Adsorption heat pumps (AHP) have conventionally used packed bed design, making their operation sluggish leading to difficulty in using heat for the adsorbent regeneration. While thin adsorbent coatings improve the performance of AHPs when implemented in microscale geometries like minichannels, integrating the adsorbent coating procedure into the scaled-up adsorbent bed manufacturing has been impractical because of the finite time required for the coating process. Meanwhile, separately coated plates manifest sealing issues. This research details an innovative avenue to fabricate a unified adsorbent bed integrated with thin adsorbent coatings. Here, a compact adsorbent bed was fabricated through the integration of additive manufacturing using a fused deposition modeling (FDM) 3D printer for the substrate and resin curing for the MIL-101 (Cr) adsorbent layer. The multi-layered bed was designed to exchange heat between heat transfer fluid (HTF) and the passages through which the refrigerant vapor flows. The vapor channels were coated with a MIL-101 (Cr) adsorbent. The research incorporated both experiments and computational models to evaluate the operation of this adsorbent bed through the measurement of pressure during the adsorption and desorption stages for this component. Various HTF temperatures (80 °C − 90 °C) and flow rates (0.125 kg min−1 – 0.25 kg min -1) were tested. The findings revealed the much-desired asymmetrical operation with long adsorption (75–80 % of the cycle time) and short desorption stages (20 %-25 % of the cycle time), opening the possibility of employing a single bed in adsorption cooling systems to produce a near continuous cooling effect leading to more compact AHPs. The computational model developed for this test setup using MATLAB strongly aligned with experimental findings, with an error margin of 4–12 %.
Read full abstract