Helium Isotope Ratios Research Articles

Origin of Helium and Associated Fluid in Fault‐Related Hydrothermal Systems of the Eastern Pyrenees

ABSTRACTIntense hydrothermal activity hosted by regional tectonic structures occurs in the Eastern part of the Pyrenees. Helium isotope ratios (3He/4He) in hot springs along the Têt (0.033–0.099 Ra) and the Tech (0.171–0.375 Ra) faults indicate different signatures from purely crustal to slightly contaminated by magmatic helium. 3He/4He ratio increased towards the East, consistently with the observed thinning of the continental crust. These results suggest localised and not interconnected hydrothermal systems at fault scale. The origin of magmatic helium contamination is discussed in the light of the Gulf of Lion geodynamic evolution and data from comparable orogenic hydrothermal systems in the Alps.

Upper mantle scale enrichment of Cenozoic intraplate magmatism in Northeast Asia: He-Sr-Nd-Pb-O isotope geochemistry of the basalts around the Korean peninsula

The Earth’s mantle is considered to be geochemically heterogeneous, which is reflected by the diverse composition of oceanic island basalts (OIB). The mantle enrichment resulting in this is attributed primarily to the influx of recycled crustal materials into the mantle through subduction. Additionally, the sub-continental lithospheric mantle (SCLM) complicates the elucidation of mantle heterogeneity. From this perspective, Northeast Asia, where the Pacific stagnant slab in the mantle transition zone and the SCLM distribution are presented, is the suitable site for examining the upper mantle scale enrichment. Here we report He-Sr-Nd-Pb-O isotope values of basalts that erupted around the Korean Peninsula to illustrate the source lithology and components that led to mantle heterogeneity. Our measured helium isotope ratios ranging from 5.7 to 7.3 Ra (3He/4He ratio of air, Ra = 1.39 x 10-6) are mostly within the SCLM range (6.1 ± 0.9 Ra) but lower than the mid-ocean ridge basalt range (MORB; 8 ± 1 Ra). The Sr-Nd-Pb isotope compositions of the basalts generally display a mixture of depleted MORB mantle (DMM), enriched mantle 1 (EM1), and enriched mantle 2 (EM2) components. In addition, the basalts have δ18Oolivine (vs. V-SMOW) values ranging from 4.7 to 5.7 ‰ that deviate from the DMM range (δ18Oolivine = 5.1 ± 0.2 ‰). Our isotopic analysis results highlight the role of the pyroxenite source in the metasomatized SCLM in the genesis of basalts. The low 3He/4He range of the basalts indicates a significant role in the SCLM. Moreover, the delaminated cratonic SCLM and asthenosphere-lithosphere interaction are candidate scenarios for the low 3He/4He ratios. Therefore, we propose that mixing of DMM (high 3He/4He ratio; 7 to 9 Ra) and the metasomatized SCLM (low 3He/4He ratio; 5 to 7 Ra) allowed enrichment within the upper mantle scale for the Cenozoic intraplate magmatism in Northeast Asia.

Noble gas characteristics of microbial gas in the Qaidam Basin, China: Implications for helium enrichment processes

