High-precision X-ray Research Articles

Technology development and applications of high precision extreme ultraviolet and X-ray thin film optical systems

Technology development and applications of high precision extreme ultraviolet and X-ray thin film optical systems

MMC Array to Study X-Ray Transitions in Muonic Atoms

The QUARTET collaboration aims to significantly improve the precision of the absolute nuclear charge radii of light nuclei from Li to Ne by using an array of metallic magnetic calorimeters to perform high-precision X-ray spectroscopy of low-lying states in muonic atoms. A proof-of-principle measurement with lithium, beryllium and boron is planned for fall 2023 at the Paul Scherrer Institute. We discuss the performance achieved with the maXs-30 detector module to be used. To place the detector close to the target chamber where the muon beam will impact the material under study, we have developed a new dilution refrigerator sidearm. We further discuss the expected efficiency given the transparency of the X-ray windows and the quantum efficiency of the detector. The expected muonic X-ray rate combined with the high resolving power and detection efficiency of the detector suggest that QUARTET will be able to study the de-excitation of light muonic atoms at an unprecedented level, increasing the relative energy resolution by up to a factor of 20 compared to conventional detector techniques.

High-precision X-ray polarimeter based on channel-cut crystals

High-precision X-ray polarimeter based on channel-cut crystals

High-pressure plasma etching up to 9 atm toward uniform processing inside narrow grooves of high-precision X-ray crystal optics

We developed a new etching technique using plasma generated at high pressure up to 9 atm. Operating at 9-atm pressure with a 30-μm-diameter wire electrode, we demonstrated the generation of well-ordered plasma at a narrow gap of ∼10 μm between the electrode and workpiece, and realized a high spatial resolution of <40 μm during processing. This technique should allow for the processing of high-precision X-ray crystal optical devices with compact and complex structures, such as a micro channel-cut crystal monochromator with an extremely narrow (sub-100 μm width) groove for realization of Fourier-transform-limited X-ray lasers with high intensity.

Would it be better for partition prediction of heavy metal concentration in soils based on the fusion of XRF and Vis-NIR data?

Heavy metal (HM) contamination in soil necessitates effective methods to diagnose suspected contaminated areas and control rehabilitation processes. The synergistic use of proximal sensors demonstrates significant potential for rapid detection via accurate surveys of soil HM pollution at large scales and high sampling densities, and necessitates the selection of appropriate data mining and modeling methods for early diagnosis of soil pollution. The aim of this study is to evaluate the performance of a subarea model based on geographically partitioned and global models based on high-precision energy dispersive X-ray fluorescence (HD-XRF) and visible near-infrared (vis-NIR) spectra using a random forest model for predicting soil Cu and Pb concentrations. A total of 166 soil samples are acquired from a contaminated plot in Baiyin, Gansu Province, China. The soil samples are subjected to HM analysis and proximal sensor scanning in a laboratory. Vis-NIR spectral data are preprocessed using the Savitzky Golay (SG) and first-order derivative with Savitzky Golay (SGFD) methods. The results show that for predicting Cu and Pb concentrations in soil, the subarea models performs better than the global models in terms of quantitative prediction, based solely on individual HD-XRF data. For the subarea and global models, the R2 values are 0.961 and 0.981, respectively; the RMSE values are 27.8 and 79.6, respectively; and the RPD values are 4.96 and 7.38, respectively. However, making use of the random forest algorithm trained with data fusion obtained from the HD-XRF and vis-NIR sensors, the global model achieves the best predictions for Cu and Pb concentrations via HD-XRF + vis-NIR (SGFD) and HD-XRF + vis-NIR (SG), respectively. The results will provide a new perspective for modeling approaches to rapidly invert HM concentrations based on proximal sensor data fusion within a large scope of the study area.

Design and preliminary evaluation of a multi-channel multi-energy point integrated Wolter microscope.

