Clay Mineral Groups Research Articles

MXene-montmorillonite nanocomposites-based scaffold sensors for early pancreatic cancer diagnosis

Pancreatic cancer is increasingly prevalent and characterized by a high mortality rate. Due to the limitations of current diagnostic methods, early-stage detection remains elusive, contributing to persistently low survival rates among affected individuals. Nanomaterials have garnered significant attention in cancer research for their potential diagnostic applications. Among these, MXenes – a novel family of two-dimensional nanomaterials composed of transition metal carbides, nitrides, and carbonitrides – are of particular interest due to their unique properties. These include high electrical conductivity, hydrophilicity, thermal stability, large interlayer spacing, tunable structure, and high surface area. These characteristics make MXenes highly effective for detecting trace amounts of various analytes. In addition, their tunable structure enables precise manipulation of their properties, allowing for optimized sensing responses. Montmorillonite nanoclay (MMT), a member of the smectite group of natural clay minerals, is known for its ability to promote bone development and influence cell behavior. When combined with MXenes, MMT forms promising nanocomposites for early pancreatic cancer detection through sensing applications. The Ti3C2 MXene-MMT nanocomposites exhibit potential as scaffold sensors capable of distinguishing cancerous from non-cancerous samples by observing the distinctive patterns in resistance changes. In addition, MXenes possess excellent selectivity, allowing for the reliable identification of targeted analytes from a complex mixture of chemical and biological analytes. Due to the advanced sensing capabilities of MXene-MMT composite scaffold sensors, they hold great promise for early cancer diagnosis and tissue regeneration, providing a novel therapeutic approach to improving patient outcomes.

Research on the Biogas Production Mechanism of Mudstone in the Qaidam Basin under Different CO2 Pressures.

Mudstone, a class of sedimentary rocks rich in organic matter, possesses considerable potential for biogas production. Mudstones possess a rich biological origin, which is conducive to refining the mechanisms and enrichment patterns of biogenic gas reservoirs. This has significant theoretical and practical implications for guiding the exploration and development of Quaternary mudstone gas reservoirs. Furthermore, the Qaidam Basin is an excellent place for the geological storage of CO2 due to its rich petroleum reservoir conditions. Experimental research on biogas production under diverse CO2 pressure-mudstone-microorganism-water interactions is conducted to determine the biogas production mechanism of mudstone under different CO2 pressures during sequestration circumstances. According to the results: (1) under supercritical carbon dioxide conditions, there is a slight initial increase in biogas production, followed by a gradual decrease. The periods and peaks of gas production vary among the different reaction groups. As carbon dioxide pressure increases, the gas production cycle lengthens significantly, while the gas yield declines. (2) Siderite and secondary carbonate minerals have increased in the mudstone's mineral fraction both before and after biogas production, while clay mineral groups have decreased. Specifically, there was a notable drop in chlorite and kaolinite. (3) Microorganism species in the system were analyzed, and the results showed that there was a gap in each microorganism's ability to adapt to its surroundings, and the diversity and quantity of bacteria declined with increasing pressure. After carbon dioxide was fluxed, there was a considerable shift in the pattern of biogas generation, which consequently had a major impact on the alterations in mineral fractions.

Analysis of Mineral Types, Density, and Porosity in the Lam Teuba Formation Using Infrared Spectroscopy Method

The Lam Teuba Formation is one of the local fault areas of the Seulimuem segment located in the Grand Mosque sub-district of Aceh Besar regency. The Lam Teuba Formation has several types of rocks such as basaltic andesite lava, pyrolastic flows, pyroclastic falls, and sedimentary rocks, namely claystone, limestone sandstone, agglomerate, limestone. Rocks have physical characteristics, namely density and porosity which have different values in each rock. This difference can be caused by the minerals contained in the rock. The method used to calculate the density and porosity values used the Archimedes method, and the identification of mineral types using the infrared spectroscopy method. The results of data processing obtained the highest original density value at location 1 sample 1 with a value of 3.42 and the lowest value at location 5 sample 2. The highest dry density value was in location 1 of sample 1 with a value of 3.33 and the lowest value was in location 5 of sample 2. The highest saturation density value was in location 1 of sample 1 with a value of 3.43, the lowest value was in location 5 of sample 2 with a value of 2.07. The average porosity value was the highest with a value of 5.41 in the poor quality category in sample 4, while the lowest value was 4.62 in the very bad category in sample 1. The types of minerals found in the Lam Teuba formation are illite, montmorillonite, kaolinite minerals with a mixture of smectite which is a clay mineral group and siderite minerals which are carbonate mineral groups.

