Ooid Growth Research Articles

The where, when, and how of ooid formation: What ooids tell us about ancient seawater chemistry

Ooids are a common constituent of carbonate rock throughout the last 3.2 billion years. The chemical and physical characteristics of ooids record essential details of the carbonate chemistry and hydrodynamic conditions of their depositional environment. As a result, ooids may be a powerful tool for reconstructing Earth's ancient climates and environments. However, lack of constraints on fundamental aspects of ooid formation, such as the role of abrasion, underscores the potential for additional discoveries utilizing ooids as paleoenvironmental proxies. Here, we use three-dimensional models built by serially grinding and imaging ooids to show how ooid shape changes during growth. We find that ooid abrasion plays only a small role in the formation of ooids, even in giant ooids, where the mass should cause abrasion to be most intense. A lack of abrasion during ooid formation suggests a greater sensitivity of ooid distribution and size to the chemistry of depositional environments. This insight enables us to harmonize our understanding of ooid formation with longstanding questions regarding their spatial and temporal distribution, as well as size variations. With a new database of ooid occurrences, we analyze the influence of seawater chemistry, carbonate shelf area, and evolutionary developments on ooid abundance in the Modern, Last Glacial Period, and throughout the Phanerozoic. Finally, we leverage our new understanding of ooid growth to show how ooid size, including giant ooids, can shed light on relative changes in alkalinity throughout the Phanerozoic.

Radiocarbon Chronology/Growth Rates of Ooids from Great Salt Lake, Utah

Ooids (calcium carbonate coated grains) are common in carbonate environments throughout geologic time, but the mechanism by which they form remains unclear. In particular, the rate of ooid growth remains elusive in all but a few modern marine environments. In order to investigate the rate of ooid growth in a non-marine setting, we used 14C to date ooids from Great Salt Lake, Utah, a well-known site of aragonitic ooids. Bulk ooids obtained from the northern shore of Antelope Island and the northeast shore of Great Salt Lake near Spiral Jetty were sieved into different size fractions and produced mean ages ranging between 2728±15 and 4373±20 14C yr BP. Larger ooids were older than smaller ooids, implying that larger ooids grew in the environment for a longer duration, with the caveat that bulk age dating integrates the growth history of an ooid. To better resolve growth history, ooids from the coarse fraction were sequentially dissolved, and 14C ages were obtained for each dissolution step to create a time series of ooid growth. The results of the sequential dating indicate that the coarse Great Salt Lake ooid growth began between 5800-6600 ± 60 14C yr BP while their outer cortices are nearly modern. Sequentially dated ooids from the South Arm of Great Salt Lake at Antelope Island record a nearly linear growth history (~ 10-15 µm/kyr), whereas ooids from Spiral Jetty record somewhat faster growth between ~6000 and 4000 years ago (0.03 – 0.06 µm/yr) followed by a 10x slower growth history for the remainder of their lifespan (0.003 – 0.008 µm/yr). The lifespan of Great Salt Lake aragonitic ooids is two to six times longer than those from modern marine environments, and thus provides a unique end member for understanding the mechanisms behind ooid formation. The ooid age range indicates that geochemical parameters measured from bulk ooid dissolution integrates over ~6000 years and thus does not represent a geochemical snapshot in time, as some previous studies have suggested.

A tale of two Arabian Cenozoic ooids: Factors controlling the differential growth of ooids across the Arabian Plate

