This work introduces a new higher-order accurate super compact (HOSC) finite difference scheme for solving complex unsteady three-dimensional (3D) non-Newtonian fluid flow problems. As per the author's knowledge, the proposed scheme is the first ever developed higher-order compact finite difference scheme to solve 3D non-Newtonian flow problems. The proposed scheme is fourth-order accurate in space and second-order accurate in time, utilizing only seven adjacent grid points at the (n+1)th time level for the finite difference discretization. A time-marching methodology is employed with pressure calculated via a pressure-correction strategy based on the modified artificial compressibility method. Using the power-law viscosity model, we tackle the benchmark problem of a 3D lid-driven cavity, systematically analyzing the varied rheological behavior of shear-thinning (n = 0.5), shear-thickening (n = 1.5), and Newtonian (n = 1.0) fluids across different Reynolds numbers (Re=1,50,100,200). Both Newtonian and non-Newtonian results are carefully investigated in terms of streamlines, velocity variation, pressure distributions, and viscosity contours, and the computed results are validated with the existing benchmark results. The findings demonstrate excellent agreement with the existing results. It is found that for shear-thinning fluid (n = 0.5), u velocity is higher near the top moving wall than the case of Newtonian (n = 1.0) and shear-thickening fluid (n = 1.5) for all Re values. This extensive analysis, using the new HOSC scheme, not only increases our understanding of non-Newtonian fluid behavior but also provides a robust foundation for future research and practical applications.