High Configurational Entropy Research Articles

High Configuration Entropy Promises Electrochemical Stability of Chloride Electrolytes for High‐Energy, Long‐Life All‐Solid‐State Batteries

AbstractSolid‐state electrolytes (SSEs) with high ionic conductivity, stability, and interface compatibility are indispensable for high‐energy‐density and long‐life all‐solid‐state batteries (ASSBs), yet there are scarce SSEs with sufficient ionic conductivity and electrochemical stability. In this study, with a high‐entropy SSE (HE‐SSE, Li2.9In0.75Zr0.1Sc0.05Er0.05Y0.05Cl6), we show the high configuration entropy has a thermodynamically positive relationship with the high‐voltage stability. As a result, the ASSBs with HE‐SSE and high‐voltage cathode materials exhibit superior high‐voltage and long‐cycle stability, achieving 250 cycles with 81.4 % capacity retention when charged to 4.8 V (vs. Li+/Li), and even 5000 cycles if charged to 4.6 V (vs. Li+/Li). Experimental characterizations and density functional theory calculations confirm that the HE‐SSE greatly suppresses the high‐voltage degradation of SSE at the interface, promoting the high‐voltage stability coordinately through high entropy and interface stability. The high entropy design offers a general strategy to simultaneously improve the high‐voltage stability and ionic conductivity of SSEs, creating an avenue to building high‐energy and long‐life ASSBs.

High Configuration Entropy Promises Electrochemical Stability of Chloride Electrolytes for High-Energy, Long-Life All-Solid-State Batteries.

Solid-state electrolytes (SSEs) with high ionic conductivity, stability, and interface compatibility are indispensable for high-energy-density and long-life all-solid-state batteries (ASSBs), yet there are scarce SSEs with sufficient ionic conductivity and electrochemical stability. In this study, with a high-entropy SSE (HE-SSE, Li2.9In0.75Zr0.1Sc0.05Er0.05Y0.05Cl6), we show the high configuration entropy has a thermodynamically positive relationship with the high-voltage stability. As a result, the ASSBs with HE-SSE and high-voltage cathode materials exhibit superior high-voltage and long-cycle stability, achieving 250 cycles with 81.4 % capacity retention when charged to 4.8 V (vs. Li+/Li), and even 5000 cycles if charged to 4.6 V (vs. Li+/Li). Experimental characterizations and density functional theory calculations confirm that the HE-SSE greatly suppresses the high-voltage degradation of SSE at the interface, promoting the high-voltage stability coordinately through high entropy and interface stability. The high entropy design offers a general strategy to simultaneously improve the high-voltage stability and ionic conductivity of SSEs, creating an avenue to building high-energy and long-life ASSBs.

Enhancing the performance of PNN-PHT perovskite ferroelectric via configurational entropy strategy: Component design, electric properties, and mechanism analysis

The traditional approach to designing ferroelectrics through phase boundaries has limitations in regulating polarization configuration and achieving significant performance enhancements. In contrast, the concept of high-entropy materials has emerged as a promising strategy for designing new materials with enhanced properties. Herein, by incorporating the high configurational entropy (Sconfig) strategy, the investigation explored the influence of Sconfig on the electrical properties of PNN-PHT piezoceramics. The results demonstrated that high Sconfig values were highly beneficial in improving the piezoelectric properties and significantly influenced the microstructure and grain size. The increase in Sconfig value was found to be positively correlated with the Rayleigh coefficient (α), dielectric loss (tanδ), and frequency dispersion (γ), while inversely correlated with the coercive electric field (Ec). By exploring the mechanism via Raman and simulation analyses, it was discovered that high Sconfig induces enhanced disorder, increased lattice distortion, and sharp volume changes. This ultimately resulted in a richer phase structure, reducing the potential energy barriers and leading to a lower activation energy (Ea) required for polarization switching. This finding provides novel strategies and directions for the development of high-voltage and high-coercive-field materials, holding promise for designing piezoelectric devices with enhanced power density and precision.

Element Screening Engineering for High-Entropy Alloy Anodes: Achieving Fast and Robust Li-Storage With Optimal Working Potential.