Helium is a critical, strategic and nonrenewable resource with limited reserves and unstable supplies. However, the helium sources and migration processes in petroliferous basins remain unclear. The Qaidam Basin features multiple reservoir layers, multiple genetic types of natural gas, and varying helium concentrations, providing an ideal natural laboratory for understanding the helium enrichment processes. Here, we present the original noble gas isotopic compositions and major gas components of 11 microbial gas samples from three gas layers in the Sebei No.1 gas field, eastern Qaidam Basin, China. The helium isotopic ratios range from 0.007 to 0.057 Ra, reflecting a predominantly crustal source. The Quaternary Sebei microbial gas features much lower helium concentration (0.0003–0.001%), 21Ne/22Ne ratio (0.031–0.034), and 40Ar/36Ar ratio (292–380) than thermogenic natural gases in the Qaidam Basin. The middle gas layer (II) of the Sebei gas field features higher 21Ne/22Ne and 40Ar/36Ar ratios than the top and bottom gas layers, displaying positive correlations with higher 4He groundwater concentrations before degassing, as calculated from 4He/20Ne ratios and 20Ne concentrations in air-saturated water. However, the correlations between the 4He contents in natural gas and the 21Ne/22Ne and 40Ar/36Ar ratios are unclear, suggesting that 4He dissolves into the groundwater system before degassing into a gas reservoir and that the variations in the 4He concentration in the gas phase are caused by the different levels of hydrocarbon dilution. Quantitative calculations of helium production revealed an external helium flux from the crustal basement except for the in-situ production from sedimentary strata even in this broadly-defined self-generating and self-preserving natural gas system. The helium resources in the Qaidam Basin are mainly distributed in tectonically active zones with uplifted pre-Jurassic basement rocks (providing sufficient helium sources), ancient groundwater systems (accumulating more helium) and suitable hydrocarbon production (acting as a carrier gas but diluting helium as slightly as possible).

Characterization of an undocumented CO2 hydrothermal vent system in the Mediterranean Sea: Implications for ocean acidification forecasting.

A previously undocumented shallow water hydrothermal field from Sicily (Southern Tyrrhenian Sea, Italy) is here described, based on a multidisciplinary investigation. The field, covering an area of nearly 8000 m2 and a depth from the surface to -5 m, was explored in June 2021 to characterise the main physico-chemical features of the water column, describe the bottom topography and features, and identify the main megabenthic and nektonic species. Twenty sites were investigated to characterise the carbonate system. Values of pH ranged between 7.84 and 8.04, ΩCa between 3.68 and 5.24 and ΩAr from 2.41 to 3.44. Geochemical analyses of hydrothermal gases revealed a dominance of CO2 (98.1%) together with small amounts of oxygen and reactive gases. Helium isotope ratios (R/Ra = 2.51) and δ13CCO2 suggest an inorganic origin of hydrothermal degassing of CO2 and the ascent of heat and deep-seated magmatic fluids to the surface. Visual census of fishes and megabenthos (mainly sessile organisms) allowed the identification of 64 species, four of which are protected by the SPA/BIO Protocol and two by the International Union for Conservation of Nature. The macroalgae Halopteris scoparia and Jania rubens and the sponge Sarcotragus sp. were the dominant taxa in the area, while among fishes Coris julis and Chromis chromis were the most abundant species. This preliminary investigation of San Giorgio vent field suggests that the site could be of interest and suitable for future experimental studies of ocean acidification.

Vertical distribution of groundwater age in and around the freshwater–saltwater transition zone determined using noble gases and carbon isotopes

The distribution of groundwater ages in coastal aquifers are complicated because of the heterogeneity of the hydrogeology and the mixing of terrestrial and marine water sources. Therefore, multiple studies verifying the groundwater age distribution via borehole surveys are required to better understand groundwater flow in coastal aquifers. This study examined groundwater age distributions in coastal aquifers adjacent to a high-elevation volcano (Mt. Fuji, Japan) by analyzing geochemical and isotopic tracers retrieved from drilling 350- and 160-m-deep boreholes. Brackish groundwater samples collected from the boreholes had high helium isotope ratios, indicating a large contribution of mantle-derived helium. Groundwater ages determined from carbon and helium isotopes indicate that terrestrial groundwater recharged at high elevations flows from the volcano to the coast, mixing with seawater in a transition zone. The groundwater age at the freshwater–saltwater transition zone and the upper part of the saltwater zone is older than that of the underlying saline water. The distributions of the groundwater age in the study area confirm that the conventional groundwater flow system in coastal aquifers is applicable even in deep aquifers. The complex patterns of groundwater age and mixing derived from geochemical and isotopic tracers can guide sustainable use of groundwater resources and the subsurface.

