High ET Research Articles

Spatial data modelling of atmospheric water availability and stress in Jharkhand, India

Due to climate and human activity, water supply in Jharkhand, India, fluctuates. This study measured AWS and AWA in Jharkhand, India. MODIS NDVI and Terra Climate data processed by Google Earth Engine (GEE) are used in the analysis. Based on mean annual values for NDWI, run-off, precipitation, and ET, AWS and AWA are categorised. Results show significant regional differences in ET, precipitation, runoff, AWS, and AWA in Jharkhand. Purbi Singhbhum has far higher ET rates than Garhwa, Palamu, and Chatra. High AWS levels in Sahibganj, Godda, Pakur, Garhwa, and Kodarma indicate serious water scarcity. Therefore, these locations need focused water management approaches. Different districts including Giridih, Chatra, Jamtara, Latehar, Simdega, and Hazaribagh have different levels of AWS, highlighting the need for individualised treatments. The AWA index helps resource managers make educated decisions by detecting water-scarce places. Climate variability affects temperatures and precipitation, worsening AWS in high-AWS areas. Water scarcity mitigation requires local infrastructure development and water management measures. To verify remote sensing data accuracy, future study should improve data resolution and include in-situ measurements. These findings can help policymakers and stakeholders in Jharkhand create efficient water resource management strategies to reduce water stress and assure water supply.

Hydrological regimes and evaporative flux partitioning at the climatic ends of high mountain Asia

Abstract High elevation headwater catchments are complex hydrological systems that seasonally buffer water and release it in the form of snow and ice melt, modulating downstream runoff regimes and water availability. In High Mountain Asia (HMA), where a wide range of climates from semi-arid to monsoonal exist, the importance of the cryospheric contributions to the water budget varies with the amount and seasonal distribution of precipitation. Losses due to evapotranspiration and sublimation are to date largely unquantified components of the water budget in such catchments, although they can be comparable in magnitude to glacier melt contributions to streamflow. Here, we simulate the hydrology of three high elevation headwater catchments in distinct climates in HMA over 10 years using an ecohydrological model geared towards high-mountain areas including snow and glaciers, forced with reanalysis data. Our results show that evapotranspiration and sublimation together are most important at the semi-arid site, Kyzylsu, on the northernmost slopes of the Pamir mountain range. Here, the evaporative loss amounts to 28% of the water throughput, which we define as the total water added to, or removed from the water balance within a year. In comparison, evaporative losses are 19% at the Central Himalayan site Langtang and 13% at the wettest site, 24 K, on the Southeastern Tibetan Plateau. At the three sites, respectively, sublimation removes 15%, 13% and 6% of snowfall, while evapotranspiration removes the equivalent of 76%, 28% and 19% of rainfall. In absolute terms, and across a comparable elevation range, the highest ET flux is 413 mm yr−1 at 24 K, while the highest sublimation flux is 91 mm yr−1 at Kyzylsu. During warm and dry years, glacier melt was found to only partially compensate for the annual supply deficit.

Sub-Second Long Lifetime Triplet Exciton Reservoir for Highly Efficient and Stable Organic Light-Emitting Diode.

In organic light-emitting diode (OLED), achieving high efficiency requires effective triplet exciton confinement by carrier-transporting materials, which typically have higher triplet energy (ET) than the emitter, leading to poor stability. Here, an electron-transporting material (ETM), whose ET is 0.32 eV lower than that of the emitter is reported. In devices, it surprisingly exhibits strong confinement effect and generates excellent efficiency. Additionally, the device operational lifetime is 4.9 times longer than the device with a standard ETM, 1,3,5-tri(1-phenyl-1H-benzo[d]imidazol-2-yl) phenyl (whose ET 0.36 eV is higher than the emitter). This anomalous finding is ascribed to the exceptionally long triplet state lifetime (≈0.2 s) of the ETM. It is named as long-lifetime triplet exciton reservoir effect. The systematic analysis reveals that the long triplet lifetime of ETM can compensate the requirement for high ET with the help of endothermic energy transfer. Such combination of low ET and long lifetime provides equivalent exciton confinement effect and high molecular stability simultaneously. It offers a novel molecular design paradigm for breaking the dilemma between high efficiency and prolonged operational lifetime in OLEDs.