While the high-entropy strategy is highly effective in enhancing the performance of materials across various fields, an optimal methodology for selecting component elements for performance optimization is still lacking. Here the findings on uncovering the element selection rules for rational design of high-entropy alloy anodes with exceptional lithium storage performance are reported. It is investigated high-entropy element screening rules by modifying stable diamond-structured Ge with P to induce a tetrahedrally coordinated sphalerite structure for enhanced metallic conductivity, further stabilized by incorporating Zn and other elements. Moreover, both theoretical and experimental results confirm that Li-storage performance improves with increasing atomic number: BZnGeP3 < AlZnGeP3 < GaZnGeP3 < InZnGeP3. InZnGeP3-based electrodes demonstrate the highest Li-ion affinity, fastest electronic and Li-ion transport, largest Li-storage capacity and reversibility, and best mechanical integrity. Further element screening based on the above criteria leads to high entropy alloy anodes with metallic conductivity like GaCuSnInZnGeP6, GaCu(or Sn)InZnGeP5, CuSnInZnGeP5, InZnGePSeS(or Te), InZnGeP2S(or Se) which show superior Li-storage performances. The excellent phase stability is attributed to their high configurational entropy. This study offers profound insights into element screening for high-entropy alloy-based anodes in Li-ion batteries, providing guidance and reference for the element combination and screening of other high-entropy functional materials.

Designing water resistant high entropy oxide materials

The ubiquitous presence of moisture usually shows adverse effects on industrial catalysis. Herein, a concept of engineering entropy to design water-resistant oxide catalysts is proposed. The C3H6 oxidation by spinel ACr2O4 (A=Ni, Mg, Cu, Zn, Co) catalysts is selected as a model. Through DFT calculation, the adsorption energy of C3H6, the dissociation energy of molecular H2O on the oxide surface, and the formation energy of oxygen vacancy all suggest better performance induced by higher configurational entropy. Indeed, (Ni0.2Mg0.2Cu0.2Zn0.2Co0.2)Cr2O4 experimentally show excellent water resistance (>100 h) in C3H6 oxidation, while in sharp contrast binary oxides (e.g., NiCr2O4, CoCr2O4) are deactivated in 20 h. H2O-TPD, in-situ Raman, and in-situ FTIR all confirm the low H2O adsorption energy and strong hydrothermal stability of high entropy oxide, which is attributed to their lower Gibbs free energy. This work may inspire the rational design of water-resistant catalysts.

Nano‐High Entropy Materials in Electrocatalysis

AbstractHigh entropy materials (HEMs) compositing of at least five elements have gained widespread attention in the field of electrocatalysis due to their tunable activities and high stability. These intrinsic properties can be further highlighted when the size of HEMs comes to the nanoscale. In nanostructured HEMs, the fascinating properties including large composition space, multi‐element synergy, and high configuration entropy are expected to endow nano‐HEMs with excellent catalytic activity and stability, thus providing greater potential for the design of advanced electrocatalysts. In this review, nano‐HEMs are differentiated in detail in dimensions and the common synthesis methods are summarized. Additionally, from the perspective of the complex nanostructure‐performance relationship, the applications of nano‐HEMs in electrocatalysis systems, including water‐splitting (hydrogen evolution reaction (HER), oxygen evolution reaction (OER)), hydrogen oxidation reaction (HOR), oxygen reduction reaction (ORR), carbon dioxide reduction reaction (CO2RR), nitrogen reduction reaction (NRR) and alcohol oxidation reaction (AOR) are discussed. Finally, the main challenges faced by nano‐HEMs electrocatalysis are underscored. This review is expected to provide more insights into understanding and developing efficient electrocatalytic materials for practical applications.

Enhanced high-temperature performance of selected high-entropy rare earth disilicates

First-principles calculations were utilized to evaluate the synthesis feasibility of (Yb0.2Y0.2Lu0.2Ho0.2Er0.2)2Si2O7, (Yb0.2Tm0.2Lu0.2Sc0.2Er0.2)2Si2O7, (Yb0.2Tm0.2Lu0.2Sc0.2Gd0.2)2Si2O7, and (Yb0.2Y0.2Lu0.2Sc0.2Gd0.2)2Si2O7, followed by their fabrication using the solid-phase reaction method. This study investigates the thermal properties of four novel high-entropy rare earth disilicates and compares them with Yb2Si2O7, a material known for its high-temperature stability. The aim was to explore the influence of high configurational entropy and small grain size on enhancing material properties that are critical in high-temperature applications. Key findings demonstrated that these high-entropy materials exhibit lower thermal conductivity, higher specific heat capacity, an0d reduced coefficient of thermal expansion compared to Yb2Si2O7. Among them, (Yb0.2Tm0.2Lu0.2Sc0.2Er0.2)2Si2O7 and (Yb0.2Y0.2Lu0.2Ho0.2Er0.2)2Si2O7 have the lowest thermal conductivity and suitable CTE, making them the best choices for advanced thermal/environmental barrier coatings in high-temperature applications. Furthermore, the in-depth discussion in this study provides guidance for designing high-entropy rare earth disilicate materials with ideal CTE and thermal insulation properties.

