Appropriate saturation flux and long fluorescence lifetime are essential requirements for the gain medium in high-energy solid-state laser systems. A novel laser crystal Nd:PbF2 was grown successfully, and the optical performances were evaluated in detail. A theoretically relatively practical method revealing the relationship between the excited state population and doping concentration was developed to guide the optimization of Nd3+ doping concentration. The optical properties of different doping concentrations of Nd:PbF2 single crystals were studied in detail and compared with our theory to demonstrate the accuracy and feasibility of the proposed method. Furthermore, we found that the optimal doping concentration of Nd3+ in the PbF2 crystal was 1 %, with a fluorescence lifetime of 395.3 μs at ∼ 1.06 μm and a saturation flux of 5.8 J/cm2, which is close to the current one is comparable to phosphate glass widely used in nuclear fusion systems, indicating that the 1 % Nd: PbF2 crystal can be used as an excellent gain medium for high-energy lasers.
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