Highly efficient red and green phosphorescent OLEDs based on benzonitrile and carbazole as bipolar host materials

In this work, two novel bipolar host materials 3''-(9H-carbazol-9-yl)-5'-(2,6-diphenylpyridin-4-yl)-[1,1':3′,1″-terphenyl]-4-carbonitrile (p-PyCNCz) and 3''-(9H-carbazol-9-yl)-5'-(2,6-diphenylpyridin-4-yl)-[1,1':3′,1″-terphenyl]-3-carbonitrile (m-PyCNCz) were designed and synthesized by incorporating diphenylpyridine, benzonitrile and phenylcarbazole. Both materials exhibit excellent thermal stability with their glass transition temperatures (Tg) of exceeding 120 °C and thermal decomposition temperatures (Td) of reaching approximately 490 °C. The p-PyCNCz and m-PyCNCz not only possess a high ET of 2.75 eV and 2.84 eV, but their HOMO/LUMO are completely separated. Moreover, red and green phosphorescent OLEDs (PhOLEDs) hosted by the two materials were prepared. The m-PyCNCz exhibits better device performance, with the Ƞc,max, Ƞp,max and EQEmax of achieving 88.32 cd/A, 98.19 lm/W and 24.3 % for the green PhOLED, and 22.19 cd/A, 24.38 lm/W and 25.3 % for the red PhOLED, respectively.

The influence of radical trachelectomy on endometrial thickness in in vitro fertilization-embryo transfer.

Both morbidity and mortality rates of cervical cancer are increasing, especially in reproductive-aged women. Radical trachelectomy (RT) is an effective fertility-preserving surgery for early-stage cervical cancer. This study aimed to determine the influence of RT on endometrial thickness during in vitro fertilization-embryo transfer (IVF-ET). Forty-four patients had undergone RT, and 23 women undergoing IVF-ET treatment (105 ET cycles) were included. Endometrial thickness during hormone replacement therapy (HRT) was retrospectively evaluated and compared between patients with and without RT. Eleven patients (50 ET cycles) in the RT group and 12 (52 ET cycles) in the control group were investigated. Compared with the control group, higher ET cancellation rates were observed in patients in the RT group (1 of 52 cycles [control group] vs. 8 of 50 cycles [RT group], p < 0.01). Endometrial thinning was not affected by patient age at first IVF-ET treatment, history of artificial abortion, preservation of uterine arteries during RT, or postoperative chemotherapy (p = 0.27, 1, 1, and 1, respectively). Our data revealed that RT influenced endometrial thickness in IVF-ET. This was not affected by the background of the patients or perioperative management in this study. We could not reveal the underlying mechanism, but it is postulated that the transient postoperative uterine blood flow status and postoperative infections may have some effect on the endometrium. To resolve these issues, accumulation of evidences are required. We recommend informing patients about the impact of RT on IVF-ET before starting assisted reproductive technology (ART).

The impact of antenatal and postnatal indoor air pollution or tobacco smoke exposure on lung function at 3 years in an African birth cohort.

Indoor air pollution (IAP) and tobacco smoke exposure (ETS) are global health concerns contributing to the burden of childhood respiratory disease. Studies assessing the effects of IAP and ETS in preschool children are limited. We assessed the impact of antenatal and postnatal IAP and ETS exposure on lung function in a South African birth cohort, the Drakenstein Child Health Study. Antenatally enrolled mother-child pairs were followed from birth. Lung function measurements (oscillometry, multiple breath washout and tidal breathing) were performed at 6 weeks and 3 years. Quantitative antenatal and postnatal IAP (particulate matter [PM10 ], volatile organic compounds [VOC]) and ETS exposures were measured. Linear regression models explored the effects of antenatal and postnatal exposures on lung function at 3 years. Five hundred eighty-four children had successful lung function testing, mean (SD) age of 37.3 (0.7) months. Exposure to antenatal PM10 was associated with a decreased lung clearance index (p < 0.01) and postnatally an increase in the difference between resistance at end expiration (ReE) and inspiration (p = 0.05) and decrease in tidal volume (p = 0.06). Exposure to antenatal VOC was associated with an increase in functional residual capacity (p = 0.04) and a decrease in time of expiration over total breath time (tE /tTOT ) (p = 0.03) and postnatally an increase in respiratory rate (p = 0.05). High ETS exposure postnatally was associated with an increase in ReE (p = 0.03). Antenatal and postnatal IAP and ETS exposures were associated with impairment in lung function at 3 years. Strengthened efforts to reduce IAP and ETS exposure are needed.

