High Porosity Research Articles

Removal of sulphur and nitrogen compounds from model fuel by adsorption of modified activated carbon

This study aimed to achieve the highest percentage removal of dibenzothiophene (DBT), quinoline (QUI), and indole (IND) adsorbed by double-impregnated modified activated carbon (MAC). Modification of commercial activated carbon (AC) by sulphuric acid (H2SO4) of 15%, 30%, 45%, 60%, and 75% w/v followed by subsequent 1 zinc chloride (ZnCl2): 1 AC impregnation ratio and activated at 500 oC in a muffle furnace under self-generated atmosphere for an hour. The determination of optimized MAC was identified through the highest removal rate of DBT, QUI, and IND from adsorption experiments which were analysed using an ultraviolet-visible (UV-Vis) spectrophotometer. It was found that DBT and IND showed a removal high percentage of up to 86.23% and 82.77% respectively by using 75% H2SO4 with ZnCl2 MAC. Meanwhile, QUI favoured 30% H2SO4 with ZnCl2 MAC with a removal percentage of 33.17% which was still higher than unmodified AC. Physical and chemical properties such as the morphological structure, elemental analysis, porosity, pore size, surface functional group, percentage yield, pH, bulk density, content, ash content, and iodine number were studied for the optimized MAC. Scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) spectroscopy and Fourier transform infrared spectroscopy (FTIR) were used to characterize the MAC. Both MACs showed high percentage yields of 72.08% and 71.13% for 30% and 75% H2SO4 and ZnCl2 MAC respectively. Meanwhile, the pH was between the ranges of 5.36-5.53 for both MACs. Bulk densities were also favourable while the moisture and ash content were within acceptable limits. Iodine numbers for 30% and 75% H2SO4 and ZnCl2 MAC were 857 and 861 mg/g respectively, hence indicating that the MAC achieved high porosity and good adsorption performance. Langmuir, Freundlich, and Temkin adsorption isotherm models as well as pseudo-first order (PFO) and pseudo-second order (PSO) kinetic models were considered for understanding the adsorption mechanisms. The study revealed that DBT, QUI, and IND removal processes, followed the Langmuir adsorption isotherm model with correlation coefficients, R2 of 0.9905, 0.9791, and 0.9964 respectively. Moreover, the adsorption kinetic data of DBT, QUI, and IND provided a better fitting to the PSO kinetic model with R2 of 0.9992, 0.9987, and 0.9998 respectively. According to the Langmuir isotherm model and PSO kinetic model, the adsorption mechanisms of DBT QUI and IND were chemisorbed under monolayer formations.

Enhancing polymeric bone scaffolds mechanical characteristics using supercritical CO2 foaming and reinforcing agents

BackgroundAs an alternative to conventional medicine, scaffolds have emerged to mimic and/or replace damaged tissue. 3D porous matrix scaffolds made of biodegradable and biocompatible polymers, including PLGA, have proven to be of particular interest for use as bone substitutes in Tissue Engineering. MethodsThe study used high-pressure CO2 foaming to produce PLGA-based foams. Previously, melt-extrusion was used to introduce reinforcement agents, Mg(OH)2, Hydroxyapatite (HAp) and Mg, to achieve foams with improved properties. Foam morphology was analysed using SEM, EDS, and 3D scanner techniques, and foam strength was measured using compression tests. A statistical analysis was carried out to study the effect of pressure and temperature on foams pore size and hardness. Significant findingsThe foams produced were rigid, non-sticky and time-stable, and showed high porosity. The pressure was found to be the only significant variable to tune both porosity and cell densities of scaffolds. Setting a pore size at 500 μm, compressive stresses of 1.85 MPa, 3.81 MPa were achieved for Mg(OH)2 and HAp, respectively. Those results were comparable to literature´s trabecular bovine bone compression resistance of 4.2 MPa. This finding indicated the possibility of getting, at the same time, convenient results for porosity and mechanical resistance for their use as bone replacement agents. Finally, a 20 % w/w ratio of reinforcing agent was found to produce the best pore size-stress ratio.

