Heat-moisture Treatment Starch Research Articles

Impacts of Konjac Glucomannan on the Pasting, Texture, and Rheological Properties of Potato Starch with Different Heat–Moisture Treatments

AbstractFew studies reported the impact of hydrocolloid addition on starches after heat moisture treatment (HMT). In this study, potato starch is modified by HMT under different moisture content (18–35%), and the impact of konjac glucomannan (KGM) addition on the pasting, gel texture, and rheological properties of potato starch after HMT are investigated. The results showed that after HMT, the granule structure of the starch is changed with higher heat stability, shown as higher pasting temperature and trough viscosity. The impact of KGM addition is similar on the potato starch before and after HMT, but the change extent of the latter is larger in most cases, such as decreased pasting temperature and gel hardness, increased peak viscosity, breakdown viscosity, and final viscosity. This indicated that KGM benefited the gelatinization behavior of HMT starch but might not enhance the retrogradation process. The intrinsic high viscosity of KGM in water resulted in a softer starch gel and also contributed to the enhanced shear stress of the mixture paste. Therefore, the impact of KGM on the HMT starch is more significant than the original starch, and this guided the use of HMT starch in the food industry with other hydrocolloid involvement.

Influence of Heat Moisture, Ultrasonication, and Gamma Irradiation on Pasting, Thermal, Morphological, and Physicochemical Properties of Indian Teff (Eragrostis tef) Starch

AbstractThe present work is conducted to study the effect of heat‐moisture treatment (HMT), ultrasonication (US), and gamma‐irradiation (GI) on various properties of teff starch. Starch is subjected to HMT at 28% moisture level, US at a frequency of 20 kHz for 30 and 60 min, and GI at 5 and 10 kGy. US has an increased swelling power (8.22–9.39 g g−1) and solubility (9.5–10.5%). Water binding and Oil binding capacity are improved in modified starches than native. The highest amylose content (24.94–25.24%) is observed in US than native (20.82%). Thermal characteristics show an increment in the modified teff starches with enthalpies varied from 2.30 to 3.81 J g−1. Significant differences in starch gel textural properties are identified. Similar outcomes for native and modified findings are seen in Fourier transform infrared spectroscopy spectra. X‐ray diffraction shows a similar X‐ray pattern with crystallinity decreases for HMT (28.07%) and gamma irradiated starches (30.21%) and increases for ultrasonicated samples (32.23%). The morphological changes in teff starch are observed after physical modification. All in all, significant improvements have been reported in modified teff starch, which not only increases its industrial application but also improves the utilization of teff grain globally.

Banana starch modified by heat moisture treatment and annealing: Study on digestion kinetics and enzyme affinity

Starch modification by annealing (ANN) and heat-moisture treatment (HMT) results in a lower crystallinity compared to native but the change of B crystalline type to A type is only observed in HMT starch. All starches possess two different digestion rate constants i.e. k1 (at rapid phase) and k2 (at slow phase) which may be linked to the preserved intact starch granule following thermal treatment. HMT starch contains higher content of slowly digestible starch (C2∞) compared to the C2∞ of the other starches. The lower enzyme binding to HMT starch (Kd value increases from 0.12 mg/mL in native starch to 0.83 mg/mL) may be linked to the increase in the degree of ordered structure of the granule surface (observed from the absorption band ratio of 1000 cm−1/1022 cm−1). The lower affinity may lead to a lower k1 value. This holds true for ANN and native starch which displays similar k1, Kd value and degree of ordered to disordered structure. Lower k2 in HMT starch compared to the corresponding k2 in the other starches may be linked to the slower enzyme diffusion into the core of starch granule due to the tightly packed structure of A crystalline type in HMT starch.