An Improved Satellite‐Based Evapotranspiration Procedure for China

AbstractEvapotranspiration (ET) is a critical process that regulates the transfer of heat and water between land and the atmosphere. While satellite‐based ET algorithms can provide area‐wide daily ET estimates, few are independent of local meteorological measurements. The Variant of the Moderate Resolution Imaging Spectroradiometer Standard Evapotranspiration Algorithm (VISEA) can potentially run without ground‐based observations. However, the surface energy budgets used in VISEA generally overpredict daily net radiation and related ET. To improve the accuracy of net radiation and ET, we incorporated Brutsaert's atmosphere emissivity model and corrected the routine to calculate the downward long‐wave radiation on cloudy days (which we called VISEA2023 model). The VISEA2023 model predicted net radiation and ET that agreed well with measurements at seven ChinaFlux sites, with an R2 of 0.8 and an Root Mean Square Error (RMSE) of 30 W m−2 for net radiation, and an R2 of 0.6 and an RMSE of 1 mm day−1 for ET, respectively. Additionally, the VISEA2023 model is more robust in comparison to the Variable Infiltration Capacity hydrologic model output in 10 major river basins and 80 sub‐river basins, with an R2 of 0.91 (0.78) and an RMSE of 85 (127.4) mm year−1, than MOD16, which has an R2 of 0.81 (0.82) and an RMSE of 134.8 (157.7) mm year−1, and Advanced Very High Resolution Radiometer ET, which has an R2 of 0.92 (0.62) and an RMSE of 90.1 (136.1) mm year−1. The improved VISEA2023 model can offer near‐real‐time ET on a larger scale, improving our understanding of water cycles and their relation to climate change.

Spatial characteristics of urban evapotranspiration effects on the thermal environment

Abstract Evapotranspiration (ET) is an important process of the regional hydrothermal cycle. However, it is unclear how the mitigation of urban ET in urban thermal environments occurs in a spatial context. Landsat 8 satellite images from 2014 to 2018 of Xuzhou and corresponding meteorological observations were selected, and the improved mono-window algorithm (IMW) and urban RS-PM model were applied to invert land surface temperature (LST) and ET, respectively. In addition, spatial analysis methods (a profile analysis, standard deviation ellipse (SDE) analysis, and bivariate Moran's I) were employed to quantify and simulate the spatial characteristics of the ET effect on LST. The results indicated the following: (1) There was a significant linear negative correlation between ET and LST, which confirms that ET has a negative effect on LST; (2) the SDE overlap ratios between patches with higher ET and lower LST imply that higher ET patches have a significant impact on the spatial distribution of LST; and (3) bivariate Moran's I between ET and LST and their linear mixture spectral analysis (LISA) maps reveal a significant negative spatial correlation between ET and LST. In addition, the landscape pattern of higher ET parches is also an important factor affecting the environmental temperature.

Interpreting water demands of forests and grasslands within a new Budyko formulation of evapotranspiration using percolation theory

The relationship between carbon cycle and water demand is key to understanding global climate change, vegetation productivity, and predicting the future of water resources. The water balance, which enumerates the relative fractions of precipitation P that run off, Q, or are returned to the atmosphere through evapotranspiration, ET, links drawdown of atmospheric carbon with the water cycle through plant transpiration. Our theoretical description based on percolation theory proposes that dominant ecosystems tend to maximize drawdown of atmospheric carbon in the process of growth and reproduction, thus providing a link between carbon and water cycles. In this framework, the only parameter is the fractal dimensionality df of the root system. Values of df appear to relate to the relative roles of nutrient and water accessibility. Larger values of df lead to higher ET values. Known ranges of grassland root fractal dimensions predict reasonably the range of ET(P) in such ecosystems as a function of aridity index. Forests with shallower root systems, should be characterized by a smaller df and, therefore, ET that is a smaller fraction of P. The prediction of ET/P using the 3D percolation value of df matches rather closely results deemed typical for forests based on a phenomenology already in common use. We test predictions of Q with P against data and data summaries for sclerophyll forests in southeastern Australia and the southeastern USA. Applying PET data from a nearby site constrains the data from the USA to lie between our ET predictions for 2D and 3D root systems. For the Australian site, equating cited “losses” with PET underpredicts ET. This discrepancy is mostly removed by referring to mapped values of PET in that region. Missing in both cases is local PET variability, more important for reducing data scatter in southeastern Australia, due to the greater relief.