Diverse Origins of Gases From Mud Volcanoes and Seeps in Tectonically Fragmented Terrane

AbstractIdentification of methane origins remains a challenging work as current diagnostic signals are often not sufficient to resolve individual formation and post‐formation processes. To address such a knowledge gap in a tectonically active and fragmented terrain, samples from mud volcanoes, gas seeps, and springs distributed along structural features onshore and offshore of Taiwan were analyzed for their isotopic compositions of methane, nitrogen, helium, dissolved inorganic carbon, CO2, and water. Our analyses yielded Δ13CH3D and Δ12CH2D2 values ranging between +1.9‰ and +7.8‰ and between +3.0‰ and +19.9‰, respectively. A portion of the samples were characterized by values that represent the thermodynamic equilibrium at temperatures of 99°–260°C. These temperature estimates, together with the bulk isotopic compositions and local geothermal gradients (25°–30°C/km), suggest that methane was formed by thermal maturation of organic matter at depths of 2–9 km below the land surface and channeled upward along faults. Other samples were found to deviate from equilibrium by varying degrees. Considering the geological background, helium isotopic ratios, and nitrogen isotopologue compositions, and methanogens detected at some sites, these gases are either abiotic in origin or a mixture of microbial and thermogenic sources. Regardless of whether the equilibrium of methane isotopologues was reached, few sites hosted by sedimentary formations were characterized by mantle‐like helium signatures, indicating decoupled origins and potential degassing of helium from the relic igneous source. Overall, these results suggest the extraction of methane and other gases from multiple depths from strata fragmented by fault displacement in an active orogenic belt.

Validation of Play Fairway Analysis of the geothermal potential of Camas Prairie, south-central Idaho, by an exploration well

Play Fairway Analysis (PFA) methodology was adapted for geothermal exploration at Camas Prairie, Idaho. Geophysical data, structural and geologic mapping, volcanic rock ages and vent locations, and the distribution of thermal springs and wells all indicated a relatively high geothermal potential along the southern margin of the Prairie. An exploration well (USU Camas-1) was drilled to a depth of 618.3 m to validate the PFA. A permeable zone was encountered at ~ 357.5 m with a maximum measured temperature of ~ 80 °C, which was suppressed following the injection of cold water. A moderate transmissivity of ~ 0.25–1 cm2/s estimated from an injection test as well a seasonal artesian flow at ~ 0.7 L/s corroborate the presence of a permeable zone. The existence of a lacustrine clay seal was confirmed near the bottom of the basin-fill sediment occupying the upper 314 m of the well. Geothermometers suggest the USU Camas-1 well water equilibrated at a reservoir temperature of ~ 120 °C. Based on the locations of both thermal and cold wells, geothermal fluids appear to be flowing upward along one or both of two fault systems. The presence of young basalts and elevated helium isotope ratios suggest that the heat source of Camas Prairie is magmatic. However, the faults may be acting as a conduit for geothermal fluids to rise from great depth without a shallow magmatic source being present. Camas Prairie is a promising area for geothermal development, but the relatively low reservoir temperatures indicate this resource may not be suitable for electric generation. Perhaps the best use would be for heating.

Fault-related basins as carbon reservoirs: Soil CO2 emissions in the SE Korean Peninsula

Carbon dioxide (CO2) is one of the main components of greenhouse gases, and there is a great concern about emissions mainly from human activities. However, long term CO2 emissions during the Earth’s history are largely related to natural emissions by geological factors. Natural CO2 emissions are mainly at highly permeable passages below the surface (e.g., volcanoes or faults). Unlike volcanoes, which actively release mantle-derived volatiles, faults can be affected by CO2 of more diverse origins and are relatively lacking in research. Here, we note that it is important for CO2 emissions that faults as channels with high permeability take topographical control to form sedimentary basins and produce mature soils. To this end, we performed CO2 flux measurements in the Yangsan Fault System (YFS), Republic of Korea. As this fault is an active fault, topographical variations are clear and accessible. In the YFS, high spring CO2 fluxes (119.5 g m−2 d-1 to 77,699.5 g m−2 d-1) were observed in Sector 1, and high soil CO2 fluxes (0.5 g m−2 d-1to 1,240 g m−2 d-1) were observed along the Hyeongsan River in Sector 2. The carbon isotope composition indicates that the mantle contributes to fault-related spring CO2 (δ13C = -14.03 ‰ to −7.44 ‰), and soil CO2 comes from shallow biogenic sources (δ13C = –22.82 ‰ to −13.53 ‰) deposited in fault-forming basins. In addition, the helium isotope ratios indicative of the mantle contribution (3He/4He = 1.86 to 6.02 Ra) are shown in the gas samples of the springs. Furthermore, in a post-earthquake survey, we found temporal changes in soil CO2 flux values near the epicenter, which may be related to the earthquake. A simple calculation of overall CO2 emissions suggests that significant amounts of CO2 (6.2 Mt yr−1) are being emitted along the YFS. Therefore, this study reports both large-scale structural degassing and biological CO2 emissions from fault zones, providing implications for the role of sedimentary basins and soil types formed in fault zones.