Ooids are a critical yet enigmatic carbonate grains in the geological record. Previous studies have focused their efforts on studying the mode of ooid formation throughout the Phanerozoic via experimental, numerical simulations, and field studies. To date, however, there is little discussion around factors governing the texture, mineralogy, structure, size, and geometry of Cenozoic ooids, particularly in Saudi Arabia. The present article aims to provide insights on key factors controlling the differential growth of Cenozoic ooids in Saudi Arabia by comparing two contrasting carbonate environments and tectonic settings. Here, we studied the Holocene (0.4–2 kya) ooids developed in the tidally dominated carbonate ramp of the Arabian Gulf under a passive margin setting and the Miocene (15–21 mya) ooids from the Red Sea that were developed in a tectonically active, wave-dominated fault-bounded carbonate platform. The Holocene ooids were characterized by aragonitic, heavily micritized and small (max:550 μm) ooids with bioclast-dominated nuclei. In contrast, the Miocene ooids were replaced by dolomite, larger in size (max:820 μm) and significantly less micritized with variable nuclei compositions, such as rock fragments and bioclasts. The variation in the intensity of bioerosion and micritization suggest the Miocene ooids experienced lesser resting stage time than the Holocene ooids developed under the tide regime due to active wave actions. In addition, the Miocene ooids were developed in a fault-bounded margin allowing a higher carbonate saturation state to concentrate in that zone while the Holocene ooids were developed under a widespread distribution of carbonate saturation state in a vast carbonate ramp setting. These findings indicate that original platform geometry and depositional system (tide-vs wave-dominated) are substantial in dictating the duration of ooid resting stage and distribution of carbonate saturation state across the platforms. All these combined, allows the Miocene ooids to grow larger and reaching its equilibrium size faster. This study highlights the importance of coupling platform architecture and other key environmental parameters (wave actions, sediment supply, and tectonic activities) in understanding the formation of Cenozoic ooids.

Depositional processes of the mixed siliciclastic-carbonate system in the Lower Cambrian Xiannüdong Formation in the northern Sichuan Basin, South China

Mixed siliciclastic-carbonate systems contain significant heterogeneity of facies associations which complicates the interpretation of depositional environments and platform evolution. The Lower Cambrian Xiannüdong Formation in the northern Sichuan Basin was deposited in a mixed system which is characterized by the non-skeleton grain (ooids and microbialites) dominated carbonates mixed with siliciclastic sediments. Such a depositional system provides a template to decipher the facies variability of mixed depositional systems and the evolution of platform geometry. Based on the facies analysis in outcrops and drilling wells, seventeen lithofacies were identified and grouped into seven lithofacies associations which represents a shallow-marine environment dominated by wave and storm activities. The vertical stacking pattern of lithofacies in the Xiannüdong Formation archives a regressive cycle which can be subdivided into four sub-cycles (i.e., S1 to S4). All the four sub-cycles exhibit the characteristic of the shallowing-upward successions, which are overlain by a flooding unit. The spatial distribution of lithofacies suggests an eastward-inclined platform. The migrating ooid shoals together with the storm activities may prevent the platform from evolving into a rimmed shelf. The lateral and vetical distribution of the terrigenous materials indicates that the provenance of terrigenous sediments were mainly sourced from the Kangdian and Bikou massifs, which indicates that the mixed system and the provenance area were separated by the Mianyang-Changning trough. Therefore, the transport of siliciclastic materials was related to the available accommodation space on the shelf, and was controlled by the eustatic sea-level fluctuation, with increased input of siliciclastic material occurred during phases of relative sea-level rise. The input of siliciclastic sediments brings nutrition for the growth of algal–archaeocyathan mounds, and therefore the mounds were mainly developed in the lower part of Xiannüdong Formation. Moreover, high siliciclastic sediments influx would also influence the growth of ooids by serving nuclei and promoting abrasion, which resulted in smaller ooid size compared to those of the relatively pure oolite. This study provides clues to understanding the facies variability in mixed systems and servers as a valuable reference for studies of other similar platforms.

Quantitative evaluation of the roles of ocean chemistry and climate on ooid size across the Phanerozoic: Global versus local controls

AbstractOoid size in natural systems can be predicted based on the expected equilibrium between precipitation and abrasion rates. Therefore, ooid size distributions may enable quantitative inferences about past ocean and climate conditions from sedimentology that complement insights from geochemistry. A few previous attempts have been made to compile information on ooid sizes across the Phanerozoic, but no systematic ooid size dataset is available and equilibrium models of ooid growth have not been explored comprehensively. In this study, convolutional neural network‐based segmentation was used to automate ooid size measurement and provide a systematic sampling of ooid sizes spanning the Phanerozoic. This data set is coupled with Monte Carlo simulations to quantitatively explore the interplay between three testable physicochemical parameters (long‐term average carbonate saturation state, bed shear velocity and intermittency of transport) in determining equilibrium ooid size. The numerical model shows that a typical‐sized ooid (≤1000 µm) can grow under a wide range of parameter combinations whereas giant ooids (>2000 µm) can only form under a more restricted set of circumstances. Furthermore, the model predicts that the formation of giant ooids is common when conditions favourable for rapid CaCO3 precipitation are achieved. This finding is consistent with the naturally rare occurrences of giant ooids, which developed under exceptional environmental conditions and are primarily associated with intervals of bimineralic seas and elevated sea‐surface temperature (greenhouse or transitional climate). Whereas global controls could help explain secular trends in ooid size, significant spatial variability of ooid size in several time intervals further demonstrates the importance of local environmental parameters in the growth of ooids. Together, spatial and temporal variation in ooid size distributions can complement geochemical proxies in quantitatively reconstructing ancient tropical marine environments.