Effects of single and dual modifications with debranching and heat-moisture treatments on physicochemical, rheological, and digestibility properties of proso millet starch

The effects of single and dual modifications with heat-moisture treatment (HMT) and enzymatic debranching on the structural, physicochemical, rheological, and in-vitro digestibility properties of proso millet starch (PMS) were comparatively studied. Amylose content increased after gelatinization and all modification treatments. Debranching and dual modification (debranching followed by HMT) decreased the average chain length and swelling power but increased the solubility of PMS. HMT did not change the average chain length and chain length distribution in native and debranched starches but decreased the swelling power and solubility of native starch. The A-type X-ray diffraction pattern of PMS was converted to the A + V type by HMT and to the B + V type by debranching and dual modification. FTIR investigation showed that the short-range molecular order of all modified starches was disrupted. The viscoelasticity and viscosity of all starch pastes decreased in the following order: PMS > HMT starch > debranched starch > dual modified starch. In-vitro starch digestibility showed that HMT increased slowly digestible starch (SDS) to 32.88 %, while debranching increased resistant starch (RS) to 77.14 %. HMT increased RS to 86.17 % in the dual modified starch. Debranching therefore predominates in the dual modification of starch compared to HMT.

Heat-moisture-treated rice starches with different amylose and moisture contents as stabilizers for nonfat yogurt

Food producers are interested in enhancing native starch properties without chemical modifications. Here, rice starches were physically modified via heat-moisture treatment (HMT) using different amylose (high, medium, low, and waxy) and moisture (15 %, 20 %, 25 %, and 30 %) contents. Hydration properties and pasting viscosities differed for different amylose and moisture contents. The HMT starch with high amylose content and 15 % moisture (High_HMT15) exhibited the highest final viscosity (6.16 Pa.s), and 31.7 % and 35.1 % increased amount of resistant starch compared to native starch in the granule and paste states, respectively. Hence, High_HMT15 was used as a stabilizer for nonfat yogurt. The nonfat yogurt prepared with 1.0 % High_HMT15 as the stabilizer exhibited 37.3 % reduced whey separation, 2.8 times increased viscosity, a high total solids content, and acceptable sensory properties compared to the nonfat yogurt without starch. These HMT starches can replace chemically modified starches derived from other grains in various food applications.

Hydrothermal treatments of starch impact reaction patterns during subsequent chemical derivatization

Differences in derivatization patterns (using a fluorescent reagent, fluorescein isothiocyanate) of wheat, pea, and potato starches between native granular (NAT) starches and their respective annealed (ANN) and heat-moisture treated (HMT) starches were investigated to reveal structural changes associated with starch hydrothermal treatments. Size-exclusion chromatography with fluorescence and refractive index detection assessed the reactivity of amylose (AM), intermediate chains (IM1 and IM2), and amylopectin branch chains (AP1, AP2, and AP3) within the different starches. Shifts in X-ray diffraction patterns of HMT starches and in the gelatinization properties of both ANN and HMT starches confirmed molecular rearrangement. The reaction homogeneity (wheat and pea) and the overall extent of reaction (pea and potato) increased for HMT starches compared to other starches. The lower reactivities of IM2 chains (HMT starch) and AP3 chains (ANN starch) relative to NAT starches, indicated their involvement in molecular rearrangements and improved double helical order. IM2 and AP branch chains in ANN pea starch also were less reacted than NAT starch chains, suggesting their co-crystallization. Molecular rearrangements in ANN and HMT starches led to altered swelling and pasting viscosities. Thus, changes in the relative crystallinity of individual starch branch chains induced by hydrothermal processing impact the final physical properties.

Physicochemical properties of pressure moisture treated (PMT) and heat moisture treated (HMT) starches

Physicochemical properties of pressure moisture treated (PMT, 550 MPa, 10 min) and heat moisture treated (HMT, 100 °C, 10 h) starches were investigated. Effects of PMT and HMT were different depending on starch type. PMT starches showed dramatic changes in moisture sorption isotherm, pasting properties, thermal characteristics, solubility and swelling power (at 90 °C), and in vitro digestibility. The most dramatic difference between PMT and HMT starches was amylopectin melting transition, i.e., broadening in PMT and shift to high temperature in HMT starches. Moreover, B- and C-type starches revealed the more increase in amylopectin melting enthalpy than A-type starch. Both PMT and HMT did not increase the crystallinity but reorganized the amorphous area to compact, resulting in lower rapidly digestible starch and higher slowly digestible starch than those of native starches. Consequently, PMT changed the digestibility and physicochemical properties of starches with different modes of action compared with HMT.

