W ild temperature swings can crack a plate as surely as dropping it on a hard kitchen floor. A ceramic dish taken from the freezer and thrust into a hot oven splits apart because some parts heat up and expand faster than others. This problem isn't unique to dishes. Computer chips, fiber optic cables, and dental fillings, for example, all risk failure when they expand differently from the materials around them. An unusual compound called zirconium tungstate, however, might make these annoyances a thing of the past. Although most materials grow when they get hot, zirconium tungstate does the exact opposite-it shrinks. A few other compounds have this characteristic, but they tend to shrink in one direction while they stretch out in others in order to preserve an overall volume. Zirconium tungstate, a blend of zirconium, tungsten, and oxygen, stands out from its peers because it shrinks equally in all directions. Moreover, zirconium tungstate exhibits this behavior over a huge temperature range-from near absolute zero to 777?C. Although scientists have known about zirconium tungstate's weird behavior for 30 years, they have only recently begun to explain why the material acts so contrarily. With this new understanding, researchers are also beginning to learn how to blend zirconium tungstate with other compounds so as to make new composite materials resistant to thermal shock.
Read full abstract