Highly efficient and reusable polyacrylonitrile-based nanocomposite sorbents for oil spill removal

Nanostructured porous materials are desirable sorbents for separating and removing oil spills from water. This work examines the performance of the prepared efficient sorbents in the oil sorption process. Polyacrylonitrile (PAN) fibers served as the skeleton matrix, while glutaraldehyde and poly(vinyl alcohol) (PVA) served as cross-linking agents. The prepared polymer sorbents showed high adsorption capacity (12.47 g/g), porosity (95.41%) and low density (0.069 g/cm3). The incorporation of carbon nanostructures (nanotubes or graphene oxide) in the sorbent increased the adsorption capacity to 14.85 g/g. The hydrophobic nature of carbon nanotubes significantly increases the contact angle of water with the surface of the nanocomposite absorber and reaches 137.5 degrees. The obtained sorbents showed good reusability in the adsorption process and maintained an adsorption capacity of about 10 g/g after 5 cycles. The optimal temperature range for using nanocomposite sorbents was 25°C to 35°C. The combination of high sorption capacity, low porosity and density in modified polyacrylonitrile, along with its reusability, makes this designed sorbent highly suitable for efficient removal of oil spills.

Application and Challenge of Metal/Covalent Organic Frameworks in Ammonia Sorption and Separation.

As both a critical chemical feedstock and an environmental pollutant, the production and utilization of ammonia (NH3) are accompanied by the progress of social civilization. In recent years, research on metal/covalent organic framework materials as NH3 adsorbents has attracted increasing attention due to their high porosity, versatile architecture and tunable functionality. This review was organized to highlight the recent advancement of MOF/COF materials for NH3 sorption, which successively presented the key properties of solid adsorbents and summarized the strategies along with their mechanisms for enhancing NH3 adsorption. In addition, perspectives and outlook regarding the future development of MOF/COF-based NH3 adsorbents were outlined to meet the requirements of practical applications under various condition.

Flux synthesis of two-dimensional covalent organic frameworks.

Covalent organic frameworks (COFs) are crystalline porous polymers constructed from organic building blocks into ordered two- or three-dimensional networks through dynamic covalent bonds. Attributed to their high porosity, well-defined structure, tailored functionality and excellent chemical stability, COFs have been considered ideal sorbents for various separation applications. The synthesis of COFs mainly employs the solvothermal method, which usually requires organic solvents in sealed Pyrex tubes, resulting in unscalable powdery products and environmental pollution that seriously limits their practical applications. Herein, our protocol focuses on an emerging synthesis method for COFs based on organic flux synthesis without adding solvents. The generality of this synthesis protocol has been applied in preparing various types of COFs, including olefin-linked, imide-linked, Schiff-based COFs on both gram and kilogram scales. Furthermore, organic flux synthesis avoids the disadvantages of solvothermal synthesis and enhances the crystallization and porosity of COFs. Typically, COF synthesis takes 3-5 d to complete, and subsequent washing procedures leading to pure COFs need 1 d. The procedure for kilogram-scale production of COFs with commercially available monomers is also provided. The resulting COFs are suitable for separation applications, particularly as adsorbent materials for industrial gas separation and water treatment applications. The protocol is suited for users with prior expertise in the synthesis of inorganic materials and porous organic materials.

The influence of different diagenesis on the elastic properties of different shale lithofacies: a case study of the upper Permian Wujiaping formation in East Sichuan Basin, China

