We study a particular involution in the class {mathcal {M}^succcurlyeq _{q}({[alpha ,beta ]})} of all Non-negative Hermitian {qtimes q} measures on a compact interval {[alpha ,beta ]} of mathbb {R}. Several connections to the matricial version of the Hausdorff moment problem on {[alpha ,beta ]} are investigated in terms of {[alpha ,beta ]}-Stieltjes transforms as well as in the language of matricial Hausdorff moment sequences and associated matricial canonical moments.