Facing the huge gap between the growing CO2 emissions and net-zero emissions target to mitigate global warming, the long-term storage of excess CO2 becomes an intractable issue. Sequestering CO2 in the oceans as clathrate hydrates is a promising solution. Many unanswered questions still exist at the molecular level regarding how ions in seawater kinetically affect the formation of CO2 hydrates, particularly the dual effect: as the concentration rises, salt ions shift from being a promoter of hydrate formation to becoming an inhibitor. Herein, we report the homogeneous nucleation process of CO2 hydrates in saline solutions via molecular dynamics simulations. Consistent with experimental findings, our results show that nucleation is promoted within certain salt concentration ranges; however, the evidence suggests that ions do not act as nucleation sites. Multiple ion-induced variations in the aqueous phase are analyzed, including changes in the mobility, structure, and CO2 solubility. We find that the presence of ions strengthens the hydrophobic interactions among the dissolved CO2 molecules, which are associated with the salting-out phenomenon, accounting for the promoting effect of salts at low concentrations. However, as the salt concentration increases, this advantage is offset, leading to the inhibiting effect at high salt concentrations. We demonstrate that anions are inevitably involved in the construction of the solid hydrate phase. Their presence disrupts the native tetrahedral connectivity of water molecules and imparts negative charges to the solid phase, thereby attracting cations. In addition to advancing our understanding of the intricate interactions among water, guest, and additive molecules to germinate ordered solid structures, these findings can accelerate the development and utilization of sustainable hydrate-based applications.
Read full abstract