Influence of pre- or post-electron beam irradiation on heat-moisture treated maize starch for multiscale structure, physicochemical properties and digestibility

Electron beam irradiation (EBI) as a green technological method for starch modification can generate starch-based materials with new functions. This study modified maize starch by heat-moisture treatment (HMT) for 1 h and 3 h, and EBI with various intensities (5 kGy and 10 kGy), and their effects of treatment sequence on the multiscale structure, physicochemical properties and in vitro digestibility were investigated. EBI or HMT alone did not change the granule morphology and crystalline type, but reduced the crystallinity and molecular weight and increased the resistant starch content. HMT alone had no significant effect on the solubility of starch, while EBI led to a considerable increase in the solubility of maize starch. The combined treatment of EBI and HMT aggravated apparent viscosity reduction, and the HMT starch pretreated with EBI had a smaller molecular weight and lower viscosity. In contrast, post-EBI samples had higher solubility and RS content. Primarily, it has excellent potential for producing low-viscosity and high-solubility starch foods.

Effect of heat-moisture treatment on the physicochemical properties and digestibility of proso millet flour and starch

Proso millet flour (PMF) and starch (PMS) were subjected to heat-moisture treatment (HMT) at 25 % moisture content and 110 °C for 4 h. The effects of HMT on physicochemical and structural properties and in vitro digestibility of PMF and PMS were analyzed. After HMT, SEM showed aggregation and damage to the surface of starch granules, while CLSM showed proteins wrapped around the granules. The amylopectin chain length distribution (CLD) remained unchanged in PMF and PMS after HMT, indicating intact covalent bonds between glucose units. HMT decreased the swelling power, solubility, viscosity of the paste, and gelatinization enthalpy and increased the pasting temperature and gelatinization temperature of PMF and PMS. HMT changed the XRD pattern of PMF from A to A + V type starches, whereas that of PMS remained unchanged. FTIR study showed an increase in the degree of short-range molecular order of PMF and PMS after HMT. In vitro digestibility evaluation showed that the rapidly (RDS) and slowly digestible starch (SDS) contents of PMF and PMS increased, whereas the resistant starch (RS) content decreased after HMT. HMT flour and starch have suitable properties for use in a wide range of food products, from canned to frozen, as well as non-food products.

Comparison of Properties of Films Prepared from Potato Starch Modified by Annealing and Heat–Moisture Treatment

AbstractThis study modified potato starches using hydrothermal treatment, i.e., annealing (ANN) and heatmoisture treatment (HMT). ANN in the ratio (1:2) of potato starch and water at 60 °C is performed for a day. For HMT, native starch is exposed to 110 °C maintained at 20% moisture content (M.C.) for 8 h. Potato bio‐films (native and modified) are prepared by solution casting method using glycerol as a plasticizer. The properties of native and modified starches along with developed films are evaluated. HMT‐modified starches showed lower solubility (10.5%), lower swelling power (21.2 g g−1), lower freeze‐thaw stability, and exhibited non‐Newtonian fluid behavior. Films produced from HMT starch have decreased solubility (13.57%), WVP (0.20 g mm m−2 h−1 kPa−1), and enhanced mechanical properties (7.62 MPa tensile strength, elongation of 11.36%, and seal strength 4.06 MPa) compared to annealed and native starch films. ANN starch increased the elongation (9.36%) with lower solubility (17.31%) and WVP (0.65 g mm m−2 h−1 kPa−1) of the starch films compared to the native starch. Also, the result shows that the potato starch‐based films biodegraded within 15 days. The developed biodegradable packaging films could meet various packaging requirements using physically modified potato starch which has better film forming properties and is also eco‐friendly.

