Pulse power multilayer ceramic capacitors (pulse power-MLCC) are commonly used in complex composite environments with high overload and high voltage due to their large size and capacitance. In order to study the electromechanical coupling response characteristics of pulse power-MLCC in high-impact and high-voltage composite environments, a split Hopkinson pressure bar (SHPB) testing system was used to simulate high impact. The mechanical and electrical parameters of pulse power-MLCC were collected under high-impact and voltage environments, and the capacitance changes at different impact velocities were obtained. The stress wave transmission characteristics of pulse power-MLCC were studied by combining numerical simulation and theoretical analysis, and the structural deformation of ceramic dielectric under impact stress was analyzed. The relationship between the capacitance and DC bias of the capacitor was analyzed. A capacitance calculation model for pulse power-MLCC in an electromechanical coupling environment was established, revealing the electromechanical coupling mechanism of pulse power-MLCC.