composite. These outstanding properties are achieved by optimizing the dangling chains and spherical aluminum fillers, resulting in the combined effects of crack pinning and interfacial slippage. The dangling chains that lengthen the polymer chains between cross-linked points pin the cracks and the rigid fillers obstruct the cracks, enhancing the energy per unit area needed for fatigue failure. The dangling chains also promote polymer/filler interfacial slippage, enabling effective deflection and blunting of an advancing crack tip, thus enhancing mechanical energy dissipation. Moreover, the elastomer composite exhibits low thermal resistance (≈0.12K cm2 W-1), due to the formation of a thermally conductive network. These remarkable characteristics render this elastomer composite promising for application as a thermal interface material in electronic devices.

Dynamic Metal-Coordinated Adhesive and Self-Healable Antifreezing Hydrogels for Strain Sensing, Flexible Supercapacitors, and EMI Shielding Applications.

Dynamic metal-coordinated adhesive and self-healable hydrogel materials have garnered significant attention in recent years due to their potential applications in various fields. These hydrogels can form reversible metal-ligand bonds, resulting in a network structure that can be easily broken and reformed, leading to self-healing capabilities. In addition, these hydrogels possess excellent mechanical strength and flexibility, making them suitable for strain-sensing applications. In this work, we have developed a mechanically robust, highly stretchable, self-healing, and adhesive hydrogel by incorporating Ca2+-dicarboxylate dynamic metal-ligand cross-links in combination with low density chemical cross-links into a poly(acrylamide-co-maleic acid) copolymer structure. Utilizing the reversible nature of the Ca2+-dicarboxylate bond, the hydrogel exhibited a tensile strength of up to ∼250 kPa and was able to stretch to 15-16 times its original length. The hydrogel exhibited a high fracture energy of ∼1500 J m-2, similar to that of cartilage. Furthermore, the hydrogel showed good recovery, fatigue resistance, and fast self-healing properties due to the reversible Ca2+-dicarboxylate cross-links. The presence of Ca2+ resulted in a highly conductive hydrogel, which was utilized to design a flexible resistive strain sensor. This hydrogel can strongly adhere to different substrates, making it advantageous for applications in flexible electronic devices. When adhered to human body parts, the hydrogel can efficiently detect limb movements. The hydrogel also exhibited excellent performance as a solid electrolyte for flexible supercapacitors, with a capacitance of ∼260 F/g at 0.5 A/g current density. Due to its antifreezing and antidehydration properties, this hydrogel retains its flexibility at subzero temperatures for an extended period. Additionally, the porous network and high water content of the hydrogel impart remarkable electromagnetic attenuation properties, with a value of ∼38 dB in the 14.5-20.5 GHz frequency range, which is higher than any other hydrogel without conducting fillers. Overall, the hydrogel reported in this study exhibits diverse applications as a strain sensor, solid electrolyte for flexible supercapacitors, and efficient material for electromagnetic attenuation. Its multifunctional properties make it a promising candidate for use in various fields as a state-of-the-art material.

Can rubberized-asphalt comprising tire-derived aggregates produced through dry process be an alternative subsurface road material?

The major objective of this study was to investigate the suitability of utilizing tire-derived aggregates (TDA) at varying contents for the design of rubberized-asphalt base / subsurface layers through the dry process, along with (i) understanding the cracking potential and mechanical stress-strain response of the different materials under cyclic and confining stresses through triaxial resilient modulus (MR), dynamic modulus |E*|, and static semi-circular bend test, and (ii) assessing bonding strength of TDA with binder-aggregate matrix through moisture susceptibility test. The scope encompassed preparation of ten base course mixtures: one unbound granular base (UGB), three cement treated base (CTB), two asphalt treated base (ATB), and four rubberized-asphalt treated base (RATB) and obtaining mechanical performance at varying temperature-frequency combinations totaling 2636 data points. Triaxial MR tests indicated that CTB mix displayed highest modulus followed by ATB and RATB mixes, which was then followed by the UGB mix mainly ascribed to cement / asphalt treatment of the unmodified control subsurface material. Further, a finite element modeling study helped optimize the confinement levels to obtain realistic |E*| of ATB and RATB mixes. |E*| test results depicted that RATB mixtures would be rut-resistant at higher temperatures as they performed similar to the ATB mixes as well as crack-resistant at low to intermediate temperatures with significantly lower |E*| than ATB mixes, attributed to slower rate of change of viscosity with changing temperature in conjunction with enduring viscoelastic property (1.5–3 times higher phase angle than ATB) ascribed to high asphalt binder content and resilient nature of the rubber particles. Albeit the fracture toughness of ATB was twice higher than RATB, the latter had higher fracture energies, mainly due to the resiliency rendered by the rubber inclusions in concert with the extra viscous effect provided by the rubber-asphalt binder conglomerate. Based on the performance-based ranking, RATB mixes performed better than control mixes, and thus were adjudged as the most suitable alternative subsurface / base course materials in a pavement system. It is envisioned that this research will advance the current understanding of utilizing TDA in asphalt base / subbase courses using the dry process, and further assist in judging the viability of using rubberized-asphalt as potential sustainable alternatives to conventional systems to develop futuristic resilient pavement infrastructures with a strong emphasis on recycling of end-of-life tires, conservation of materials, and circular economy.