Fabrication of aqueous asymmetric supercapacitor device by using spinel type (FeCoNiCuZn)3O4 high entropy oxide and green carbon derived from plastic wastes

As the world shifts towards renewable energy and more efficient energy storage systems, the demand for advanced materials that can support these technologies has increased. One such promising material class is High Entropy Alloys (HEAs). Unlike conventional alloys, which are typically composed of one or two principal elements, HEAs consist of multiple principal elements in near-equiatomic proportions. Their unique atomic structure, characterized by high configurational entropy, endows them with enhanced stability, tunability, and a high specific surface area—qualities that are highly desirable in supercapacitor applications. HEAs offer significant advantages as supercapacitor electrodes, including increased energy storage capacity, superior electrochemical stability, and the potential for synergistic effects that improve overall performance such as higher energy density, longer cycle life, and greater reliability. FeCoNiCuZn)3O4 has been synthesized by utilizing multiple induction melting process in a quartz tube at 1100 °C, followed by ball milling in order to transform the small pieces into nanostructured powder. The highest specific capacitance obtained is 245.7 F g−1 at 1.5 A g−1 in three electrode measurement system. In addition, plastic biochar was prepared using pyrolysis techniques from plastic wastage. Moreover, it is utilized for supercapacitor application, which shows a maximum specific capacitance of 180 F g−1 at 1 A g−1 for three electrode system. The combing above two electrode materials, the fabricated asymmetric device shows a maximum specific capacitance of 58 F g−1 at 1 A g−1 for 3M KOH electrolyte with maximum specific energy of 23.44 Wh kg−1 at specific power of 1700 W kg−1.

High-Entropy Metal-Organic Frameworks (HEMOFs): A New Frontier in Materials Design for CO2 Utilization.

High-entropy materials (HEMs) emerged as promising candidates for a diverse array of chemical transformations, including CO2 utilization. However, traditional HEMs catalysts are nonporous, limiting their activity to surface sites. Designing HEMs with intrinsic porosity can open the door toward enhanced reactivity while maintaining the many benefits of high configurational entropy. Here, a synergistic experimental, analytical, and theoretical approach to design the first high-entropy metal-organic frameworks (HEMOFs) derived from polynuclear metal clusters is implemented, a novel class of porous HEMs that is highly active for CO2 fixation under mild conditions and short reaction times, outperforming existing heterogeneous catalysts. HEMOFs with up to 15 distinct metals are synthesized (the highest number of metals ever incorporated into a single MOF) and, for the first time, homogenous metal mixing within individual clusters is directly observed via high-resolution scanning transmission electron microscopy. Importantly, density functional theory studies provide unprecedented insight into the electronic structures of HEMOFs, demonstrating that the density of states in heterometallic clusters is highly sensitive to metal composition. This work dramatically advances HEMOF materials design, paving the way for further exploration of HEMs and offers new avenues for the development of multifunctional materials with tailored properties for a wide range of applications.

Synergistic Performance of Thermoelectric and Mechanical in Nanotwinned High-Entropy Semiconductors AgMnGePbSbTe5.

Introducing nanotwins in thermoelectric materials represents a promising approach to achieving such a synergistic combination of thermoelectric properties and mechanical properties. By increasing configurational entropy, a sharply reduced stacking fault energy in a new nanotwinned high-entropy semiconductor AgMnGePbSbTe5 is reached. Dense coherent nanotwin boundaries in this system provide an efficient phonon scattering barrier, leading to a high figure of merit ZT of ≈2.46 at 750K and a high average ZT of ≈1.54 (300-823K) with the presence of Ag2Te nanoprecipitate in the sample. More importantly, owing to the dislocation pinning caused by coherent nanotwin boundaries and the chemical short-range disorder caused by the high configurational entropy effect, AgMnGePbSbTe5 also exhibits robust mechanical properties, with flexural strength of 82MPa and Vickers hardness of 210HV.