Distribution and Controlling Growth Factors of Ooids in Qinghai Lake, Northern Tibet Plateau, China

Ooids are coated carbonate grains, which exist in shallow water marine and lacustrine environments. There is an ongoing debate about whether the origin of ooids is inorganic or organic. Qinghai Lake is the largest inland lake in China, and ooids are seen on the lake shore. This paper focuses on whether environmental energy has an impact on the growth and size of ooids. Through hydrochemical analysis, thin section observation, and scanning electron microscope, the carbonate coats of beach sands from Qinghai Lake were studied. The research shows that the carbonate-coated grain content from the different shores of the lake present variations. The hydrodynamics and particularly the waves seem to control the distribution of carbonate coats in the lake shore, not the hydrochemical condition. In addition, the integrity and thickness of carbonate coats from the shores with a strong hydrodynamic force are high and thick, respectively. The carbonate coats are often observed on medium-grained sands, and the maximum carbonate-coated grain occurred under the strongest waves, indicating that ooids can be produced only when hydrodynamic force and particle size are well matched. Bacteria or extracellular polymeric substances are not observed within the ooid cortices by scanning electron microscopy. So, bacteria may not be a major factor in the formation and growth of ooids, but hydrodynamic forces appear to play a great role in carbonate grain coat distribution, integrity, thickness, and ooid grain size.

A case for the growth of ancient ooids within the sediment pile

ABSTRACT In modern ooid-forming environments in the Caribbean, aerobic respiration of organic matter below the sediment–water interface drives an increase in pCO2 and a corresponding decrease in carbonate saturation state (Ω) that creates shallow sediment porewater that is neutral or slightly caustic to carbonate. The locus of ooid growth, therefore, is presumed to be in the water column during suspension, where supersaturation with respect to calcium carbonate is the norm. In the past, however, during conditions of low aqueous O2, high Ω, or low organic-matter input, the shallow sub-sediment marine burial environment was conducive to carbonate precipitation. Here we present petrographic and electron probe microanalyzer (EPMA) data from exquisitely preserved oolites through time that suggests that some ancient ooids may have grown within the sediment pile. We propose that each increment of ooid cortical growth originated as incipient isopachous marine cement formed during shallow burial within migrating ooid dunes. After a period of burial (∼ weeks to months), ooids were remobilized and rounded during bedload transport. This “bedform model” for ooid growth explains: 1) why ancient ooids are not limited by the precipitation–abrasion balance that appears to prohibit modern tangential Caribbean ooids from achieving grain sizes larger than coarse sand, 2) the radial crystal fabric that defines the internal structure of many ancient ooids, and 3) the first-order correlation of the abundance of large and giant ooids in the rock record to periods with predicted high porewater Ω. This model implies that photosynthetic microbes were unimportant for growth of large and giant ooid but it remains agnostic to the effect of other microbes. The physical and chemical milieu of modern marine ooid-forming environments is perhaps not the best analogue for ancient ooid-forming environments; this should be considered when using ancient ooids to reconstruct secular trends in ocean chemistry.

Ooid growth: Uniqueness of time-invariant, smooth shapes in 2D

Evolution of planar curves under a nonlocal geometric equation is investigated. It models the simultaneous contraction and growth of carbonate particles called ooids in geosciences. Using classical ODE results and a bijective mapping, we demonstrate that the steady parameters associated with the physical environment determine a unique, time-invariant, compact shape among smooth, convex curves embedded in ℝ2. It is also revealed that any time-invariant solution possesses D2 symmetry. The model predictions remarkably agree with ooid shapes observed in nature.

