High-grade Metasedimentary Rocks Research Articles

Detrital zircon U–Pb age constraints on the Meso-Tethys Ocean closure in SE Asia

Abstract The location of the Meso-Tethyan suture in SE Asia is ambiguous due to the strong overprint by the later India–Asia collisional tectonics. For the SE Asian extension of the Meso-Tethyan Bangong–Nujiang Suture (BNS) in Tibet, the two main candidates are the Longling–Ruili Suture (between the Tengchong and Baoshan blocks) and the Myitkyina ophiolite belt. Here, we present new detrital zircon U–Pb ages from high-grade metasedimentary rocks of the Gaoligong Group, which is considered to be the basement of the Tengchong Block located between the Longling–Ruili Suture and Myitkyina ophiolite belt. Our data suggest that the Gaoligong Group contains Cambrian, Triassic and Cretaceous zircons and is not a Precambrian basement, with a diagnostic age population peak at c. 1110 Ma. This peak is comparable to the c. 1170 Ma peak reported in the Australia-derived blocks (e.g. Lhasa and West Australia). Such similarities, as well as the similarities in the stratigraphy, palaeobiogeography and magmatic history of the Tengchong Block, suggest that the Tengchong Block was located adjacent to the northern Australia margin in Gondwana, and was most likely to have been linked with the Lhasa Block (southern Tibet) since the Early Paleozoic. Thus, the Longling–Ruili Suture is likely to represent a continuation of the Meso-Tethyan BNS in SE Asia.

U-Pb zircon ages from metasedimentary and plutonic rocks in the Bras d'Or terrane of Cape Breton Island, Nova Scotia, Canada: insights into the Ediacaran–Cambrian tectonomagmatic evolution of Ganderia

The Bras d'Or terrane of central Cape Breton Island, Nova Scotia, Canada, contains a well-preserved record of the Ediacaran to early Cambrian evolution of Ganderia, a Gondwana-derived terrane in the northern Appalachian orogen. A complex assemblage of low- to high-grade metasedimentary rocks has varied detrital zircon signatures from laser ablation inductively coupled plasma mass spectrometry U-Pb zircon dating, but combining three or more samples yielded representative age spectra that support correlation of the low- and high-grade metasedimentary rocks throughout the Bras d'Or terrane and the corresponding Ganderian Brookville terrane of southern New Brunswick. In quartzite samples from the McMillan Flowage Formation in the northwestern Bras d'Or terrane, the youngest detrital zircons have ages >900 Ma, in contrast to previously studied psammitic and semipelitic samples from correlative units in the eastern Bras d'Or terrane in which youngest detrital ages are 620–600 Ma. Both quartzite and semipelitic samples from the McMillan Flowage Formation contain Neoproterozoic dates from zircon rims, which reflect metamorphic overgrowths during peak metamorphism at ca. 550 Ma, providing a robust age for peak metamorphism in the Bras d'Or terrane that supports similar, albeit sparse, ages reported previously from monazite and titanite samples. This metamorphism is coeval with the emplacement of voluminous dioritic to granitic plutons that occur throughout the Bras d'Or terrane and form in an Andean-type continental margin subduction zone. New U-Pb zircon ages presented here from plutons in the northern Bras d'Or terrane, combined with previously published ages, are consistent with subduction-related magmatism and associated metamorphism between ca. 575 and 540 Ma.

Geochronological constraints of high-grade metasedimentary rocks of the Italva and Costeiro basins: Reconstructing the Outer Magmatic Arc System of the ribeira belt, SE Brazil

U-Pb provenance studies of the magmatic arc-related basins of the Ribeira Orogen are essential to unravel the depositional history and the paleogeography prior to the diachronic collision that has resulted in Neoproterozoic to Cambrian Western Gondwana assembly. This work brings new geology and LA-ICPMS data from metasedimentary units and felsic to mafic magmatic rocks that compose the Outer Magmatic Arc System (OMAS) in the Ribeira segment of the Araçuaí-Ribeira Orogenic system (AROS), contributing to unravel the construction of the West-Gondwana supercontinent. The OMAS evolution started in Tonian time (860–790 Ma) as the juvenile intra-oceanic Serra da Prata arc and evolved into the immature continental Rio Negro arc during the Cryogenian-Ediacaran times (650–620 Ma). The long-term subduction revealed the coeval stages development of arc-related basins. In the first Tonian stage, basin development is associated with the Italva group, divided into two sequences representing both fore and back-arc settings. The forearc sequence (Euclidelândia unit) comprises meta-psammitic sedimentary rocks with a single provenance source from the SP arc (peaks at 812 Ma and 828 Ma). The back-arc sequence (São Joaquim unit) consists of marbles with MORB-like interlayered amphibolites (ca. 831 Ma) bracketing the maximum age of carbonatic platform deposition. On the other hand, the younger Cryogenian to Early Ediacaran Costeiro back-arc basin is represented by three units of the São Fidélis group. The proximal Macuco unit, comprising meta psammitic rocks with marble, yielded a bimodal provenance distribution (852–815 Ma; 643–634 Ma), which reflects only the SP and RN magmatic arcs sources. The pelitic distal Upper and Lower units point out multimodal sources, coming from the SP-RN arc-rocks (ca 950–734 Ma; ca. 693–621 Ma) and Archean to Mesoproterozoic sources (ca. 3.12–3.0 Ga; 2.98–2.49 Ga; 2.29–1.50 Ga; 1.49–1.01 Ga), derived from ancient cratonic blocks located eastern wards, in African side. All units of the OMAS recorded two metamorphic episodes, with the oldest M1 (ca. 600–590 Ma) related to the collision of the OMAS against the Inner Magmatic Arc System (IMAS) and the younger M2 (ca. 545–533 Ma) that resulted from the final docking of the Cabo Frio terrane (Angola block) and finally closed the OMAS back-arc basin. Data obtained reinforces the long-term E-verging subduction that built the OMAS.