Enhancing Resistant Starch Content of High Amylose Rice Starch through Heat-Moisture Treatment for Industrial Application.

The objective of the present study is to enhance the resistant starch (RS) content of high amylose rice starch with heat–moisture treatment (HMT) for industrial application. The optimized HMT condition for achieving the highest RS content established using response surface methodology (RSM) was a temperature of 100 °C, moisture content of 24.2%, and a time of 11.5 h. Upon HMT, the RS content increased from 32.1% for native starch to 46.4% in HMT starch with optimized condition. HMT of the starches reduced the solubility and swelling power. The surface of HMT starch granules was more irregular than native starch. The X-ray diffraction (XRD) peak intensity at 2θ = 5° was greatly reduced by HMT, and the peaks at 22.7° and 24.2° were merged. HMT increased the gelatinization temperature and reduced the gelatinization enthalpy. HMT provides a method for the production of high-yield RS2 with high amylose rice starch in industrial application.

Optimization of heat-moisture treatment on potato starch and study on its physicochemical properties

The object of research is the technology of modified potato starch obtained by heat-moisture treatment. Heat-moisture treatment (HMT) of starch is a hydrothermal treatment technique to modify their functional properties. Setback viscosity of potato starch gelatinization characteristic is the key factor that influences the quality of potato starch noodle. In order to obtain a green, safe and highly efficient potato starch product for vermicelli production, this study take setback viscosity as response value, a Box-Behnken model was established on the basis of single factor experiment results to optimize the modify technique. A response surface analysis was used to investigate the effects of moisture content of starch, heat-moisture treatment temperature and heat-moisture treatment time on setback viscosity of heat-moisture treatment modified potato starch. The viscosity properties, textural properties and retrogradation characteristics of HMT starch gel were estimated. The results of response surface methodology showed the optimal parameters of HMT were that moisture content of potato starch was 23.56 %, heat-moisture treatment temperature was 90 °C, and heat-moisture treatment time was 1.5 h. Under such conditions, setback viscosity of heat-moisture treatment modified potato starch (HMTS) paste was 3677 cP, which was higher than native starch (496 cP) obviously, indicating that the gel strength and hardness of potato starch was improved significantly. Compared with native potato starch (NS), HMTS had lower peak viscosity (2966 cP), lower hold viscosity (2882 cP) and lower breakdown viscosity (84.50 cP), but higher paste temperature (71.08 °C), higher final viscosity (6559 cP) and setback viscosity(3677 cP). The results of retrogradation was consistent with the viscosity properties, all of which indicating that potato starch modified by heat-moisture treatment was more prone to retrogradation. TPA tests demonstrated that HMT can enhance the textural properties of starch gel. Compared with native starch (NS) gel, the hardness, cohesiveness, gumminess, chewiness and resilience of heat-moisture treatment starch (HMTS) gel were increased significantly, and there was no significant difference in springiness. Compared with native starch gel, heat-moisture treatment starch gel had better functional properties.

Comparative Study of Heat‐Moisture Treatment and Annealing on Morphology, Crystallinity, Pasting, and Thermal Properties of Sohphlang (Flemingia vestita) Starch

AbstractThe impact of heat‐moisture treatment (HMT) and annealing (ANN) on morphology, crystallinity, pasting, and thermal properties of sohphlang starch are determined. Heating of starch with 20%, 25%, and 30% moisture at 100 °C for 16 h is done for HMT while ANN is done for 24 h using 70%, 75%, and 80% moisture levels at 50 °C. Both HMT and ANN result in a rough surface structure and decreased birefringence at the center. The 1047/1022 ratio and crystallinity increase on modification but the A‐type polymorph remains unchanged. Hydrothermal treated starches have significantly increased pasting temperatures and reduced pasting viscosity; HMT starches no longer possess pasting profiles because of lack of trough viscosity; hence no breakdown and setback. Annealed starches show higher final viscosity than native starch (NS) and HMT starches. Both HMT and ANN improve the thermal properties by elevating gelatinization temperatures and gelatinization enthalpy. Moisture levels have a significant impact on the properties of NS, HMT, and ANN starches. Though annealing with 80% moisture alters the sohphlang starch properties, the effect is found to be lesser when compared to heat moisture treatment with 30% moisture. Thus, overall results convey that HMT and ANN can be used as modification techniques of sohphlang starch to modify the properties that can be useful in food applications.