Upward Earthquake Swarm Migration in the Northeastern Noto Peninsula, Japan, Initiated From a Deep Ring‐Shaped Cluster: Possibility of Fluid Leakage From a Hidden Magma System

AbstractThis study describes an ongoing intense earthquake swarm in the crust of the northeastern Noto Peninsula, Japan, that began around the end of 2019. Fluid movement related to volcanic activity is often involved in earthquake swarms in the crust. However, no volcanic activity has occurred in this region since the Middle Miocene (15.6 Ma). This study investigates the cause of this earthquake swarm based on the spatiotemporal evolution of earthquake hypocenters and seismic reflectors. The hypocenter relocation of 10,940 earthquakes (M > 1) reveals that they are all crustal and migrated upward, activating a complex network of faults at depths shallower than 20 km. The initiation of this earthquake swarm occurred at a locally deep depth (z = 17 km), and the local hypocenter distribution shows a characteristic circular pattern. We find a distinctive S‐wave reflector in the immediate vicinity. A low‐velocity anomaly exists below the reflector, and a high helium isotope ratio and a low‐gravity anomaly were observed at the surface. These observations suggest that the current seismicity is associated with fluids released by ancient or possibly unrecognized modern magmatic activity, although no volcanic activity has been documented in this area for 15 million years. Significant crustal deformation was observed during this swarm and is probably related to the fluid movement and aseismic deformation that contributed to this earthquake swarm. The strongest M5.4 earthquake (as of October 2022) occurred near the migration front on the largest planar structure, leaving the shallow extension unruptured.

Geothermal springs with high δ13CCO2-DIC along the Xianshuihe fault, Western Sichuan, China: A geochemical signature of enhanced deep tectonic activity

Geothermal springs are controlled by deep faults, which are the major causes of earthquakes. A series of geochemical indicators of hot springs, such as carbon dioxide content (CO2), carbon isotope and noble gas isotope etc., have been used for earthquake monitoring and early warning at home and abroad. Given that previous studies have failed to establish an inevitable link between the carbon isotopic variations of hot springs and seismic activities, in this study, mass spectrometry techniques were used to analyze the carbon isotopes of gaseous CO2 and noble gas isotope in hot springs, thermal water, and newly formed travertines from western Sichuan before and after an Ms4.8 earthquake (i.e., 7.14 earthquake). The results showed that the carbon isotope level of the hot spring system increased significantly before the earthquake, i.e., δ13CCO2 = -2‰ to 3.3‰, δ13CDIC = 2.2‰ to 6.6‰ (DIC = dissolved inorganic carbon in geothermal water), R/RA = 0.90–1.83, and δ13Ctravertine = 1.76‰ to 5.75‰. These indicators decreased markedly 1 week after the earthquake, whereas the helium isotope ratio of R/RA did not exhibit a noticeable change (δ13CCO2 = -3.9‰ to 0.4‰, δ13CDIC = 1.6‰ to 4.1‰, R/RA = 0.68–1.87). Combined with previous thermodynamic calculation and experimental results on carbon isotope fractionation of the CO2–calcium carbonate system, we suggest that the high carbon isotope characteristics of hot springs are caused by carbon isotope fractionation following the release of CO2 from fault carbonate decomposition owing to tectonic activity, not by a mixture of different carbon sources. A high carbon isotopic delivery path in geothermal water, from released CO2 to DIC and then to travertine, was observed. The new mechanism proposed in this paper reveals the intrinsic relations between the changes of the hot spring geochemical properties and deep tectonic activities, and the variations of these geochemical parameters before and after earthquakes may assist in capturing seismic precursors. A post-peak earthquake warning model has thus been preliminarily proposed, however, long-term monitoring data are required to reduce some uncertainties.

