High Working Capacity Research Articles

Locking Alignment of Liquid Crystal Actuators Using Hydrogen Bonds to Enable Room‐Temperature Shape Programmability and Enhanced Work Capacity

AbstractSoft actuators that mimic the softness and deformability of living organisms have great potential for use in various fields. For most soft actuators, achieving both reprogrammable shape and high work capacity is crucial but challenging. These properties are mutually exclusive for liquid crystal elastomers (LCEs), an important type of soft actuators. Herein, a room‐temperature shape‐programmable LCE capable of high‐energy actuation is developed. Our approach utilizes hydrogen bonds to stabilize the aligned liquid crystal phases. The slow recovery of H‐bonds at room temperature provides a specific processing window, during which the sample shape can be programmed after the thermal treatment. The temperature‐dependent rearrangement of hydrogen bonds allows for fabrication of actuators with customized shapes in a facile do‐it‐yourself manner. Additionally, the integration of strong covalent cross‐links is vital for holding structural integrity. The combination of non‐covalent and covalent cross‐linking significantly improves the mechanical properties, enabling the actuators to perform reversible actuation with a work capacity (440 kJ m−3) higher than that of traditional LCEs (<100 kJ m−3). This study provides a turnkey strategy to address the conflict between shape reprogrammability and work capacity, advancing the development of soft actuators.

Adsorption capability and regenerability of carbon slit micropores for CO2 capture

To date, the exceptional performance of microporous carbon in CO2 capture has been widely acknowledged as a crucial step towards achieving global zero carbon emissions. In this molecular simulation study, we employ grand canonical Monte Carlo simulation (GCMC) to shed light on the significant influence of micropores on CO2 adsorption capability and regenerability, emphasizing the need for a rigorous selection of the swing adsorption process based on pore size. Our findings corroborate numerous experimental and numerical studies that the ultramicropore (pore size < 7 Å) is the appropriate range for CO2 capture, as it facilitates the formation of a horizontal monolayer of CO2 molecules. Furthermore, we highlight the importance of designing porous carbon materials with a large pore volume at the optimal ultramicropore sizes (approximately 5.8-6.4 Å depending on adsorption and desorption conditions) for obtaining high CO2 capture capacity and effective adsorbent regeneration. For the first time, taking into account the operational parameters of practical swing adsorption processes, our simulation study provides valuable guidance for selecting the most appropriate technology tailored to each specific range of micropore size in porous carbon. For porous carbon materials with an abundant volume of ultramicropores, pressure swing adsorption (PSA) and pressure-temperature swing adsorption (PTSA), as conventional and hybrid swing adsorption processes respectively, are the most effective practices, achieving high CO2 working capacity and regenerability exceeding 80%.

Reversible Phase Transformations in a Double-Walled Diamondoid Coordination Network with a Stepped Isotherm for Methane.

Flexible metal-organic materials (FMOMs) with stepped isotherms can offer enhanced working capacity in storage applications such as adsorbed natural gas (ANG) storage. Unfortunately, whereas >1000 FMOMs are known, only a handful exhibit methane uptake of >150 cm3/cm3 at 65 atm and 298 K, conditions relevant to ANG. Here, we report a double-walled 2-fold interpenetrated diamondoid (dia) network, X-dia-6-Ni, [Ni2L4(μ-H2O)]n, comprising a new azo linker ligand, L- (L- = (E)-3-(pyridin-4-yldiazenyl)benzoate) and 8-connected dinuclear molecular building blocks. X-dia-6-Ni exhibited gas (CO2, N2, CH4) and liquid (C8 hydrocarbons)-induced reversible transformations between its activated narrow-pore β phase and γ, a large-pore phase with ca. 33% increase in unit cell volume. Single-crystal X-ray diffraction (SCXRD) studies of the as-synthesized phase α, β, and γ revealed that structural transformations were enabled by twisting of the azo moiety and/or deformation of the MBB. Further insight into these transformations was gained from variable temperature powder XRD and in situ variable pressure powder XRD. Low-temperature N2 and CO2 sorption revealed stepped Type F-II isotherms with saturation uptakes of 422 and 401 cm3/g, respectively. X-dia-6-Ni exhibited uptake of 200 cm3/cm3 (65 atm, 298 K) and a high CH4 working capacity of 166 cm3/cm3 (5-65 bar, 298 K, 33 cycles), the third highest value yet reported for an FMOM and the highest value for an FMOM with a Type F-II isotherm.

