In one experiment, having the aperture of the beam, comparable with dimensions of the sample, we compared the real optical damage of the main transparent materials for CO2-lasers: BaF2, NaCl, KCl, KBr, RbI, AgCl, CsI, KРС-5, KPC-6, ZnSe, ZnS, GaAs и Ge. Experimentally and theoretically we compared the nonlinear losses in 13 crystals, when the radiation in the range of 107—4 × 108 W/сm2 passed through them. The «tail» of the impulse was practically completely absorbed by plasma of optical breakdown of air in TEA CO2-laser, but the «peak» — only partially — by «hot» disbalanced charge carriers in the crystal. The losses of laser radiation exponentially depend on band gap of material. he peculiarities of damage Ge single crystals by high power pulsed CO2-laser were investigated. For the first time windows from Ge (diameter — 420 mm) were elaborated, produced and tested. We looked into, how parameters of crystal lattice, admixtures and structure of point defects, which can be changed by influence X -ray irradiation and annealing, can influence on the process of laser volume pores generation in alkali halides. We revealed dependence of pore dimensions from influence conditions, parameters of high-power laser beam, energy of crystal lattice. We studied kinetics of thermal annealing for to diminish dimensions of this pores.
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