Manufacturing of Ni-Co-Fe-Cr-Al-Ti High-Entropy Alloy Using Directed Energy Deposition and Evaluation of Its Microstructure, Tensile Strength, and Microhardness.

High-entropy alloys (HEAs) have drawn significant attention due to their unique design and superior mechanical properties. Comprising 5-35 at% of five or more elements with similar atomic radii, HEAs exhibit high configurational entropy, resulting in single-phase solid solutions rather than intermetallic compounds. Additive manufacturing (AM), particularly direct energy deposition (DED), is effective for producing HEAs due to its rapid cooling rates, which ensure uniform microstructures and minimize defects. These alloys typically form face-centered cubic (FCC) or body-centered cubic (BCC) structures, contributing to their exceptional strength, hardness, and mechanical performance across various temperatures. However, FCC-structured HEAs often have low yield strengths, posing a challenge for structural applications. In this study, a Ni-Co-Fe-Cr-Al-Ti HEA was manufactured using the DED method. This study proposes that the addition of aluminum and titanium creates a γ + γ' phase structure within a multicomponent FCC-HEA matrix, enhancing the thermal stability and coarsening the resistance and strength. The γ' phase with an ordered FCC structure significantly improves the mechanical properties. Analysis confirmed the presence of the γ + γ' structure and demonstrated the alloy's high tensile strength and microhardness. This approach underscores the potential of AM techniques in advancing HEA production for high-performance applications.

Structural Particularities, Prediction, and Synthesis Methods in High-Entropy Alloys

High-Entropy Alloys (HEAs) represent a transformative class of materials characterized by multiple principal elements and high configurational entropy. This review article provides an in-depth examination of their structural particularities, prediction methodologies, and synthesis techniques. HEAs exhibit unique structural stability due to high-entropy effects, severe lattice distortions, and slow diffusion processes. Predictive models, including thermodynamic and kinetic approaches, are essential for understanding phase stability. Various synthesis methods impact HEA properties, and advanced characterization techniques are crucial for their study. The article highlights current applications and future research directions, emphasizing the potential of HEAs in diverse technological fields.

Temperature-dependent dielectric behavior of A6B2O17 (A = Zr, Hf; B = Nb, Ta) phases

We report on temperature-dependent dielectric behavior of disordered ternary A6B2O17 (A = Zr, Hf; B = Nb, Ta)-form oxides in the GHz frequency range. The microwave dielectric properties including relative permittivity, dielectric loss, and temperature-dependent relative permittivity were characterized using cylindrical dielectric resonators using a resonant post measurement technique. Dielectric measurements through the resonant post method approach generally agree with dielectric measurements of A6B2O17 bulk ceramics measured through standard resonant post techniques. Coefficients describing the temperature-dependent relative permittivity for ternary A6B2O17 phases are strongly positive, suggesting contributions to polarizability arising from long-range mechanisms potentially associated with structural disorder. These observations support the working hypothesis that material functionality can be engineered by the chemical diversity and structural disorder possible in high configurational entropy A6B2O17 phases.

High Entropy Protected Sharp Magnetic Transitions in Highly Disordered Spinel Ferrites.

How disorder affects magnetic ordering is always an intriguing question, and it becomes even more interesting in the recently rising high entropy oxides due to the extremely high disorder density. However, due to the lack of high-quality single crystal samples, the strong compositional disorder effect on magnetic transition has not been deeply investigated. In this work, we have successfully synthesized high-quality single crystalline high entropy spinel ferrites (Mg0.2Mn0.2Fe0.2Co0.2Ni0.2)xFe3-xO4. Our findings from high-temperature magnetization and neutron diffraction experiments showed ferrimagnetic transitions at 748, 694, and 674 K for x values of 1, 1.5, and 1.8, respectively. Notably, the magnetic transition almost showed no broadening for x values of 1 and 1.5, compared to Fe3O4. Extended X-ray absorption fine structure measurements provided insights into the elemental distribution among the octahedral and tetrahedral sites. The random distribution of elements across these sites reduced the formation of local clusters and short-range orders, enhancing sample homogeneity and preserving the sharpness of the magnetic transition, despite bond length variation. Our study not only marks the first successful synthesis of an HEO bulk single crystal exhibiting long-range magnetic order but also sheds light on the interaction between high configurational entropy and magnetic orderings. This opens new avenues for future research and applications of magnetic high entropy oxides.