Active Ooid Growth Driven By Sediment Transport in a High-Energy Shoal, Little Ambergris Cay, Turks and Caicos Islands

Ooids are a common component of carbonate successions of all ages and present significant potential as paleoenvironmental proxies, if the mechanisms that control their formation and growth can be understood quantitatively. There are a number of hypotheses about the controls on ooid growth, each offering different ideas on where and how ooids accrete and what role, if any, sediment transport and abrasion might play. These hypotheses have not been well tested in the field, largely due to the inherent challenges of tracking individual grains over long timescales. This study presents a detailed field test of ooid-growth hypotheses on Little Ambergris Cay in the Turks and Caicos Islands, British Overseas Territories. This field site is characterized by westward net sediment transport from waves driven by persistent easterly trade winds. This configuration makes it possible to track changes in ooid properties along their transport path as a proxy for changes in time. Ooid size, shape, and radiocarbon age were compared along this path to determine in which environments ooids are growing or abrading. Ooid surface textures, petrographic fabrics, stable-isotope compositions (δ^(13)C, δ^(18)O, and δ^(34)S), lipid geochemistry, and genetic data were compared to characterize mechanisms of precipitation and degradation and to determine the relative contributions of abiotic (e.g., abiotic precipitation, physical abrasion) and biologically influenced processes (e.g., biologically mediated precipitation, fabric destruction through microbial microboring and micritization) to grain size and character. A convergence of evidence shows that active ooid growth occurs along the transport path in a high-energy shoal environment characterized by frequent suspended-load transport: median ooid size increases by more than 100 μm and bulk radiocarbon ages decrease by 360 yr westward along the ∼ 20 km length of the shoal crest. Lipid and 16S rRNA data highlight a spatial disconnect between the environments with the most extensive biofilm colonization and environments with active ooid growth. Stable-isotope compositions are indistinguishable among samples, and are consistent with abiotic precipitation of aragonite from seawater. Westward increases in ooid sphericity and the abundance of well-polished ooids illustrate that ooids experience subequal amounts of growth and abrasion—in favor of net growth—as they are transported along the shoal crest. Overall, these results demonstrate that, in the Ambergris system, the mechanism of ooid growth is dominantly abiotic and the loci of ooid growth is determined by both carbonate saturation and sediment transport mode. Microbes play a largely destructive, rather than constructive, role in ooid size and fabric.

Contribution of Benthic Processes to the Growth of Ooids on a Low-Energy Shore in Cat Island, The Bahamas

Ooids are typically found in frequently reworked coastal sediments, and are thought to accrete by inorganic chemical precipitation around moving grains. The high organic content and the presence of biosignatures, however, suggest that ooids interact with benthic microbial communities. Here, we investigate the role of benthic processes on ooid growth on a leeward shore of Cat Island, The Bahamas. Polished ooids are present in the surf zone, whereas dull ooids and grapestones are present in microbially colonized sediments seaward of the surf zone. Wave hydrodynamics and sediment transport modeling suggest that microbially colonized sediments are mobilized at monthly time scales. We propose a new conceptual model for both ooids and grapestone. Ooids rest and accrete in the area covered by microbial mats, but are periodically transported to the surf zone where wave abrasion polishes them within days. Ooids are then transported back to microbially colonized areas where the accretion cycle resumes. Ooids too large to be transported become trapped outside the surf zone, exit the “conveyor belt” and become grapestones. The benthic growth mechanism predicts petrographic characteristics that match observations: successive ooid laminae do not thin outward, laminae exhibit irregularities, and some ooids include multiple nuclei.

A biofilm and organomineralisation model for the growth and limiting size of ooids

Ooids are typically spherical sediment grains characterised by concentric layers encapsulating a core. There is no universally accepted explanation for ooid genesis, though factors such as agitation, abiotic and/or microbial mineralisation and size limitation have been variously invoked. Here we examine the possible influence of microbial organomineralisation on the formation of some naturally occurring ooids. We develop a mathematical model for ooid growth, inspired by work on avascular brain tumours, that assumes mineralisation in a biofilm to form a central core which then nucleates the progressive growth of concentric laminations. The model predicts a limiting size with the sequential width variation of growth rings comparing favourably with those observed in experimentally grown ooids generated from biomicrospheres. In reality, this model pattern may be complicated during growth by syngenetic aggrading neomorphism of the unstable mineral phase, followed by diagenetic recrystallisation that further complicates the structure. Our model provides a potential key to understanding the genetic archive preserved in the internal structures of some ooids.