Comparative Assessment of Thermal Treatment for Mycotoxins Adsorption Potential of Indigenous Clay from Balochistan, Pakistan

The current study aimed to investigate the physical characteristics and mycotoxins (Aflatoxins B1 (AFB1) and Ochratoxin A (OTA) binding efficacy of indigenous clays before and after thermal treatment (calcination). The clay sample was collected from various mountainous areas of Balochistan, Pakistan. The samples were ground into a 360 mesh size and thermally treated initially at 200 °C and thereafter at 800 °C for 30 minutes with the help of a muffle furnace. XRD analysis revealed montmorillonite as the most commonly occurring group of clay minerals. The thermally treated clays showed that the binding potential was significantly (P <0.05) improved against mycotoxins. Enzyme-linked immunoassay (ELISA) determination showed significantly (P <0.05) lower residual concentrations of mycotoxins in thermally treated clays. The mycotoxin adsorption capacity (%) was found to be higher in the clay samples procured from Pishin (79.17% for AFB1 and 67.34% for OTA) and Bolan (62.0% for AFB1 and 50.17% for OTA). Calcination also caused a significant decrease in Cation Exchange Capacity (CEC) in some clay samples. Overall, the findings of the study showed that thermal treatment enhanced the in vitro binding capacity of clays against the studied mycotoxins. An increase in the mycotoxin binding capacity of the clays not only reduces the bioavailability of mycotoxins but also decreases their toxic effects. It is recommended that Balochistan clay have the potential to be used as an adsorbent for the removal of mycotoxins from the environment and animal feeds.

Clay minerals control silicon isotope variations of fine-grained river sediments: Implication for the trade-off between physical erosion and chemical weathering

Stable silicon (Si) isotopes in fluvial sediments can provide insights into understanding silicate weathering processes on the Earth's surface. However, a lack of comprehensive studies has hindered full understanding of the factors influencing Si isotope fractionation during continental weathering. In this study, through the analysis of Si isotopes in fine-grained sediments from 13 rivers surrounding the South China Sea, significant variation of Si isotopes in bulk detrital sediments (<63 μm) was observed, with δ30Si values ranging from −0.17‰ to −1.09‰. At basin scale, the δ30Si values are influenced by multiple controlling factors such as climatic conditions, lithology, and tectonic settings, which have a close relationship with the content of clay minerals. The characteristics of weathering types and intensities are ultimately reflected in the weathering products, specifically clay minerals. Compiling data across multiple grain sizes from major rivers globally, robust correlations based on clay mineral classification between δ30Si and Al/Si ratio have been observed, which are unaffected by regional and grain-size variations. As the dominant clay mineral group transitions from illite/chlorite to smectite and kaolinite, the degree of Si isotope fractionation increases progressively. This sequence indicates a shift from stronger physical erosion to more intensive chemical weathering, suggesting a transition in the weathering regime from weathering-limited to transport-limited. This study reveals the intrinsic link between Si isotopic compositions and clay mineral assemblages, providing implications for similar stable isotope research and offering a potential indicator for understanding continental weathering processes and their contributions to the global carbon cycle.

Swelling and delamination of inorganic homoionic montmorillonite clay in water-polar organic mixed solvents.

The smectite group of clay minerals (smectites) consists of negatively charged clay layers and interlayer exchangeable cations. They are spontaneously delaminated in water to form single clay layers when the interlayer cations are small alkaline cations such as Na+ or Li+. This phenomenon known as osmotic swelling has fundamental importance in constructing novel clay-based nanomaterials. However, osmotic swelling of smectites has not been systematically investigated in organic solvents although this phenomenon should be useful for developing novel clay-organic nanocomposites. We report herein that montmorillonite, a typical smectite, with monovalent and divalent inorganic interlayer cations shows osmotic swelling accompanied by delamination of clay layers in water-acetonitrile and water-2-propanol mixed solvents, although inorganic interlayer cations have been believed to be inappropriate for delamination of smectites in organic solvents. The delamination is confirmed by a combination of macroscopic sample appearances, XRD patterns, and SEM images. Montmorillonite with interlayer Na+ or Li+ ions shows osmotic swelling in pure water and the mixed solvents but not in pure organic solvents. Montmorillonite with alkaline earth dications in the interlayer spaces is swollen in water-organic mixed solvents but not in either pure water or organic solvents alone. Partial delamination in several systems can be clarified from SEM images even though the sample appearances and XRD patterns do not give firm evidence. Such non-uniform swelling behavior of montmorillonite is related to the disordered stacking of the aluminosilicate layers with different morphologies in the clay powders as observed by SEM.

