Heat Exchanger Tubes Of Steam Generators Research Articles

Evaluation of the Influence of the Hydrogenation of Metal on the Durability of Heat-Exchanger Tubes of Steam Generators

Evaluation of the Influence of the Hydrogenation of Metal on the Durability of Heat-Exchanger Tubes of Steam Generators

Long-term effects of a chemical decontamination procedure on the corrosion state of the heat exchanger tubes of steam generators

Our previous studies have revealed that a ”hybrid” structure of the amorphous and crystalline phases is formed in the outermost surface region of the austenitic stainless steel tubes of steam generators (SGs) as an undesired consequence of the industrial application of the AP-CITROX (AP: alkaline permanganate; CITROX: citric and oxalic acid) decontamination technology. The formation of this mobile oxide-layer increased the amount of the corrosion products in the primary circuit significantly, resulting in magnetite deposition on fuel assemblies. Owing to the fact that there is no investigation method available for the in-situ monitoring of the inner surfaces of heat exchanger tubes, a research project based on sampling as well as on ex-situ electrochemical and surface analytical measurements was elaborated. Within the frame of this project, comprehensive investigation of the general corrosion state and metallographic features of 36 stainless steel specimens, cut out from various locations of the 21 steam generators of the Paks NPP in the time period of 2000-2007 has been performed. The present work gives a brief overview on the general corrosion state of the heat exchanger tubes of SGs, concerning the long-term effects of the AP-CITROX procedure on the chemical composition and structure of the protective oxide-layer.

Comprehensive investigation of the corrosion state and surface properties of the stainless steel tubes of steam generators

Evaluating the water chemistry in the primary circuit and the effect of chemical econtamination
 of the heat exchanger tubes performed by the AP-CITROX (AP: alkaline permanganate; CITROX: citric and oxalic acid) procedure at Paks NPP (Hungary), a project dealing with the comprehensive investigation of the general corrosion state of the steam generators (SGs) has been initiated. Owing to the fact that there is no investigation method available for the in-situ monitoring of the inner surfaces of heat exchanger tubes, a research program based on sampling as well as on ex-situ electrochemical (voltammetric) and surface analytical measurements (SEM-EDX, CEMS, XRD, XPS) was developed and elaborated. In the time period of 2000-2008 - within the frame of the above project - 45 stainless steel specimens, cut out from various locations of the steam generators of the Paks NPP were investigated. Based on the measured corrosion characteristics (corrosion rate, thickness and chemical composition of the protective oxide-layer) it was found that these parameters are strongly dependent on the decontamination history of steam generators. The present work gives a brief overview on the general corrosion state of the heat exchanger tubes of SGs, concerning the long-term effects of the AP-CITROX procedure on the chemical composition and structure of the protective oxide-layer.

Application with Simultaneous Electrocontact Heating Stretching to Reduce Residual Stresses in the Heat Exchange Tube

The main reason of appearance and growth of corrosion damages of the nuclear steam generator heat exchanger tubes is the process of stress-corrosion cracking of metal under the influence of residual tensile stress.The article contain the suggestion of the method that combines the operation of heat processing and straightening of pipes by stretching. The approbation of the method was carried out in the laboratory conditions. There is described the construction and working principle of a trial installation. During the experiments different parameters of electrocontact heating with stretching were tested. Approbation showed that the proposed method can reduce the level of tensile residual stresses or get compressive residual stresses in the wall of the tubes, which increases their resistance to corrosion.Keywords:Steam generator, heat exchange tubes, stress corrosion cracking, intercrystalline corrosion, residual stresses