Mesozoic crustal melting and metamorphism in the U.S. Cordilleran hinterland: Insights from the Sawtooth metamorphic complex, central Idaho

In this study, we present whole-rock geochemistry and Sm-Nd data; zircon trace element, U-Pb, and Lu-Hf data; titanite U-Pb dating; and structural analysis of igneous and metasedimentary rocks of the Sawtooth metamorphic complex that provide insight into regional metamorphism, partial melting, and crustal thickening in the Idaho batholith segment of the Cordilleran orogen. Four magmatic events are revealed: (1) pre-tectonic felsic magmatism at ca. 156 Ma, (2) syn-tectonic mafic and felsic magmatism between ca. 100 Ma and ca. 92 Ma, (3) felsic magmatism concurrent with late-stage deformation at ca. 89−84 Ma, and (4) post-tectonic felsic magmatism at ca. 77 Ma. The multiple generations of felsic magmatism include a variety of sedimentary- and igneous-derived granitoids distinguished by zircon trace element compositions (e.g., U/Ce versus Th and Ce/Sm versus Yb/Gd) and were sourced from progressively more evolved crustal components as shown by Lu-Hf and Sm-Nd isotopic data. U-Pb data of metamorphic zircons and titanites from high-grade metasedimentary rocks suggest that regional metamorphism occurred from ca. 100−93 Ma, which was characterized by granulite-facies partial melting and concurrent growth of metamorphic zircons and garnets. The episodic magmatism in the Sawtooth metamorphic complex records pervasive melt migration in a hot, mid-crustal setting at ca. 100‒92 Ma and additional magma ascent in a cool, upper-crustal setting at ca. 77 Ma. The uplift of the Sawtooth metamorphic complex from mid- to upper-crust was likely caused by underthrusting at lower crustal levels coupled with erosion and thinning of the upper crust. This work suggests that the crust of the Cordilleran hinterland in the Idaho batholith region underwent significant thickening from ca. 100‒84 Ma, and a crust of Andean-like thickness was probably achieved by ca. 84 Ma. By ca. 77 Ma, the central Idaho crust started to thin likely due to mid-crustal flow and surface erosion. The new data from the Sawtooth metamorphic complex are consistent with the two major magmatic flare-ups in the Late Jurassic and Late Cretaceous in the U.S. Cordilleran orogen.

Sulfur isotope behavior during metamorphism and anatexis of Archean sedimentary rocks: A case study from the Ghost Lake batholith, Ontario, Canada

