High Steam Research Articles

Integration of a solid oxide electrolysis system with solar thermal and electrical energy: A testing campaign for operation and control strategy definition

AbstractThe EU project PROMETEO has the scope of testing a 25 kW solid oxide electrolysis system integrated with a concentrated solar power plant via thermal energy storage in a relevant environment. Given the plant layout and the hydrogen demand characteristics, this work aims to identify how to operate the system effectively when renewable electricity is unavailable and how to modulate the load during hydrogen generation, thus defining the system's operation modes and control strategy. A 5 kWe stack has been tested at the FBK facility. The hot standby tests show that feeding a reducing gas at the negative electrode and air at the positive electrode, without polarizing the stack, effectively keeps the stack hot at 750°C and prevents degradation. Conversely, the electric protection approach leads to significant stack degradation (15% voltage drop in 200 h for one cluster). Regarding modulation of hydrogen generation, with low steam flowrates, the stack current and the flow rate of produced hydrogen mainly depend on the steam flow rate, while it is not affected by the stack temperature; conversely, with high steam flowrates, the current depends only on the stack temperature (from 25 A at 670°C to 65 A at 760°C). Based on the results, two hot standby modes and two load control strategies to be implemented and tested in the PROMETEO prototype are proposed.

Life cycle sustainability assessment of microbial oil from organic waste

Microbial oils (MOs) are lipids produced by oleaginous microorganisms, which constitute an alternative to vegetable and fossil-derived oils. They can be produced from organic waste by coupling acidogenic fermentation (AF) with oleaginous fermentation (OF). This study addresses a life cycle sustainability assessment (LCSA) of MO produced from the organic fraction of municipal solid waste. First, a system was modelled using simulation tools. This model combines AF for the production of volatile fatty acids from organic waste, OF for the production of lipid-rich yeasts, and MO extraction. LCSA results indicate the need for improvements in the disruption of yeasts and the overall efficiency of the system. Particularly, slightly acidified thermolysis turned out to involve excessively high steam requirements. An enhanced sustainability performance could be achieved by exploring alternative disruption methods or alternative sources of energy for the production of steam such as biogas from the valorisation of the sludges produced in the system.

Study on the influence parameters and anti‐abrasion performance of steam‐cured hydraulic concrete for prefabricated water conveyance channel

AbstractExcessive sediment concentration in water can cause damage to prefabricated concrete channels. This study evaluates the impact of sediment‐laden water flow on the mass loss of concrete after abrasion, incorporating scanning electron microscope‐energy dispersive spectrometer (SEM‐EDS) and X‐ray diffraction (XRD) analyses to assess the effects of four steam‐curing parameters—delay time, heating rate, constant temperature duration, and steam curing temperature—on the abrasion resistance of concrete used in enterprise prefabricated water conveyance channels. The results indicate that the abrasion resistance of concrete for prefabricated channels improves gradually with increases in delay time and constant temperature duration. When the delay time exceeds 3 h and the constant temperature time exceeds 4 h, the concrete's abrasion resistance can reach more than 5 h(g/cm2)−1. Rapid heating rates and excessively high steam curing temperatures adversely affect the concrete's abrasion resistance. However, when the heating rate is controlled within 20°C/h and the steam curing temperature does not exceed 70°C, the concrete's abrasion resistance can achieve more than 5 h(g/cm2)−1. In compliance with the standard DL/T5201‐2021 requirements, it is recommended that concrete with high demands for abrasion resistance should preferentially select steam‐curing parameters within these ranges.

Study on the Continuous Whole Process Preparation of Peptizable Pseudoboehmite by High Gravity Strengthening Reaction of CO2 and Heat Transfer.