Fe-reinforced silkworm silk with superstrong mechanical properties for mass production

Silk is a versatile material known for its outstanding properties, including good mechanical performance, luster, and biocompatibility in various fields. However, the growing demand for silk in diverse applications necessitates further improvements in its performance. Traditional methods for improving silk performance face challenges such as low strength, toughness, and limited mass production. Here, we report a novel approach that combines genetic engineering and ion reinforcement to produce silk fibers with exceptional strength and stiffness. By overexpressing iron ion-related protein genes in the anterior silk gland of silkworms, this study successfully increased the iron ion content in the resulting silk. Furthermore, when applied to the large-scale production of hybrid silkworm varieties, the mechanical properties of silk were significantly enhanced, thus facilitating mass production. The resulting silk exhibited remarkable mechanical properties, including a high fracture strength (790.3 MPa), fracture energy (123.2 MJm−3), stretchability (∼21.41 % strain) and Young’s modulus (15.41 GPa). Comprehensive analysis involving dynamic simulation, synchrotron radiation infrared spectroscopy, X-ray diffraction, fluorescence spectroscopy, and circular dichroism analysis confirmed the specific interaction between iron ions and tyrosine within the silk protein. This interaction promoted the formation of increased the β-sheet and crystal contents in the silk fibers, contributing to their improved mechanical properties. Importantly, this concept can be extended to other metal ions, offering a promising method for enhancing silk structure and mechanical properties without changing the silk protein sequence.

Mechanical analysis and bionic improvement on buckling of CFRP tubes with high energy absorption capacity

Fiber-reinforced composite tubes have remarkable advantages in energy absorption due to the high specific strength, stiffness, and fracture energy, etc. While, the energy absorption capacity is severely dominated by buckling deformation. To this end, the buckling behaviors and corresponding mechanism of CFRP (carbon fiber reinforced polymer) tubes are systematically investigated in this work. Furthermore, an advanced bionic method referring to bamboo and human bones is adopted to improve the buckling. To effectively analyze the buckling, drop weight impact experiments and corresponding numerical simulations are carried out. The results show that the specific energy absorption (SEA) of CFRP tubes is significantly affected by the diameter-to-height ratio and fiber ply direction, and the influencing mechanism is excessive buckling caused by the geometric characteristics and brittle failure of CFRP. At last, the SEA of CFRP tubes were improved through bio-inspired multi-layered metal/composite hybrid, where the buckling is suppressed reasonably well. The conclusions drawn would be inspiring or guiding the optimal design of high energy-absorbing composite tubes in engineering application.

Microstructure, mechanical properties and interaction mechanism of seawater sea-sand engineered cementitious composite (SS-ECC) with Glass Fiber Reinforced Polymer (GFRP) bar

With increasing demand for sustainable and long-lasting materials, seawater sea-sand engineered cementitious composite (SS-ECC) has emerged as a promising alternative to conventional concrete in near-ocean construction projects. Glass fiber reinforced polymer (GFRP) bar with excellent corrosion resistance is an ideal choice for these applications. This study evaluated the bond performance of GFRP bars embedded in normal-strength ECC with polyvinyl alcohol (PVA) fibers and high-strength ECC with polyethylene (PE) fibers through pull-out tests. Additionally, tests were conducted on GFRP bars in pristine ECC made with freshwater and river sand for comparison. Further investigation explored the structural properties and uncovered load transfer mechanisms. Results indicated that saline content facilitated early cement hydration of normal-strength ECC, resulting in finer pore structure (10.5% lower porosity and 12.5% lower sorptivity), slightly enhanced compressive performance (1.2% higher compressive strength and 8.3% higher elastic modulus), denser microstructure at GFRP-ECC interface (13.7% lower porous transition zone thickness, 19.2% narrower transition zone and 19.7% higher Ca/Si ratio), and superior bond performance (28.3% higher bond strength and 22.6% higher fracture energy). Conversely, saline content imposed a limited impact on the mechanical properties of high-strength ECC, primarily attributed to the ultra-fine microstructure and early strength characteristics exhibited by the silica fume (SF)-based cementitious binder.