Immobilizing lead using loess and nanoscale zerovalent iron (nZVI)-amended loess: Insights from macroscopic and microscopic tests

Lead (Pb) can accumulate in organisms causing damage to liver and kidney functions. Preventing Pb2+ migration to surrounding environments is considered of great necessity. This study explored the potential of applying the loess and nanoscale zerovalent iron-amended loess (nZVI-AL) to Pb immobilization. The static equilibrium adsorption analyses showed that the adsorption of Pb2+ by the loess and nZVI-AL was classed as homogeneous monolayer surface adsorption. The nZVI particles provided Pb2+ with more sites for their attachment and prevented their migration using Fe-O and Fe-O-H bonds. Their attachment encouraged the formation of cerussite precipitation, which not only caused the reduction in the diffraction peak of calcite mineral but shifted the peak of adsorption band from around 1430 cm−1 to a lower wavenumber. The unbonded electrons of the functional groups on the surface of quartz mineral coordinated with the empty orbit of Pb2+, leaving the diffraction peak at 3.3429 Å. Further, Ca2＋ distribution of the nZVI-AL sample was not as blurry as that of the loess sample because of the retardant of the depletion of calcite and quartz by the nZVI particles. Moreover, the hydroxyl groups bound via hydrogen bonds were formed by the nZVI amendment, displacing the peak of the adsorption band from 701 cm−1 to 698 cm−1. The hydroxyl groups of clay minerals coordinated with Pb2+ as well to form Pb(OH)+, corresponding to O-H stretching vibrations at 3616 cm−1 and 3430 cm−1 respectively. The nZVI-AL shows its potential in landfills as a bottom liner system.

Territory Suitability Assessment for Conducting Detailed Geological and Mineralogical Mapping Based on Statistical Methods of Remote Sensing Data Processing Landsat-8: A Case Study in the Southeastern Transbaikalia, Russia

The work considers the suitability of using multispectral satellite remote sensing data Landsat-8 for conducting regional geological and mineralogical mapping of the territory of south-eastern Transbaikalia (Russia) in conditions of medium- low-mountain relief and continental climate. The territory was chosen as the object of study due to its diverse metallogenic specialization (Au, U, Mo, Pb-Zn, Sn, W, Ta, Nb, Li, fluorite). Diversity in composition and age of ore-bearing massifs of intrusive, volcanogenic and sedimentary rocks are also of interest. Statistical processing algorithms to increase spectral information content of satellite data Landsat-8 were used; they include: principal component analysis (PCA); minimum noise fraction (MNF) and independent component analysis (ICA). Eigenvector matrices analysed on the basis of statistical processing results and two-dimensional correlation graphs were built to compare thematic layers with geological material classes: oxide/hydroxide group minerals containing transition iron ions (Fe3+ and Fe3+/Fe2+); a group of clay minerals containing A1–OH and Fe, Mg–OH; minerals containing Fe2+ and vegetation cover. Pseudo-coloured RGB composites representing the distribution and multiplication of geological materials classes was generated and interpreted. Integration of informative thematic layers with using fuzzy logic model was carried out to construct a prospectivity map. Received map was compared with geological information, and positive conclusions about territory suitability for further remote mapping research of hydrothermally altered zones and hypergenesis products in order to localize areas promising for identifying hydrothermal-metasomatic mineralization were made.

