Higher Crustal Levels Research Articles

Oxygen isotope evidence for progressively assimilating trans-crustal magma plumbing systems in Iceland

Abstract The oxygen isotope composition of mantle-derived melts can place important constraints on how magmas are processed as they traverse the crust. Assimilation of crustal material is a crucial aspect of basalt petrogenesis, as it affects the chemical and rheological characteristics of eruptive magmas at active volcanoes. We report oxygen isotope (δ18O) and trace element (TE) data from a suite of well-characterized basaltic melt inclusions and groundmass glasses from the Bárðarbunga volcanic system in Iceland to assess how and where in the plumbing system crustal rocks interact with ascending magmas. While both melt inclusions and groundmass glasses record a large range in δ18O values (+3.2‰ to +6.4‰ and +2.6‰ to +5.5‰, respectively) groundmass glasses record lower values on average. Relationships between incompatible trace element (e.g., Zr/Nb) and oxygen isotope ratios are best explained with three-component mixing, where primary melts derived from depleted and enriched mantle components with distinct δ18O values mix and acquire a low-δ18O character upon progressive contamination with altered Icelandic crust. The majority (60%) of melt inclusions require 10–30% exchange of oxygen with the Icelandic crust. In addition, for the first time, we link the extent of oxygen isotope exchange with melt equilibration depths, showing that most of the contamination occurs at 1–2 kbar (3–7 km depth). We propose that a progressively assimilating, multi-tiered plumbing system is a characteristic feature of the Bárðarbunga volcanic system, whereby chemical modifications resulting from interaction with the crust systematically increase as melts migrate through higher crustal levels. We show that similar processes may also occur across the active rift zone in Iceland.

Permian Remelting and Maturity of Continental Crust Revealed by the Daqing Peraluminous Granitic Batholith, Inner Mongolia

AbstractThe Phanerozoic granites in northeast China bear key information for studying the tectonic evolution and crustal growth or reworking in the Central Asian Orogenic Belt (CAOB). The Daqing granitic batholith widely outcrops as a high-level intrusion in the Xing’an-Mongolia Orogenic Belt, southeastern CAOB. Three types of enclaves in granites have been identified: (1) mafic magmatic enclaves (MMEs), (2) volcanic xenoliths, and (3) biotite-rich enclaves. The batholith is mainly composed of peraluminous biotite granite and granodiorite with SiO2=63.95−69.48 wt.%, A/CNK=1.15−1.27, and 2.54 to 4.30 wt.% of normative corundum. They exhibit remarkable enrichment in large ion lithophile elements (LILEs; K, Rb, Th, and Pb) and depletion in high field strength elements (HFSEs; Nb, Ta, and Ti), P, Eu, and Sr, as well as relatively enriched Sr-Nd isotopes (87Sr/86Sri=0.70530−0.70576, εNdt=–0.1−+0.2). Zircon U-Pb dating suggests that this batholith was emplaced in the Early Permian (ca. 283-282 Ma), consistent with a period of intensive magmatic activities in northern Inner Mongolia. The Nb/Ta ratios of MMEs (17.6-20.1) are higher than those of the host granites (11.4-12.5), together with the reaction rims where biotite crystals cluster around the amphibole cores, suggesting magma mixing between mantle- and crust-derived melts. Zircons from a biotite-rich enclave define a protolith age of ca. 320 Ma and an anatectic age at ca. 281 Ma. Whole-rock Sr-Nd isotopic modelling and zircon Hf isotopes reveal that the batholith was mainly produced by remelting of newly accreted continental crust with minor addition of mantle-derived materials. The geochemical compositions imply that their precursor magmas originated from a relatively high crustal level (<5 kbar) with crystallization temperatures ranging from 800 to 850°C. We suggest that the Daqing peraluminous granitoids were derived from partial melting of newly accreted crustal materials at a relatively shallow crustal depth, associated with a ridge subduction-related heat source. Such mantle-derived magmas through a slab tear window resulting from ridge subduction provide not only the heat for the widespread crustal remelting and therefore maturity but also juvenile materials for crustal growth.

Variable magma flow in sills: Can a magma source be constrained?

It has been increasingly recognized that emplacement of mafic sills plays an important role in magma transport throughout the crust. However, further understanding of sill propagation and merging of flow within sill complexes in large igneous provinces is needed. This study focuses on outcrop along the KwaZulu-Natal North Coast (South Africa), where dolerite sills of the Karoo Large Igneous Province intruded shales, siltstones, and sandstones of the Permian-aged Vryheid Formation. These sills intruded at high crustal levels and are associated with significant vesiculation, host rock fluidization and brecciation. An integrated approach is used to examine sill morphology, intrusive relationships, and inherent structures in the sills in relation to the magma flow processes. Mesoscale magma flow indicators preserved in the sills include bridge structures, intrusive steps, deformed vesicles, and magma lobes. The predominantly prolate magnetic fabrics determined by anisotropy of magnetic susceptibility techniques indicate magma flow in the sills was oriented NW, NE–SW and SSE, and largely locally coaxial with field evidence. The mesoscale magma flow indicators developed from linkage between numerous sill segments and variation in the magma propagation direction within the plane of intrusion and show directional variation within (and between) sills. The local flow dynamics within each sill can be revealed in this way; however, the possible variation in flow in the intrusion must be considered when interpreting the gross magma flow direction of the entire sill network. The sills occur in close vertical proximity and are inferred to have intruded through lateral and upward magma flow within merging sill segments creating an interconnected sill network, fed from an eastward local magma source. Interpretation of magma flow in sills should be done with care, to avoid oversimplification regarding regional flow, and highly variable flow in sills is best reconciled at the field scale.