Neogene and Quaternary dikes and related joints as conduits for recent juvenile degassing: case studies from the seismically active region of NW-Bohemia, Czech Republic

The contemporary occurrence of juvenile gas emissions at springs or mofettes in active volcanic areas can be observed worldwide. This correlation is less frequent in areas with dormant or post-volcanic activity. The NW-Bohemia/Vogtland region located at the Eger rift zone (Czech Republic) provides an intriguing example of this correlation between numerous Neogene-aged post-volcanism locations and juvenile fluid emission sites. Newly discovered dikes and diatremes are located close to vents with the highest helium isotope ratios (3He/4He) of about 6 Ra. Our results lend support to the hypothesis that feeder dikes and their fractured wall rocks should be considered the predominant conduits for the continuous upwelling of juvenile fluids. Moreover, 77% of the CO2 gas emission sites are located close to dikes or diatremes, i.e., within a distance of 4 km. Our studies reveal a spatial dependence of the Ra values at the spring sites with the estimated distances to the basaltic bodies. The results confirm the negative trend known from the literature. That is, Ra values decrease with increasing distance from the feeder dikes.

Estimation of the depth of origin of fluids using noble gases in the surface sediments of submarine mud volcanoes off Tanegashima Island

The helium isotope ratio (3He/4He), concentration ratio of neon-20 to helium-4 (20Ne/4He), argon (Ar), krypton (Kr), and xenon (Xe) concentrations were measured in the porewater of surface sediments of several submarine mud volcanoes. From the 3He/4He values (0.18–0.93RA), the estimated He origin is almost 90% crustal He, with little contribution from mantle-derived He. The determined Ar, Kr, and Xe concentrations lie within the solubility equilibrium range expected for temperatures from 83 °C up to 230 °C and are consistent with the temperature range of the dehydration origin of clay minerals. Considering the geothermal gradient in the investigated region (25 °C/km), these gases are considered to have reached dissolution equilibrium at a depth of about 3.3 km to 9.2 km below the seafloor. As the depth of the plate boundary is 18 km below the seafloor, the noble gas signatures are likely to originate from the crust, not from the plate boundary. This is consistent with the results presented by the He isotope ratios.

Groundwaters and deep-seated fluid circulation around Aso Volcano, Southwest Japan, revealed by multivariate statistical analysis of the geochemical data

To understand the fluid circulation under volcanoes and their surrounding area, geochemical compositions of 590 groundwater and spring/river water samples from the central Kyusyu in SW Japan, including hot and mineral spring waters around Aso and Kuju Volcanoes, have been analyzed for 12 major solutes as well as oxygen‑hydrogen and helium isotopic ratios. To extract independent processes and sources involved in formation of the groundwaters, whitened data-based k-means cluster analysis (KCA) has been applied to the data set of 12 major solutes. Eight clusters have been identified by KCA, which were mapped geographically and were compared with the isotopic compositions, temperature, and pH that were not included in KCA. By the geographical mapping, a concentric zonal structure of the clusters emerges in the Aso caldera, which resulted broadly from two fluid cycling systems from caldera rim and central cones. In the entire study area including Aso and Kuju Volcanoes, the mapping also shows geographical provenance, and the distribution of each cluster shows characteristics related to geological features, such as upwelling of deep-seated fluids along the prominent tectonic lines. On the other hand, the Piper diagram-based classification is significantly different from the KCA results and exhibits neither a concentric zonal structure within the Aso caldera nor a regional geographical provenance. These results suggest that multivariate statistical analysis such as KCA is potentially useful for investigating the origins of groundwaters and shows the advantages over classical Piper diagram-based evaluations.