Trace metal fate in soil after application of digestate originating from the anaerobic digestion of non-source-separated organic fraction of municipal solid waste

Introduction: Digestate originating from anaerobic digestion of non-source-separated organic fraction of municipal solid waste (OFMSW) is produced abundantly worldwide and generally discarded in landfills. However, it can be a valuable resource for many bioeconomy strategies as land restoration, only if a consolidated understanding of the contaminants’ presence and behaviour in digestate-amended soil is achieved. This study aimed to investigate the fate of trace metals, namely Zn, Cu, Pb, and Cr found in the digestate, along the soil profile after digestate application on soil, and the influence that other contaminants as pharmaceutical compounds can have on their behaviour in the soil system.Methods: For that, a 90-day soil column experiment was conducted using a fine loamy sand soil topped with a layer of digestate-amended soil. Digestate-amended soil had a soil to digestate proportion of 14 to 1 (dry weight). Two experimental conditions were tested: soil amended with digestate, and soil amended with digestate spiked with the antidiabetic drug metformin. Soil samples were taken at 4 depths on days 1, 7, 21, 35 and 90, and total trace metals concentrations and fractionation were determined via atomic absorption spectroscopy.Results: Results showed that Zn, Cu, Pb ad Cr initially present in the digestate were transferred from the digestate-amended soil layer to the underlying soil layer over time, although in low amounts. Nevertheless, no transfer was detected to the deeper soil layers. Trace metals in soil were predominantly in immobile and less bioavailable forms associated with clay and silicate mineral groups, whereas in the digestate-amended soil they were in more bioavailable forms, which could be related to metals’ migration in the soil layers below. Results also show that the presence of metformin had no influence on trace metal behaviour, giving insight also on possible interactions with other potentially present contaminants as microplastics.Conclusion: The current study showed that OFMSW digestate can be a promising organic nutrient-rich matrix for land restoration even if it may contain high metals’ concentrations because low metal mobility along the soil profile can be expected.

Fabrication of Complex Three-Dimensional Structures of Mica through Digital Light Processing-Based Additive Manufacturing

Mica is a group of clay minerals that are frequently used to fabricate electrical and thermal insulators and as adsorbents for the treatment of cationic pollutants. However, conventional subtractive manufacturing has the drawback of poor three-dimensional (3D) shape control, which limits its application. In this study, we propose digital light processing (DLP)-based additive manufacturing (AM) as one of the most effective ways to address this drawback. Two major challenges for the ceramic DLP process are the production of a homogeneous and stable slurry with the required rheological properties and the maintenance of printing precision. The mica green body was fabricated using a 53 vol.% solid loading slurry through DLP, which exhibited good dimensional resolution under an exposure energy dose of 10 mJ/cm2. The precise, complex 3D structure was maintained without any defects after debinding and sintering at 1000 °C. The use of ceramic AM to overcome the shape-control limitations of mica demonstrated in this study offers great potential for expanding the applications of mica.

Atom Probe Tomography Analysis of Mica.

Laser-assisted atom probe tomography (APT) is a relatively new, powerful technique for sub-nanometric mineral and biomineral analysis. However, the laser-assisted APT analysis of highly anisotropic and chemically diverse minerals, such as phyllosilicates, may prove especially challenging due to the complex interaction between the crystal structure and the laser pulse upon applying a high electric field. Micas are a representative group of nonswelling clay minerals of relevance to a number of scientific and technological fields. In this study, a Mg-rich biotite was analyzed by APT to generate preliminary data on nonisotropic minerals and to investigate the effect of the crystallographic orientation on mica chemical composition and structure estimation. The difference in results obtained for specimens extracted from the (001) and (hk0) mica surfaces indicate the importance of both experimental parameters and the crystallography. Anisotropy of mica has a strong influence on the physicochemical properties of the mineral during field evaporation and the interpretation of APT data. The promising results obtained in the present study open the way to future innovative APT applications on mica and clay minerals and contribute to the general discussion on the challenges for the analysis of geomaterials by atom probe tomography.

Geological and Mineralogical Mapping Based on Statistical Methods of Remote Sensing Data Processing of Landsat-8: A Case Study in the Southeastern Transbaikalia, Russia