In inertial confinement fusion, high-precision x-ray imaging is crucial for understanding the states of matter under extreme conditions. To observe the target asymmetry during compression, multiple imaging spots with varying energy responses are necessary. However, integrating multiple imaging channels in a grazing incidence x-ray imaging scheme is challenging, and there is an urgent need for effective combination of multi-color and high-throughput diagnostics. This study presents a design method for a multi-channel integrated Wolter microscope with high spatial resolution, wide-band response, and high throughput. The basic optical configuration, adjustment method, and multi-channel integration scheme are discussed in detail. A 10keV-class three-channel integrated Wolter microscope is proposed for verification, with an estimated spatial resolution better than 4.0µm in a field of view of ±500µm. The peak response efficiencies for each imaging channel are calculated as 5.2×10-5 s r, 8.6×10-5 s r, and 2.2×10-4 s r, respectively.

Mixed stitching interferometry with correction from one-dimensional profile measurements for high-precision X-ray mirrors.

This work presents a mixed stitching interferometry method with correction from one-dimensional profile measurements. This method can correct the error of stitching angles among different subapertures using the relatively accurate one-dimensional profiles of the mirror, e.g., provided by the contact profilometer. The measurement accuracy is simulated and analyzed. The repeatability error is decreased by averaging multiple measurements of the one-dimensional profile and using multiple profiles at different measurement positions. Finally, the measurement result of an elliptical mirror is presented and compared with the global algorithm-based stitching, and the error of the original profiles is reduced to one-third. This result shows that this method can effectively suppress the accumulation of stitching angle errors in classic global algorithm-based stitching. The accuracy of this method can be further improved by using high-precision one-dimensional profile measurements such as the nanometer optical component measuring machine (NOM).

Proof-of-Principle Experiment for Testing Strong-Field Quantum Electrodynamics with Exotic Atoms: High Precision X-Ray Spectroscopy of Muonic Neon.

To test bound-state quantum electrodynamics (BSQED) in the strong-field regime, we have performed high precision x-ray spectroscopy of the 5g-4f and 5f- 4d transitions (BSQED contribution of 2.4 and 5.2eV, respectively) of muonic neon atoms in the low-pressure gas phase without bound electrons. Muonic atoms have been recently proposed as an alternative to few-electron high-Z ions for BSQED tests by focusing on circular Rydberg states where nuclear contributions are negligibly small. We determined the 5g_{9/2}- 4f_{7/2} transition energy to be 6297.08±0.04(stat)±0.13(syst) eV using superconducting transition-edge sensor microcalorimeters (5.2-5.5eV FWHM resolution), which agrees well with the most advanced BSQED theoretical prediction of 6297.26eV.

Comprehensive analysis of Japanese nationwide cohort data of particle beam therapy for pulmonary, liver and lymph node oligometastases: particle beam therapy versus high-precision X-ray radiotherapy.

Japanese national oncological experts convened to evaluate the efficacy and safety of particle beam therapy (PT) for pulmonary, liver and lymph node oligometastases (P-OM, L-OM and LN-OM, respectively) and to conduct a statistically comparative analysis of the local control (LC) rate and overall survival (OS) rate of PT versus those of X-ray stereotactic body radiotherapy (X-SBRT) and X-ray intensity-modulated radiotherapy (X-IMRT). They conducted [1] an analysis of the efficacy and safety of metastasis-directed therapy with PT for P-OM, L-OM and LN-OM using a Japanese nationwide multi-institutional cohort study data set; [2] a systematic review of X-ray high-precision radiotherapy (i.e. X-SBRT/X-IMRT) and PT for P-OM, L-OM and LN-OM; and [3] a statistical comparison between LC and OS of the cohort data set in PT and that of the extracted historical data set in X-SBRT/X-IMRT from the preceding systematic review. Safety was evaluated as the incidence of grade ≥ 3 adverse events, while statistical comparisons of LC and OS were conducted by estimating the incidence rate ratios (IRR) for local progression and mortality, respectively. This study demonstrated that PT provided durable LC (3-year LC rate: 72.8-83.2%) with acceptable OS (3-year OS rate: 38.5-68.1%) and risk of severe toxicity incidence of 0.8-3.5% in radical metastasis-directed therapy for P-OM, L-OM and LN-OM. Compared to LC with X-SBRT or X-IMRT, LC with PT was potentially superior for P-OM; superior for L-OM; and equivalent for LN-OM. In particular, this study demonstrated that PT may be a new treatment option for L-OM tumors measuring > 5cm.