Structural Controls on Iron Oxide Copper-Gold Mineralization and Related Alteration in a Paleoproterozoic Supracrustal Belt: Insights from the Nautanen Deformation Zone and Surroundings, Northern Sweden

Abstract The Nautanen deformation zone in the Gällivare area of northern Sweden is a highly Cu-mineralized, magnetite-rich, large-scale shear zone with a long-lived (~100 m.y.) deformation, hydrothermal alteration, and mineralization history. This composite structure hosts the Aitik porphyry Cu-Au-Ag ± Mo deposit and several Cu-Au ± Fe ± Ag ± Mo occurrences assigned to the iron oxide copper-gold (IOCG) deposit class. The Nautanen deformation zone was a locus for polyphase deformation and intermittent metasomatic-hydrothermal activity that overprinted middle Orosirian (ca. 1.90–1.88 Ga) continental arc-related volcanic-plutonic rocks. The deformation zone is characterized by intense shearing fabrics that form a series of subvertical to moderately W-dipping, NNW-SSE–trending, first-order shear zones with oblique reverse kinematics and related NNE-SSW–oriented second-order shear zones that control hydrothermal alteration patterns and Cu-Au mineralization. Hydrothermal alteration in the study area formed during several phases. Volcanic-volcaniclastic rocks to the east and west of the Nautanen deformation zone display low to moderately intense, pervasive to selectively pervasive (i.e., patchy zones or bands, disseminations) sericite ± feldspar, amphibole + biotite + magnetite ± tourmaline, and K-feldspar + hematite alteration. Both the amphibole + biotite and K-feldspar + hematite associations occur adjacent to NNW- and NE-oriented deformation zones and are locally associated with minor sulfide. Within the deformation zone, a moderate to intense biotite + amphibole + garnet + magnetite + tourmaline + sericite alteration assemblage is typically associated with chalcopyrite + pyrrhotite + pyrite and forms linear and subparallel, mainly NNW-oriented seams, bands, and zones that locally appear to overprint possibly earlier scapolite + sericite ± feldspar alteration. Late-stage epidote ± quartz ± feldspar alteration (retrograde saussuritization) forms selectively pervasive zones and epidote veinlets across the area and is partly related to brittle faulting. A magnetite-amphibole-biotite–rich, penetrative S1 foliation records shortening during early Svecokarelian-related deformation (D1) and can be related to ca. 1.88 to 1.87 Ga arc accretion processes and basin inversion that overlaps with regional peak metamorphism to near mid-amphibolite facies conditions and a potential initial Cu mineralization event. Folding and repeated shearing along the Nautanen deformation zone can be assigned to a second, late-Svecokarelian deformation event (D2 stage, ca. 1.82–1.79 Ga) taking place at a higher crustal level. This D2 deformation phase is related to late-stage accretionary processes active during a transition to a stage of postorogenic collapse, and it was accompanied by abundant, syntectonic intrusions. D2-related magmatism produced high-temperature and low-pressure conditions and represents a regional magmatic-hydrothermal event that controlled the recrystallization/remobilization of magnetite, biotite, and amphibole. Associated shear zone reactivation during D2 favors the utilization of the Nautanen deformation zone as a fluid conduit, which preferentially controlled the siting and formation of epigenetic Cu-Au mineralization with distinctive IOCG characteristics within second-order shear zones.

U-Pb zircon geochronology and geochemical constraints on the Ediacaran continental arc and post-collision Granites of Wadi Hawashiya, North Eastern Desert, Egypt: Insights into the ~600 Ma crust-forming Event in the northernmost part of Arabian-Nubian Shield