Understanding the impact of diagenesis on the elastic properties of organic-rich shale reservoirs is essential for evaluating unconventional hydrocarbon reservoirs and interpreting seismic data. Recent advancements in the exploration of the Permian Wujiaping Formation in the eastern Sichuan Basin indicate its potential to become a significant succession within the Sichuan Basin. However, the effect of different lithofacies in the Wujiaping Formation on shale elastic properties under varying diagenetic conditions remains unclear, hindering detailed reservoir interpretation. This study employs X-ray diffraction, thin section analysis, scanning electron microscopy, organic geochemistry, and dynamic elastic property tests to investigate the Wujiaping Formation shale. The results reveal three primary lithofacies types: argillaceous shale, mixed shale, and siliceous shale. Argillaceous shale, subjected to intense compaction, forms a dense rock framework of oriented clay minerals, characterized by low porosity (1.66%), low elastic wave velocity (4122.30 m/s), low elastic modulus (2174.59 m/s), and high Poisson's ratio (32.24 GPa). Mixed shale, dominated by carbonates and quartz, exhibits a rock framework formed through dissolution and cementation, with high elastic wave velocity (5196.54 m/s), relatively high elastic modulus (2975.86 m/s), and moderate Poisson's ratio (58.53 GPa). Siliceous shale, comprising biogenic quartz particles, shows strong resistance to compaction. During hydrocarbon generation, it develops abundant organic matter pores, resulting in the highest porosity (2.36%), high elastic wave velocity (5177.92 m/s), high elastic modulus (2975.86 m/s), and low Poisson's ratio (62.23 GPa). The significant differences in mineral composition and diagenetic processes across the lithofacies lead to distinct elastic properties. This study provides a rock physics framework for the detailed seismic prediction of "sweet spots" in the Wujiaping Formation shale reservoirs and offers new insights into characterizing the diagenesis of unconventional shale reservoirs using geophysical properties.

Restricted Growth of Vinylene-Linked Covalent Organic Frameworks along Two-Dimensional Plane Using Heterogeneous Catalysis.

The vinylene-linked covalent organic frameworks (viCOFs) have been generally synthesized in the presence of homogeneous catalysts such as KOH or trifluoroacetic acid. However, highly ordered viCOFs cannot always be obtained due to the uncommitted growth of viCOF layers in the homogeneous system with ubiquitous catalysts. Here, we propose a scalable protocol to restrict the growth of viCOFs along the two-dimensional (2D) plane by introducing a heterogeneous catalyst, polyoxometalates (POMs). With the unique Brønsted alkalinity and catalytic surface, POMs induce the growth of 2D viCOF layers along the surface of the catalytic substrate and restrain the generation of out-of-plane branches. Based on this protocol, six typical 2D viCOFs with high crystallinity and porosity were synthesized within a shorter reaction time as compared with the reported works using the common homogeneous catalysts for viCOF synthesis. On the basis of the density functional theory calculations and experimental results, a bottom intercalation growth pattern of viCOFs was revealed during the heterogeneous reaction. The unique growth pattern greatly promotes the orderly assembly of monomers, thus shortening the reaction time and improving the crystallinity of viCOFs. Furthermore, this heterogeneous catalysis strategy is suitable for the gram-scale preparation of 2D viCOFs. These results provide a novel avenue for the synthesis of high-quality viCOFs and may bring new insights into the synthetic methodology of COFs.

Metal-organic framework incorporated polybenzimidazole aerogel fibers with dual protections for thermal hazards and chemical warfare agents

Aerogel fibers possess the flexibility of fiber materials and the high porosity and low thermal conductivity of aerogel materials, which hold great promising for applications in thermal insulation and personal protection. However, the inferior mechanical performance and the lack of functionality have impeded the wider applications of these fascinating materials. Herein, we report a novel kind of MOF/polybenzimidazole composite aerogel fibers (CAFs) with both physical and chemical protection functions. The CAFs are fabricated by an oxidation induced sol–gel transition spinning method that utilized the transition of labile imidazole/Co2+ coordination bonds to stable imidazole/Co3+ coordination bonds upon oxidation. The incorporation of MOF has obviously improved the strength and ductility of CAFs due to the good interfacial interactions with matrix and increased crosslinking among polymer chains. The CAFs maintain the high thermal stability and flame retardancy of polybenzimidazole matrix, while the increased porosity and surface area with the addition of MOF have lowered the thermal conductivity and improved the thermal insulation performance of CAFs. The uniform porous skeleton also facilitates the access of chemical warfare agents (CWAs) to MOF inside the fiber. The catalytic experiments show that the CAFs have better degradation effect on CWAs than pure MOF powder, dense composite fiber, and MOF coated fiber. This work is expected to provide an efficient strategy for strong and multifunctional aerogel fibers.