Surface figure correction with roughness reduction using carbon-doped platinum film for high-precision X-ray mirror fabrication.

To obtain the surface shape of an X-ray mirror with high precision, a differential deposition method was used instead of a direct removal method. To modify the mirror surface shape using the differential deposition method, it is necessary to coat it with a thick film, and the co-deposition method is used to suppress the increase in surface roughness. The addition of C to the Pt thin film, which is often used as an X-ray optical thin film, resulted in lower surface roughness compared with that with the Pt coating alone, and the stress change according to the thin film thickness was evaluated. Differential deposition controls the speed of the substrate during coating based on continuous motion. The stage was controlled by calculating the dwell time through deconvolution calculations based on the accurate measurement of the unit coating distribution and target shape. We successfully fabricated an X-ray mirror with high precision. This study indicated that an X-ray mirror surface could be manufactured by modifying the surface shape at a micrometer level through the coating. Changing the shape of existing mirrors can not only result in the manufacture of high-precision X-ray mirrors but also improve their performance.

Development and Commercial Application of Glue-Free Adaptive High Precision X-Ray Mirror

Development and Commercial Application of Glue-Free Adaptive High Precision X-Ray Mirror

X-ray Spectroscopy Based on Micro-Calorimeters at Internal Targets of Storage Rings

With metallic-magnetic calorimeters (MMCs), promising detectors for high-precision X-ray spectrometry in atomic and fundamental physics experiments are available. In this work, we present a pilot experiment based on a maXs-30 type MMC-spectrometer for recording X-rays emitted in collisions of lithium-like uranium ions with a molecular nitrogen gas jet in the internal target of the ESR storage ring of the GSI. Sample spectra have been measured, and a multitude of X-ray transitions have been unambiguously identified. As a first test and for comparison with data recorded at an EBIT, the 2s Lamb shift in lithium-like uranium was estimated.

Octahedra-Tilted Control of Displacement Disorder and Dielectric Relaxation in Mn-Doped SrTiO3 Single Crystals.

Strontium titanate SrTiO3 (STO) is a canonical example of a quantum paraelectric, and its doping with manganese ions unlocks its potential as a quantum multiferroic candidate. However, to date, the specifics of incorporation of the manganese ion into the perovskite lattice and its impact on structure-property relationships are debatable questions. Herein, using high-precision X-ray diffraction of a Mn (2 atom %)-doped STO single crystal, clear fingerprints of the displacement disorder of Mn cations in the perovskite B-sublattice are observed. Moreover, near the temperature of the antiferrodistortive transition, the off-center Mn position splits in two, providing the unequal potential barrier's distribution for possible local atomic hopping. A link with this was found via analysis of the dielectric response that reveals two Arrhenius-type relaxation processes with similar activation energies (35 and 43 meV) and attempt frequencies (1 × 1011 and ∼1.6 × 1010 Hz), suggesting similar dielectric relaxation mechanisms.