The Wadi Hawashiya, North Eastern Desert of Egypt, is a mountainous granitic terrain exposing two Ediacaran granitoid suites, namely the Hawashiya Older Granites (HOG) and the Hawashiya Younger Granites (HYG). The HOG comprise normal to high-K, calc-alkaline, metaluminous granitoids (mainly quartz diorites), while the HYG are strongly high-K, calc-alkaline, slighty peraluminous syeno- and monzogranites. Zr is strikingly high (av. 335 ppm) in the HOG and is notably depleted (av. 108 ppm) in the more evolved HYG. The HYG have very low Nb contents almost matching those of the HOG (Nb ~ 6 ppm), which is typical of I-type granites generated at arc-type settings. Although the REE patterns of the HOG and HYG are comparably LREE-enriched with moderately steep slopes, the patterns of the HYG have significant deep negative Eu anomalies of variable magnitudes, whereas those of the HOG usually exhibit very shallow negative and occasional positive Eu anomalies. The assessed apatite crystallization temperatures for both granitoid suites are higher than those estimated from the zircon and monazite thermometers indicating that apatite crystallized before zircon and monazite from the melt. HOG evolved by assimilation-fractional crystallization processes from mantle-derived magmas, which subsequently interacted with crustal sources during ascent and residence in higher crustal levels. Correlating the whole-rock composition of the HYG to melts generated by experimental dehydration melting of meta-sedimentary and magmatic rocks reveals that they appear to be derived by extended melting of psammitic and pelitic metasediments. The HYG were emplaced (586–601 Ma) after the collision between the juvenile crust of the Arabian-Nubian Shield (ANS) and the older pre-Neoproterozoic continental blocks of Saharan Metacraton. The emplacement of HOG (622-611 Ma) had occured earlier (ca. 10 Ma) in a normal mature continental arc. The geochemical signatures and age data suggest that the terminal collision between East and West Gondwanaland in the northern tip of the ANS occurred before ~620 Ma, most likely at ~630 Ma, and transitioned to an extensional setting at ~600 Ma.

Granitoids of the Khara Complex in the Eastern Bureya Continental Massif of the Central Asian Orogenic Belt: Age and Geodynamic Settings of Formation

Petrogeochemical and geochronological studies were conducted on the main varieties of granitoids from the Sedelga and Berezovsky batholiths in the eastern Bureya continental Massif of the Central Asian Fold Belt. SHRIMP-II U–Pb zircon dating of granitoids constrained the time of formation to the Late Triassic and Early Jurassic between 208 to 193 Ma. Our studies revealed that the batholiths contain peraluminous granitoids of high K calc-alkaline series clearly enriched in Rb, K, Th, U, and Pb and relatively depleted in Nb, Ta, Y, HREE, Sr, Ba, Ti, and P and belong to I-type granites. Synthesis of the U–Pb geochronological data indicates that magmatism of tectonic blocks constituting the Bureya Massif at 213–183 Ma was accompanied by the emplacement of granitoid rocks of the Khara Complex. Strike-slip tectonics as a reflection of oblique collision of continental blocks and transform movement might have been an important mechanism of granitoid derivation in the Bureya Massif. Strike-slip faults were likely to penetrate deep into the crust initiating the ascent of an asthenospheric diapir and its fluids into the higher crustal levels thus transferring the heat and triggering melting with appreciable concentrations of Th, U, Rb, Pb and losses of Sr, P, Ba, and Ti. The depletion in Nb, Ta, Ti, and P and the enrichment in Pb make these granitoids similar to those of subduction zones. Granitoids of the Khara Complex display subduction-related (associated with the preceding subduction) and within-plate (associated with an asthenospheric diapir and its fluids) geochemical features, which is characteristic of transform margin environments. The most likely settings for granitoid magmatism to occur throughout the eastern margin of the Bureya Massif in the Late Triassic and Early Jurassic were transform settings associated with asthenospheric diapirism following the cessation of subduction.

Chapter 17 Accretionary orogens reworked in an overriding plate setting during protracted continent–continent collision, Sveconorwegian orogen, southwestern Sweden

Abstract The Eastern Segment in the Sveconorwegian orogen, southwestern Sweden, is dominated by 2.0–1.8, 1.7 and 1.5–1.4 Ga crust; and the overlying Idefjorden terrane by 1.6–1.5 Ga crust. Assuming reorganization of a subduction system prior to 1.5–1.4 Ga and applying a sinistral transpressive component of disruption during the subsequent Sveconorwegian orogeny (1.1–0.9 Ga), the Idefjorden terrane is inferred to be indigenous outboard rather than exotic with respect to the continental plate Fennoscandia (Baltica). The geological record then records successive westwards shift of accretionary orogens along a convergent plate boundary for at least 500 million years. Sveconorwegian foreland-younging tectonic cycles at c. 1.05 (or older)–1.02 Ga (Idefjorden terrane) and at c. 0.99–0.95 Ga (Eastern Segment) prevailed. Crustal thickening and exhumation during oblique convergence preceded migmatization, magmatic activity and a changeover to an extensional regime, possibly triggered by delamination of continental lithosphere, in each cycle. Convergence after 0.95 Ga involved antiformal doming with extensional deformation at higher crustal levels (Eastern Segment) and continued magmatic activity (Idefjorden terrane). An overriding plate setting is inferred during either accretionary orogeny or, more probably, protracted continent–continent collision. Continuity of the erosional fronts in the Grenville and Sveconorwegian orogens is questioned.

