As Mach number increases, thermochemical nonequilibrium is recognized as potentially affecting the flow field structure, as well as mixing and combustion characteristics, where shock-induced thermochemical nonequilibrium is a common and crucial phenomenon in compressible flow fields. A numerical study of shock-induced thermochemical nonequilibrium effects within a high Mach flow field of the electre vehicle is conducted by employing a two-temperature model-based solver hy2foam. The validation through experimental and simulation data confirms that hy2foam coupled with Park's two-temperature model and Park's five-species mechanism correctly predicts the flow structure and nonequilibrium characteristics. Four regime cases of thermochemical equilibrium, thermal nonequilibrium, chemical nonequilibrium, and thermochemical nonequilibrium are designed for comparison. First, the mechanism of shock-induced nonequilibrium is revealed. The shock induces the thermal nonequilibrium to occur instantly, and then the equilibrium is reestablished by undergoing the relaxation process. However, chemical nonequilibrium works delayed after the shock, and the high temperature induced by the shock motivates deviation from the chemical equilibrium by turning on chemical reactions. Further comparison of the four cases reveals that thermodynamic nonequilibrium significantly affects both shock position and intensity. In contrast, chemical nonequilibrium only significantly affects the distance to the shock detachment. Furthermore, it is found that thermodynamic and chemical nonequilibria behave in a complex coupling relationship after the shock.
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