3D Printed PLA Porous Scaffolds with Engineered Cell Size and Porosity Promote the Effectiveness of the Kelvin Model for Bone Tissue Engineering

AbstractIn this study, the aim is to investigate the effect of engineering the cell size and porosity of 3D‐printed poly lactic acid (PLA) porous scaffolds from the Kelvin model for bone tissue engineering applications. The Kelvin model is used as a bone tissue scaffold with different cell sizes and porosities. PLA, as a biodegradable and biocompatible polymer, is used to fabricate these scaffolds using the FDM technique. A compression test is used to evaluate the mechanical properties of scaffolds. The MTT assay has been used to investigate cell viability. For osteogenic differentiation studies, ALP activity and ARS assays are used. Increasing the porosity reduces the mechanical properties of the scaffold. While increasing the cell size at constant porosity increases the Young's modulus and yield stress in the samples, it is also observed that, in high porosities, the increase in cell size weakens the mechanical properties. Also, Kelvin model scaffolds help the proliferation and osteogenic differentiation of cells and have no toxic effect. It is demonstrated that this approach promotes the effectiveness of the Kelvin architecture for bone tissue engineering. As a result, designing the most suitable model based on cell size and porosity for the treatment process in the targeted area could be promising.

Synthesis of Activated Charcoal from Coconut Shell for the Removal of Crude Oil Spill

Crude oil spills have devastating effects on the environment, particularly aquatic ecosystems. The purpose of the present research is to determine whether dry coconut shells can be used as raw materials to make activated charcoal (AC) via pyrolysis and whether they can be utilized as natural sorbents to clean up crude oil spills. The UV-Vis spectrum of the synthesized CSAC shows distinct peaks at 230 and 260 nm, whereas the activated charcoal exhibits peaks at 231 and 261 nm. The FTIR spectra of the synthesized CSAC reveal a medium broad absorption peak at 3307.2 cm⁻¹, while the raw coconut shell's FTIR spectra show a medium sharp peak at 2945.3 cm⁻¹. The SEM images highlight the unique structural properties of CSAC, showcasing high porosity, varied pore sizes, rough surface topography, and the presence of micropores and mesopores. The chemical activation significantly increased the hydrophobicity of the adsorbent, creating CSAC with a much better adsorption capacity for crude oil removal, having a maximum adsorption capacity of 4840.0 mg/g and the highest percentage of crude oil removal at 99.9985%, as proven by batch experiments for different adsorbent dosages. The batch experimental results indicated that the percentage of crude oil removal increased with an increase in adsorbent dosage and contact time. Based on the correlation coefficients (R²) values (close to unity), it was generally observed that the plots match the Freundlich isotherm better than the Langmuir isotherm model. These findings have made the synthetic CSAC an attractive, useful, and environmentally friendly adsorbent.

Recent strategies to improve the electroactivity of metal–organic frameworks for advanced electrocatalysis

AbstractMetal–organic frameworks (MOFs) have emerged as promising materials in the realm of electrocatalysis due to their high surface area, tunable porosity, and versatile chemical functionality. However, their practical application has been hampered by inherent limitations such as low electrical conductivity and a limited number of active metal sites. Researchers addressed these challenges through various strategies, including enhancing conductivity by incorporating conductive materials and metal nanoparticles, modifying the structure and composition of MOFs by replacing metal nodes and functionalizing linkers, and preparing MOFs catalysts through thermal processes such as decarburization and conversion into metal oxides, phosphides (MPs), and sulfides (MSs). This review provided a comprehensive summary of the strategies that were employed to enhance the electroactivity of MOFs for improved electrocatalytic performance in recent years. It also explored future directions and potential innovations in the design and synthesis of MOF‐based electrocatalysts, offering valuable insights for advancing their application in sustainable energy technologies.

Seismic Inversion Techniques and Attribute Analysis for Accurate Well Placement in Offshore Niger Delta Basin, Nigeria