Body mass assessment of male soldiers of the Armed Forces of Ukraine

Body weight control of male soldiers of the Armed Forces of Ukraine is not only about ensuring their somatic (physical) health. It is also the choice of proper nutrition, neat appearance, successful passing physical training tests, high work capacity and timely performance of military duties. Moreover, it is also the presence of special criteria – norms (standards), the development of which has unreasonably little attention in the past in the Armed Forces of Ukraine, but in the current conditions they are extremely relevant. Excessive body weight, and especially obesity, reduces a person’s work capacity, complicates intellectual and physical activity, causes disability, premature aging and shortened life expectancy. Body weight standards should be universal enough to take into account as much as possible departmental interests, in particular the military, and to cover individual characteristics of human development, such as height, age, and body constitution. The purpose of the study is to improve body weight assessment system of male servicemen of the Armed Forces of Ukraine with different height, age and body constitution. Methods of the study are as following: theoretical analysis and generalization; extrapolation; method of least squares; regression analysis. Material: according to the authors’ formula of optimal body weight for men of different height, age and different body constitution, the limits of body weight norms for nine age groups were obtained in accordance with the requirements of physical training standards. Results: a table of minimum and maximum body weight for servicemen of different heights depending on the age group was developed. A methodology for assessing the body weight of military personnel, taking into account their body constitution, has been developed. Conclusions. To estimate the body weight of male servicemen of the Armed Forces of Ukraine, a table has been developed within the height range from 1.50 to 2.06 m in nine age groups from 18 to 60 years and older for soldiers with different body constitutions. In the case when body weight of male servicemen of the Armed Forces of Ukraine exceeds the table requirements, it is necessary to obtain the percentage of its deviation from the optimal body weight for men of different height, age and different body constitution, which is calculated according to the formula: Optimal body weight for men = (4.7619 × wrist circumference – 90.4762) × (0/08135×age+21.6916) × L2 / 100+(0.08135 × age + 21.6916) × L2 . If the body weight differs from the optimal body weight for men by no more than ±10%, then it meets the requirements of the norm.

Integrating Multiscale Simulation with Machine Learning to Screen and Design FIL@COFs for Ethane-Selective Separation.

Efficient and economical separation of C2H6/C2H4 is an imperative and extremely challenging process in the petrochemical industry. The C2H6-selective adsorbents with high working capacity and high selectivity are highly desirable from a practical application standpoint. In this study, we constructed a database of fluorinated ionic liquid@covalent organic frameworks (FIL@COFs) and screened out the high-performing FIL@COFs for C2H6-selective separation. Utilizing the optimal machine learning (ML) algorithm (XGBoost) and hyperparameters, we further revealed the key factors influencing the separation performance. The multiscale simulation not only validated the prediction accuracy of ML but also demonstrated that adjusting the largest cavity diameter of COFs with FILs could yield FIL@COFs with high performance for C2H6-selective separation. Our work provides essential guidance for designing new FIL@COF adsorbents for value-added gas purification.