The preparation of highly peptizable pseudoboehmite faces challenges such as slow reaction rate, prolonged aging times leading to poor peptization performance, and difficulty in achieving continuous production. In this study, a novel approach was proposed involving a high gravity reactor to enhance carbonation reaction control for pseudoboehmite nucleation, a high gravity steam heating process, and a continuous aging process in pipelines. By coupling these three processes, the continuous whole process production of highly peptizable pseudoboehmite under high gravity conditions was achieved. First, the effect of high gravity reactor enhancement on the reaction and the resulting solid phase was investigated. Second, the impact of aging temperature and time on the solid phase formed at different reaction end points was studied using high gravity and steam heating of the liquid phase. Furthermore, the influence of synthesis conditions on the peptization performance of pseudoboehmite was extensively examined. Finally, the nucleation and growth mechanisms of pseudoboehmite under high gravity conditions were analyzed. It was found that increasing high gravity factor, CO2 gas flow rate, and CO2 content accelerated carbonation reaction rate, promoting pseudoboehmite crystal nucleation. Increasing aging temperature and time facilitated the growth of pseudoboehmite nuclei and improved peptization performance. The high gravity device altered the gas-liquid phase contact state of traditional kettle-type equipment, reducing the reaction time and heating time from minutes to seconds, thus achieving the continuous whole process production of pseudoboehmite with a peptization index of 100% from sodium aluminate solution by kiln flue gas.

Experimental study of viscosity reducer-assisted gas huff-n-puff in heavy oil reservoirs

With the diminishing of conventional high-quality oil resources and the advancement of both thermal and non-thermal recovery techniques for heavy oil, the development of heavy and ultra-heavy oil resources is becoming economically feasible. To address some of the reservoir challenges, such as the high heat loss and steam injection costs when using thermal recovery techniques in deep heavy oil reservoirs, as well as the prohibitive cost of CO2 injection when applying non-thermal techniques in heavy oil reservoirs located far from CO2 sources, this study explores the potential application of viscosity reducer-assisted CO2/N2 huff-n-puff (HnP) technique. The effect of different types of gases (N2, CO2 and hybrid N2/CO2) and viscosity reducers is evaluated by analyzing the pressure change, oil recovery rate and oil recovery factor in sandpack models. The results show that 96.62% and 60.75% viscosity reduction is achieved by the water-soluble viscosity reducer ASD-J-202 and the oil-soluble viscosity reducer KR-4, respectively. The oil recovery factors for the hybrid gas and CO2 gas are 17.98% and 18.58%, respectively, in presence of KR-4. In addition, high-quality, stable foamy oil is observed during production coupled with increased formation energy and reduced viscosity. For these runs, the residual oil at the injection end drops to 38.7%. During the soaking stage, N2 dominates the pore space while CO2 gradually diffuses to the distal end, dissolves in the heavy oil, causing oil swelling and increasing the sweep efficiency and oil recovery.

Comparison of non-premixed and premixed flamelets for ultra WET aero engine combustion conditions

The Water-Enhanced Turbofan (WET) is a future concept for aero engine applications being developed by MTU Aero Engines AG. Steam is injected into the combustion chamber to reduce temperature peaks and emission of pollutants. Depending on the steam content, the combustion process is modified. To analyze the effect of steam on the reaction kinetics and the temperature, detailed chemistry has to be employed. By comparing laminar flame speed and mole fraction distribution across the flame front, an appropriate chemical mechanism for the considered operating conditions including high steam loads was selected. Tabulated chemistry based on flamelets was employed, which enables the use of complex mechanisms in CFD analysis at reasonable computational costs. A comparison of premixed freely propagating flames and non-premixed counterflow diffusion flames to represent the manifolds was investigated. Various definitions of the progress variable are studied for ultra WET combustion considered under aero engine conditions. The manifolds from both model flames are compared from dry to ultra WET conditions with kerosene in an adapted Sandia Flame D large eddy simulation. While the premixed flamelets are generated efficiently, the results obtained with non-premixed flamelets are more reliable for the range of operating conditions investigated.