The work considers the suitability of using multispectral satellite remote sensing data Landsat-8 for conducting regional geological and mineralogical mapping of the territory of south-eastern Transbaikalia (Russia) based on statistical methods for processing remote sensing data in conditions of medium–low-mountain relief and continental climate. The territory was chosen as the object of study due to its diverse metallogenic specialization (Au, U, Mo, Pb-Zn, Sn, W, Ta, Nb, Li, fluorite). Diversity in composition and age of ore-bearing massifs of intrusive, volcanogenic, and sedimentary rocks are also of interest. The work describes the initial data and considers the procedure for their pre-processing, including radiometric and atmospheric correction. Statistical processing algorithms to increase spectral information content of satellite data Landsat-8 were used. They include: principal component analysis, minimum noise fraction, and independent component analysis. Eigenvector matrices analyzed on the basis of statistical processing results and two-dimensional correlation graphs were built to compare thematic layers with geological material classes: oxide/hydroxide group minerals containing transition iron ions (Fe3+ and Fe3+/Fe2+); a group of clay minerals containing A1-OH and Fe, Mg-OH; and minerals containing Fe2+ and vegetation cover. Pseudo-colored RGB composites representing the distribution and multiplication of geological material classes are generated and interpreted according to the results of statistical methods. Integration of informative thematic layers using a fuzzy logic model was carried out to construct a prediction scheme for detecting hydrothermal mineralization. The received schema was compared with geological information, and positive conclusions about territory suitability for further remote mapping research of hydrothermally altered zones and hypergenesis products in order to localize areas promising for identifying hydrothermal metasomatic mineralization were made.

Non‐exchangeable stable hydrogen isotope ratios in clay minerals and soil clay fractions: A method test

AbstractStable hydrogen isotope ratios (δ2H values) in structural hydroxyl groups of pedogenic clay minerals are inherited from the surrounding water at the time of their formation. Only non‐exchangeable H preserves the environmental forensic and paleoclimate information (δ2Hn value). To measure δ2Hn values in structural H of clay minerals and soil clay fractions, we adapted a steam equilibration method by accounting for high hygroscopicity. Our δ2Hn values for USGS57 biotite (−95.3 ± SD 0.9‰) and USGS58 muscovite (30.7 ± 1.4‰) differed slightly but significantly from the reported δ2H values (−91.5 ± 2.4‰ and −28.4 ± 1.6‰), because the minerals contained 1.1%–4.4% of exchangeable H. The low SD of replicate measurements (n = 3) confirmed a high precision. The clay separation method including destruction of Fe oxides, carbonates and soil organic matter, and dispersion did not significantly change the δ2Hn values of five different clay minerals. However, we were unable to remove all organic matter from the soil clay fractions resulting in an estimated bias of 1‰ in two samples and 15‰ in the carbon‐richest sample. Our results demonstrate that δ2Hn values of structural H of clay minerals and soil clay fractions can be reliably measured without interference from atmospheric water and the method used to separate the soil clay fraction.Highlights We tested steam equilibration to determine stable isotope ratios of structural H in clay. Gas‐tight capsule sealing in Ar atmosphere was necessary to avoid remoistening. Our steam equilibration method showed a high accuracy and precision. The clay separation method did not change stable isotope ratios of structural H in clay.

A comparative study on adsorption and catalytic degradation of tetracycline by five magnetic mineral functional materials prepared from steel pickling waste liquor

Palygorskite (Pal), bentonite (Bent), sepiolite (Sep), zeolite (Zeol), and kaolin (Kaol) were used with steel pickling waste liquor to synthesize magnetic palygorskite (Pal@Fe3O4), magnetic bentonite (Bent@Fe3O4), magnetic sepiolite (Sep@Fe3O4), magnetic zeolite (Zeol@Fe3O4), and magnetic kaolin (Kaol@Fe3O4), for adsorption and catalytic degradation of tetracycline (TC), respectively. Through the study of adsorption kinetics and adsorption isotherms, the maximum adsorption capacity of Pal@Fe3O4 to TC was 149.439mg/g, which was 1.239 times, 2.260 times, 3.161 times, and 3.448 times of Bent@Fe3O4, Zeol@Fe3O4, Kaol@Fe3O4, and Sep@Fe3O4, respectively. The kinetic study of tetracycline degradation demonstrated that the maximum reaction rate constant of Bent@Fe3O4/H2O2 system was K(obs) = 2.12 × 10-2min-1, which was close to that of Pal@Fe3O4/H2O2, Kaol@Fe3O4/H2O2 system, and was 2.000 times, 2.356 times, 2.650 times, and 4.711 times of Fe3O4/H2O2, Zeol@Fe3O4/H2O2, Sep@Fe3O4/H2O2, and H2O2 system, respectively. The results showed that Pal@Fe3O4 and Bent@Fe3O4 were more advantageous in the treatment of wastewater containing tetracycline, and efficient reuse of exhausted magnetic minerals and deep mineralization of organic pollutants were achieved by constructing an advanced oxidation system. The BET, VSM, SEM, XPS, XRD, and FTIR were used to characterize the five clay minerals before and after magnetic modification. It was speculated that the surface structure - OH groups of clay minerals might be significant factors influencing the adsorption performance of magnetic minerals on TC, and reduction ability of clay minerals to Fe3+ importantly affected the catalytic performance of magnetic minerals. The specific surface area and morphological structure of clay minerals both affected the adsorption and catalytic degradation of TC by the five magnetic minerals.