Recycling of surface-derived sulfur into the deep earth can impart distinct sulfur isotope signatures to magmas. The details of sulfur transfer from sedimentary rocks to magmas (and ultimately igneous rocks) through metamorphism and devolatilization and/or partial melting, however, is difficult to trace. To understand this process in detail we studied multiple-sulfur isotope compositions of sulfides in the Archean (c. 2685 Ma) Ghost Lake batholith (GLB) and its surrounding host metasedimentary rocks of the Superior Craton (Ontario, Canada) by high spatial resolution secondary ion mass spectrometry, complemented by high-precision gas source isotope ratio mass spectrometry measurements. The GLB comprises strongly peraluminous biotite+cordierite, biotite+muscovite, and muscovite+garnet+tourmaline granites to leucogranites, which are thought to represent the partial melts of surrounding metagreywackes and metapelites. The metasedimentary rocks display a range of metamorphic grades increasing from biotite-chlorite (280-380°C) at ∼5 km away from the GLB to sillimanite-K-feldspar grade (∼660°C) immediately adjacent to the batholith, thus providing a natural experiment to understand sulfur isotope variations from low- to high-grade Archean sedimentary rocks, as well as granites representative of their partial melts.We find that metasedimentary sulfide δ34S values increase with progressive metamorphism at most 2-3‰ (from −1‰ up to +1 to +2‰). An increase in δ34S values in pyrrhotite during prograde metamorphism can be explained through Rayleigh fractionation during pyrite desulfidation reactions. Pyrite from all but one of the granite samples preserve δ34S values similar to that of the high-grade metasedimentary rocks, indicating that partial melting did not result in significant fractionation of δ34S. The exception to this is one granite sample from a part of the batholith characterized by abundant metasedimentary inclusions. This sample contains pyrite with heterogeneous and low δ34S values (down to −16‰) which likely resulted from incomplete homogenization of sulfur between the granitic melt and metasedimentary inclusions. Small (several tenths of a permil), mostly positive Δ33S are observed in both the metasedimentary rocks and granites.Our results suggest that Archean strongly peraluminous granites could be a high-fidelity archive to quantify the bulk sulfur isotope composition of the Archean siliciclastic sediments. Further, our findings indicate that subduction of reduced sulfur-bearing sediments in the Archean with δ34S at or near 0‰ should result in release of sulfur-bearing fluids in the mantle wedge with similar values (within a few permil). S-MIF (if initially present in Archean surface material) may be preserved during this process. However, the absence of S-MIF in igneous rocks does not preclude assimilation of Archean sedimentary material as either S-MIF may not be originally present in the Archean sedimentary sulfur and/or homogenization or dilution could obscure any S-MIF originally present in assimilated Archean sediments.

Spatiotemporal constraints on the western Cauaburi Belt tectonics – northwestern Amazon Craton, Brazil

ABSTRACT The study of Precambrian tectonics is an intricate task, demanding a holistic approach to take an accurate view of geologic history. Here we attempt to set up the overview of an Orosirian-Statherian continental arc in the northwestern Amazon Craton, the Cauaburi Belt. Field relations, petrological, geochemical, and geochronological data of calc-alkaline metagranitoids, high-grade metasedimentary rocks, and peraluminous metasyenogranites yielded new interpretations about its tectonic evolution. The record of intense and episodic calc-alkaline magmatism between ca. 1805 and 1759 Ma, assign to the Cauaburi Complex, with field evidence of magma mixing and lodgement in a compressional tectonic regime, suggest a continental arc as the tectonic setting. During the magmatic lulls, deformation and metamorphism increase, culminating with the partial fusion of the high-grade metasedimentary rocks of the Taiuaçu-Cauera Complex. This succession composes the precursor paleobasin, presenting maximum and minimum depositional ages of 1819 and 1794 Ma, and was a relevant source for the calc-alkaline magmatism. The geochronological record of a low-volume production of peraluminous crustal rocks (Igarapé Tocandira Granite), with crystallization age at ca. 1791 Ma and metamorphic age at ca. 1771 Ma, also highlights the time and effect of the magmatic lulls. The Cauaburi Belt structural framework follows a general E-W to ENE-WSW trend, expressed in the Paleoproterozoic rocks as syn-magmatic and solid-state deformation fabrics. Assuming that Columbia Supercontinent nucleus assembled in the late Orosirian, we interpret that this coeval continental arc developed at its border and followed a north-south shortening direction, at current orientation.

Zircon oxygen and hafnium isotope decoupling during regional metamorphism: implications for the generation of low δ18O magmas

Measurements of U–Th–Pb, Lu–Hf and oxygen isotopes as well as selected trace and rare earth elements were carried out on zircon grains from high-grade metasedimentary rocks from the Albany–Fraser Orogen in southwest Australia. Oxygen isotopes from detrital zircon domains yield δ18O (VSMOW) values ranging from 5.8 to 8.0‰ and exhibit coupled Hf- and O-isotope compositions. In contrast, metamorphic zircon domains show considerably less variability in O-isotope compositions with a median δ18O of 5.6 ± 0.5‰ and exhibit decoupled Hf- and O-isotope compositions. 176Hf/177Hf isotope ratios of metamorphic zircon grains are within the evolutionary trend defined by the detrital grains implying negligible input from external sources during their growth. In addition, the relatively low δ18O value of the metamorphic zircons implies crystallisation from a relatively 18O depleted crustal melt. Such δ18O values are lower than those typically observed in most metamorphic zircon, including those preserved in partial melts of metasediments (10–12‰) and suggest that the sedimentary protolith was hydrothermally altered by meteoric fluids prior to high-temperature metamorphism. We suggest that alteration of the sedimentary protolith is related to the proximity to the Fraser Shear Zone, a major crustal scale structure within the orogen, which may represent an old reactivated structure. Occurrences of low δ18O metamorphic zircon, and potentially also low δ18O igneous rocks, in ancient collisional settings may, therefore, delineate long-lived fluid pathways within the crust.