Feasibility and recovery efficiency of in-situ shale oil conversion in fractured reservoirs via steam heating: Based on a coupled thermo-flow-chemical model

Shale oil is a type of liquid hydrocarbon obtained through the pyrolysis of organic matter such as kerogen in oil shale reservoirs. Effective extraction of shale oil can significantly alleviate the pressure on oil supply. Among the various methods proposed for shale oil extraction, in-situ conversion of shale oil through high-temperature steam heating is a promising technique. This study employs a newly developed thermo-flow-chemical numerical simulator to establish a heterogeneous geological model and provides a detailed description of the evolution of different components within the shale oil reservoir during the in-situ conversion process. Additionally, the study thoroughly analyzes the role of high-permeability channels, such as fractures, in fluid transport and heat transfer during this process. In comparison with homogeneous reservoirs, fractures play a controlling role in the transport of steam. After injection, steam forms a preferential transport path between the heating well and the production well through the fractures. Subsequent injected steam will preferentially travel through this path, leading to faster heating of the reservoir. However, the uneven distribution of fractures may result in incomplete pyrolysis of the organic matter within the reservoir. Additionally, we found that the producing pressure and the steam injection rate significantly affect the pyrolysis of kerogen and the production of oil and gas. Both excessively low producing pressure and excessively high steam injection rate are detrimental to shale oil extraction. Based on these findings, this study aims to develop more rational heating strategies for reservoirs with different characteristics.

Mechanically robust and anisotropic hydrogel composites for high efficiency steam generation

Solar-driven interfacial evaporation (SDIE) has now become a promising desalination technique to harvest fresh water, and challenges remain to develop high performance solar evaporators that can achieve high performance SDIE while at the same time maintain good mechanical properties. In this work, anisotropic Polydopamine (PDA)/polyvinyl alcohol (PVA)@acidified carbon nanotubes (ACNTs) hydrogels (PPCHs) are prepared for SDIE and dye adsorption. The introduction of PDA and ANCTs improves the overall mechanical properties of the hydrogels and also imparts the hydrogel abundant active adsorption sites. PPCHs possess hierarchically vertical channels and hence powerful water transport capability. The PPCH evaporator with reduced water enthalpy exhibits high evaporation rate and efficiency, up to 3.43 kg m−2 h−1 and 91.6 % even during the long-term evaporation, respectively. In addition, PPCH can also work stably in harsh conditions such as high concentration brine, emulsions, acid and alkali solutions, etc. Due to the electrostatic interaction, PPCHs can effectively adsorb methylene blue (MB) in wastewater. PPCHs show broad application prospects in the field of solar desalination and dye adsorption. This study provides a rational structure design of the hydrogel composites for simultaneous SDIE and organic pollutant removal.

Experimental study on heat transfer characteristics of steam condensation in the presence of air and CO2 outside a vertical tube

Under severe accident conditions, in addition to steam and air, there are also other non-condensable gases inside the containment, such as CO2 produced by the molten corium concrete interaction (MCCI). Due to the significantly higher molecular weight and density of CO2 compared to steam and air, CO2 will have a significantly different impact on the steam condensation process compared to air. However, few scholars have paid attention to the impact of CO2 on the condensation process, and there is no empirical correlation applicable to this condition. Therefore, this article investigates the effect of different CO2 concentrations on the steam condensation heat transfer coefficient (CHTC) in the range of system pressure from 0.2 to 1.3 MPa and subcooling from 30 to 130 °C through experimental methods. Meanwhile, based on relevant experimental data, a new correlation suitable for calculating the steam CHTC in the presence of CO2 and air was fitted. The results indicate that under low steam concentration conditions, the addition of CO2 will reduce CHTC, while under high steam concentration conditions, CO2 will increase CHTC. The increase in system pressure will strengthen the condensation promotion effect of CO2 and weaken its inhibitory effect on condensation. In addition, by comparing experimental data under different component conditions, it was found that the new empirical correlation has high computational accuracy, and the calculation results of this correlation can contain more than 90 % of the data within a 15 % error range.