Continuous polyamorphic transition in high-entropy metallic glass

Polyamorphic transition (PT) is a compelling and pivotal physical phenomenon in the field of glass and materials science. Understanding this transition is of scientific and technological significance, as it offers an important pathway for effectively tuning the structure and property of glasses. In contrast to the PT observed in conventional metallic glasses (MGs), which typically exhibit a pronounced first-order nature, herein we report a continuous PT (CPT) without first-order characteristics in high-entropy MGs (HEMGs) upon heating. This CPT behavior is featured by the continuous structural evolution at the atomic level and an increasing chemical concentration gradient with temperature, but no abrupt reduction in volume and energy. The continuous transformation is associated with the absence of local favorable structures and chemical heterogeneity caused by the high configurational entropy, which limits the distance and frequency of atomic diffusion. As a result of the CPT, numerous glass states can be generated, which provides an opportunity to understand the nature, atomic packing, formability, and properties of MGs. Moreover, this discovery highlights the implication of configurational entropy in exploring polyamorphic glasses with an identical composition but highly tunable structures and properties.

Carbon cloth supporting (CrMnFeCoCu)3O4 high entropy oxide as electrocatalyst for efficient oxygen evolution reactions

High-entropy oxides (HEOs) have received more attentions for the oxygen evolution reaction (OER) due to their rich active sites and high configurational entropy. However, the difficulty of electron transfer during the catalysis process limits the application of HEOs in OER catalysis. Herein, we proposed the carbon cloth (CC) supporting (CrMnFeCoCu)3O4 HEO with spinel structure synthesized by the hydrothermal method following with the calcination. The carbon cloth used as the support of HEO could improve the conductivity and stability of the catalyst. Meanwhile, the excellent catalytic activity of HEO with the synergistic effects of multiple metal elements would be maintained. And the homo-disperse HEO nanoparticles were exposed on the surface carbon fibers, which was conducive to contact with electrolyte. Based on the above merits, the intrinsic catalytic activity of (CrMnFeCoCu)3O4/CC was enhanced, which was attributed to the self-regulating electronic structure and the fine HEO nanoparticles exposed on the surface of catalysts. And the catalytic kinetic process of (CrMnFeCoCu)3O4/CC was accelerated, mainly due to its conductivity and richer oxygen vacancies. The (CrMnFeCoCu)3O4/CC exhibited the outstanding OER performance with an ultralow overpotential (210.8 mV @10 mA·cm−2), a smaller Tafel slope value (59.4 mV·dec−1), and super long-term durability, which was competitive with other transition metal oxides based catalysts and noble metal oxides. Therefore, the excellent OER performance implied that the (CrMnFeCoCu)3O4/CC is an OER catalyst candidate for practical application.

High-entropy relaxor ferroelectric ceramics for ultrahigh energy storage

Dielectric ceramic capacitors with ultrahigh power densities are fundamental to modern electrical devices. Nonetheless, the poor energy density confined to the low breakdown strength is a long-standing bottleneck in developing desirable dielectric materials for practical applications. In this instance, we present a high-entropy tungsten bronze-type relaxor ferroelectric achieved through an equimolar-ratio element design, which realizes a giant recoverable energy density of 11.0 J·cm−3 and a high efficiency of 81.9%. Moreover, the atomic-scale microstructural study confirms that the excellent comprehensive energy storage performance is attributed to the increased atomic-scale compositional heterogeneity from high configuration entropy, which modulates the relaxor features as well as induces lattice distortion, resulting in reduced polarization hysteresis and enhanced breakdown endurance. This study provides evidence that developing high-entropy relaxor ferroelectric material via equimolar-ratio element design is an effective strategy for achieving ultrahigh energy storage characteristics. Our results also uncover the immense potential of tetragonal tungsten bronze-type materials for advanced energy storage applications.

High Entropy Spinel Oxide (AlCrCoNiFe2)O as Highly Active Oxygen Evolution Reaction Catalysts.