Ultraviolet photodissociation of 2-methylallyl radical

Ultraviolet photodissociation dynamics of 2-methylallyl radical from the 3p Rydberg state were investigated in the wavelength region of 226–244 nm using the high-n Rydberg atom time-of-flight (HRTOF) technique. The 2-methylallyl radicals were generated by 193 nm photolysis of 3-chloro-2-methyl-1-propene precursors. The photofragment yield spectrum of H-atom products increases in intensity with decreasing wavelengths in 226–244 nm. The TOF spectra of H-atom products show a bimodal structure. The predominant product channel (with ∼98% branching ratio) has a kinetic energy release peaking at ∼7 kcal/mol, with an average ratio of ET in the total available energy, (fT), of ∼0.18 in 226–244 nm and an isotropic product angular distribution. At the low ET, isotropic component is from statistical unimolecular decomposition of highly vibrationally excited hot 2-methylallyl to the methylenecyclopropane+H products, following internal conversion from the excited electronic state. The minor product channel (with ∼2% branching ratio) has a large kinetic energy peaking at ∼50 kcal/mol, with (fT)≈0.63 and an anisotropic angular distribution (β≈−0.2). At the high ET, anisotropic component is non-statistical and is postulated to be from direct loss of H atom via the 3p Rydberg state or repulsive part of the ground state to the 1,3-butadiene+H products.

Diphenyldihydropentalenediones: Wide Singlet-Triplet Energy Gap Compounds Possessing the Planarly Fixed Diene Subunit.

2,2,5,5-Tetramethyl-3,6-diphenyl-2,5-dihydropentalene-1,4-dione (PD-H) and its dimethoxy (PD-OCH3) and bis(trifluoromethyl) derivatives (PD-CF3) were developed as a new class of compounds possessing a wide excited singlet-triplet energy gap. The PD derivatives would also have a high energy level of the triplet-excited state (E T) due to the planarity of the fused-diene subunit. The results of photophysical studies revealed that the energy level of the singlet-excited state (E S) and E T of PD-H are 2.88 and 1.43 eV, respectively. These values indicate that PD-H has the energy relationship, E S > 2E T, required for it to be a singlet fission (SF) material. Moreover, the introduction of electron-donating or -withdrawing groups on the benzene rings in PD-H enables fine-tuning of E S and E T. The results of transient absorption spectroscopic studies show that PD-H, PD-OCH3, and PD-CF3 in CH2Cl2 have respective T1 lifetimes of 71, 118, and 107 μs, which are long enough to utilize its triplet exciton in other optoelectronic systems. These findings suggest that the PDs are potential candidates for SF materials with high E T levels.

Effects of Farmland Landscape Fragmentation on Agricultural Irrigation in Hotan Oasis

Farmland landscape fragmentation is an important problem affecting the agricultural modernization process in China. However, farmland landscape fragmentation leads to land being wasted and increases management costs, particularly in the dryland’s oasis regions. Therefore, investigating the impact of farmland landscape fragmentation on agricultural irrigation is of great significance in developing oasis agriculture. This paper used the landscape quantitative index (DIVISION), the moving window method, and gradient analysis methods to study the temporal and spatial pattern changes in farmland fragmentation in the Hotan Oasis. Additionally, the impact of fragmentation on irrigation in the oasis was elaborated upon by exploring the relationship between evapotranspiration and its components in farmland fragmentation. The results showed that the farmland area of the Hotan Oasis increased from 1546.19 km2 in 2000 to 2068.23 km2 in 2020, and farmland landscape fragmentation increased with the expansion of the Hotan Oasis. In addition, a significant relationship between farmland fragmentation and evapotranspiration and its components was evident. A lower DIVISION value corresponded to a higher ET value, a lower ETs/ETc ratio, and a higher water use efficiency. When the total farmland area is assumed to remain unchanged, the irrigation water consumption is reduced by 4.82 × 108 m3 according to the size and proportion of arable land with the lowest degree of fragmentation (L1, division value of 0.46). In addition, with the increase in the proportion of farmland, the scale of oasis decreases by 2431.56 km2 for the reduction in field roads, shelterbelt, and bare land. These findings suggest that solving the problem of farmland fragmentation can effectively reduce irrigation water consumption, realize the internal expansion of the oasis through intensive land use, and relieve the pressure of the external expansion of the oasis.