The fracture energy of concrete reinforced with double-helix macro basalt-fibre-reinforced polymer fibre

A novel type of fibre – double-helix macro basalt-fibre-reinforced polymer (DHM BFRP) fibre – is proposed to increase the cracking, tensile strength and ductility of concrete. The novel fibre is made from micro basalt fibres and resin, twisted together in a double helix. BFRP offers high tensile strength, good corrosion resistance and low cost, while the double-helix geometry provides excellent bond–slip performance between the fibre and the concrete matrix. Three-point bending (3PB) tests were conducted to measure the fracture energy of concrete reinforced with DHM BFRP fibres. The influences of fibre orientation (aligned and random) on cracking load, peak load, flexural strength and fracture energy were analysed. Compared with random DHM BFRP fibres, aligned fibres resulted in a 26.4% higher fracture energy and a 29.7% increase in flexural strength. Finite-element models of the 3PB tests were established using LS-Dyna. The Karagozian & Case concrete model was calibrated based on the fracture energy results to obtain a material model of fibre-reinforced concrete (FRC) considering fibre orientation. The errors between the simulated and tested maximum loads for 3PB tests of plain concrete, FRC and fibre-reinforced self-compacting concrete were 8.3%, 4.0% and 11.4%, respectively, indicating that the simulated and test results were in good agreement. This study provides a theoretical foundation and technical support for practical engineering applications of DHM BFRP fibres.

Crack-Resistant and Tissue-Like Artificial Muscles with Low Temperature Activation and High Power Density.

Constructing soft robotics with safe human-machine interactions requires low-modulus, high-power-density artificial muscles that are sensitive to gentle stimuli. In addition, the ability to resist crack propagation during long-term actuation cycles is essential for a long service life. Herein, a material design is proposed to combine all these desirable attributes in a single artificial muscle platform. The design involves the molecular engineering of a liquid crystalline network with crystallizable segments and an ethylene glycol flexible spacer. A high degree of crystallinity can be afforded by utilizing aza-Michael chemistry to produce a low covalent crosslinking density, resulting in crack-insensitivity with a high fracture energy of 33720 J m-2 and a high fatigue threshold of 2250 J m-2. Such crack-resistant artificial muscle with tissue-matched modulus of 0.7MPa can generate a high power density of 450W kg-1 at a low temperature of 40°C. Notably, because of the presence of crystalline domains in the actuated state, no crack propagation is observed after 500 heating-cooling actuation cycles under a static load of 220kPa. This study points to a pathway for the creation of artificial muscles merging seemingly disparate, but desirable properties, broadening their application potential in smart devices.

Carbodiimide‐Driven Toughening of Interpenetrated Polymer Networks

AbstractRecent work has demonstrated that temporary crosslinks in polymer networks generated by chemical “fuels” afford materials with large, transient changes in their mechanical properties. This can be accomplished in carboxylic‐acid‐functionalized polymer hydrogels using carbodiimides, which generate anhydride crosslinks with lifetimes on the order of minutes to hours. Here, the impact of the polymer network architecture on the mechanical properties of transiently crosslinked materials was explored. Single networks (SNs) were compared to interpenetrated networks (IPNs). Notably, semi‐IPN precursors that give IPNs on treatment with carbodiimide give much higher fracture energies (i.e., resistance to fracture) and superior resistance to compressive strain compared to other network architectures. A precursor semi‐IPN material featuring acrylic acid in only the free polymer chains yields, on treatment with carbodiimide, an IPN with a fracture energy of 2400 J/m2, a fourfold increase compared to an analogous semi‐IPN precursor that yields a SN. This resistance to fracture enables the formation of macroscopic complex cut patterns, even at high strain, underscoring the pivotal role of polymer architecture in mechanical performance.

Carbodiimide-Driven Toughening of Interpenetrated Polymer Networks.

Recent work has demonstrated that temporary crosslinks in polymer networks generated by chemical "fuels" afford materials with large, transient changes in their mechanical properties. This can be accomplished in carboxylic-acid-functionalized polymer hydrogels using carbodiimides, which generate anhydride crosslinks with lifetimes on the order of minutes to hours. Here, the impact of the polymer network architecture on the mechanical properties of transiently crosslinked materials was explored. Single networks (SNs) were compared to interpenetrated networks (IPNs). Notably, semi-IPN precursors that give IPNs on treatment with carbodiimide give much higher fracture energies (i.e., resistance to fracture) and superior resistance to compressive strain compared to other network architectures. A precursor semi-IPN material featuring acrylic acid in only the free polymer chains yields, on treatment with carbodiimide, an IPN with a fracture energy of 2400 J/m2, a fourfold increase compared to an analogous semi-IPN precursor that yields a SN. This resistance to fracture enables the formation of macroscopic complex cut patterns, even at high strain, underscoring the pivotal role of polymer architecture in mechanical performance.