Geochemistry and fluxes of gases from hydrothermal features at Newberry Volcano, Oregon, USA

We present the chemical and isotopic compositions of gases and fluxes of CO2 from the hydrothermal features of Newberry Volcano, a large composite volcano located in Oregon's Cascade Range with a summit caldera that hosts two lakes, Paulina and East Lakes. Gas samples were collected from 1982 to 2021 from Paulina Hot Springs (PHS) on the shore of Paulina Lake, East Lake Hot Springs (ELHS) on the shore of East Lake, and Obsidian Flow Gas Seep (OFGS), an area of diffuse gas emissions. Surveys of CO2 flux were conducted in 2020 at OFGS (1400 m2) and East Lake (4.1 km2). Gases from all three sites were CO2-rich (≥79 mol% in dry gas) but showed considerable compositional variability over time due to interaction with ground and surface water. An increase in H2S concentrations and decline in CO2/H2S ratios in ELHS gases coincided with a drop in East Lake water level from 1999 to 2021. ELHS and OFGS gases were high in CH4 relative to PHS and the δ13C of CH4 values for ELHS gases (−72.2 and − 63.6 ‰) reflected a predominantly biogenic origin. The dominant source of N2 and Ar in PHS, ELHS, and OFGS samples was likely groundwater. Helium isotopic ratios (6.47 to 8.02 Rc/Ra) support a persistent source of magmatic He beneath Newberry caldera and consistently high values measured at OFGS and PHS relative to ELHS suggest distinct fluid flow paths from depth to the surface features. The δ13C of CO2 and CO2/3He values (−8.9 to −5.35 ‰ and 1.3 × 109 to 4.6 × 1010, respectively) measured in gases reflect contributions of CO2 from both mantle and crustal sources. Measured CO2 fluxes at OFGS and East Lake ranged from 1 to 8808 and < 1 to 364 g m−2 d−1, respectively. A CO2 emission rate of 0.5 t d−1 was calculated for OFGS. The CO2 emission rate estimated for East Lake was 30 t d−1 and when compared to prior estimates, reflects steady-state lake degassing. An enhanced geochemical monitoring plan, including annual sampling of gases at ELHS, OFGS, and PHS for geochemical analysis, installation of a continuous lake-level monitoring station at East Lake, and annual CO2 flux surveys at OFGS, would provide valuable background data and insights into any precursor volcanic activity. Integrating geochemical data with data from the real-time seismic and GPS network at Newberry Volcano could better resolve and interpret potential changes in its magma-hydrothermal system.

Early Precursory Changes in the 3He/4He Ratio Prior to the 2021 Tajogaite Eruption at Cumbre Vieja Volcano, La Palma, Canary Islands

AbstractWe report significant changes in the 3He/4He ratio measured at the Dos Aguas CO2‐rich cold mineral spring (La Palma, Canary Islands) that represent early precursory signals of the 2021 Tajogaite eruption at Cumbre Vieja volcano. Air‐corrected 3He/4He ratio has an average value of 9.80 RA in the last 30 years (1991–2021). Helium isotope ratios higher than the average value were observed during the period 2008–2013 suggesting an input of 3He‐rich less‐degassed magma beneath La Palma lithosphere. Magma ascended in 2017–2018 toward another reservoir located beneath Cumbre Vieja at 10–15 km depth, causing detectable seismic swarms located between 15 and 25 km, followed in 2020 by additional inputs of 3He‐rich less‐degassed magma that intruded at depth. Finally, in 2021 the buoyancy of magma and the pressure of the exsolved gases overcame the lithospheric resistance and a volcanic eruption took place between 19 September and 13 December 2021.