Agronomic management practices in dryland wheat result in variations in precipitation use efficiency due to their differential impacts on the steps in the precipitation use process

Yield loss due to low precipitation use efficiency (PUE) occurs frequently in dryland crop production. PUE is determined by a complicated process of precipitation use in farmland, which includes several sequential steps: precipitation infiltrates into the soil, the infiltrated precipitation is stored in soil, the soil-stored precipitation is consumed through transpiration or evaporation, transpired precipitation is used to produce dry-matter, and finally dry-matter is re-allocated to grains. These steps can be quantified by six ratios: precipitation infiltration ratio (SW/SWe; SW, total available water; SWe, available soil water storage at the end of a specific period), precipitation storage ratio (SWe/P; P, effective precipitation), precipitation consumption ratio (ET/SW; ET, evapotranspiration), ratio of crop transpiration to evapotranspiration (T/ET; T, crop transpiration), transpiration efficiency (B/T; B, the increment of shoot biomass) and harvest index (Y/B; Y, grain yield). The final efficiency is then calculated as: PUE=SWeP×SWSWe×ETSW×TET×BT×YB. Quantifying each of those ratios is crucial for the planning and execution of PUE improvements and for optimizing the corresponding agronomic practices in a specific agricultural system. In this study, those ratios were quantified and evaluated under four integrated agronomic management systems. Our study revealed that PUE and wheat yield were significantly increased by 8–31% under manure (MIS) or biochar (BIS) integrated systems compared to either conventional farmers’ (CF) or high N (HN) integrated systems. In the infiltration and storage steps, MIS and BIS resulted in lower SWe/P but higher SW/SWe compared with CF and HN. Regarding the consumption step, the annual ET/SW under MIS and BIS did not increase due to the higher ET after regreening and the lower ET before regreening compared with CF or HN. The T/ET was significantly higher under MIS and BIS than under CF or HN. In the last two steps, transpiration efficiency and harvest index were less strongly affected by the agronomic management system, although both values varied considerably across the different experimental years. Therefore, attempts to achieve higher PUE and yields in rainfed wheat through agronomic management should focus on increasing the T/ET and SW/SWe, while maintaining ET/SW throughout the year and keeping SWe/P relatively low at harvest time.

Achieving Balanced Electrical Performance of Host Material through Dual N-P═O Resonance Linkage for Efficient Electroluminescence.

Developing high-performance host materials is one of the biggest challenges for blue and white thermally activated delayed-fluorescence (TADF) organic light-emitting diode (OLED) technology due to the rigorous requirements of both efficient carrier flux ability and high triplet energy (ET) levels in static donor-acceptor molecules. Here, with the aid of a dual-resonance strategy, a host molecule showing dynamic adaption features in the acceptor-resonance-donor-resonance-acceptor (A-r-D-r-A) molecular configuration has been successfully developed through the implantation of two acceptors of diphenylphosphine oxide into electron-donating 5,10-dihydrophenazine with N-P═O resonance linkages. Owing to the dual enantiotropic N+═P-O- resonances, the designed A-r-D-r-A molecule exhibits an extraordinarily balanced charge flux transportation attribute at high ET (2.96 eV). Excitingly, blue and warm-white TADF OLEDs hosted by the A-r-D-r-A molecule exhibit outstanding external quantum efficiencies of 14.7 and 20.3%, respectively. Our studies not only broaden the scope of resonance molecules but also indicate that a resonance structure is an effective linkage to develop optoelectronic materials with dynamically adaptive properties.