Chafalote Metamorphic Suite (Uruguay): Reflections on the evolution of the Punta del Este Terrane

The Chafalote Metamorphic Suite, located in the Uruguayan sector of the Punta del Este Terrane, southeasternmost Dom Feliciano Belt, comprises semipelitic, migmatitic metapelites, mafic granulites, and calc-silicate/amphibolitic gneisses. These supracrustal rocks occur as roof pendants in a granodiorite belonging to the Cerro Olivo Complex. The main structure of the Chafalote Metamorphic Suite is a composite S0/S1 banding, related to the main deformation event (D1) developed under upper-amphibolite/granulite facies conditions. This work presents an integrated study on the latter rocks, involving different geochronological methods (monazite U-Pb LA-ICP-MS and zircon U-Pb SHRIMP) and whole rock Sm-Nd isotope data in order to better understand the metamorphic evolution of the Chafalote Metamorphic Suite during the amalgamation of the SW Gondwana paleocontinent in the Neoproterozoic. The studied rocks record a peak metamorphic event (M2) occurred at around 660 Ma (monazite U-Pb ages), which was followed by decompression and partial melting (M3 event) at around 640 Ma (zircon U-Pb ages), probably during the late stages of the D1 event. The retrograde methamorphic event (M4) is related to the transition between the D1 and the development of NE-SW striking, low-grade sinistral shear zones (D2 event) and intrusion of syn-to post-orogenic Brasiliano granitoids of the Aiguá Batholith at around 600 Ma. The metamorphic conditions, together with geochronological and isotopic similarities, allow the correlation between the studied high-grade metasedimentary rocks and those from the Paso del Dragón Complex in Uruguay, and from the Várzea do Capivarita, Arroio Grande, and Telho Complex in Brazil. The latter rocks possibly share similar source areas and represent different portions of the Neoproterozoic fore-arc and/or back-arc basins developed in the Dom Feliciano Belt during the Brasiliano/Pan-African orogenic cycle.

Geochemistry, zircon U-Pb and Lu-Hf systematics of high-grade metasedimentary sequences from the South Muya block (northeastern Central Asian Orogenic Belt): Reconnaissance of polymetamorphism and accretion of Neoproterozoic exotic blocks in southern Siberia

High-grade metasedimentary rocks of the South Muya block (Baikal-Muya Foldbelt) have been studied with respect to whole-rock elemental and Nd isotopic compositions, as well as the U-Pb and Lu-Hf systematics of detrital zircon and in-situ grown metamorphic grains in order to reveal the initial source provenance for sedimentation and the age of major metamorphic modification. Based predominantly on trace-elemental compositions, the sedimentary protolith is most likely a poorly sorted and immature greywacke, such as those formed in island arc or active continental margin settings. The island arc-related chemical signature coupled with zircon U-Pb age data supports a Neoproterozoic (>760 Ma) sedimentation age, whereas Nd-Hf isotope data of precursor sediments are linked to a relatively immature Tonian (∼940–780 Ma) continental arc involving Paleoproterozoic crustal basement. The limited provenance information and metamorphic history of the Muya block suggests it was exotic to Siberia and originally related to another continent, e.g. – subduction-accretion complexes of South China. The polyphase metasediments experienced high-grade metamorphism in the Tonian during the 764–754 Ma arc accretion to an enigmatic continental block and then in the Ediacaran during the 622–608 Ma accretion of the Baikal-Muya belt to the arc situated at the southern Siberia margin. Metamorphic overprinting during the introduction of supracrustal rocks to deeper-crustal levels led to protracted recrystallization of primary igneous zircon population and growth of new granulite-facies grains that did not involve notable juvenile input. Tonian sedimentary provenance and two metamorphic events suggest a protracted evolution for the Baikal-Muya belt associated with the formation of precursor complexes beyond the southern margin of Siberia and their later accretion to Late Cryogenian – Ediacarian arc complexes of the southern Siberian, which proceeded only after the opening of the Paleoasian Ocean (670–630 Ma).

Zircon U-Pb age constraints for Tonian-early Cryogenian deposition of metasedimentary rocks from the Schirmacher Oasis, East Antarctica: Implications for correlations across the Mozambique Ocean