Morphological, Structural, and Paste Characteristics of Native and Heat‐Moisture Treated Treculia africana Starch

AbstractStarch is isolated from the seeds of Treculia africana at an initial moisture content of 15% and is modified by heat‐moisture treatment (HMT) at desired moisture contents (Heat treated native; 15%, HMT18%, HMT24%, and HMT30%). The parameters analyzed includes granule size, X‐ray diffraction, amylose leaching, pasting properties, shear viscosity, paste clarity, and freeze‐thaw stability. The native starch is compared to HMT starch in terms of characteristics. The A‐type X‐ray diffraction pattern of native T. africana starch (15.5°, 17.4°, 18.0°, 23.0°) is lost during HMT, resulting in a change to the B‐type. The swelling profile at different temperatures shows that swelling decreased with increasing moisture of HMT. The deep blue coloration of the starch‐iodine complex increases with the increasing moisture of HMT. The rapid visco analyzer paste characteristics show pasting temperature increased while peak, breakdown, and setback viscosities decreased with increasing moisture of HMT. The shear viscosity of the starch pastes decreases with HMT. Paste clarity decreases while syneresis increases with HMT. Overall, increasing the moisture of HMT stabilizes the starch pastes against breakdown and improves their properties and potential for application as thickener in foods requiring severe processing conditions.

CRYSTALLINE AND DIGESTIVE CHARACTERISTICS OF HEAT MOISTURE TREATED AND ANNEALED LESSER YAM (Dioscorea esculenta) STARCH

Hydrothermal modification is a physically safe modification applied in a food product to enhance its functional properties and to extend the starch application in the food industry. Heat Moisture Treatment (HMT) and Annealing (ANN) affect the starch’s functional properties in its crystalline and digestive characteristics. Native starch is modified by HMT with 25% moisture content and 4 hours heating time, by ANN with starch and water ratio of 1:3 (w/w), and 10 hours at 50°C. Modified lesser yam starch by HMT and ANN have different crystalline and digestive characteristics from its native, although the modification do not change its granule morphology. The diffraction pattern of HMT starch is changed from A-type to A+B-type, but not on the ANN starch. Starch content and digestive value decreased, while amylose and resistant starch content increased compared to native starch. Hydrothermally modified starch could be considered as a raw material in thermally stable functional foods.

Effect of heat-moisture treatment on the physicochemical properties of native canistel starch

The modification process in starch can improve starch characteristics and expand its application into food products. The objective of this research was to study the effect of heat moisture treatment (HMT) modification on the properties of new canistel starch and study their potential application to food products. The research methods were isolating the native starch and modifying it using HMT modification. Pasting profile, moisture content, starch and amylose content, yield, color, granule morphology, and crystallinity properties of native and HMT canistel starches were analyzed. Statistical analysis showed that HMT modification increased the initial and peak temperatures of gelatinization, peak time, trough viscosity, final viscosity, and setback value. However, it decreased peak viscosity and breakdown levels. In addition, this modification significantly reduced the yield, brightness, and amylose content of canistel starch. HMT modification made a more tenuous structure than native starch, however it did not change spherical shape and small size of the granules. Also, HMT-modified canistel starch had higher crystallinity degree than native starch. Based on these obtained properties, native canistel starch was suitable for frozen food, whereas HMT starch can be applied in noodle processing and as a thickener.