Alloying strategy to stabilize monocrystalline zinc anode under high utilization and working capacity

Zn(002) has been proven as a dendrite-free anode for Zn batteries. However, stable Zn plating/stripping behavior at an areal capacity exceeding 5 mAh cm−2 has remained unfulfilled so far. In this study, we show that the planar deposit on pure Zn (002) substrate is loosely stacked with high corrosion tendency by the aqueous electrolyte, the key obstacle to achieving considerable efficiency under high-capacity working conditions. To mitigate the side reactions, we introduce an alloying approach by combining monocrystalline Zn(002) with eutectic Al and Cu. The alloying strategy enhances the electrostatic interaction between deposits and substrate, favoring a dense-packed deposition morphology with improved corrosion resistant ability. Solid solution property of Al and Cu in Zn matrix also ensures the structure stability during repeated plating/stripping cycles. As a result, significant extension in cycle life of Zn alloy (002)-based symmetric cells even under 50 mA cm−2 and 25 mAh cm−2 and performance with high utilization also achieves a leading level without extra methods on surface protection. The modified Zn alloy (002) anode induces high anode utilization, paving the way for Zn batteries to meet the requirements of practical applications.

Hydration Programmable, Shape Memorable Artificial Muscles for Antagonistic Movements

AbstractShape memory polymers (SMPs) capable of generating various deformations from anisotropic temporary shapes to permanent shapes have been emerging as soft robots. However, traditional SMPs cannot imitate the antagonistic movement of human skeletal muscles due to their modulus limitations in shape programming and recovery process. Herein, hydration programmable shape memory polymer (HP‐SMP)‐based fibers that can undergo reversible actuation by assembling antagonistic pairs are reported, where the shape programming of the antagonist muscle relies on the contraction of agonist muscle. HP‐SMP fibers are composed of tunicate cellulose nanocrystals (TCNCs) reinforced semi‐interpenetrating polymer networks. Leveraging their distinctive structure and hydration programmability, the HP‐SMP fibers exhibit large actuation strain (−60%) and high work capacity (751 J kg−1), allowing for reversible actuation under constant stress. Most significantly, the continuous antagonistic movements of HP‐SMP fibers assembled into artificial limbs are demonstrated to realize humanoid motion. This work provides new possibilities for replicating a series of lifelike human movements through the biomimetic design of antagonistic pairs of artificial muscles, utilizing renewable and sustainable biosourced materials.

Improved Cycle Life and Determination of Li Ion Transport Parameters in Mixed Cation Doped Ni-Rich NMC

Ni-rich Li-ion cathode materials like NMC-9.5.5 (LiNi0.9Mn0.05Co0.05O2) are of interest due to their higher energy density and limited cobalt content, aiding the transition away from critical raw materials, when compared to materials like NMC111 - 622. This has the advantage of reducing production costs while maintaining a high working voltage and capacity. However, the high nickel content of these materials can be detrimental due to disorder brought by Li+/Ni2+ cation mixing, lithium residuals, and irreversible phase changes during operation resulting in significant capacity fade during cycling. Similarly, the different synthesis methods and treatments drastically affect the morphological, structural, and electrochemical propertiesWe present a structural and electrochemical study of NMC-9.5.5 prepared at scale via a hydroxide coprecipitation synthesis in a 5 L continuous stirred reactor tank (CSTR). In this work, bulk doping and co-doping with two metal cations are investigated with a simple and scalable method to achieve mixed metal and mixed valence doped NMC-9.5.5 with the aim to further improve cycle life and stability. Additionally, the effect of bulk doping on the thermodynamic and kinetic properties of the cathode material are investigated in both half-cells and full-cells using galvanostatic intermittent titration technique (GITT) and electrical impedance spectroscopy (EIS), where a 3-electrode configuration is used to elucidate the individual electrode potentials and stoichiometries.The bulk doping of the transition metal layer was found to significantly reduce the capacity fade in the NMC-9.5.5, increasing the capacity retention after 100 cycles from 78% in the undoped material to 92% and 89% in the doped and co-doped NMC-9.5.5 half-cells. The mixed metal co-doped material was also effective in delivering a higher specific capacity than the baseline throughout the full cycling range. The improved cycling performance can be understood by the inspection of the differential capacity plots, which show a suppression of the H2-H3 irreversible phase transition in the doped material and stabilisation of the peak to a higher voltage compared to the baseline. The effect of doping on the structural stabilisation is similarly reflected in the XRD characterisation, in which the introduction of the metal cation acts to constrain the detrimental Li+/Ni2+ cation mixing due to a widening of the transition metal channel. This is also supported by the EXAFS characterisation that indicate the dopants may act to stabilise the local Ni environment. These structural changes appear to be further beneficial in facilitating improved Li ion transport properties in the doped material as evidenced by the lower charge transfer resistances during cycling and increased diffusion coefficient.This research illustrates the high capacity performance of low cobalt cathode materials thus reducing the reliance on critical materials, as well as the ability to produce Ni-rich cathode material at large scale and further stabilise its cycle life by simple structural engineering. Improved materials manufacturing processes will enable a greater understanding of the synthesis process and enable more sustainable methods of synthesis. There are also benefits for cell makers with improvement in processability and additional stabilisation knowledge for battery manufacturers, as well as the consumers that benefit from longer driving ranges and battery life in their EV’s. Figure 1