Genesis of the Banxi Sb deposit, South China: Constraints from wall-rock geochemistry, fluid inclusion microthermometry, Rb–Sr geochronology, and H–O–S isotopes

The Banxi Sb deposit is located in the world-class central-western Hunan Sb belt in South China, with quartz-vein type Sb-only mineralization hosted by Neoproterozoic epimetamorphic clastic sedimentary rocks. In this contribution, microthermometric, Rb–Sr geochronological and H–O isotopic analyses on fluid inclusions trapped in quartz, S isotopic studies on stibnite, and major-trace elemental measurements on fluid-altered and unaltered wall-rocks are presented to constrain the genesis of the deposit. The fluid inclusions are characterized by low homogenization temperature (170–260 °C) and low salinity 3–7 wt% NaCl equiv., with a low fluid density of 0.72–0.93 g/cm3 and a pH of 5.59. The low δDw (fluid δ2H, –140‰ to –107‰) whereas positive δ18OV-SMOW (15.9–17.2‰) and δ18Ow (fluid δ18O, 5.9–8.4‰) values in quartz indicate that the mineralizing fluid was generated from the low-grade metamorphic basement rocks and received a certain input of meteoric water. The Rb–Sr isotopic compositions of quartz samples yielded an isochron age of 196 ± 4 Ma (1σ, MSWD = 0.70) for quartz-stibnite ores. A highly radiogenic 87Sr/86Sr value (0.72663–0.74002, initial 87Sr/86Sr = 0.72640) indicates that ore-forming materials are derived mainly from basement rocks, and a direct material contribution from local granitic rocks can be ruled out. The δ34SV-CDT values of stibnite range narrowly from 4.81‰ to 6.72‰ and are in the δ34SV-CDT range of the metamorphic rocks, indicating that the sulfur was sourced from the basement rocks by sulfate reduction. Compositional differences between fluid-altered (decolorized) and unaltered wall-rocks are obvious: the migrated SiO2, SO3, LREE, Hf, Nb, Zr, Ta, Th, U, Mo, Sn, W into altered wall-rocks suggests a deep basement metamorphic rocks-derived Si-rich alkaline brine for the fluid-rock interaction; while the leached Fe2O3, MgO, MnO, TiO2, Ba, Cs, Rb, As, Co, V, Ni, Sb, Sc, Cu, Pb and Zn from the altered rocks imply a material contribution of Banxi Group wall-rocks during the Sb mineralization process. Consequently, we conclude that the quartz-stibnite stage of the Banxi Sb deposit was formed during the Late Triassic orogeny in the Xuefeng Mountain region. Heated by granitic magmatism, Sb and S were leached from the basement rocks, forming an initial Si-rich and alkaline ore-bearing fluid. Precipitation of stibnite from the fluid resulted from interacting with wall-rocks and mixing of meteoric water, coupled by releasing of stress, decreasing of temperature and lowering of the pH at higher crustal levels.

Magnetic fabric constraints for syn-magmatic doming of the laccolithic Brocken granite pluton (Harz Mountains, northern Germany)

Hyper-solidus fabrics of the early Permian Brocken granite pluton, exposed over an area of c. 160 km² and elongated in NNE–SSW direction, were determined by measuring the anisotropy of magnetic susceptibility (AMS). The Brocken granite pluton consists of five petrographically distinguishable and mappable granitic varieties characterized by a generally paramagnetic behavior with primary biotite, partly altered to chlorite, and secondary tourmaline as the major carrier of the susceptibility. Whereas biotite modal content isolines roughly follow petrographic trends, the tourmaline modal contents do not, hence implying secondary, post-emplacement processes that controlled tourmaline distribution. A few samples with primary and secondary magnetite show ferrimagnetic behavior and are co-axial with the paramagnetic fabrics. The generally low magnetic anisotropies in all granitic varieties are a distinct and challenging feature for determining magmatic flow directions. AMS data indicate the predominance of sub-horizontal fabrics outlining an NNE–SSW trending dome axis interpreted to have resulted from granite sheets stacked syn-magmatically in a high crustal level building up a laccolithic pluton. AMS fabrics together with age data and geophysical indications suggest that the emplacement and distribution of the Brocken granite pluton is structurally controlled by NNE–SSW striking deep fault structures, and only weakly influenced by WNW/NW-trending structures. Late Carboniferous-to-early Permian plutonism in the Harz Mountains evolved in an E–W directed extensional regime, and was accompanied by volcanic activity and development of NW- and NE-trending sedimentary basins.

Syn-orogenic magmatism over 100 m.y. in high crustal levels of the central Grenville Province: Characteristics, age and tectonic significance

