The pressure-induced shift and broadening of H 2S absorption lines in the ν 2-band due to collisions between H 2S molecules and quadrupole molecules, such as O 2, H 2, D 2, N 2, and CO 2, were studied in the spectral region between 1050 and 1325 cm −1. The measurements were carried out using a pulse-driven diode laser spectrometer with two multipass Herriott cells. The data concerning the collisional broadening and shift coefficients, γ and δ, respectively, and their dependencies on the rotational quantum number J″ and the quadrupole moment Q of the molecular perturber are presented for 14 P-branch transitions (3≤ J″≤8,0≤ K a Prime;≤3, 2≤ K c Prime;≤8), 7 Q-branch transitions (7≤ J Prime;≤10, 1≤ K a Prime;≤2, 6≤ K c Prime;≤9), and 18 R-branch transitions (2≤ J Prime;≤11, 0≤ K a Prime;≤4, 0≤ K c Prime;≤11). The broadening coefficients γ were determined with an accuracy to within 2% and shift coefficients δ were determined with an uncertainty of less than 10 −3 cm −1/atm for the majority of lines and broadening gases.
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