Surface property tuning of LaCr0.7Ni0.3O3 based perovskite catalysts enable efficient operation of SOFCs on liquid fuels

A-site Sr or Ca substituted perovskite LaCr0.7Ni0.3O3 (LSCN, LCCN) are prepared in this work as catalysts of simulated diesel fuel (N-hexadecane) steam reforming for the on-board hydrogen supplement of solid oxide fuel cells (SOFCs). The effect of different dopants on active metals dispersion and surface properties on catalyst performance is analyzed. The results of the investigation reveal that LCCN possesses the highest catalytic activity coupled with exceptional stability, achieving full fuel conversion at WHSV = 5 mL/g·h, S/C = 3.0, and 750 °C and keeping stable for 200 h, thereby emerging as a potential candidate for liquid fuel processing. SEM, H2-pulse chemisorption and XPS results confirm that the excellent performance is due to the high metal dispersion and steam activation capacity. The poor catalytic performance observed in LSCN is primarily attributed to the presence of Sr segregation and the formation of the SrCrO4 second phase. Sr segregation decreases the steam activation ability of the catalyst as confirmed by XPS. DFT calculation also shows that Sr dopant and Sr segregation decrease the exsolution trend of metal Ni in the perovskite matrix, leading to poor metal dispersion. A simulated reforming gas is used in SOFC and the cell can keep stable for 120 h at a discharging current density of 0.4 A/cm2. This study analyzes the difference between Ca and Sr dopants, and reveals the detrimental effect of Sr segregation, which could enlighten the effect of surface tunning on the performance of perovskite catalysts.

Ni coarsening under humid atmosphere in the electrode of solid oxide cells: A combined study of density-functional theory and phase-field modeling

Ni coarsening in solid oxide cell (SOC) electrodes is known to be significantly faster under a humid atmosphere. The underlying mechanisms, though, have not been fully understood. In this work, we examine the surface diffusion of Ni(OH)x by a combination of density-functional theory and phase-field modeling. Density-functional theory is used to evaluate the adsorption and diffusion of the Ni(OH)x species on Ni (111) surface, and the results are used to obtain the effective surface diffusivity of Ni versus steam and hydrogen gas partial pressures. This diffusivity is used as an input for a phase-field model to investigate the Ni coarsening in SOC electrodes. It is found that Ni(OH)x formed through chemical reaction cannot accelerate coarsening unless an extremely high steam to hydrogen ratio is reached. However, if Ni(OH)x is formed through electrochemical reactions near triple phase boundaries (TPBs), surface diffusion of Ni(OH)x may cause faster Ni coarsening in fuel cell mode under a large overpotential. Specifically, surface diffusion of Ni(OH) may be comparable to or faster than that of Ni under an overpotential that is large but still possible under fuel cell operating conditions.

A thermogravimetric comparative study of the high temperature steam oxidation of bare and pre-oxidized Zircaloy-4, M5Framatome and Optimized ZIRLO™

For Loss of Coolant Accident (LOCA) analysis, high-temperature oxidation kinetics in steam of Zircaloy-4 and the two Nb-bearing alloys used in French Pressurized Water Reactors (PWRs), M5Framatome11M5 and M5Framatome are trademarks or registered trademarks of Framatome or its affiliates, in the USA or other countries. and Optimized ZIRLO™22Optimized ZIRLO is a trademark or registered trademark of Westinghouse Electric Company LLC, its affiliates and/or its subsidiaries in the United States and may be registered in other countries throughout the world. All rights reserved. Unauthorized use is strictly prohibited. Other names may be trademarks of their respective owners., have been studied using Thermo-Gravimetric Analysis (TGA) technique in the temperature range of 900–1200 °C. A specific test procedure allowing the use of a high steam flow rate and good steam supply to the whole specimen surface, as well as fast heating of the specimen, has been developed. Clean kinetic data, not affected by steam starvation, were obtained on the bare, as-received alloys. For as-received claddings, oxidation kinetics are comparable and close to parabolic for the three alloys at 1100 °C and above. Below 1100 °C, a significant deviation from the parabolic kinetic regime was observed, and M5 Framatome oxidizes slower than Zircaloy-4 and Optimized ZIRLO. Thanks to the fast-heating protocol, the influence of pre-oxidation, simulating corrosion in normal reactor operation, could be investigated, avoiding evolution of the pre-oxidation scale during a slow, long heating phase. Pre-oxidized Zircaloy-4 and M5 Framatome were investigated. A strong protective effect is observed below 1200 °C, while at 1200 °C, the pre-oxidation layer appears to be much less protective, possibly due to the monoclinic to tetragonal zirconia phase transformation.