The Escoumins Supracrustal Belt (ESB) represents higher levels of the infrastructure of a large hot orogen, exposed in a broadly dome and basin pattern. It consists of remnants of a Pinwarian-age (1.52–1.46 Ga) oceanic arc and arc-rift sequence, preserved in the low-P Belt of the central Grenville Province, and was intruded by diverse Grenvillian-age plutons. The plutonic rocks range from quartz monzodiorite to granite and have intrusion ages covering a time interval of ~100 My, that represents the entire range of the Grenvillian orogeny. Moreover, the ages, field relations and geochemical signatures of the different intrusions can be matched with different documented stages of the orogeny. The oldest pluton, the magnesian, biotite-bearing Bon-Désir granite (1086 ± 2 Ma), has positive εNd (+0.6), TDM = 1.52 Ga, and is attributed to melting of a juvenile Pinwarian crust as a result of slab break-off, at the onset of continental collision. The ferroan and Ba–Sr enriched, biotite-, amphibole- and clinopyroxene-bearing Michaud plutonic suite (1063 ± 3 Ma) and biotite-rich felsic sill (1045 ± 3 Ma) have εNd (−0.01 − +0.8) and TDM = 1.45–1.48 Ga. Their geochemistry is consistent with fractionation of a mafic magma derived from melting of a Geon 14 subduction-modified subcontinental lithospheric mantle. This magmatism is consistent with convective thinning of subcontinental lithosphere, potentially linked to tectonic extrusion and orogenic collapse. This collapse ultimately led to the juxtaposition of the low-P Belt with the high-T mid-P Belt in the hinterland of the Grenville Province and to amphibolite-facies metamorphism in the former, producing metamorphic zircon overgrowths at 1037 ± 10 Ma. Finally, 988 ± 5 Ma to 983 ± 5 Ma syn-kinematic peraluminous two-mica garnetiferous leucogranite bodies and pegmatites with inherited 1055 ± 2 Ma metamorphic monazite were derived from melting of previously metamorphosed deeper levels of the low-P Belt. This is consistent with a high geothermal gradient linked to thinning of the crust in a Basin and Range setting. The geochemical and age pattern of Grenvillian-age magmatism in the ESB, in conjunction with the overall architecture of the Province, suggests that Laurentia was the upper plate during the Grenvillian orogeny.

Petrography, geochemistry, and U–Pb geochronology of pegmatites and aplites associated with the Alvand intrusive complex in the Hamedan region, Sanandaj–Sirjan zone, Zagros orogen (Iran)

The Alvand intrusive complex in the Hamedan area in Iran is in the Sanandaj–Sirjan zone of the Zagros orogen. It consists of a wide range of plutonic rocks, mainly gabbro, diorite, granodiorite, granite, and leucogranites that were intruded by aplitic and pegmatitic dykes. At least three successive magmatic episodes generated an older gabbro–diorite–tonalite assemblage, followed by a voluminous granodiorite–granite association, which was then followed by minor leucocratic granitoids. Aplitic and pegmatitic dykes and bodies have truncated both plutonic rocks of the Alvand intrusive complex and its metamorphic aureole. Chemically they belong to peraluminous LCT (Li-, Cs-, and Ta-bearing) family of pegmatites. Mineralogically, they resemble Muscovite (MS) and Muscovite Rare Element (MSREL) classes of pegmatites. High amounts of some elements, such as Sn (up to 10,000 ppm), Rb (up to 936 ppm), Ba (up to 706 ppm), and LREE (up to 404 ppm) indicate the highly fractionated nature of some of these aplites and pegmatites. U–Pb dating of monazite, zircon, and allanite by LA-ICPMS indicate the following ages: monazite-bearing aplites of Heydareh-e-Poshteshahr and Barfejin areas, southwest of Hamedan, give an age range of 162–172 Ma; zircon in Heydareh-e-Poshteshar gives an average age of ~165 Ma and for allanite-bearing pegmatites of Artiman area, north of Tuyserkan, an age of 154.1 ± 3.7 Ma was determined. These overlap with previously reported ages (ca. 167–153 Ma) for the plutonic rocks of the Alvand complex. Therefore, these data reveal that the Jurassic was a period of magmatism in the Hamedan region and adjacent areas in the Sanandaj–Sirjan zone, which was situated at the southern edge of the central Iranian micro-plate (southern Eurasian plate) at this time. Our results also suggest that advective heating in a continental arc setting has caused melting of fertile supracrustal lithologies, such as meta-pelites. These partial melts were then emplaced at much higher crustal levels, but within a thermally anomalous environment, which, therefore, leads to formation of evolved felsic rocks, such as the studied LCT aplite–pegmatite suite and their parental granitic rocks. This is a new result that indicates the role of syn-subduction crustal partial melting in the region as part of Zagros orogeny.

Emplacement and temporal constraints of the Gondwanan intrusive complexes of northern Patagonia: La Esperanza plutono-volcanic case