Enhancing Cement Paste Properties with Biochar: Mechanical and Rheological Insights

Biochar, the solid sub-product of biomass pyrolysis, is widely considered an effective water retention material thanks to its porous microstructure and high specific surface area. This study investigates the possibility of improving both mechanical and rheological properties of cement pastes on a micro-scale. The results show that using biochar as a reinforcement at low percentages (1% to 5% by weight of cement) results in an increase in compressive strength of 13% and the flexural strength of 30%. A high fracture energy was demonstrated by the tortuous crack path of the sample at an early age of curing. A preliminary study on the rheological properties has indicated that the yield stress value is in line with that of self-compacting concrete.

Peanut shaped auxetic cementitious cellular composite (ACCC)

Auxetic cementitious cellular composites (ACCCs) exhibit desirable mechanical properties (e.g., high fracture resistance and energy dissipation), due to their unique deformation characteristics. In this study, a new type of cementitious auxetic material, referred to as peanut shaped ACCC, has been designed and subsequently architected using additive manufacturing techniques. Two peanut shaped ACCCs specimens with different pseudo-minor axes have been tested under uniaxial compression with Digital Image Correlation (DIC) to assess their compressive behavior, peak strength, Poisson’s ratio, and energy dissipation capacity. Additionally, cyclic tests were conducted to investigate their compressive resilience properties, further elucidated through microstructural analysis using a digital optical microscope. The mechanical test results were also compared with those of previously developed elliptical-shaped ACCCs. Furthermore, a numerical model was used to simulate the mechanical behavior of peanut shaped ACCCs under uniaxial compression, and showed a good agreement with the experimental data. The auxetic behavior observed in peanut shaped ACCCs arises from the rotation of sections facilitated by fiber bridging at the ligament of adjacent holes within the cementitious unit cell. In comparison to elliptical-shaped ACCCs, peanut shaped ACCCs can exhibit a slightly more negative Poisson's ratio and mitigate stress concentration. The reduction of stress concentration enables peanut shaped ACCCs to dissipate substantial energy, showcasing enhanced ductility and toughness. In cyclic tests, peanut shaped ACCCs exhibit superior recoverable deformation elasticity, attributed to robust fiber bridging capacity. The exceptional mechanical properties exhibited by peanut shaped ACCCs offer a scalable solution for developing energy-absorbent and multifunctional cementitious materials for smart infrastructure.

Mechanically resilient hybrid aerogels containing fibers of dual-scale sizes and knotty networks for tissue regeneration.

The structure and design flexibility of aerogels make them promising for soft tissue engineering, though they tend to come with brittleness and low elasticity. While increasing crosslinking density may improve mechanics, it also imparts brittleness. In soft tissue engineering, resilience against mechanical loads from mobile tissues is paramount. We report a hybrid aerogel that consists of self-reinforcing networks of micro- and nanofibers. Nanofiber segments physically entangle microfiber pillars, allowing efficient stress distribution through the intertwined fiber networks. We show that optimized hybrid aerogels have high specific tensile moduli (~1961.3 MPa cm3 g-1) and fracture energies (~7448.8 J m-2), while exhibiting super-elastic properties with rapid shape recovery (~1.8 s). We demonstrate that these aerogels induce rapid tissue ingrowth, extracellular matrix deposition, and neovascularization after subcutaneous implants in rats. Furthermore, we can apply them for engineering soft tissues via minimally invasive procedures, and hybrid aerogels can extend their versatility to become magnetically responsive or electrically conductive, enabling pressure sensing and actuation.

Mechanical properties of SiCf/SiC composites with h‐BN interphase formed by the electrophoretic deposition method

AbstractSilicon carbide fiber–reinforced silicon carbide (SiCf/SiC) composites have been expected to be used as next‐generation heat resistant structural materials with high reliability. The fiber/matrix interface for SiCf/SiC composites plays an important role for toughening and strengthening, and it is important to form the optimal interphase for SiCf/SiC composites. In this study, hexagonal‐boron nitride (h‐BN), which shows better oxidation resistance than carbon, was selected as the interphase for SiCf/SiC composites, and h‐BN coating was formed on low‐conductive SiC fibers by the electrophoretic deposition (EPD) method using flaked h‐BN suspension prepared by wet‐jet milling. Unidirectional SiCf/SiC composites with the BN interphase formed by the EPD method were prepared by polymer impregnation and pyrolysis (PIP) method, and their mechanical properties were evaluated. The uniform h‐BN interphase was successfully formed on the low‐conductive SiC fibers by EPD when thin polypyrrole (Ppy) coating, that is, conductive polymer, was formed on the SiC fibers. The h‐BN coating became denser by heat‐treatment at 1000°C, and the h‐BN coating deposited tightly on the SiC fibers was confirmed. It was demonstrated that the SiCf/SiC composites with the uniform and relatively dense h‐BN interphase formed by EPD using flaked h‐BN particles exhibited pseudo‐ductile fracture behavior with large amount of fiber pullout and higher fracture energy.