Schirmacher Oasis, central Dronning Maud Land, East Antarctica, a dispersed fragment of the 660-610 Ma East African Orogen (EAO), exposes platformal-facies high-grade metasedimentary rocks. Here we constrain the depositional age of these sedimentary rocks to test models relating to timing of the closure of the Mozambique Ocean, the southern segment of the EAO, since Tonian time. Zircon, a proxy for detritus, was dated by LA-MC-ICPMS (206Pb/238U ages) that includes both magmatic and (older) metamorphic populations, in addition to those formed during the granulite-facies metamorphic events (660-600 Ma and 580-555 Ma) having an age range between 1240 and 500 Ma. In conjunction with field evidence, their depositional time is constrained to the Neoproterozoic (Tonian to early Cryogenian, i.e. 1000 >Tdep >800 Ma and 930 >Tdep>800 Ma) with their provenance likely dominated by metamorphic (orogenic) over magmatic rocks.These metacarbonate and psammitic rocks are correlated with similar rocks from the Montepuetz Complex, Northeastern Mozambique, metacarbonate rocks from the Sør Rondane Mountains and with the Linta Group, Vohibory Domain, Southeastern Madagascar. The coeval deposition of platformal sedimentary protoliths, interpreted as occurrence of multiple Mozambique Oceanic strands, were incorporated into the continental arc crust during collision between the Congo and Azania cratonic blocks forming the EAO.

Isotope Lu–Hf composition of detrital zircon from paragneisses of the Sharyzhalgai uplift: evidence for the Paleoproterozoic crustal growth

We present results of study of the trace-element and Lu–Hf isotope compositions of zircons from Paleoproterozoic high-grade metasedimentary rocks (paragneisses) of the southwestern margin of the Siberian craton (Irkut terrane of the Sharyzhalgai uplift). Metamorphic zircons are represented by rims and multifaceted crystals dated at ~1.85 Ga. They are depleted in either LREE or HREE as a result of subsolidus recrystallization and/or synchronous formation with REE-concentrating garnet or monazite. In contrast to the metamorphic zircons, the detrital cores are enriched in HREE and have high (Lu/Gd)n ratios, which is typical of igneous zircon. The weak positive correlation between 176Lu/177Hf and 176Hf/177Hf in the zircon cores evidences that their Hf isotope composition evolved through radioactive decay in Hf = the closed system. Therefore, the isotope parameters of these zircons can give an insight into the provenance of metasedimentary rocks. The Paleoproterozoic detrital zircon cores from paragneisses, dated at ~2.3–2.4 and 2.0–1.95 Ga, are characterized by a wide range of εHf values (from +9.8 to –3.3) and model age TC 2.8–2.0 Ga. The provenance of these detrital zircons included both rocks with juvenile isotope Hf parameters and rocks resulted from the recycling of the Archean crust with a varying contribution of juvenile material. Zircons with high positive εHf values were derived from the juvenile Paleoproterozoic crustal sources, whereas the lower εHf and higher TC values for zircons suggest the contribution of the Archean crustal source to the formation of their magmatic precursors. Thus, at the Paleoproterozoic stage of evolution of the southwestern margin of the Siberian craton, both crustal recycling and crustal growth through the contribution of juvenile material took place. On the southwestern margin of the Siberian craton, detrital zircons with ages of ~2.3–2.4 and 1.95–2.0 Ga are widespread in Paleoproterozoic paragneisses of the Irkut and Angara–Kan terranes and in terrigenous rocks of the Urik–Iya graben, which argues for their common and, most likely, proximal provenances. In the time of metamorphism (1.88–1.85 Ga), the age of Paleoproterozoic detrital zircons (2.4–2.0 Ga), and their Lu–Hf isotope composition (εHf values ranging from positive to negative values) the paragneisses of the southwestern margin of the Siberian craton are similar to the metasedimentary rocks of the Paleoproterozoic orogenic belts of the North China Craton. In the above two regions, the sources of detrital zircons formed by both the reworking of the Archean crust and the contribution of juvenile material, which is evidence for the crustal growth in the period 2.4–2.0 Ga.

Detrital-zircon geochronology of the Sawtooth metamorphic complex, Idaho: Evidence for metamorphosed lower Paleozoic shelf strata within the Idaho batholith

U-Pb ages of detrital zircons from metasedimentary rocks of the Sawtooth metamorphic complex (SMC) are key for identifying the stratigraphic age of metamorphosed strata within the Idaho batholith region of the Cordilleran orogen. The SMC is an exposure of medium- to high-grade metasedimentary rocks surrounded by the Idaho and Sawtooth batholiths. U-Pb ages of detrital zircons from SMC quartzites and quartzofeldspathic gneisses yield two distinctive age spectra consisting of primary 2900–2510 Ma and 1990–1760 Ma zircons for one group and 1870–1670 Ma, 1490–1330 Ma, and 1220–1020 Ma zircons for the other group. The suite of samples also yields a small number of zircons with concordant Cambrian and Neoproterozoic ages. Statistical and visual comparisons of age spectra with detrital-zircon data from Proterozoic and Paleozoic strata deposited on the western passive margin of Laurentia suggest that the SMC rocks were deposited in the Cambrian and Middle Ordovician. The identification of lower Paleozoic shelf strata in the SMC, along with similar sections recently identified in the Stibnite and Gospel Peaks inliers of the Idaho batholith, suggest that the Cordilleran passive margin sequence was continuous along the western margin of Laurentia, including the area occupied by the Idaho batholith.