Experimental evidence that ooid size reflects a dynamic equilibrium between rapid precipitation and abrasion rates

Ooids are enigmatic concentrically coated carbonate sand grains that reflect a fundamental mode of carbonate sedimentation and inorganic product of the carbon cycle—trends in their composition and size are thought to record changes in seawater chemistry over Earth history. Substantial debate persists concerning the roles of physical, chemical, and microbial processes in their growth, including whether carbonate precipitation on ooid surfaces is driven by seawater chemistry or microbial activity, and what role—if any—sediment transport and abrasion play. To test these ideas, we developed an approach to study ooids in the laboratory employing sediment transport stages and seawater chemistry similar to natural environments. Ooid abrasion and precipitation rates in the experiments were four orders of magnitude faster than radiocarbon net growth rates of natural ooids, implying that ooids approach a stable size representing a dynamic equilibrium between precipitation and abrasion. Results demonstrate that the physical environment is as important as seawater chemistry in controlling ooid growth and, more generally, that sediment transport plays a significant role in chemical sedimentary systems.

Geochemistry of the apulian allochthonous karst bauxite, Southern Italy: Distribution of critical elements and constraints on Late Cretaceous Peri-Tethyan palaeogeography

A comprehensive study of pebbles from the 'Salento-type' allochthnous bauxite deposit (Otranto, southern Italy), originally derived from a pristine Campanian bauxite, has been performed for evaluating: 1) the chemical fractionation and inter-elemental relationships, especially for critical elements, 2) the climatic conditions that promoted bauxite formation, and 3) the provenance of the protolith(s) using zircon age data and conservative elemental proxies. The study confirms the capability of bauxite to concentrate many elements defined as critical by the European Union report on critical raw materials. Sc, Co, Ga, and especially Cr, are enriched when compared with the UCC composition and assuming Nb is immobile. Other critical elements such as the REEs, with the exception of La, are moderately depleted. R-mode factor analysis suggests that most of the variance in our chemical dataset is explained by a factor with significant weightings for TiO2, Al2O3, Fe2O3, Sc, V, Nb, REEs, Pb and Th. This arises from climate effects affecting the distribution of the more abundant oxides and some trace elements, including the critical metals Nb and REEs. The texture of the pebbles is typical for Apulian karst bauxites and consists of sub-spheroidal ooids composed of boehmite and dispersed in a fine-grained matrix. The growth of the ooids, which formed under dry climate, was described in terms of fractal geometry. The average fractal dimension value of the ooids in the pebbles is close to that of the diffusion-limited aggregation models suggesting the ooid growth can be modelled using a molecular diffusion pattern, based on Fick's first law. The calculated time required for growth of the boehmite concretions is ~45÷310ka. This finding is consistent with an intra-Campanian emersion event (74–76Ma) that occurred during a dry and warm climatic stage. Since most of the karst bauxites worldwide have an ooidic texture, evaluation of the composition of concretions and the time required for their growth represents a powerful tool in reconstructing the palaeoenvironment. The zircon grains collected from the pebbles of the Salento-type karst bauxite define several concordant age populations. The youngest cluster, Early Cretaceous in age (99÷127.5Ma), suggests that windborne particles from Cretaceous volcanics, possibly originating in the Carpatho-Balkan orogenic belts, provided material for further bauxitisation. The largest cluster (623÷689Ma) is of Neoproterozoic age, predominately from the Late Ediacaran and Cryogenian p.p.. The 900–540Ma Pan-African orogenic cycle was followed by continental-scale uplift and erosion, leading to the deposition of thick Cambrian–Ordovician siliciclastic sequences that represent the most widespread detrital sequence ever deposited on continental crust and that now cover large parts of North Africa. These Cambrian–Ordovician sandstones contain a large population of Neoproterozoic zircons of Cryogenian age. Neoproterozoic zircons also occur in the youngest (Silurian–Mesozoic) sandstones of the Saharan Metacraton. These sandstones also contain 1.0Ga detrital zircons, suggesting as the oldest zircons found in the Salento-type bauxite pebbles (866Ma and 941Ma in age) are younger representatives of the zircon cluster present in this sandstone unit.These zircon age determinations suggest that the source material for the Salento-type bauxite pebbles was a combination of magmatic material from a distant source and clastic material derived from a continental margin (North Africa). This result concurs with the Eu/Eu* vs. Sm/Nd binary diagram, on which bauxite pebbles fall close to a mixing curve with andesite and cratonic sandstone end-members. As our results indicate that material was sourced from the North African continental margin, we suggest that a continental bridge separated oceanic domains in the Late Cretaceous of the Peri-Tethyan domain.