Friction testing of tube-guided electrically heated Nitinol shape-memory alloy wires

In this study, a test scenario for the friction testing of electrically heated shape-memory alloy (SMA) wires against polymer surfaces was developed. As alloy, Nickel-Titanium (Nitinol, NiTi) was specially selected due to its high working capacity, the good corrosion resistance and the quick actor response at low bias forces. As the materials in contact with the actuator must resist friction forces and elevated temperatures up to 200 °C, a combination with high performance polymers is preferable. In many applications, the actuators use redirections to enhance the actuator capabilities or enable the use in complex structures. To better understand and compare the tribological properties of Nitinol against various polymer materials, it was needed to manufacture a customized testing device.

Constructing copper-organic framework with exceptionally high volumetric working capacity for efficient methane storage

Extensive efforts have been devoted to developing novel porous structures for methane storage with high volumetric uptake and volumetric working capacity. In this study, a NbO-type copper–organic framework (CMOF-1) was designed and synthesized. Notably, the CMOF-1 posses suitable nanocages decorated with carboxylate groups and nitrogen sites, exhibiting a remarkable volumetric uptake of 260 cm3 cm−3 (at 65 bar/298 K) and a volumetric working capacity of 202 cm3 cm−3 (from 5 to 65 bar). These values are comparable to those of the benchmark material HKUST-1 (267 cm3 cm−3 and 190 cm3 cm−3) and exceed those of the structural analogue ZJU-5a (249 cm3 cm−3 and 188 cm3 cm−3) under the same conditions. The grand canonical Monte Carlo simulations and density functional theory calculations reveal that the high methane volumetric uptake might be contributed by the open CuII sites and nanocages with suitable sizes/shapes and functional sites, which can enforce strong gas-framework and gas–gas interactions. The methodology presented in this work should envision potential practical applications in methane storage and could be generalized to design other novel materials for the storage of other gases like hydrogen.

Synthesis and characterization of biodegradable seaweed-based paper battery for sustainable energy storage

This article deals with the design and development of a seaweed-based paper battery, synthesized using different material coatings. Batteries have a high potential to power up the next generation of medical devices, electronics and hybrid vehicles but it require high working capacity. With the presence of several deficiencies like a regular, fluctuating voltage, spill out and damage issues, itching and irritation during human direct contact with wet and non-paper batteries, a need for dry and paper-based batteries has arisen. The design and fabrication of paper-based batteries with enhanced electrochemical and structural stability play a pivotal role to fix the above-mentioned problems. A battery made up of seaweed paper offers remarkable capacity with better performance and also helps to avoid the use of wood-based paper. The battery has been prepared with different materials of cathode and electrolyte, which are further tested for identifying an optimum match in terms of generated voltage. A biodegradability test and toxicity test were performed which ensured the eco-friendly nature of the proposed battery. The proposed battery is made of nanocomposites, which can pack more power into smaller spaces. Moreover, it is found that there is a reduction of weight by 58%, an enhancement of 16.7% in voltage capacity and eco-friendly compared to conventional AA 1.5–3.5 V Li-on battery.