Before this study, simple methods like seismic attribute analysis have often been used for reservoir characterization with successes however, there is still the need to reduce exploration uncertainty to a negligible level and boost investors’ confidence. This study integrated seismic inversion with seismic attribute analysis to better characterize the reservoirs in MTW Field in deep-offshore Niger Delta Basin. Five (5) wells with complete suite of petrophysical logs, three-Dimensional (3-D) seismic data, checkshot and other well information were used. The well data were thoroughly quality checked, reservoirs were litho-stratigraphically delineated and used for petrophysical analysis across the wells. This was followed by seismic-to- well-tie, seismic interpretation, and seismic attribute analysis (Root Mean Square-RMS) generated using depth surface maps. 3-D static reservoir model and volumetric evaluation were carried out. Petrophysical properties were derived and distributed across the 3-D static model using sequential gaussian simulation algorithm to ascertain shale volume spread across the model. To improve the seismic resolution and reduce interpretation uncertainty at greater depth, model- based post-stack seismic inversion was performed to obtain acoustic impedance cube. Litho-stratigraphic and petrophysical analysis result revealed five reservoir sands (A, B, C, D, and E). Reservoir-A was seen to be more viable with a thickness of 13.42 m, high effective porosity of 27%, permeability of 3187.53 mD, low water saturation of 34% and low shale volume of 11% which are indication good reservoir quality and producibility. The seismic interpretation revealed thirty-one (31) growth and antithetic faults oriented in the NE-SW and NW-SE directions, respectively. The RMS result revealed high amplitude reflectivity which is a measure of zone of interest. Based on this, seven (7) prospects and three (3) leads were identified. The seismic inversion result shows a high level of accuracy with a correlation coefficient of 0.997; 0.997; 0.995; and 0.996 in MTW-001, MTW-003ST1, MTW-004ST1 and MTW-005 wells, respectively. The acoustic impedance successfully resolved and improved on the resolution of the seismic stacking velocity especially at reservoir layers and at depth deeper than 3600 ms. Acoustic impedance as a layer property has improved on the lateral and vertical resolutions of the data beyond what the usual seismic interval velocity could image thus, validating some of the prospects and leads identified in this study. This demonstrated that uncertainty can be reduced by a blend of RMS and seismic inversion in identifying reservoir for accurate placement of wells. It is therefore recommended that E and P operators should adopt the technique in their future hydrocarbon exploration endeavor in frontier and matured basins.

Rough and porous silica-modified fiber membranes decorated with oleic acid for ultra-high flux and pH-responsive oil/water separation

The design of fiber membranes with both ultra-high flux and pH-responsive oil/water separation is challenging but of great significance to environmental protection and human health. In this work, the pH-responsive fiber membranes were prepared by immersing the silica-modified polyacrylonitrile fiber substrates into oleic acid solution. The obtained membranes exhibited highly rough surface structures (Ra = 14.26 µm), large pore sizes (5.35 µm), high porosities (86.04%), and pH-responsive functional groups, respectively. The pH-responsive fiber membranes also had superhydrophobic surfaces and excellent selective separation for oil/water mixtures, for example, a trichloromethane permeation flux of 87,829 L m-2h-1 for immiscible oil/water separation, and a water permeation flux of 69,802 L m-2h-1 after turning the pH of water from 7 to 13. The above data were much higher than those of stimulus-responsive fiber membranes used for oil/water separation. In addition, the pH-responsive fiber membranes were also used for separating water-in-oil emulsions and oil-in-water emulsions, and achieved the highest separation flux of 15,120 L m-2h-1. This work provides a simple strategy for the preparation of a stimulus responsiveness and high-performance material that can be used in the direction of treating practical oily wastewater.

Zeolitic imidazolate framework-8 as a high-affinity adsorbent for dispersive solid-phase extraction in the analysis of plant growth regulators in fruits.

Facile and sensitive determination of plant growth regulators (PGRs) in food samples is crucial but still poses a significant challenge. In this study, to enhance the sensitivity of the HPLC-DAD method for PGR detection, a dispersive solid phase extraction (d-SPE) method using zeolitic imidazolate framework-8 (ZIF-8) as the highly effective adsorbent is developed. ZIF-8 nanoparticles are formed through the coordination of Zn2+ with 2-methylimidazole. Due to its high porosity, large surface area, abundant π electronics and nitrogen electronics, ZIF-8 exhibits a strong affinity to PGRs due to the synergistic effects of π-π interaction, van der Waals force, H-bond, and surface effect. Under the optimal d-SPE conditions, the sensitivity of the method is significantly enhanced with outstanding performances, including a wide range of linearity (2.0-200 ng g-1) with high correlation coefficients (R ≥ 0.9989), low limits of detection (LODs, 0.9-8.0 ng g-1 for all PGRs), satisfactory precision (intra-day RSDs ≤ 3.3%, inter-day RSDs ≤ 4.2%), and high accuracy (recovery: 86.6-101.5%). The developed method was successfully applied to quantitatively detect 9 PGRs in fruit samples, yielding satisfactory results. This d-SPE-HPLC-DAD method, characterized by high sensitivity, simplicity, efficiency, ease of practice and cost-effectiveness for PGR detection, shows potential for detecting PGRs in other complex samples and provides a strategy for designing target-affinity adsorbents.