Field relations, age, and tectonic setting of metamorphic and plutonic rocks in the Creignish Hills – North Mountain area, southwestern Cape Breton Island, Nova Scotia, Canada

The Creignish Hills and North Mountain areas of southwestern Cape Breton Island consist mostly of Neoproterozoic rocks typical of the Ganderian Bras d’Or terrane. U-Pb ages presented here for detrital zircon in the Blues Brook Formation of the Creignish Hills confirm a depositional age no greater than about 600 Ma. Although it is possible that some components of the formation are much older, similarities in rock types and field relations suggest that this is not the case. It is likely that the equivalent Malagawatch Formation of the North Mountain area, as well as high-grade metasedimentary rocks of the Melford Formation and Chuggin Road complex in the Creignish Hills and Lime Hill gneiss complex in the North Mountain area, represent the same or stratigraphically equivalent units as the Blues Brook Formation. The minimum ages of all of these units are constrained by cross-cutting syn- and post-tectonic plutons with ages mostly between 565 and 550 Ma, indicating that sediments were deposited, regionally metamorphosed, deformed, and intruded by plutons in less than 40–50 million years. The assemblage of pelitic, psammitic, and carbonate rocks indicates that a passive margin in a tropical climate was quickly changed to an active Andean-type continental margin in which voluminous calcalkaline dioritic to granitic plutons were emplaced. This sedimentary and tectonic history is characteristic of the Bras d’Or terrane and is shared by its likely correlative, the Brookville terrane in southern New Brunswick.

Evolution of a Palaeoproterozoic giant magmatic dome in the Finnish Svecofennian; New insights from U–Pb geochronology

The Svecofennian domain comprises a c. 800km by 800km area in Finland and Sweden, mainly composed of Palaeoproterozoic granitoids, schists and gneisses. In the central part of the domain in western Finland, the Vaasa complex hosts a sequence of high-grade metamorphic rocks and granites formed by crustal anatexis during the culmination of the ∼1.9Ga Svecofennian orogeny. The Vaasa complex consists of a c. 8000km2 granitoid batholith surrounded by diatexitic and metatexitic migmatites as well as metasedimentary rocks. In order to enhance the perception of the crystallisation history, provenance, and maximum sedimentation age of the protoliths involved, nine granitoid-xenolith pairs and a palaeosome-neosome pair were collected from the main body of the Vaasa batholith and surrounding rocks, and zircon from them was U–Pb dated using the LA-MC-ICPMS method.The U–Pb zircon crystallisation ages of the granitoids are 1.88–1.87Ga, which is in accordance with the few previous results from the Vaasa region, and confirms a relatively swift crystallisation of the granite core throughout the Finnish part of the complex. The samples from the central part of the batholith have younger zircon ages than those from batholith margin. The inherited zircon age distribution pattern of the granitoids resembles that of the metasedimentary xenoliths. Our new comprehensive data, combined with whole-rock geochemistry from previous studies, render an in situ origin of the Vaasa granite probable. The maximum sedimentation age of the supracrustal precursors of the Vaasa complex is 1.92Ga. Some of the metasedimentary xenoliths from the Vaasa complex host zircon that is coeval with their host granitoids and register incipient melting. Based on these ∼1.88–1.86Ga zircon grains, the maximum sedimentation age would be deemed too young. Therefore, our data calls for caution when determining maximum sedimentation ages of high-grade metasedimentary rocks.

Provenance of the Neoproterozoic high-grade metasedimentary rocks of the arc-related Oriental Terrane of the Ribeira belt: Implications for Gondwana amalgamation

The Costeiro domain integrates the Oriental terrane of the Ribeira belt, which encompasses arc-related orthogneisses of the Rio Negro complex (ca.790–605 Ma), with a well-documented subduction signature, and the high-grade metasedimentary rocks of the São Fidélis group. The arc-related rocks intruded the lower unit of the São Fidélis group, while both units are crosscut by syn-to late collision granitoids related to the development of different stages of the Brasiliano Orogeny (ca. 605–480 Ma). New U–Pb (LA-ICP-MS) data of detrital zircon grains from quartzites of the top unit of the São Fidélis group yielded a large spectrum of Mesoproterozoic and Paleoproterozoic ages, with subordinated Archean and Neoproterozoic ones. The largest age peaks occur at ca. 1.2 Ga and 2.2 Ga. The youngest detrital zircon of ca. 613 Ma, and metamorphic overprints, with ages varying from ca. 602 to 570 Ma bracket the age of sedimentation of the top unit. Two orthogneisses of the Rio Negro complex intruded within the basal unit of the São Fidélis Group rendered similar ages of ca.620 Ma. These orthogneisses and the basal unit of the São Fidélis group are interpreted as possible sources of the upper unit. The provenance pattern of the São Fidélis Group is similar to that of the Kaoko Belt, suggesting that the Angolan basement, where Mesoproterozoic ages are common, constitutes another important source area.