The advancement of water electrolyzer technologies and the production of sustainable hydrogen fuel heavily rely on the development of efficient and cost-effective electrocatalysts for the oxygen evolution reaction (OER). High entropy ceramics, characterized by their unique properties, such as lattice distortion and high configurational entropy, hold significant promise for catalytic applications. In this study, we utilized the sol-gel autocombustion method to synthesize high entropy ceramics containing a combination of 3d transition metals and aluminum ((AlCrCoNiFe2)O). We then compared their electrocatalytic performance with other series of synthesized multimetal and monometallic oxides for the OER under alkaline conditions. Our electrochemical analysis revealed that the high entropy ceramics exhibited excellent performance and the lowest charge transfer resistance, Tafel slope (29 mV·dec-1), and overpotential (η10 = 230 mV). These remarkable results can be primarily attributed to the high entropy effect induced by the addition of Al, Cr, Co, Ni, and Fe, which introduces increased disorder and complexity into the material's structure. This, in turn, facilitates more efficient OER catalysis by providing diverse active sites and promoting optimal electronic configurations for the reaction. Furthermore, the strong electronic interactions among the constituent elements in the metallic spinels further enhance their catalytic activity in the initiation of the OER process. Combined with the reduced charge transfer resistance, these factors collectively play pivotal roles in enhancing the OER performance of the electrocatalysts. Overall, our study provides valuable insights into the design and development of high-performance electrocatalysts for sustainable energy applications. By harnessing the high entropy effect and leveraging strong electronic interactions, electrocatalytic materials can be tailored to improve efficiency and stability, thus advancing the progress of clean energy technologies.

High-Entropy Alloy Electrocatalysts Bidirectionally Promote Lithium Polysulfide Conversions for Long-Cycle-Life Lithium-Sulfur Batteries.

High-entropy alloys (HEAs) have attracted considerable attention, owing to their exceptional characteristics and high configurational entropy. Recent findings demonstrated that incorporating HEAs into sulfur cathodes can alleviate the shuttling effect of lithium polysulfides (LiPSs) and accelerate their redox reactions. Herein, we synthesized nano Pt0.25Cu0.25Fe0.15Co0.15Ni0.2 HEAs on hollow carbons (HCs; denoted as HEA/HC) by a facile pyrolysis strategy. The HEA/HC nanostructures were further integrated into hypha carbon nanobelts (HCNBs). The solid-solution phase formed by the uniform mixture of the five metal elements, i.e., Pt0.25Cu0.25Fe0.15Co0.15Ni0.2 HEAs, gave rise to a strong interaction between neighboring atoms in different metals, resulting in their adsorption energy transformation across a wide, multipeak, and nearly continuous spectrum. Meanwhile, the HEAs exhibited numerous active sites on their surface, which is beneficial to catalyzing the cascade conversion of LiPSs. Combining density functional theory (DFT) calculations with detailed experimental investigations, the prepared HEAs bidirectionally catalyze the cascade reactions of LiPSs and boost their conversion reaction rates. S/HEA@HC/HCNB cathodes achieved a low 0.034% decay rate for 2000 cycles at 1.0 C. Notably, the S/HEA@HC/HCNB cathode delivered a high initial areal capacity of 10.2 mAh cm-2 with a sulfur loading of 9 mg cm-2 at 0.1 C. The assembled pouch cell exhibited a capacity of 1077.9 mAh g-1 at the first discharge at 0.1 C. The capacity declined to 71.3% after 43 cycles at 0.1 C. In this work, we propose to utilize HEAs as catalysts not only to improve the cycling stability of lithium-sulfur batteries, but also to promote HEAs in energy storage applications.

Thermal Stability of High-Entropy Alloy Nanoparticles Evaluated by In Situ TEM Observations.

High-entropy alloy (HEA) nanoparticles (NPs) have attracted attention in several fields because of their fascinating properties. The high mechanical strength, good thermal stability, and superior corrosion resistance of HEAs, which are derived from their high configurational entropy, are attractive features. Herein, we investigated the thermal stability of FeCoNiCuPd HEA NPs on reduced graphene oxide via in situ transmission electron microscopy observations at elevated temperatures. The HEA NPs maintained their structure, size, and composition at 700 °C, and their size gradually decreased accompanied by the preferential sublimation of Cu. On the contrary, the deterioration of the monometallic Pd NPs begins at temperatures greater than 700 °C according to Ostwald ripening, which involves the migration of adatoms or mobile molecular species. Theoretical calculations revealed that the detachment of adatoms from clusters (i.e., the first step of Ostwald ripening) was suppressed in the case of HEA NPs because of the high-configuration-entropy effect.