Boronic acid-functionalized magnetic covalent organic frameworks based solid-phase extraction coupled with hydrophilic interaction chromatography-tandem mass spectrometry for the determination of trace gentamicin residues in milk

Boric acid-functionalized magnetic covalent organic frameworks (Fe3O4-TpBD-B) with large surface area and high porosity were prepared and applied for magnetic solid-phase extraction adsorbent of gentamicin from milk before UPLC-MS/MS detection. By utilizing a new HILIC chromatographic column with zwitterionic sulfoalkyl betaine stationary phase based on ethyl bridged hybrid particles (BEH), isomers of gentamicin (C1, C1a, and C2+C2a components). The developed methods demonstrated good linearity (R2 > 0.99), acceptable accuracy and good precision (<10 %), and low limit of quantitation (1.59 ng mL⁻1 for C1, 1.52 ng mL⁻1 for C1a and 2.72 ng mL⁻1 for C2+C2a). In addition, this method has been effectively applied to the analysis of real milk samples.

Wetting-induced collapse of loess: Tracing microstructural evolution

Loess is a silt-dominated, clastic yellow-to-yellowish brown aeolian sediment with high porosity and low density. The metastable microstructure of loess makes it highly susceptible to collapse, which plays a major role in landform evolution, geohazard development and engineering damages, particularly the widespread occurrences of settlement, deformation and cracking of civil engineering structures. Differing from the existing investigations based on pre- and post-collapse comparison, the present study is to report the microstructural changes during the collapse process and to determine how each microstructural constitutive element participates in this process. A series of laboratory tests was conducted on undisturbed loess specimens to simulate and capture snapshots of microstructure at five representative points during the entire collapse process. Results show that the loess microstructure becomes more homogeneous as the outstanding macropores are crushed into smaller (meso- and mini-pores) pores, the number of pores is dramatically increased, and the pore throats become narrower. The pore shapes have no obvious changes and remain elongated and rough-edged morphology from the point of view of statistic. Regarding solids, the pre-collapse unstable point-to-point contacts tend to transform into relatively stable edge type contacts, whilst coarse particles tend to reorient along the horizonal direction. XRD, SEM and EDS analysis indicates that these changes in the nature and distribution of pores and particles result from (1) the breakage and disintegration of moderately to highly weathered particles, (2) the disintegration of the matrix due to the swelling of clay minerals and the dissolution of calcium carbonates, (3) the consequential modifications of the microscopic forces which lead to slipping, rotation and therefore dislocation of particles, and (4) the collapse of mesoscale force chains along particles, reforming on smaller scales with larger numbers, shorter lengths and horizontal alignments.

Effect of laser process parameters on the pores, surface roughness, and hardness of laser selective melting of dental cobalt-chrome alloys.

To address the quality problems caused by high porosity in the preparation of dental cobalt-chrome alloy prosthetics based on selective laser melting (SLM) technology, we investigated the influence mechanism of different forming process parameters on the microstructure and properties of the materials. Moreover, the range of forming process parameters that can effectively reduce defects was precisely defined. The effects of laser power, scanning speed, and scanning distance on the pore properties, surface roughness, and hardness of dental cobalt-chrome alloy were investigated by adjusting the printing parameters in the process of SLM. Through metallographic analysis, image analysis, and molten pool simulation, the pore formation mechanism was revealed, and the relationship between the porosity and energy density of SLM dental cobalt-chrome alloy was elucidated. When the linear energy density was higher than 0.18 J/mm, the porosity defect easily appeared at the bottom of the molten pool. When the laser energy density was lower than 0.13 J/mm, defects occurred in the gap of the molten pool due to insufficient melting of powder. In particular, when the linear energy density exceeded the threshold of 0.30 J/mm or was below 0.12 J/mm, the porosity increased significantly to more than 1%. In addition, we observed a negative correlation between free surface roughness and energy density and an inverse relationship between macroscopic hardness and porosity. On the basis of the conditions of raw materials and molding equipment used in this study, the key process parameters of SLM of molding parts with porosity lower than 1% were successfully determined. Specifically, these key parameters included the line energy density, which ranged from 0.13 J/mm to 0.30 J/mm, and the scan spacing should be strictly controlled below 90 μm.