Improving the spatiotemporal resolution of remotely sensed ET information for water management through Landsat, Sentinel-2, ECOSTRESS and VIIRS data fusion

Robust information on consumptive water use (evapotranspiration, ET) derived from remote sensing can significantly benefit water decision-making in agriculture, informing irrigation schedules and water management plans over extended regions. To be of optimal utility for operational usage, these remote sensing ET data should be generated at the sub-field spatial resolution and daily-to-weekly timesteps commensurate with the scales of water management activities. However, current methods for field-scale ET retrieval based on thermal infrared (TIR) imaging, a valuable diagnostic of canopy stress and surface moisture status, are limited by the temporal revisit of available medium-resolution (100 m or finer) thermal satellite sensors. This study investigates the efficacy of a data fusion method for combining information from multiple medium-resolution sensors toward generating high spatiotemporal resolution ET products for water management. TIR data from Landsat and ECOSTRESS (both at ~ 100-m native resolution), and VIIRS (375-m native) are sharpened to a common 30-m grid using surface reflectance data from the Harmonized Landsat-Sentinel dataset. Periodic 30-m ET retrievals from these combined thermal data sources are fused with daily retrievals from unsharpened VIIRS to generate daily, 30-m ET image timeseries. The accuracy of this mapping method is tested over several irrigated cropping systems in the Central Valley of California in comparison with flux tower observations, including measurements over irrigated vineyards collected in the GRAPEX campaign. Results demonstrate the operational value added by the augmented TIR sensor suite compared to Landsat alone, in terms of capturing daily ET variability and reduced latency for real-time applications. The method also provides means for incorporating new sources of imaging from future planned thermal missions, further improving our ability to map rapid changes in crop water use at field scales.

Environmental and stomatal control on evapotranspiration in a natural oak forest

AbstractEvapotranspiration (ET) is an important component in water budgets in forest ecosystems, and the associated latent heat flux has important implications for regional climate. However, biophysical control mechanisms on variations in ecosystem ET on intra‐annual scales may have year‐to‐year variations in different years with contrasting precipitation and soil water contents. Related research is lacking in natural oak forests in Central China. Based on eddy‐covariance technique, we investigated variations of ET and controlling factors in a natural oak forest in central China over three years (2017–2019) with contrasting soil water contents (SWCs) and precipitation. The ET of the oak forest was mainly affected by surface conductance (gs) in growing seasons, and the restriction from stoma on ET was aggravated in dry year. High vapour pressure deficit (VPD) promoted gs and ET in wet year but decreased gs and ET in dry year. There was a positive relationship between shallow soil water contents and gs in dry year but no relationship between the two variables in wet year. The ET were 738.1, 750.6 and 513.1 mm, respectively, for 2017–2019, with a coefficient of variation (CV) of 20%, while the corresponding precipitation (P) were 1239.4, 855.8 and 645.6 mm, with a CV of 33%. Annual ET was the lowest in the year with the lowest P, SWC and gs. Short‐term droughts (periods with relative extractable water content less than 0.1 for less than 15 days) only constrained gs and ET in short timescales (e.g., hours). Long‐term droughts (periods with relative extractable water content less than 0.1 for more than 15 days) evidently decreased the gs, thus reducing the ET and affecting energy partitioning in the corresponding period. ET/P were 0.6, 0.88 and 0.79 in 2017–2019, respectively, indicating that ET consumed most of the rain. The ratios of latent heat flux (LE) to net radiation (Rn) were 0.86, 0.88 and 0.6 during growing seasons in 2017–2019, respectively. Our study suggested that the natural oak forest has high ET rate and soil moisture affects the variations of ET.

Shifting concerns for the EU ETS: are carbon prices becoming too high?

Carbon prices in the EU Emissions Trading Scheme (EU ETS) have risen from around 5 euro per ton of CO2 in 2017 to above 90 euro in 2021. One probable explanation is the cancellation mechanism implemented along with the Market Stability Reserve (MSR) of the EU ETS in 2018. We identify realistic conditions under which the MSR results in truly massive cancellation of emissions allowances, pointing to the steepness of the emissions pathway over time as essential. A flattening of the emissions pathway implies huge reduction in cumulative emissions, suggesting much higher ETS prices. The concerns about too low and ‘ineffective’ carbon prices may turn into concerns for too high prices. The results have important ramifications for planned revisions of the EU ETS.