Enhancing protonic ceramic electrolysis cell performance through electrolyte composition optimization

Polarization resistance, chemical stability against high steam, and faradaic efficiency (FE) are important parameters for steam electrolysis using protonic ceramic electrolysis cells (PCEC) at an intermediate temperature range of approximately 500 °C. To investigate the effects of electrolyte composition on these parameters, PCECs were fabricated using two electrolyte compositions: one without Zr, Ba(Ce0.8Y0.1Yb0.1)O3-δ (BCYYb), and one with Zr, Ba(Ce0.3Zr0.5Y0.1Yb0.1)O3-δ (BCZYYb), as well as a double-layered electrolyte BCYYb/BCZYYb. Although Zr in BCZYYb is required for chemical stability, BCYYb without Zr can also be chemically stable against high steam at 500 °C. Additionally, BCYYb has a higher conductivity compared to BCZYYb, which contributes to lower ohmic resistance and the highest peak power density in H2 fuel at 700 °C (2.04 W/cm2) among the cells with three different electrolytes. However, the BCYYb electrolyte exhibits a slightly higher polarization resistance than BCZYYb. In PCEC operation at 500 °C, the electrolyte composition significantly affects the FE. At a high current density (0.8 A/cm2), the FE of the PCEC with the BCYYb electrolyte (85 %) is significantly larger than that with BCZYYb (68 %).

Experimental investigation and modeling of onset of condensation induced water hammer in equal-height-difference natural circulation system

Condensation induced water hammer (CIWH) in equal-height-difference natural circulation systems (EHDNCS) can lead to significant damage to associated equipment. To investigate the mechanism and the prediction of the onset of CIWH in EHDNCS, a small-scale experiment of EHDNCS was conducted under different water temperatures, heat transfer powers, and resistance coefficients of the water-side inlet. This study analyzed the thermal hydraulics, flow regimes, and the onset mechanism of CIWH through temperature and pressure measurement, U-Net image segmentation, and analytical modeling. Four distinct flow regimes were observed in the horizontal pipe: single-phase flow, non-periodic bubble, periodic bubble, and CIWH. Flow regime maps based on water temperature and heat transfer power were obtained under different inlet resistance coefficients. When the steam bubble length is smaller than the pipe length, no CIWH occurs. When the steam bubble length reaches the pipe outlet to form stratified flow, CIWH occurs at a high steam channel height. The occurrence of stratified flow and reverse flow of subcooled water in the steam channel causes the onset of CIWH in EHDNCS. A dimensionless criterion has been developed to predict the onset of CIWH when the saturated steam-water mixture is discharged through a horizontal pipe in EHDNCS. This criterion effectively predicted the transition from periodic bubble to CIWH in the experiment.

Black Silver-Decorated liquid metal nanofillers coupled with Glycerol-Modified hydrogel composites for high efficiency solar steam generation and thermoelectric conversion