The influence mechanism of water-liquid CO2 treatment on the hydrophobicity of vitrinite and inertinite

Liquid CO2 has similar properties to non-polar hydrocarbon oils and can be used to achieve hydrophobic aggregation separation of coal macerals. To reveal the influence of the water-liquid CO2 treatment on the interfacial properties of vitrinite and inertinite, the effects of the water-liquid CO2 system on the interfacial properties of vitrinite and inertinite were investigated by SEM, BET, FTIR, and XPS. The results showed that the content of oxygen-containing functional groups on the coal macerals were reduced more significant than the hydrocarbons due to the physical adsorption and chemical extraction of liquid CO2, which led to an increase in the hydrophobicity of vitrinite and inertinite. The higher porosity and specific surface area of inertinite causing the decrease in the content of oxygen-containing functional groups in inertinite was greater than that in vitrinite. This study provides theoretical support for the separation of coal macerals using liquid CO2 hydrophobic agglomerates.

Construction of heterojunctions with in situ growth of ZnIn2S4 nanosheets on the surface of atomically dispersed Cu-modified MOFs for high-performance visible-light photocatalytic antibiotic degradation

Metal-organic frameworks (MOFs) are ideal candidates for obtaining composites with excellent photocatalytic properties due to their reasonable band gaps and high specific surface area. In this study, Cu@UiO-66-NH2@ZnIn2S4 nanocomposites were prepared by a two-step photoinduction method and hydrothermal method. The prepared catalysts in a range of ratios showed high visible light degradation of tetracycline hydrochloride (TC). Among them, 10 %-Cu@UIO-66-NH2/ZnIn2S4 showed the best catalytic activity and photoelectrochemical performance. In this catalytic system, the high specific surface area and porosity of UIO-66-NH2 provide sites for the high dispersion of Cu. In addition, the introduction of Cu also reduces the band gap, which is conducive to the electron transfer between the interfaces, which results in the formation of type II heterojunctions with a unique and highly efficient electron transfer mechanism, and also enables the photocatalytic process to generate more active radicals (O2–, OH, h+). In addition, the stability of the catalyst was tested, as well as the possible degradation pathways were hypothesized to evaluate its toxicity. Thus, this study provides a strategy for the preparation of stable and efficient photocatalysts

Superamphiphilic aerogels with 2D lamellar structure of gelatin-tuned 3D supramolecular network of collagen fibers for high-performance separation of surfactant-stabilized emulsified oily wastewater

Superwetting aerogel is a promising alternative for the remediation of emulsified oily wastewater for its high porosity combined with extreme wettability enabled high separation performances to emulsion wastewater. However, it remains challenging for superwetting aerogels to accomplish high-performance dual separation to surfactant-stabilized oil-in-water (O/W) and water-in-oil (W/O) emulsions with high stability. Herein, an environmentally benign superamphiphilic composite aerogel was prepared by a green synthesis route that relied on the utilization of natural amphiphilic biomass. Collagen fibers (CFs) were utilized to construct the three-dimensional (3D) supramolecular skeleton of aerogel to provide high storage capacity of water/oil and outstanding capillary effect to boost the mass transfer. The two-dimensional (2D) lamellar structure of gelatin (Gel) was further grown on the skeleton of CFs aerogel to play the role for simultaneously enhanced demulsifying capability and spreading of emulsions. The as-prepared superamphiphilic aerogel enabled the separation of highly stable surfactant-stabilized O/W and W/O emulsions with high separation efficiency and flux. Excellent recycling performances and anti-fouling performance were also confirmed. Our investigations therefore demonstrated that the structural engineering of superamphiphilic aerogel is a promising way to realize high-performance dual separation of surfactant-stabilized O/W and W/O emulsion wastewater.Graphical