Levels of endothelin-1 and high molecular weight kininogen in blood of breast cancer patients after SARS-coV-2 infection

The aim. To analyze the blood levels of endothelin-1 (ET -1) and high molecular weight kininogen (HMWK) in patients with breast cancer (BC) previously infected with the new coronavirus.Material and methods. The study group included 20 patients with stage II -IV BC (invasive carcinoma). All patients were receiving chemotherapy at the time of their SA RS-CoV-2 infection. The comparison group included 19 women without breast cancer, who were matched for age. All women of both groups had an RT-PC R confirmed SA RS-Cov-2 infection. Blood levels of ET -1 and HMWK were measured by ELISA 3–10 weeks after the positive antigen test results. The control group included 10 women of the same age without cancer and without CO VID -19 symptoms and anti-SA RS-CoV-2 antibodies.Results. The ET -1 levels in the comparison group were within the reference range, while HMWK levels were significantly higher than those in breast cancer patients. In BC patients with lung metastases, the ET -1 levels were higher than those in the comparison group patients, while in others (no history of lung metastases, with mild infection course or pneumonia), the ET -1 levels were similar to those in the comparison and control groups. The HMWK levels in the study and comparison groups were significantly higher than those in controls. Among BC patients, there were women who had significantly higher ET -1 and HMWK levels compared to the reference levels, and the majority of these patients had lung metastases and previous CO VID -19 pneumonia.Conclusion. The measurement of HMWK blood levels demonstrated that the plasma contact activation system and the kallikrein-kinin system were active for a long period after the infection both in BC patients and in women without cancer. A high level of ET -1, the endothelial dysfunction marker, persisted for a long time in some BC patients. Our results were consistent with results of other studies supporting the hypothesis that SA RS-CoV-2 virus infection is a systemic vascular disease with long-term consequences, and its mechanisms require further study.

Design of new visible light Pt photocatalyst based on the TDDFT study of properties of transition metal complexes

AbstractVisible light photocatalysis has been paid a lot of attention because of its green and lower energy consuming. To trigger a reaction via energy transfer, a potential visible light photocatalyst not only has absorption under visible light but also needs a high triplet excitation energy. In this scene, the density functional theory B3LYP methods were used to investigate the properties of transition metal complex photocatalysts and design new potential visible light photocatalysts. The calculation result shows that the studied Ir complexes have a relatively high ET values (energy gap between the triplet excited state and ground state). The introduction of electron‐donating groups to Ir complexes causes a slight redshift in the absorption spectrum. Moreover, the electronic structure and atomic radius of the central metal atom have a great influence on the properties of those complexes of “fac‐M(ppy)3” (transition metal complexes with facial structure and three ppy ligands, M = Pt, Ni, Rh, Ru, Fe). Based on the study of transition metal complexes, new visible light Pt complex photocatalysts that have both good absorption under visible light and high ET value have been designed here. The designed new Pt complexes are expected to be potential candidates as visible light photocatalysts.

A remote sensing data fusion method for continuous daily evapotranspiration mapping at kilometric scale in Sahelian areas

Thermal infrared (TIR) remote sensing-based ET estimates are very appealing for a wide range of scientific applications in hydrology. However, they are prone to infrequency due to satellite revisit interval and cloud cover. Temporal interpolation techniques or multi-resolution and multi-frequency data fusion approach have thus recently been studied to provide continuous ET estimates. It has been already shown that the interest of temporal interpolation techniques is limited to short return interval that is troublesome in Sahelian regions where mesoscale convective systems linked to the West African Monsoon (WAM) renders unusable most of TIR images during the rainy season. Here we developed a data fusion approach to provide remote sensing-based continuous daily ET estimates at kilometric resolution in Sahelian areas. The proposed algorithm fill gaps in MODIS-based ET estimates from EVASPA S-SEBI Sahel (E3S) using the Global Land Evaporation: the Amsterdam Methodology (GLEAM) product and/or ET estimates from a simple parametric model for typical Sahelian ecosystems as a normalized basis. The fusion algorithm is evaluated at the pixel scale against eddy-covariance measurements and simulations of a locally calibrated and validated land surface model (LSM) on a millet crop and a fallow of shrubby savannah in the southwest of the Republic of Niger. Consistency of the fusion approach is also evaluated at mesoscale by comparing it with a set of 20 regional LSMs. Globally both level of comparison highlight the very good agreement of ET estimates based on the fusion approach with both in situ measurements and LSMs simulations. We also show the benefit of such a fusion approach compared to linear temporal interpolation techniques of the ratio between ET and either incoming solar radiation or reference evapotranspiration. The main benefits are observed during the first months of the rainy season in the depiction of the surface response to rainfall events and consecutive drying up of the surface soil layer. We suggest that such a fusion approach could be later used in disaggregation chain to enhance field scaled ET estimates by the combination of coarse, moderate and high resolution remote sensing-based ET estimates.