Simple thermal and freezing treatments to improve absorption capacity and alter digestibility of canna starch granules

Swollen canna starches (SCS) were prepared by controlled heating of unmodified and heat-moisture treated (HMT) starch suspensions at sub-gelatinization temperatures; subsequently, freezing was conducted to stabilize the structure of the SCS. Sizes of both unmodified and HMT swollen granules increased with increasing heating temperatures (up to 2.5 times), and freezing resulted in a significant reduction of granular size. The absorption capacities of the swollen starches increased up to 6 times for water and 3 times for tributyrin and palm oil compared to unmodified starch. The differences in absorption capacities of the unmodified and HMT swollen starches were small. Freezing the swollen starches tended to decrease oil and water absorptions, except for unmodified starch swollen at 70 °C, where freezing increased water absorption. Freezing significantly decreased the susceptibility of the swollen unmodified starches to amylase digestion and slowed down the digestion of the swollen HMT starches.

Effects of heat–moisture treatment conditions on the physicochemical properties and digestibility of field bean starch (Vicia faba var. minor)

In the presented study, starch of two cultivars of field bean was modified via the heat-moisture treatment (HMT) at various moisture contents (15 and 30%) and temperatures (100 and 120 °C) to determine HMT effect on its physicochemical properties and digestibility. Non-modified (NM) starches showed only slight variation in properties, with the tested varieties differing only in slowly digestible starch (SDS) and resistant starch (RS) content. The HMT was shown to decrease the swelling power and amylose leaching and higher phase transition temperatures and wider gelatinization temperature ranges in all modification conditions. These effects were caused by changes in the starch structure, as evidenced by the observed the decrease in relative crystallinity. The changes were the most pronounced in the starches treated at the higher moisture level. The HMT modification modified also starch digestibility. The total content of SDS and RS in non-gelatinized HMT starches modified at 15% moisture content was higher than that determined in the starch modified at 30% moisture content. In most gelatinized HMT starches, the SDS content decreased and that of RS did not change significantly compared to the native starch. Despite modified physicochemical properties, those starches still represent a good source of resistant starch.

Use of heat‐moisture treated maize starch to modify the properties of wheat flour and the quality of noodles

SummaryWaxy, normal and high‐amylose maize starches were subjected to heat‐moisture treatment (HMT) and then added to wheat flour (WF) in different ratios (1%, 5% and 10%). The properties of blends and their cooked noodles were studied to investigate the effects of HMT starches. The incorporation of HMT starch in WF led to an increase in swelling power, peak viscosity and breakdown and to a decrease in setback, thus inhibiting retrogradation, hence enhancing resultant noodle softness. Compared to the same addition ratio of native starch to WF, HMT starch led to higher tensile strength and extensibility in resultant noodles. WF with added HMT starch had higher resistant starch than with native starch. This study showed that addition of HMT maize starch has potential to bring nutritional benefits. However, it is necessary to select the proper blending ratio and amylose content of starch to add, in consideration of its effect on noodle quality.

Pectin interaction with thermally modified starch affects physicochemical properties and digestibility of starch as revealed by logarithm of slop plot

ABSTRACT Interaction of pectin with starch modified by heat-moisture treatment (HMT) was evaluated. HMT preserved the presence of starch fractions with k1 and k2 (digestion rate constants at rapid and slow phase, respectively) being 4.5 and 0.42 × 10−2 min−1. Compared to the native starch, HMT starch had lower k1 and k2 probably due to the change in crystalline type. HMT increased total digestible starch from 1.02% in native to 27.23% in HMT starch. The decrease in k1 and/or k2 with the increase in pectin might be linked to the effect of viscosity or pectin–amylase interaction, while the decrease in digestible starch at rapid phase (C1∞ ) could be attributed to pectin–starch interaction. Pectin affected significantly water absorption capacity, syneresis, cohesiveness and gumminess of HMT starch but did not alter those of native starch. The effect of HMT on functional, textural and pasting properties was more remarkable than the effect of pectin.