Neoarchean and Paleoproterozoic crust formation in the Ubendian Belt of Tanzania: Insights from zircon geochronology and geochemistry

LA-ICP-MS U–Pb zircon geochronological and geochemical data of meta-igneous and metasedimentary rock types of the Katuma Block of the Paleoproterozoic Ubendian Belt in Tanzania are used to unravel the crustal evolution of this metalliferous terrain. The protoliths of the metabasites and orthogneisses previously considered to be Paleoproterozoic are in fact mostly Neoarchean in age (2713±11Ma to 2638±5Ma), from which the oldest rocks experienced their first metamorphism during the same Neoarchean orogenic cycle at ca. 2650Ma. A second event of mafic magmatism (2021±11Ma) was concomitant with the migmatization of the Neoarchean orthogneisses and was succeeded by granitic intrusions at 1990–1940Ma. All rocks of the Katuma Block experienced their main metamorphic reworking during several Paleoproterozoic orogenic events, which were recognized by dating of various metamorphic zircon growth zones and the age of magmatic events dated at ca. 2050, 1960 and 1880Ma. The detritus of the high-grade metasedimentary rocks derived from Neoarchean (Katuma Block or Tanzania Craton?) and Paleoproterozoic provenances and the minimum age for the deposition is constrained by its first metamorphism at ca. 1960Ma. The Neoarchean and Paleoproterozoic metabasites, gabbronorites and orthogneisses are sub-alkaline in composition displaying a REE and trace element geochemistry akin to those of rocks formed in modern-arc settings. On the basis of the geochemical data, the presence of eclogites, deformation and metamorphic ages, we suggest that in Paleoproterozoic time the Katuma Block was again at an active continental margin, below which a Paleoproterozoic oceanic lithosphere was subducting.

Geoquímica de las rocas metasedimentarias del Cámbrico medio al Ordovícico temprano de la Sierra de Los Llanos (Sierras Pampeanas, Argentina): Fuente de sedimentos, correlación y ambiente geotectónico

The metamorphic complex of Sierra de Los Llanos is composed of low- to high-grade metasedimentary rocks, namely phyllites, schists, gneisses and migmatites that out crop like large septa within lower Ordovician magmatic units. Cornubianite associated with the intrusion of basic composition bodies are locally recognized. Chemical compositions of these metasedimentary rocks are equivalent to pelite and arenite (sublitharenite-subarkose). Chemical ratios of Ti/Zr (5.4-8.4), La/Sc (5.2-8.5), Th/Sc >1 (2.2-3.4), La/Th (2.0-2.5) and Zr/Sc (60-103), along with contents of Hf (7.9 a 12.4 ppm) and Sc (4.4-5.2 ppm) in meta-psammites, suggest that the source of the sediments was enriched in felsic components or recycled material and limited participation mafic components. A similar composition of source areas for meta-psammites of this complex and Chepes, La Cébila and Pringles metamorphic complexes is suggested from geochemical data. Ti, Zr, Hf, La, Th and Sc concentrations are variable and do not allow to clearly define a specific geotectonic context and suggest that the composition of the protoliths was largely controlled by sedimentary processes rather than compositional heterogeneity of the sources. The integration of geochemical and known geochronological data and the regional correlation of Ordovician metamorphic complexes strengthen the interpretation that defines igneous and metamorphic rocks from Pampean orogenic belt and Río de La Plata craton as the mayor sources of these complexes. Furthermore, this information is consistent with the existence of an extensive continental shelf in the southwestern margin of Gondwana during the Middle Cambrian to Early Ordovician.

Mesoproterozoic high-grade metamorphism in pelitic rocks of the northwestern Ubendian Belt: Implication for the extension of the Kibaran intra-continental basins to Tanzania