Highly Stable Amide-Functionalized Zirconium-Organic Frameworks: Synthesis, Structure, and Methane Storage Capacity.

With the development of crystalline porous materials toward methane storage, the stability issue of metal-organic framework (MOF) materials has caused great concern despite high working capacity. Considering the high stability of zirconium-based MOFs and effective functions of amide groups toward gas adsorption, herein, a series of UiO-66 type of Zr-MOFs, namely, Zr-fcu-H/F/CH3/OH, were successfully designed and synthesized by virtue of amide-functionalized dicarboxylate ligands bearing distinct side groups (i.e., -H, -F, -CH3, and -OH) and ZrCl4 in the presence of trifluoroacetic acid as the modulator. Single-crystal X-ray diffraction and topology analyses reveal that these compounds are archetypal fcu MOFs encompassing octahedral and tetrahedral cages, respectively. The N2 sorption isotherms and acid-base stability tests demonstrate that the materials possess not only relatively high surface areas, pore volumes, and appropriate pore sizes but also great hydrolytic stabilities ranging pH = 3-11. Furthermore, the volumetric methane storage working capacities of Zr-fcu-H, Zr-fcu-F, Zr-fcu-CH3, and Zr-fcu-OH at 298/273 K and 80 bar are 187/217, 175/193, 167/187, and 154/171 cm3 (STP) cm-3, respectively, which indicate that the zirconium-based crystalline porous materials are capable of storing relatively high amounts of methane.

Effect of Physical Activity on Portal Vein Resistance Index

INTRODUCTION: In norm, adaptation of an organism to physical exercise is determined by the liver functions that ensure high working capacity. To this end, of a special interest are parameters of portal hemodynamics, in particular, the resistance index (RI) as the main coordinator of the differences in the linear velocity of blood flow between the phases of cardiac cycle. Dosed physical exercise is a relevant way of health improvement for not only practically healthy people, but also for people who have suffered COronaVIrus Disease 2019 (COVID-19), and who were diagnosed with liver damage. Such patients are prescribed physical rehabilitation for their health recovery.&#x0D; AIM: To study age-related changes in the portal vein (PV) RI and the effect of physical exercise in the form of forced dosed running on this parameter of the portal hemodynamics in an experiment on rats.&#x0D; MATERIALS AND METHODS: In young rats of 14–16-month age, which corresponds to 35–40 years of human age, the age-related changes in the portal vein RI were studied using ultrasound Dopplerometry. In animals of the control group, PV RI was studied during 75-day observation, in the experimental group — in the course of daily forced, dosed running on the 1st day, after 15, 30, 45 and 60 days, and also in 15 days after cessation of physical exercise. The actual effect of physical exercise on the change in the PV RI was evaluated with the deduction of age-related changes of the parameter.&#x0D; RESULTS: In the animals of the control group, after 60 days of the experiment, the PV RI increased by 5.44 ± 1.22%, and in the experimental group — by 24.10 ± 2.12%. After a 15-day recovery period, the parameter declined, but remained 9.11 ± 0.70% above the initial level. After deduction of the age-related changes of the parameter, the PV RI was 4.36 ± 1.93% above the initial one.&#x0D; CONCLUSION: Changes in the PV RI in daily dosed physical exercise did not go beyond the physiological norm and were transient. After a 15-day recovery period, the PV RI practically approached the initial parameter.

Design of Amine-Containing Nanoporous Materials for Postcombustion CO2 Capture from Engineering Perspectives.