Rapid, high-resolution 14C chronology of ooids

Ooids are small, spherical to ellipsoidal grains composed of concentric layers of CaCO3 that could potentially serve as biogeochemical records of the environments in which they grew. Such records, however, must be placed in the proper temporal context. Therefore, we developed a novel acidification system and employed an accelerator mass spectrometer (AMS) with a gas accepting ion source to obtain radiocarbon (14C) chronologies extending radially through ooids within one 8-h workday. The method was applied to ooids from Highborne Cay, Bahamas and Shark Bay, Australia, yielding reproducible 14C chronologies, as well as constraints on the rates and durations of ooid growth and independent estimates of local 14C reservoir ages.

Lipid biomarkers in ooids from different locations and ages: evidence for a common bacterial flora

Ooids are one of the common constituents of ancient carbonate rocks, yet the role that microbial communities may or may not play in their formation remains unresolved. To search for evidence of microbial activity in modern and Holocene ooids, samples collected from intertidal waters, beaches and outcrops in the Bahamas and in Shark Bay in Western Australia were examined for their contents of lipid biomarkers. Modern samples from Cat and Andros islands in the Bahamas and from Carbla Beach in Hamelin Pool, Western Australia, showed abundant and notably similar distributions of hydrocarbons, fatty acids (FAs) and alcohols. A large fraction of these lipids were bound into the carbonate matrix and only released on acid dissolution, which suggests that these lipids were being incorporated continuously during ooid growth. The distributions of hydrocarbons, and their disparate carbon isotopic signatures, were consistent with mixed input from cyanobacteria together with small and variable amounts of vascular plant leaf wax [C27 -C35 ; δ(13) C -25 to -32‰Vienna Pee Dee Belemnite (VPDB)]. The FAs comprised a complex mixture of C12 -C18 normal and branched short-chain compounds with the predominant straight-chain components attributable to bacteria and/or cyanobacteria. Branched FA, especially 10-MeC16 and 10-MeC17 , together with the prevalence of elemental sulfur in the extracts, indicate an origin from sulfate-reducing bacteria. The iso- and anteiso-FA were quite variable in their (13) C contents suggesting that they come from organisms with diverse physiologies. Hydrogen isotopic compositions provide further insight into this issue. FAs in each sample show disparate δD values consistent with inputs from autotrophs and heterotrophs. The most enigmatic lipid assemblage is an homologous series of long-chain (C24 -C32 ) FA with pronounced even carbon number preference. Typically, such long-chain FA are thought to come from land plant leaf wax, but in this case, their (13) C-enriched isotopic signatures compared to co-occurring n-alkanes (e.g., Hamelin Pool TLE FA C24 -C32 ; δ(13) C -20 to -24.2‰ VPDB; TLE n-alkanes δ(13) C -24.1 to -26.2 -‰VPDB) indicate a microbial origin, possibly sulfate-reducing bacteria. Lastly, we identified homohopanoic acid and bishomohopanol as the primary degradation products of bacterial hopanoids. The distributions of lipids isolated from Holocene oolites from the Rice Bay Formation of Cat Island, Bahamas were very similar to the beach ooids described above and, in total, these modern and fossil biomarker data lead us to hypothesize that ooids are colonized by a defined microbial community and that these microbes possibly mediate calcification.