Thermal properties and microstructural evolution of coal spontaneous combustion

With the increase of coal energy mining depth in China, coal spontaneous combustion phenomenon becomes more frequent, which makes the safe mining of coal energy in China under serious threat. In order to prevent coal spontaneous combustion, it is significant to investigate the process of coal oxidation and spontaneous combustion by combining thermal and microstructural properties, which is a necessary study to figure out the mechanism of coal spontaneous combustion. A series of coal oxidation experiments were conducted with the aid of high precision Calorimeter and X-ray diffractometer. The results show that the thermal properties of coal spontaneous combustion have obvious segmentation characteristics which is not affected by the degree of metamorphism and heating rates, and the initial exothermic temperature is positively correlated with heating rates. The effect of temperature on microscopic characteristics is not uniform, but the degree of metamorphism has a regular change for microscopic characteristics. Although temperature does not play a decisive role, the spatial structure of coal oxidation process has some reversibility with the change of temperature. Besides, thermal dynamic balance is an important cause of microstructure changes. It is expected that this work will contribute to the refinement of the theory of coal spontaneous combustion.

Basic principles and optical system design of 17.48keV high-throughput modified Wolter x-ray microscope.

High-precision x-ray imaging diagnostics of hotspot at the stagnation stage are essential for regulating implosion asymmetry and retrieving physical implosion parameters. With regard to 10-20keV energy band imaging, existing diagnostic instruments such as Kirkpatrick-Baez microscopes and pinhole cameras are insufficient in terms of spatial resolution and collection efficiency. The situation is even worse when high-speed, time-resolved imaging diagnostics are performed by coupling framing cameras or line-of-sight imagers. This article presents the basic principles and optical system design of a 17.48keV modified Wolter x-ray microscope, to resolve the problems encountered in high-energy imaging diagnostics. The proposed optical configuration offers a better spatial resolution, greater depth of field, and preliminary compliance with the requirements of high precision optical processing techniques. The spatial resolution is better than 1 µm in a field range ±150 µm, and is better than 3 µm in a total field of view ∼408 µm in diameter. The geometric solid angle is calculated as 3.0 × 10-5 sr and is estimated to be 1.2 × 10-6 sr, considering the reflectivity of the double mirrors. The proposed microscope is expected to effectively improve spatial resolution and signal-to-noise ratio for high-energy imaging diagnostics.

Identification of heavy metal pollutants and their sources in farmland: an integrated approach of risk assessment and X-ray fluorescence spectrometry

Investigation and assessment of farmland pollution require an efficient method to identify heavy metal (HM) pollutants and their sources. In this study, heavy metals (HMs) in farmland were determined efficiently using high-precision X-ray fluorescence (HDXRF) spectrometer. The potential ecological risk and health risk of HMs in farmland near eight villages of Wushan County in China were quantified using an integrated method of concentration-oriented risk assessment (CORA) and source-oriented risk assessment (SORA). The CORA results showed that Cd in farmland near the villages of Liuping (LP) and Jianping (JP) posed a “very high” potential ecological risk, which is mainly ascribed to soil Cd (single potential ecological risk index ({E}_{r}^{i}) of Cd in villages LP and JP, {E}_{r}^{i} = 2307 and 568 > 320). A “moderate” potential ecological risk was present in other six villages. The overall non-carcinogenic risk (hazard index (HI) = 1.2 > 1) of HMs for children in village LP was unacceptable. The contributions of HMs decrease in the order of Cr > As > Cd > Pb > Ni > Cu > Zn. The total carcinogenic risk (TCR = 2.1 × 10–4 > 1.0 × 10–4) of HMs in village LP was unacceptable, with HMs contributions decreasing in the order of Cr > Ni > Cd > As > Pb. Furthermore, three source profiles were assigned by the positive matrix factorization: F1: agricultural activity; F2: geological anomaly originating from HMs-rich rocks; F3: the natural geological background. According to the results of SORA, F2 was the highest contributor to PER in village LP, up to 64.4%. Meanwhile, the contributions of three factors to HI in village LP were 19.0% (F1), 53.6% (F2), and 27.4% (F3), respectively. It is worth noting that TCR (1.2 × 10–4) from F2 surpassed the threshold of 1.0 × 10–4, with an unacceptable carcinogenic risk level. As mentioned above, the HM pollutants (i.e., Cd and Cr) and their main sources (i.e., F2) in this area should be considered. These results show that an integrated approach combining risk assessments with the determination of HM concentration and identification of HM source is effective in identifying HM pollutants and sources and provides a good methodological reference for effective prevention and control of HM pollution in farmland.