ConspectusCarbon dioxide (CO2) capture and storage (CCS) is a means to enable the continued use of fossil fuels in the short term. In particular, postcombustion CO2 capture has attracted considerable attention because it can be retrofitted into existing power plants and industrial plants. Among various CO2 capture technologies, the absorption of CO2 using aqueous amines has been industrially employed for decades. However, such amine scrubbing technologies have inherent limitations of environmental and health concerns due to volatile amine loss, corrosion, and high energy demands for regeneration. To overcome these limitations, CO2 adsorption using solid adsorbents has emerged as a promising alternative due to its noncorrosiveness and low energy demand. Various amine-containing adsorbents have been synthesized and investigated for postcombustion CO2 capture. These materials are prepared by physically impregnating low-vapor-pressure amine polymers or by chemically grafting amines onto nanoporous materials. A wide variety of amine guests and nanoporous hosts (e.g., SiO2, Al2O3, zeolites, MOFs, and polymers) have been combined to develop advanced CO2 adsorbents.The design of CO2 adsorbents is a multifaceted puzzle that must ultimately consider integration with large-scale CO2 capture processes. Various engineering aspects need to be carefully considered. Unfortunately, a significant proportion of previous studies has primarily focused on the use of novel materials for improving the CO2 adsorption capacity. In this Account, we describe key challenges and solutions to develop energy-efficient and stable amine-containing adsorbents for postcombustion CO2 capture via temperature swing adsorption (TSA). We found that a high CO2 working capacity, often overemphasized in the literature, does not necessarily guarantee a low energy demand for CO2 capture. Suppressing coadsorption of H2O during the CO2 adsorption in humid flue gas is also a significant factor. Amine-containing adsorbents can be degraded through various pathways, including hydrothermal degradation of nanoporous hosts and chemical degradation of amine guests via urea formation and oxidation. To inhibit such degradation pathways, it is extremely important to properly design the nanoporous structures of the hosts and the molecular structures of the amine guests. By combining macroporous silica hosts, poly(ethylenimine) (PEI) functionalized with various alkyl epoxides, and phosphate-based oxidative stabilizers, we could synthesize adsorbents exhibiting low energy demands for CO2 capture and unprecedentedly high thermochemical stability under TSA conditions. The macroporous silica host synthesized by assembling fumed silica particles via spray-drying exhibited high hydrothermal stability and enabled uniform distribution of bulky amine polymers within its pores. The functionalization of PEI with alkyl epoxides converted its primary amines into hindered secondary amines, leading to a significant reduction in energy demand for TSA cycles and a remarkable improvement in long-term stabilities. The oxidative stability of amines could be drastically improved by adding phosphate metal-binding reagents, which can poison ppm-level metal impurities that catalyze amine oxidation. The present discussions will provide important insights into designing practical adsorbents for CO2 capture from engineering perspectives.

Face-directed assembly of tailored isoreticular MOFs using centring structure-directing agents

Building blocks with low connectivity and no embedded directionality are prone to polymorphism, as demonstrated by the diversity of 4-connected zeolitic nets (>250). As a result, their deployment for design in reticular and isoreticular chemistries remains a challenge. However, the ability to control geometrical peculiarities offers potential to deviate from the assembly of default structures. Here we report the face-directed assembly of >20 isoreticular zeolite-like metal–organic frameworks (ZMOFs) by using polytopic expanding and tightening centring structure-directing agents (cSDAs). The cSDAs are selected with the appropriate geometrical coding information to alter and control the orientation of adjacent supermolecular building blocks. The ZMOFs have an underlying sodalite (sod) topology that is remarkably suited for the rational assembly of multinary materials. In addition to a variety of metal cations (In, Fe, Co and Ni), a diverse range of cSDAs (di-, tri-, tetra-, hexa-, pyridyl or imidazole) are used and combined. Our approach enables isoreticular possibilities at both extremities of the porous materials spectrum: In-sod-ZMOF-102 exhibits small pore aperture suitable for efficient separation, while Fe-sod-ZMOF-320 with 48-Å-wide mesopores exhibits high hydrogen uptake, methane storage working capacity and a high gravimetric working capacity for oxygen.