Meso–Neoproterozoic coated grains and palaeoecology of associated microfossils: The Deoban Limestone, Lesser Himalaya, India

Organically preserved microfossil assemblages occurring in association with the coated grains (ooids and pisoids) are being reported from the petrographic thin sections of the black chert. Samples have been collected from the Deoban Limestone, Garhwal Lesser Himalaya. Like any other Proterozoic microfossil assemblage, present assemblage also exhibits domination of cyanobacterial community and rare occurrence of bacterial and acritarchean affinity. The microfossils occur in three principal palaeoecological modes: a) Clast bound microfossils: These are found in detrital grains which also served as a nuclei for ooid growth. b) Epilithic or interstitial microfossils: These occur on the outer surface of the coated grains as well as within the cement. c) Euendolithic microfossils: These microorganisms actively bored into the coated grains. Coated grains comprising the microbial structures can be considered as the indicators of shallow water environments. Their size is at least partly dependant on current strength. At larger sizes, increasing rates of abrasion may come to equal rates of carbonate precipitation or accretion. Since filamentous population of specific dimensions dominate the present assemblage, it is inferred that tubular filaments ranging in diameter from 4 to 5 μm played the most significant role in the genesis of coated grains irrespective of their mode of occurrence as an epilith, endolith or as the clast bound microfossils. The assemblage adds one more record of Proterozoic endoliths, which are rarely recorded world-wide.

Magnesian calcite and chamositic ooids forming shoals peripheral to Late Ordovician (Ashgill) muddy siliciclastic shores: southern Ontario

In southern Ontario, ooids are associated with two distinct facies associations in the Queenston Formation, the final stage of Late Ordovician (Ashgill) Taconic basin fill. One facies consists of thin ooid and bioclastic grainstones interbedded with mudrock, and lies near the base of the formation, and, in southwestern Ontario, also forms a local NW-thickening wedge near the middle of the formation. Ooids have radial-fibrous and radial-concentric fabrics (Type A), with chamosite, illite, and Fe-oxide laths at intercrystalline sites. Vertical lithologic and ooid abundance patterns indicate that thresholds to carbonate production were sensitive to changes in terrigenous sediment supply, sea level, circulation, accommodation space, and tectonism. Ooids in the second facies association are admixed with abraded fragments of open-marine biota, or occur burrow fills, within a <30-cm-thick interval of mudrock near the top of the preserved Queenston succession, a few metres below the Ordovician–Silurian unconformity. Ooids have radial concentric and crosscutting patchy microcrystalline fabrics (Type B). This unit may represent a transgressive or stillstand deposit modified by bioturbation. The extent of preserved fabric suggests that both ooid types were originally magnesian calcite, but Type A ooids underwent greater burial alteration. This is shown by crystalline mosaics that cross-cut relict primary fabrics; δ 13C values (−1.82‰ to +0.67‰) and δ 18O values (−4.46‰ to −10.57‰) more negative than marine calcite of similar age; Mn and Fe concentrations more elevated above expected marine values; and a luminescence similar to that of intergranular cements. Burial meteoric diagenesis was likely promoted by excellent permeability of the host sand. We interpret authigenic chamosite and Fe-oxide to reflect diagenesis of iron-bearing and clay detritus trapped during ooid growth. Type B ooids suffered less alteration: δ 13C (+1.1‰ to +6.64‰) and δ 18O (−3.04‰ to −4.81‰) values overlap the expected marine range, including 13C enrichment that occurs within the Hirnantian (latest Ordovician) excursion. Although Mn and Fe values are still higher than those of modern calcitic ooids, negligible luminescence suggests that recrystallization occurred in the presence of marine-derived pore fluids. Further burial alteration was inhibited due to low permeability of the host mud. Type A ooid facies in the Queenston Formation forms an ancient analogue for lesser known Quaternary ooid shoals peripheral to tropical deltaic systems. The facies of Type B ooids, while more enigmatic, may preserve a geochemical herald of latest Ordovician climate change. The presence of minor chamosite in Type A ooids defines a possible distal facies of the well-known oolitic ironstones of similar age in the mid-continental USA.