Application of optically stimulated luminescence in volcanic hydrothermal uranium deposits in the Guyuan Basin, North China

Volcanic basins in North China have great potential for the discovery of volcanic-related uranium deposits. However, most of the traditional geochemical exploration that have the inadequacies of the unexpected errors, weak anti-interference ability and exception information have become untenable in exploring uranium deposits overlain by volcanic rocks and sediments. To identify and track the abnormal geochemical source, feldspar infrared stimulated luminescence (IRSL) and quartz optically stimulated luminescence (OSL) were utilized for the first time to explore deeply concealed volcanic-related uranium deposits in North China. Our results confirm that feldspar IRSL-based drill-core samples are oversaturated and therefore fail to trace the deep uranium orebodies. In contrast, quartz OSL in sedimentary covers over the drill holes hosting economic and subeconomic uranium mineralization yields older apparent ages than their actual depositional ages. The high apparent ages of quartz OSL in the sediments and low helium isotope ratios (3He/4He) of the drill core indicated that the soil radon gas (Rn) anomaly was caused by Rn migration from deeply buried uranium ore decay.

Mantle helium in pore fluids of deep-sea sediments around the Azores archipelago

We present noble gas concentrations and helium isotope ratios measured in the pore fluids of two deep-sea sediment cores taken at the Azores Plateau. NeXe concentrations were used to estimate the atmospheric noble gas component within the pore fluids and to then determine the terrigenic helium component. The concentrations of terrigenic 3He indicate the presence of hydrothermal fluids and a mantle He component within the sediment pore space. At both sampling locations, the concentration of terrigenic helium increases with sediment depth. The observed concentration gradients suggest a diffusive transport of He through the sediments. The helium isotope ratio of the source of the terrigenic helium is characterized by a typical mid-ocean ridge basalt (MORB). These results support previous studies suggesting that the pelagic sediments surrounding the Azores host active hydrothermal systems.Our data indicate that the transport of terrigenic helium takes place diffusively over larger areas of the ocean floor, and that the concentration of terrigenic helium in the pelagic sediments increases towards the Mid-Atlantic Ridge and Terceira Rift.The data further suggests that in the Azores region the terrigenic noble gas component is only detectable in the sediment pore fluids and cannot be observed in the overlying bottom water. This highlights the potential of measuring noble gas concentrations and isotope ratios in the sediment column to identify hydrothermal activity in the ocean.

Mantle-derived fluids in the continental-scale Nubian aquifer

The Nubian aquifer of northeastern Africa is one of the largest confined fossil-water aquifer systems in the world. It is central for ongoing water needs and future development goals of Egypt, Libya, Sudan and Chad. Groundwater extraction and consumptive use over the past 40 years have led to a continuous decline of water level and to the reduction and/or cessation of natural flow in artesian wells and springs. This study introduces new noble gas and stable isotope geochemical data from deep groundwater supply wells of the main oases of the Western Desert of Egypt (Bahariya, Farafra, Dahkla, and Kharga) and places these data in the context of a regional compilation of published hydrological and hydrochemical data. Helium isotopes, stable isotope compositions for water (δ2H; δ18O) and dissolved inorganic carbon (δ13C), salt compositions, and [CO2] suggest deeply derived fluid inputs. Highly variable groundwater temperatures (20–56 °C) also suggest the presence of geothermal inputs that mix with aquifer water. Nubian water displays high PCO2 (up to three orders of magnitude higher than atmosphere) and hydrochemical analysis using δ13C suggests up to ~30% of the CO2 is derived from deep geologic sources. Helium isotope (3He/4He) ratios of samples obtained from the Nubian aquifer range from crustal values of 0.02RA (where RA reflects the 3He/4He in air or 1.384 × 10−6) to values of up to 0.36RA (2.5% mantle helium) in Dahkla Oasis of Egypt and up to 1.4RA (17% mantle helium) in Libya. Correlations among excess heat, increases in [CO2], δ13C, and 3He/4He indicate that small volumes of deeply sourced fluids carrying mantle-derived volatiles are leaking into the Nubian aquifer. Geothermal water apparently ascend along faults and shear zone conduits and mix with regional groundwater. The origin of these volatiles may be partial melts in low velocity upper mantle beneath the aquifer and young magmatism surrounding the Nubian aquifer. Fluid-rock interactions along flowpaths can explain variable associations and correlations among the tracers. Variability of composition and temperature suggest complex fluid mixing within the Nubian aquifer, the existence of fault-bounded hydrologic sub-basins, and a connection between tectonics and water quality. Better understanding of the sources and admixtures of deep geothermal fluid inputs is needed for informed water management.