Chiral design of tough spring-shaped hydrogels for smart umbrellas

Developing hydrogel artificial muscles to mimic the motion of natural muscles has long attracted scientists from the perspective of materials science for potential applications in soft robotics. However, rational design of hydrogel artificial muscles with large stroke, rapid actuation speed, and high work capacity remains a major challenge. Herein, we reported two kinds of chiral spring-shaped hydrogels that were prepared via consecutive shaping process (e.g., stretching, twisting, folding, coiling, and fixing). By switching the chirality of coil, homochiral muscle and heterochiral muscle were obtained, respectively. Homochiral muscle could rapidly expand to 560% with an average speed of 6.7 % s−1 in response to NIR irradiation, whose maximum work capacity reached 45 J kg−1. On contrary, heterochiral muscle contracted 69% within 1 min under NIR irradiation with a maximum work capacity of 33 J kg−1. Interestingly, the parasol containing homochiral muscles opened autonomously during dehydration process, while the umbrellas containing heterochiral muscle could opened rapidly when water was applied. This work provided an innovative strategy for developing tough hydrogel muscles with opposite chiralities.

Adsorption of CO2, CO, H2, and N2 on Zeolites, Activated Carbons, and Metal-Organic Frameworks with Different Surface Nonuniformities

The single-component adsorption of CO2, CO, N2, and H2 at 25 and 35 °C was studied using microporous faujasite-framework zeolites (NaY and NaX), activated carbons (GCN and MSP), and metal–organic frameworks (A100 and Z1200) as starting points for the separation of CO2 from syngases produced by gasifying biomass-based solid wastes. The indicated adsorption isotherms and uptake of the adsorbates strongly depended on the adsorbates themselves as well as on the adsorbents because of significant differences in the surface features, such as surface nonuniformity, and in the molecular properties. The selectivity of CO2 to the other gases also varied with the adsorbents due to the distinctive energetic characteristics. The surfaces of the zeolites were the most energetically heterogeneous ones, yielding higher CO2 uptake at low pressures, while the two activated carbons and A100 had moderate surface heterogeneities, and MSP showed the highest CO2 uptake at high pressures, such as 6 bar, at which the micropore volume and surface area are important. Z1200, which has highly homogeneous surfaces and no high-affinity-binding sites, exhibited the lowest CO2 adsorption capacity regardless of equilibrated pressure. The surface nonuniformities of the six sorbents were consistent with the calculated isosteric heats of CO2 adsorption. CO2 could be reversibly adsorbed on NaY and MSP but not on GCN, with some metal impurities, although all these adsorbents showed a fully reversible process for CO adsorption. The estimated working capacity for CO2 adsorption at 25 °C was 0.78–6.50 mmol/g, depending on the sorbents used. The highest value was disclosed for MSP, the surface energetic heterogeneity of which was between that of zeolites and Z1200. Such a high working capacity bodes well for use in our later applications.

Study on Energy Output Characteristics of Aluminized Emulsion Explosive

In order to study the energy output characteristics of multi-component explosives mixed with aluminum powder and emulsified explosives, five groups of emulsified explosives containing aluminum with different proportions were used for underwater explosion experiments and overpressure tests in the air. The experimental data show that when the mass fraction of aluminum powder increases from 0% to 40%, the shock wave energy increases from 0.68 kJ·g-1 to 1.22 kJ·g-1, which increases by 79.41%. Bubble energy increased by 135.66% from 2.44 kJ·g-1 to 5.75 kJ·g-1; the total energy of underwater explosion increased by 123.40% from 3.12 kJ·g-1 to 6.97 kJ·g-1. The explosion overpressure in the air increased by 93.66% from 60.794 KPa to 117.734 KPa. Aluminum powder greatly increases the output level of emulsified explosives. Emulsified explosive containing aluminum has the characteristics of high working capacity and high explosive performance.

Direct Air Capture of CO2 Using Amine/Alumina Sorbents at Cold Temperature.