Solar-driven interfacial evaporation (SDIE) holds great potential in alleviating global freshwater scarcity, which requires the design of efficient energy conversion devices. Herein, a quadruply engineered hydrogel-based evaporator is developed based on multipath regulation of the four key processes involved in SDIE, i.e., heat generation, energy utilization, water transportation, and evaporation. Surface-tailored liquid metal nanoparticles (EGaIn@Ag NPs) with a high photothermal conversion efficiency (PCE) of 30.4 % serve as the nanofiller to produce heat efficiently. Vertically aligned microchannels are constructed in the poly(vinyl alcohol) (PVA) hydrogel through directional freezing to accelerate water transportation. Glycerol is introduced to the PVA matrix to synergistically a) prevent heat loss from the interface to bulk water, and b) modulate the bonding state of water in the hydrogel to reduce the vaporization enthalpy. Such an elaborate design achieves a rather high evaporation rate of 3.26 kg m−2h−1 under 1 sun illumination. The hydrogel evaporator (EGaIn@Ag/PVAG) is applicable in treating real seawater and dye-contaminated sewages, showing favorable desalination durability and self-cleaning property. The synergistic design also imparts the hydrogel with thermoelectric power generation capabilities. This work offers a new insight into the synergistic design of SDIE devices, which is expected to inspire innovations in solar energy conversion and utilization.

A hierarchically cellulose porous monolith doped with CNTs/Al2O3 fibers, exhibiting super-hydrophilicity and underwater superoleophobicity for efficient solar-driven desalination

The utilization of solar-driven interfacial desalination is widely regarded as a promising technological approach for mitigating the global water crisis. Existing solar interface evaporators often face limitations such as salt accumulation and oil waste liquid interference, impeding water supply channels and the efficient escape of interface water vapor, consequently diminishing the evaporation rate. This study proposes a novel approach by synthesizing a monolithic structure composed of carbon nanotubes (CNTs) and vertically arranged Al2O3 fibers which are embedded in cellulose skeleton, achieved through the thermally induced phase separation (TIPS) method. The resulting hierarchically porous monolith exhibits high steam generation rate, remarkable superhydrophilic properties and underwater superoleophobicity, rendering it highly effective in salt tolerance and resistance against oil pollution. In particular, highly oriented Al2O3 fibers form multiple thermal localization arrays and steam dissipation channels，complemented by interconnected hydrophilic skeleton that achieved strong synergy, enabling a stable and high evaporation rate of 1.98 kg m−2 h−1 and 2.06 kg m−2 h−1 in high salt concentration (10 wt%) seawater and oil-in-water (O/W) emulsion, respectively. This work contributes to the ongoing efforts in advancing next-generation solar vapor generators, aiming to enhance the sustainability and efficiency of freshwater production in response to the global water crisis.

Skin Electrodes Based on TPU Fiber Scaffolds with Conductive Nanocomposites with Stretchability, Breathability, and Washability.

In the context of an aging population and escalating work pressures, cardiovascular diseases pose increasing health risks. Electrocardiogram (ECG) monitoring presents a preventive tool, but conventional devices often compromise comfort. This study proposes an approach using Ag NW/TPU composites for flexible and breathable epidermal electronics. In this new structure, TPU fibers are used to support Ag NWs/TPU nanocomposites. The TPU fiber-reinforced Ag NW/TPU (TFRAT) nanocomposites exhibit excellent conductivity, stretchability, and electromechanical durability. The composite ensures high steam permeability, maintaining stable electrical performance after washing cycles. Employing this technology, a flexible ECG detection system is developed, augmented with a convolutional neural network (CNN) for automated signal analysis. The experimental results demonstrate the system's reliability in capturing physiological signals. Additionally, a CNN model trained on ECG data achieves over 99% accuracy in diagnosing arrhythmias. This study presents TFRAT as a promising solution for wearable electronics, offering both comfort and functionality in long-term epidermal applications, with implications for healthcare and beyond.