Two main lines of evidence disagree whether or not the Patagonian blocks collided with Gondwana. All models invoke the voluminous magmatism of the La Esperanza Complex as evidence for active subduction magmatic arc or to a postcollisional setting. The evolution of this bimodal igneous suite is reassessed with field, geochronological (SHRIMP U-Pb zircon and K-Ar mica) and petrophysical data. Emplacement of high-K calk-alkaline granitic magmas occurred at shallow crustal levels (2–8±2km depth) related to the development and collapse of a caldera associated with a regional NW-SE structural trend. Magmatism involved intermediate hybrid pulses at 273±2Ma and 255±2Ma (Prieto Granodiorite) that shifted like a yo-yo to acidic magmas at 260±2Ma and 250±2Ma (Donosa and Calvo granites). Absence of solid-state deformation features and the low anisotropy degrees in the granites indicate that its fabric is magmatic in origin. Magnetic fabric in granodiorites displays a concentrical pattern with subhorizontal foliations and lineations. Parallel to the volcanic axis, magnetic foliations and moderately plunging lineations indicate a common feeder system for plutonics and volcanics. Donosa Granite shows a discordant pattern with WNW-ESE ENE-WSW trending low plunging lineations and foliations. The plutono-volcanic system construction (273–255Ma) followed NW-SE and NE-SW diamond shape faults trends and supracrustal discontinuities. Magmatic Climax is bracketed at 260Ma. The collapse of the edifice is evidenced by the intrusion of acid magma plugs and dike swarms between 250 and 246Ma. A similar age range was identified in other areas of Patagonia related to syn and postcollisional tectonic events. No evidence of tectonic activity such as major uplift, metamorphism or thrusting was found excepting regional strike-slip faulting and extension. Therefore, La Esperanza Complex is a high crustal level episode, and as such may not have structurally recorded an active collision during its crystallization and cooling.

Magnetic Anomaly Interpretation of the Northern Congo Craton Boundary: Results from Depth Estimation and 2.5D Modeling

A magnetic-based geophysical study was performed across the southern part of Cameroon to investigate the boundary between the Archean Congo craton and the Pan-African metamorphic belt. Magnetic gradient techniques including Euler deconvolution and Tilt derivative have been applied to an aeromagnetic data profile to determine the depth of sources and their lateral extension. 2.5D magnetic modeling shows that the prominent magnetic positive anomalies observed on total magnetic map of south Cameroon are produced by deep and strongly magnetic bodies under the Pan-African formations mainly an important dyke formation structure with a high susceptibility of 0.041 (SI units), at an average depth of 4148 m and with a lateral extension of about 10 km. These bodies are interpreted to have emplaced at high crustal levels in a continental collision zone and were subsequently metamorphosed at granulite grade conditions, during the Pan-African orogeny about 620 Ma ago.

Breccia formation during intrusion of a dolerite sill: an example from Sheffield Beach, KwaZulu-Natal North Coast, South Africa.

The breccia documented here is the first recorded occurrence of a sub-volcanic dolerite breccia developing due to the intrusion of overlapping dolerite sill segments in the Karoo Igneous Province (KIP) along the KwaZulu-Natal North Coast, South Africa. Recognising these breccias can assist in indicating the crustal level at which the dolerite sills intruded, as fragmentation of the country rocks will not occur beyond a certain depth. The breccia developed when two overlapping sill segments intruded into water-saturated Permian country rocks creating a laterally-extending dolerite-hosted breccia. The characteristics of the breccia, such as clast angularity and size, have been used to identify the fragmentation process of the rocks and infer the environment where it formed. Fragmentation of the lithified country rock is considered to be a consequence of heating between the sills causing vapourisation of the pore fluids, resulting in a dramatic increase of pressure beyond the yield strength of the rock and lateral propagation of the fragmentation. This brecciation process indicates that the dolerites intruded at a high crustal level and were thus intruded into a thin or thinning crust, possibly related to the rifting phase of the breakup of the supercontinent Gondwana.

40Ar/39Ar hornblende and biotite geochronology of the Bulfat Igneous Complex, Zagros Suture Zone, NE Iraq: New insights on complexities of Paleogene arc magmatism during closure of the Neotethys Ocean

In NE Iraq, the eastern edge of the Arabian plate is overlain by arc rock allochthons whose genesis and tectonic emplacement were related to the consumption and closure of the Neotethys Ocean. This paper demonstrates the occurrence of unrelated Paleogene arc rocks in two adjacent allochthons. The Bulfat Igneous Complex at Wadi Rashid (NE Iraq) is an intrusion within the Upper Allochthon Albian–Cenomanian Gimo–Qandil sequence suprasubduction zone assemblage. A thrust separates this allochthon from the underlying Lower Allochthon of the Eocene-Oligocene Walash–Naopurdan volcanic-sedimentary arc rocks. The Bulfat Igneous Complex at Wadi Rashid consists of gabbro and granitic composite intrusions in which components mingle down to a small scale. Textural relationships in the Bulfat Igneous Complex rocks indicate emplacement at high crustal levels with rapid cooling, which is consistent with amphibole geobarometry indicating crystallisation pressures between ~250 and 300Mpa. Ti-rich igneous pargasite and Ti-rich igneous Fe-biotite from gabbroic and granitic components yielded 40Ar/39Ar ages of 39.23±0.21 and 38.87±0.24Ma respectively. These ages agree within analytical error and suggest coeval emplacement and rapid cooling of mafic and felsic magmas in the Eocene, in an event that was distinct and much younger than the host Albian–Cenomanian rocks. This igneous event was unrelated to formation of Cenozoic rocks in the underlying, tectonically separate, lower allochthon. The trace element signatures of the Wadi Rashi volcanic rocks show volcanic-arc characteristics for the granites and the gabbroic rocks resemble E type MORB. The presence of Eocene arc-related rocks in two allochthons suggests complexity in Paleogene subduction systems, with possibly two subduction zones operating at that time.