Lateral variation within a hiatal‐condensed bed and the controls on the formation and occurrence of berthierine ooids: a case study from the Middle Jurassic of NE England, UK

AbstractShallow‐marine sandstone and berthierinic, ooidal, sandy limestone form the Hackness Rock Member (HRM), a Callovian‐age hiatal‐condensed bed in NE England. The HRM was deposited in response to a rise in relative sea‐level. Apart from the major hiatal surfaces represented by two significant non‐sequences, it contains a number of other hiatal surfaces representing shorter periods of time. Although the HRM has its own distinctive bioclastic concentrations, early diagenetic mineral assemblages and specific types and degrees of bioturbation, the expression of this bed is variable even over short distances.Variations in the topography of the sea floor produced local hollows and highs, which account for the lateral variability of the HRM and controlled where berthierine ooids formed. Hollows created ‘clastic/colloidal’ traps where finer‐grained sediment accumulated and had low physical mobility; these conditions favoured intra‐sedimentary growth of berthierine ooids in an early (sub‐oxic) diagenetic environment. In contrast, highs were more susceptible to storm reworking and material was more mobile; these conditions resulted in a lower overall rate of accumulation and a lower degree of shallow, sub‐surface diagenesis. Copyright © 2002 John Wiley &amp; Sons, Ltd.

Numerical modeling of ooid size and the problem of Neoproterozoic giant ooids.

Temporal variation in ooid size reflects important changes in physical and chemical characteristics of depositional environments. Two numerical models are used to evaluate the effects of several processes influencing ooid size. The first demonstrates that low supply of new ooid nuclei and high cortex growth rate each promote growth of large ooids. The second model demonstrates that high average water velocity and velocity gradient also enhance ooid growth. Several Neoproterozoic oolites contain unusually large ooids, some reaching diameters of up to 16 mm. While lower nuclei supply and higher ooid growth rate may have prevailed prior to the evolution of carbonate-secreting organisms, neither difference can explain the presence of giant ooids in Neoproterozoic deposits because Archean through Mesoproterozoic ooids rarely exceed 5 mm in diameter. In the presence of lower nuclei supply and higher growth rate, high average water velocity may have allowed growth of such large ooids. Higher average water velocity could have been due to a prevalence of carbonate ramps over rimmed shelves during Neoproterozoic time.

In-Situ Rock/Water Geochemistry of Holocene Marine Radial Ooid Environment, Lizard Island, Great Barrier Reef, Australia: ABSTRACT

Although most marine ooids have concentric structure and aragonitic composition, radial-structural aragonite ooids occur in Lizard Island. Radial ooids are confined to the lagoonal sediment south of Lizard Island in water depths of 0-7 m (0-23 ft). Primary bed forms vary from minor current ripples to nondescript. Ooids comprise up to 18% of the subarkosic sands and are found in an environment protected from open-ocean energy by patch and fringing reefs. Ooids are dark gray and are frequently bored by endolithic algae. Compound and asymmetric forms are common. Individual aragonite crystals may range up to 12 µm in length. To assess the environment of formation, in-situ diurnal chemical measurements were made in the ooid and interstitial and ambient waters. Critical parameters examined in a 28-hr period were temperature, pH, PCO2, Cl ^pmil, ACa2+, and ACO32-. Cyclic diurnal changes occur in both water systems, with the ambient water experiencing the greatest changes. Measured extremes for the ambient water are day = 25.3°C, PCO2 of 10-5.08, and Alkc of 2.52 meq; night = 22.3°C, PCO2 of 10-4.98, and Alkc of 4.31 × 10-3 meq. The ACa2+ (2.6 × 10-3) and Cl ^pmil (19.24 ^pmil) are es entially time invariant. The PCO2 ranges from atmospheric saturation in the day to supersaturation during the night. Both ambient and pore waters are supersaturated with respect to aragonite (^ohmARAG-ambient=2.8 to 4.4; ^ohmARAG-porewater=3.1 to 4.1). Our findings suggest alkalinity consumption by carbonate precipitation occurs during the day and is greatest in the upper 10 cm (4 in.) of ooid sands. This physical/chemical environment differs from other monitored classic ooid localities and is diagnostic of marine radial-structured aragonite ooid growth. End_of_Article - Last_Page 511------------