Robust and multifunctional MXene/rGO composite aerogels toward highly efficient solar-driven interfacial evaporation and wastewater treatment

Given the ever-growing global water resource crisis, exploiting multifunctional materials featuring with high interfacial solar steam generation efficiency and good purification capability to achieving seawater desalination and wastewater treatment simultaneously are highly desired, yet it still remains a huge challenge to date. Herein, robust and multifunctional MXene/rGO (MRGA) and polydopamine & chitosan @ MRGA (CS&PDA@MRGA, CPM) three-dimensional composite aerogels with distinct interconnected cellular architecture were developed via a facile ice template-assisted chemical reduction self-assembly technology and subsequent sequential deposition modification. Due to the favorable graphene oxide-assisted assembly behavior, the resultant aerogels displayed a desirable mechanical robustness along with an excellent lightweight property. Benefiting from the strong electrostatic interaction deriving from aerogel surface moieties and dye molecules, MRGA-12 exhibited a prominent adsorption capability towards various dyes and achieved a superb adsorption capacity of up to 396.05 mg/g for malachite green (MG). Moreover, by virtue of the synergistic effect between the intentionally regulated low reduction degree of rGO and the integration of PDA and CS, CPM-12 achieved a dramatically reduced evaporation enthalpy of water from 2256 to 1617.18 J/g. Accordingly, this distinct feature resulted in an extraordinary solar-driven interfacial evaporation performance with a remarkable evaporation rate of 1.86 kg/m2/h and a high evaporation efficiency of 83.28 % under 1 sun illumination. Therefore, together with the terrific oil/water separation capability, these novel MXene-based aerogels hold a great potential for high-performance solar-driven interfacial evaporation and wastewater treatment.

Study of high power steam turbine forced oscilla-tions near operating frequency

Problem. Forced oscillations of the turbine unit-foundation-base system near the operating frequency are considered. Goal. The purpose of the work is to study forced vibrations of the turbine unit-foundation-base system near the operating frequency range to assess the vibration state of the system and determine the causes of increased vibrations. The object of the study is the turbine unit-foundation-base system. The system consists of a single reinforced concrete foundation on which a steam turbine and generator are installed. The subject of the study is the amplitude-frequency dependences of forced oscillations of the turbine unit-foundation-base system. Methodology. The study was carried out using vibration methods and the finite element method. Also worth noting is the use of original methods developed directly by the author for constructing models of complex mechanical engineering systems. Results. As a result of the research, three-dimensional finite element models of low-pressure cylinder housings, the foundation and the entire turbine unit-foundation-base system were built. The conducted research allows us to draw a conclusion regarding the reasons for the increased level of vibration near the operating frequency and directions for their prevention. Originality. Regarding the methods for constructing a model of the turbine unit-foundation-base system, it should be noted that they are unique. The features of the applied modeling method make it possible to take into account the variable interaction between the low-pressure cylinder bodies and the foundation. Fixpoints are also taken into account. Previous studies of the turbine unit-foundation-base system did not allow us to determine the causes of increased vibrations of the shaft line supports. Practical significance. The results of the work relate to direct practical application. As a result of the work, conclusions were drawn about the ways to increase the vibration reliability of the turbine unit-foundation-base system and further directions for research.

An Active and Stable Cobalt‐Free Ruddlesden–Popper Nd0.8Sr1.2Ni1‐xFexO4±δ Air Electrode for Reversible Proton‐Conducting Solid Oxide Cells

AbstractReversible proton‐conducting solid oxide cells (R‐PSOCs) are considered to be one of the most promising devices for efficient power generation and hydrogen production. However, the requirement of high catalytic activity for fast oxygen reduction/evolution reaction (ORR/OER) and durability under high steam concentration of air electrode materials remains the major challenge for the practical application of R‐PSOCs. Here, a series of cobalt‐free Ruddlesden–Popper perovskite of Nd0.8Sr1.2Ni1‐xFexO4±δ are reported with mixed conductivity for enhanced ORR/OER kinetics. The R‐PSOCs with an optimal Nd0.8Sr1.2Ni0.7Fe0.3O4±δ air electrode show a high peak power density of 1.28 W cm−2 in the fuel cell mode and a promising current density of 3.24 A cm−2 at 1.3 V in the electrolysis cell mode at 700 °C. In addition, the R‐PSOCs show favorable stability under the fuel cell, electrolysis, and reversible modes for hundreds of hours. This work demonstrates that the Ruddlesden–Popper materials can be utilized as suitable air electrodes for R‐PSOCs.