Paleoproterozoic basement rocks are thought to form the northwestern end of the Ubendian Belt in Tanzania that disappears towards the north below a Mesoproterozoic sedimentary cover. The northwestern end of the Ubendian Belt is known to constitute three litho-tectonic terranes of Katuma, Wakole and Ubende. Through dating of zircon (SHRIMP U–Pb) and monazite (U–Th–total Pb electron microprobe ages) of high-grade metasedimentary rocks of the Wakole Terrane we have detected solely Mesoproterozoic ages, showing no sign of reworking of older Paleoproterozoic basement. These findings signify that the Wakole Terrane hosts younger sediments of Mesoproterozoic times metamorphosed to high-grade P–T conditions (peaked at 670–680°C/8.5–8.9kbar).Two distinct phases of Mesoproterozoic metamorphic events separated by 160Ma have been dated at 1166±14Ma and 1007±6Ma (SHRIMP U–Pb zircon). Zircon ages are supported by in-situ dating of monazite with ages at 1170±10Ma, and 1022±5–1016±10Ma. The first age is closely related to the period of S-type granitoid emplacement at about 1200Ma in the Karagwe-Ankolean and Kibaran Belts. The second age cluster overlaps with a period of global Mesoproterozoic orogenic cycle, also recorded in the neighboring Irumide and Kibaran Belts. This age group is associated with the assembly of the hypothetical Mesoproterozoic Rodinia Supercontinent.The recent model for the evolution of the Kibaran Belt suitably explains the spatial and temporal settings of Mesoproterozoic metasedimentary rocks of the Wakole Terrane overlying the Paleoproterozoic Ubendian Belt. Due to its proximity to the Kibaran Belt and by being bound by the Paleoproterozoic Terranes of Ubende and Katuma, it can be interpreted that the Wakole Terrane metasediments initially were deposited in an intra-continental basin that was later squeezed between these old terranes by the regional ca. 1000Ma compressional event recorded in the Irumide, Kibaran and Karagwe-Ankolean Belts.

Origin of the Okrouhlá Radouň episyenite-hosted uranium deposit, Bohemian Massif, Czech Republic: fluid inclusion and stable isotope constraints

The Okrouhla Radouň shear zone hosted uranium deposit is developed along the contact of Variscan granites and high-grade metasedimentary rocks of the Moldanubian Zone of the Bohemian Massif. The pre-ore pervasive alteration of wall rocks is characterized by chloritization of mafic minerals, followed by albitization of feldspars and dissolution of quartz giving rise to episyenites. The subsequent fluid circulation led to precipitation of disseminated uraninite and coffinite, and later on, post-ore quartz and carbonate mineralization containing base metal sulfides. The fluid inclusion and stable isotope data suggest low homogenization temperatures (∼50–140 °C during pre-ore albitization and post-ore carbonatization, up to 230 °C during pre-ore chloritization), variable fluid salinities (0–25 wt.% NaCl eq.), low fluid δ18O values (−10 to +2 ‰ V-SMOW), low fluid δ13C values (−9 to −15 ‰ V-PDB), and highly variable ionic composition of the aqueous fluids (especially Na/Ca, Br/Cl, I/Cl, SO4/Cl, NO3/Cl ratios). The available data suggest participation of three fluid endmembers of primarily surficial origin during alteration and mineralization at the deposit: (1) local meteoric water, (2) Na–Ca–Cl basinal brines or shield brines, (3) SO4–NO3–Cl–(H)CO3 playa-like fluids. Pre-ore albitization was caused by circulation of alkaline, oxidized, and Na-rich playa fluids, whereas basinal/shield brines and meteoric water were more important during the post-ore stage of alteration.

Saps II et valorisation des séjours en unité de surveillance continue : une étonnante inadéquation

We present results of combined in situ U–Pb dating of detrital zircons and zircon Hf and whole-rock Nd isotopic compositions for high-grade clastic metasedimentary rocks of the Slyudyansky Complex in eastern Siberia. This complex is located southwest of Lake Baikal and is part of an early Paleozoic metamorphic terrane in the eastern part of the Central Asian Orogenic Belt (CAOB). Our new zircon ages and Hf isotopic data as well as whole-rock Nd isotopic compositions provide important constraints on the time of deposition and provenance of early Paleozoic high-grade metasedimentary rocks as well as models of crustal growth in Central Asia. Ages of 0.49–0.90 Ga for detrital zircons from early Paleozoic high-grade clastic sediments indicate that deposition occurred in the late Neoproterozoic and early Paleozoic, between ca. 0.62–0.69 and 0.49–0.54 Ga. Hf isotopic data of 0.82–0.69 Ga zircons suggest Archean and Paleoproterozoic (ca. 2.7–2.8 and 2.2–2.3 Ga; Hfc = 2.5–3.9 Ga) sources that were affected by juvenile 0.69–0.82 Ga Neoproterozoic magmatism. An additional protolith was also identified. Its zircons yielded ages of 2.6–2.7 Ga, and showed high positive εHf(t) values of +4.1 to +8.0, and Hf model ages tHf(DM) = tHfc = 2.6–2.8 Ga, which is nearly identical to the crystallization ages. These isotopic characteristics suggest that the protolith was quite juvenile. The whole-rock Nd isotopic data indicate that at least part of the Slyudyansky Complex metasediments was derived from “non-Siberian” provenances. The crustal development in the eastern CAOB was characterized by reworking of the early Precambrian continental crust in the early Neoproterozoic and the late Neoproterozoic–early Paleozoic juvenile crust formation.