Precise U-Pb zircon ages and geochemistry of Jurassic granites, Ellsworth-Whitmore terrane, central Antarctica

The Ellsworth-Whitmore Mountain terrane of central Antarctica was part of the early Paleozoic amalgamation of Gondwana, including a 13,000 m section of Cambrian−Permian sediments in the Ellsworth Mountains deposited on Grenville-age crust. The Jurassic breakup of Gondwana involved a regional, bimodal magmatic event during which the Ellsworth-Whitmore terrane was intruded by intraplate granites before translation of the terrane to its present location in central Antarctica. Five widely separated granitic plutons in the Ellsworth-Whitmore terrane were analyzed for their whole-rock geochemistry (X-ray fluorescence), Sr, Nd, and Pb isotopic compositions, and U-Pb zircon ages to investigate the origins of the terrane magmas and their relationships to mafic magmatism of the 183 Ma Karoo-Ferrar large igneous province (LIP). We report high-precision (±0.1 m.y.) isotope dilution−thermal ionization mass spectrometry (ID-TIMS) U-Pb zircon ages from granitic rocks from the Whitmore Mountains (208.0 Ma), Nash Hills (177.4−177.3 Ma), Linck Nunatak (175.3 Ma), Pagano Nunatak (174.8 Ma), and the Pirrit Hills (174.3−173.9 Ma), and U-Pb sensitive high-resolution ion microprobe (SHRIMP) ages from the Whitmore Mountains (200 ± 5 Ma), Linck Nunatak (180 ± 4 Ma), Pagano Nunatak (174 ± 4 Ma), and the Pirrit Hills (168 ± 4 Ma). We then compared these results with existing K-Ar ages and Nd model ages, and used initial Sr, Nd, and Pb isotope ratios, combined with xenocrystic zircon U-Pb inheritance, to infer characteristics of the source(s) of the parent magmas. We conclude that the Jurassic plutons were not derived exclusively from crustal melts, but rather they are hybridized magmas composed of convecting mantle, subcontinental lithospheric mantle, and lower continental crustal contributions. The mantle contributions to the granites share isotopic similarities to the sources of other Jurassic LIP mafic magmas, including radiogenic 87Sr/86Sr (0.706−0.708), unradiogenic 143Nd/144Nd (eNd < −5), and Pb isotopes consistent with a low-µ source (where μ = 238U/204Pb). Isotopes and zircon xenocrysts point toward a crustal end member of predominantly Proterozoic provenance (0.5−1.0 Ga; Grenville crust), extending the trends illustrated by Ferrar mafic intrusive rocks, but contrasting with the inferred Archean crustal and/or lithospheric mantle contributions to some basalts of the Karoo sector of the LIP. The Ellsworth-Whitmore terrane granites are the result of mafic rocks underplating the hydrous crust, causing crustal melting, hybridization, and fractionation to produce granitic magmas that were eventually emplaced as post-Ferrar, within-plate melts at higher crustal levels as the Ellsworth-Whitmore terrane rifted off Gondwana (47°S) before migrating to its current position (82°S) in central Antarctica.

Mafic monogenetic vents at the Descabezado Grande volcanic field (35.5°S–70.8°W): the northernmost evidence of regional primitive volcanism in the Southern Volcanic Zone of Chile

In the Andean Southern Volcanic Zone (SVZ), the broad distribution of mafic compositions along the recent volcanic arc occurs mainly south of 37°S, above a comparatively thin continental crust (≤~35 km) and mostly associated with the dextral strike-slip regime of the Liquine–Ofqui Fault Zone (LOFZ). North of 36°S, mafic compositions are scarce. This would be in part related to the effect resulting from protracted periods of trapping of less evolved ascending magmas beneath a thick Meso-Cenozoic volcano-sedimentary cover that lead to more evolved compositions in volcanic rocks erupted at the surface. Here, we present whole-rock and olivine mineral chemistry data for mafic rocks from four monogenetic vents developed above a SVZ segment of thick crust (~45 km) in the Descabezado Grande volcanic field (~35.5°S). Whole-rock chemistry (MgO > 8 wt%) and compositional variations in olivine (92 ≥ Fo ≥ 88 and Ni up to ~3650 ppm) indicate that some of the basaltic products erupted through these vents (e.g., Los Hornitos monogenetic cones) represent primitive arc magmas reaching high crustal levels. The combined use of satellite images, regional data analysis and field observations allow to recognize at least 38 mafic monogenetic volcanoes dispersed over an area of about 5000 km2 between 35.5° and 36.5°S. A link between ancient structures inherited from pre-Andean tectonics and the emplacement and distribution of this mafic volcanism is suggested as a first-order structural control that may explain the widespread occurrence of mafic volcanism in this Andean arc segment with thick crust.

