Numerous exotic hadrons with heavy quarks have been reported in the experiments. In such states, symmetries of heavy quarks are considered to play a significant role. In particular, the superflavor symmetry, or also called the heavy quark antidiquark symmetry is one of the interesting symmetries, which links a quark Q to an antidiquark Q¯Q¯ having the same color representation as Q. In this paper, we study a D¯Ξcc molecular state as a superflavor partner of the doubly charmed tetraquark Tcc reported by LHCb recently. Tcc locating slightly below the DD* threshold is a candidate of the hadronic molecule. Thus by replacing the singly charmed meson D(*) with the doubly charmed baryon Ξcc(*), superflavor symmetry predicts the existence of the D¯(*)Ξcc(*) bound state. We employ the one boson exchange model respecting with the heavy quark spin symmetry where the parameter is obtained to reproduce the Tcc binding energy. We apply this model with superflavor symmetry to the D¯(*)Ξcc(*) molecule and predict a bound state with I(JP)=0(12−). If the pentaquark state corresponding to D¯(*)Ξcc(*) molecular state is observed in future experiments as predicted in this work, it is more likely that Tcc is a DD* molecular state. Published by the American Physical Society 2024