Rising CO2 emissions are responsible for increasing global temperatures causing climate change. Significant efforts are underway to develop amine-based sorbents to directly capture CO2 from air (called direct air capture (DAC)) to combat the effects of climate change. However, the sorbents' performances have usually been evaluated at ambient temperatures (25 °C) or higher, most often under dry conditions. A significant portion of the natural environment where DAC plants can be deployed experiences temperatures below 25 °C, and ambient air always contains some humidity. In this study, we assess the CO2 adsorption behavior of amine (poly(ethyleneimine) (PEI) and tetraethylenepentamine (TEPA)) impregnated into porous alumina at ambient (25 °C) and cold temperatures (-20 °C) under dry and humid conditions. CO2 adsorption capacities at 25 °C and 400 ppm CO2 are highest for 40 wt% TEPA-incorporated γ-Al2O3 samples (1.8 mmol CO2/g sorbent), while 40 wt % PEI-impregnated γ-Al2O3 samples exhibit moderate uptakes (0.9 mmol g-1). CO2 capacities for both PEI- and TEPA-incorporated γ-Al2O3 samples decrease with decreasing amine content and temperatures. The 40 and 20 wt % TEPA sorbents show the best performance at -20 °C under dry conditions (1.6 and 1.1 mmol g-1, respectively). Both the TEPA samples also exhibit stable and high working capacities (0.9 and 1.2 mmol g-1) across 10 cycles of adsorption-desorption (adsorption at -20 °C and desorption conducted at 60 °C). Introducing moisture (70% RH at -20 and 25 °C) improves the CO2 capacity of the amine-impregnated sorbents at both temperatures. The 40 wt% PEI, 40 wt % TEPA, and 20 wt% TEPA samples show good CO2 uptakes at both temperatures. The results presented here indicate that γ-Al2O3 impregnated with PEI and TEPA are potential materials for DAC at ambient and cold conditions, with further opportunities to optimize these materials for the scalable deployment of DAC plants at different environmental conditions.

ОКРЕМІ АСПЕКТИ ВИВЧЕННЯ І РОЗВИТКУ ЕМОЦІЙНОЇ СТІЙКОСТІ В ПРОФЕСІЙНІЙ ДІЯЛЬНОСТІ ПЕРСОНАЛУ ДЕРЖАВНОЇ КРИМІНАЛЬНО-ВИКОНАВЧОЇ СЛУЖБИ УКРАЇНИ

The article examines certain aspects of the study and development of emotional stability in the professional activities of the personnel of the State Criminal and Executive Service of Ukraine (hereinafter – State Criminal and Executive Service of Ukraine). Emotional stability is an important personality trait and a professionally necessary quality in the service activities of the personnel of the State Criminal and Executive Service of Ukraine, because it directly affects the reduction of the negative effects of various stress factors, contributes to the efficiency and development of the safety component of professional activity. The purpose of the article is to outline certain aspects of emotional stability, to determine its role in the formation of the emotional and volitional sphere of the individual and its impact on the success and safety in the professional activities of the personnel of the State Criminal and Executive Service of Ukraine. The article examines the concept of emotional stability, identifies the lack of a single approach to understanding this concept. An analysis of the development of the concept of emotional stability in scientific literature was made and its main components were considered. The specified features of the professional activity of the personnel of the State Criminal and Executive Service of Ukraine. The importance of diagnosis, study and the need for the development of emotional stability for the personnel of the State Criminal and Executive Service of Ukraine as one of the main individual and psychological properties of the personality and its influence on resistance to stressful factors in difficult life circumstances and professional activity have been determined. According to the results of the research, we found that the issue of studying and developing the emotional stability of personnel is of great practical importance, because it is an important factor in safe professional activity, creates conditions for reducing tension, stress, negative effects of external factors, and promotes self-regulation, high work capacity, preservation of mental and physical health. Key words: emotional stability, emotions, stress factors, stability, tension, professional training, staff of the State Criminal and Executive Service of Ukraine.