NICER X-Ray Observations of Eta Carinae during Its Most Recent Periastron Passage

We report high-precision X-ray monitoring observations in the 0.4–10 keV band of the luminous, long-period colliding wind binary Eta Carinae, up to and through its most recent X-ray minimum/periastron passage in 2020 February. Eta Carinae reached its observed maximum X-ray flux on 2020 January 7, at a flux level of 3.30 ×10−10 ergs s−1 cm−2, followed by a rapid plunge to its observed minimum flux, 0.03 × 10−10 ergs s−1 cm−2, near 2020 February 17. The NICER observations show an X-ray recovery from the minimum of only ∼16 days, the shortest X-ray minimum observed so far. We provide new constraints for the “deep” and “shallow” minimum intervals. Variations in the characteristic X-ray temperatures of the hottest observed X-ray emission indicate that the apex of the wind–wind “bow shock” enters the companion’s wind acceleration zone about 81 days before the start of the X-ray minimum. There is a steplike increase in column density just before the X-ray minimum, probably associated with the presence of dense clumps near the shock apex. During the recovery and after, the column density shows a smooth decline, which agrees with previous N H measurements made by Swift at the same orbital phase, indicating that the changes in the mass-loss rate are only a few percent over the two cycles. Finally, we use the variations in the X-ray flux of the outer ejecta seen by NICER to derive a kinetic X-ray luminosity of the ejecta of ∼1041 ergs s−1 near the time of the “Great Eruption.”

Large area silicon drift detectors system for high precision timed x-ray spectroscopy

The current work presents the optimization of large area silicon drift detectors developed by the SIDDHARTA-2 collaboration for high precision x-ray measurements of light exotic atom transitions. Two different radiation sources were employed in the study: an x-ray tube, for investigating the energy resolution and the charge collection efficiency of the device in the range 4000 eV–13 000 eV, and a β − 90Sr radioactive source for measuring the timing response, thus qualifying the charge drift parameters inside the semiconductor. The study reports the spectroscopic response optimization, together with the tuning of the electron dynamics for the given Silicon technology, by adjusting the applied electric field and the working temperature, which allow a good control of the device’s performances for high precision, timed x-ray spectroscopy applications.

High Precision X-ray Measurements 2021

High Precision X-ray Measurements 2021 is a Special Issue related to the HPXM2021 conference, held at the INFN Laboratories of Frascati in 2021 [...]

Construction of complex digital rock physics based on full convolution network

Digital rock physics (DRP) is a paramount technology to improve the economic benefits of oil and gas fields, devise more scientific oil and gas field development plans, and create digital oil and gas fields. Currently, a significant gap is present between DRP theory and practical applications. Conventional digital-core construction focuses only on simple cores, and the recognition and segmentation effect of fractures and pores of complex cores is poor. The identification of rock minerals is inaccurate, which leads to the difference between the digital and actual cores. To promote the application of DRP in developing oil and gas fields, based on the high-precision X-ray computed tomography scanning technology, the U-Net deep learning model of the full convolution neural network is used to segment the pores, fractures, and matrix from the complex rock core with natural fractures innovatively. Simultaneously, the distribution of rock minerals is divided, and the distribution of rock conditions is corrected by X-ray diffraction. A pore–fracture network model is established based on the equivalent radius, which lays the foundation for fluid seepage simulation. Finally, the accuracy of the established a digital core is verified by the porosity measured via nuclear magnetic resonance technology, which is of great significance to the development and application of DRP in oil and gas fields.