Primordial Helium-3 Redux: The Helium Isotope Ratio of the Orion Nebula* *Based on observations collected at the European Organisation for Astronomical Research in the Southern Hemisphere under ESO program(s) 107.22U1.001, 194.C-0833.

We report the first direct measurement of the helium isotope ratio, 3He/4He, outside of the Local Interstellar Cloud, as part of science-verification observations with the upgraded CRyogenic InfraRed Echelle Spectrograph. Our determination of 3He/4He is based on metastable He i* absorption along the line of sight toward Θ2A Ori in the Orion Nebula. We measure a value 3He/4He = (1.77 ± 0.13) × 10−4, which is just ∼40% above the primordial relative abundance of these isotopes, assuming the Standard Model of particle physics and cosmology, (3He/4He)p = (1.257 ± 0.017) × 10−4. We calculate a suite of galactic chemical evolution simulations to study the Galactic build up of these isotopes, using the yields from Limongi & Chieffi for stars in the mass range M = 8–100 M ⊙ and Lagarde et al. for M = 0.8–8 M ⊙. We find that these simulations simultaneously reproduce the Orion and protosolar 3He/4He values if the calculations are initialized with a primordial ratio . Even though the quoted error does not include the model uncertainty, this determination agrees with the Standard Model value to within ∼2σ. We also use the present-day Galactic abundance of deuterium (D/H), helium (He/H), and 3He/4He to infer an empirical limit on the primordial 3He abundance, , which also agrees with the Standard Model value. We point out that it is becoming increasingly difficult to explain the discrepant primordial 7Li/H abundance with nonstandard physics, without breaking the remarkable simultaneous agreement of three primordial element ratios (D/H, 4He/H, and 3He/4He) with the Standard Model values.

Basin architecture controls on the chemical evolution and 4He distribution of groundwater in the Paradox Basin

Fluids such as 4He, H2, CO2 and hydrocarbons accumulate within Earth's crust. Crustal reservoirs also have potential to store anthropogenic waste (e.g., CO2, spent nuclear fuel). Understanding fluid migration and how this is impacted by basin stratigraphy and evolution is key to exploiting fluid accumulations and identifying viable storage sites. Noble gases are powerful tracers of fluid migration and chemical evolution, as they are inert and only fractionate by physical processes. The distribution of 4He, in particular, is an important tool for understanding diffusion within basins and for groundwater dating. Here, we report noble gas isotope and abundance data from 36 wells across the Paradox Basin, Colorado Plateau, USA, which has abundant hydrocarbon, 4He and CO2 accumulations. Both groundwater and hydrocarbon samples were collected from 7 stratigraphic units, including within, above and below the Paradox Formation (P.Fm) evaporites. Air-corrected helium isotope ratios (0.0046 - 0.127 RA) are consistent with radiogenic overprinting of predominantly groundwater-derived noble gases. The highest radiogenic noble gas concentrations are found in formations below the P.Fm. Atmosphere-derived noble gas signatures are consistent with meteoric recharge and multi-phase interactions both above and below the P.Fm, with greater groundwater-gas interactions in the shallower formations. Vertical diffusion models, used to reconstruct observed groundwater helium concentrations, show the P.Fm evaporite layer to be effectively impermeable to helium diffusion and a regional barrier for mobile elements but, similar to other basins, a basement 4He flux is required to accumulate the 4He concentrations observed beneath the P.Fm. The verification that evaporites are regionally impermeable to diffusion, of even the most diffusive elements, is important for sub-salt helium and hydrogen exploration and storage, and a critical parameter in determining 4He-derived mean groundwater ages. This is critical to understanding the role of basin stratigraphy and deformation on fluid flow and gas accumulation.