Giant plagioclase basalts: Continental flood basalt–induced remobilization of anorthositic mushes in a deep crustal sill complex

Giant plagioclase basalts, rich in plagioclase megacrysts commonly 5 cm long, form widespread lava flows and dikes in the Deccan Traps continental flood basalt province. They also occur in the Scottish Hebrides, Columbia River, and Emeishan continental flood basalt provinces, and closely similar rocks are known from Archean and Proterozoic terrains and oceanic settings. The giant plagioclase basalts have usually been interpreted as end products of magmatic cycles operating in high-level chambers, and taken as the boundaries of stratigraphic formations. A new model is proposed in which the plagioclase megacrysts grow over long (15 k.y.) time periods in a deep crustal (possibly Moho-level) sill complex, which forms tens to hundreds of thousands of years before the continental flood basalt eruptions. Megacryst flotation produces anorthositic mushes containing ferrodioritic interstitial liquids. Giant plagioclase basalts form when these components (and any melt from the crust heated by the sill complex) are remobilized by a newly injected tholeiitic magma batch, and brought to the surface or high crustal levels by dikes. Giant plagioclase basalts are thus mixed, heterogeneous rocks from the deep continental crust. The new model explains a range of geological, petrological, mineralogical, and geochemical data on the giant plagioclase basalts. Formation and remobilization of anorthositic mushes appear to be fundamental processes producing highly feldspar-phyric basalts over a wide range of tectonic settings. An important corollary of the new model is that anorthosites have continued to form well after the Precambrian, on a smaller scale, during Phanerozoic continental flood basalt events. Therefore, continental flood basalt provinces should be recognized as sites of anorthosite formation in the deep continental crust.

Thickness of the lithosphere beneath Precambrian cratons and mechanisms of their neotectonic crustal uplift

Up to 70% of the area of continents is occupied by the Precambrian crust. Shortening of this crust finished 0.5 Ga ago or earlier, while Pliocene–Quaternary rises made up of 100–200 to 1000–1500 m. In order to support these uplifts in the absence of shortening, the density in the lithosphere layer had to be considerably decreased. This lower density can be attributed to the replacement of the lower part of the mantle lithosphere with asthenospheric material or to the expansion of the inner parts of the crust resulting from repeated metamorphism. As is shown by our calculations, a decrease in density at depths of 150–250 km beneath the Precambrian cratons can lead to uplifts only up to 100 m in amplitude. Hence, the neotectonic uplifts were caused by expansion at higher crustal levels. This situation required the supply of a large amount of mantle fluid into the crust, and the volume of this fluid should be comparable to that of the new-formed relief

Mineralogy and geochemistry of indium-bearing polymetallic veins in the Sarvlaxviken area, Lovisa, Finland

A number of polymetallic vein mineralizations of different styles and metal associations, including base, alloy, noble and critical metals, have been discovered around the Sarvlaxviken bay in the westernmost parts of the Mesoproterozoic Wiborg Batholith, south-eastern Finland. The veins occur in two rapakivi granite varieties: coarse-grained wiborgite; and medium-grained Marviken granite. The veins are divided into five groups based on the dominant metal associations.The Li–As–W–Zn–Mn, Pb–Zn and Cu–As–In associations are hosted by wiborgite, and are strongly controlled by a NNW-trending tectonic pattern that evolved in two main stages. The Li–As–W–Zn–Mn association (generation 1) formed in a typical greisen environment with Li-bearing mica in significant alteration halos around a narrow quartz vein. This greisenization was accompanied by silicification, followed by sericitization and chloritization. The Pb–Zn association occurs in a similar vein type but without typical high-temperature minerals and is considered to have formed at a higher crustal level. Generations 2a and 2b formed under more brittle conditions leading to fracturing, quartz veining and metal precipitation of ore minerals. This metal association is characterized by very high contents of Cu, As and up to 1490ppm In but with ≤0.4% Zn, which leads to very high In/Zn ratios (up to 8400) enabling formation of abundant roquesite.The As–Sn–Cu and Mo–Bi–Be associations are hosted by alteration zones without hydrothermal quartz in the Marviken granite. Mineralization with moderately high contents of As, Sn and Cu is associated with greisenization while mineralization with spectacular contents of Be as well as high contents of Mo and Bi is associated with sericitization, chloritization and berylification.The internal age relations between the wiborgite-hosted, NNW-trending veins show a clear evolution from a typical greisen type environment (the Li–As–W–Zn–Mn and Pb–Zn associations of generation 1) to cooler and more brittle conditions governing quartz veining and precipitation of ore minerals belonging to the Cu–As–In association (generations 2a and 2b). The age relations between these wiborgite-hosted veins and the veins in the Marviken granite are more uncertain but the presence of a NS-trending granitic dyke on the eastern side of the Sarvlaxviken bay, with similar ore-fertile geochemical composition as the Marviken granite, indicates that the tectonically controlled veins formed simultaneously with the emplacement of the Marviken granite and associated hydrothermal activity.The polymetallic veins in the Sarvlaxviken bay are unique for the Fennoscandian Shield, not the least for the locally high indium grades and spectacular roquesite grains. There is an obvious exploration potential for similar veins (and hence a number of base, alloy, noble and critical metals) also elsewhere in the entire Wiborg Batholith.