Three‐dimensional complex construct fabrication of illite by digital light processing‐based additive manufacturing technology

AbstractIllite is a group of clay minerals that are expected to be widely used in catalyst fabrication, radioactive element adsorption, and so forth, due to its excellent adsorption properties. However, the shape control limitation of the illite product should be overcome to maximize its utilization and properties. We herein propose additive manufacturing (AM) as one of the best solutions to solve this structural drawback. Digital light processing (DLP) technology with the film‐type of the material supplying system was adapted instead of the general vat‐type DLP system to increase illite printability. The photo‐curability and printability of illite‐contained photocurable suspension were optimized. The color effect due to different ferric oxide content in yellow‐ and white‐illite which influence the photopolymerization process also adjusted thoroughly. White illite showed better photo‐curability and could be increased solid loading than yellow illite. The defect‐free illite products with three‐dimensional complex structures, which cannot be produced by typical ceramic processes, were obtained by DLP technology for both yellow‐ and white‐illite after sintering at 1100°C. The overcoming of shape control limitation of illites by ceramic AM proved in this study has excellent potential for expanding illite utilities in various applications.

Thermal stability and water-binding ability of nontronite concluded from powder X-ray diffraction, thermogravimetry, and dielectric measurements

The effect of annealing temperature on the ability to rebind water by nontronite was investigated. Nontronite is a type of layered mineral that belongs to the smectite group of clay minerals. It was found that annealing the mineral at temperatures lower than 350 °C causes loss of the interlayer water. However, after moisten water is reabsorbed to a large degree. When the mineral was annealed at approx. 640 °C, it loses definitely the ability to bind water.

An in vitro assessment of the toxicity of two-dimensional synthetic and natural layered silicates

Natural Layered Silicates (NLS) and Synthetic Layered Silicates (SLS) are a diverse group of clay minerals that have attracted great interest in various branches of industry. However, despite growing demand for this class of material, their impact on human health has not been fully investigated. Therefore, the aim of this study was to evaluate and compare the potential toxic effects of a wide range of commercially available SLS and NLS of varying physicochemical properties (lithium (Li) or fluoride (F) content and size). Mouse BALB/c monocyte macrophage (J774A.1) and human monocyte-derived macrophages (MDMs) were chosen as in vitro models of alveolar macrophages.Montmorillonite, hectorite, Medium (med) F/High Li and Low F/Med Li particles, were cytotoxic to cells and induced potent pro-inflammatory responses. The remaining particles (No F/Very (V)Low Li, No F/Med Li, No F/Low Li, High F/Med Li and High F/Med Li washed) were non- to relatively low- cytotoxic and inflammogenic, in both type of cells. In an acellular condition none of the tested samples increased reactive oxygen species (ROS), while ROS generation was observed following exposure to sublethal concentrations of Med F/High Li, Low F/Med Li, montmorillonite and hectorite samples, in J774A.1 cells.Based on the results obtained in this study the toxic potency of tested samples was not associated with lithium or fluoride content, but appeared to be dependent on particle size, with the platelets of larger dimension and lower surface area being more potent than the smaller platelet particles with higher surface area. In addition, the increased bioactivity of Med F/High Li and Low F/Med Li was associated with endotoxin contamination. Obtained results demonstrated that layered silicate materials have different toxicological profiles and suggest that toxicological properties of a specific layered silicate should be investigated on an individual basis.

The use of particle size distribution integrated with consistency limits for experimentally simulating fine-grained sedimentary units

The current study hypothesizes that reproducing sediment units that might belong to areas difficult to reach, sample, and attest is experimentally possible. The research aims to employ available sediment samples named source soils that can easily approach and sample to mix, simulate, and produce the (non-available) sedimentary units named Target Sediment Units (TSU). The particle size distribution (PSD) percentages are essentially used in the mixture procedure to construct the non-available (target) units (TSU). Several sedimentary units were targeted, designed, and simulated; They include marsh, bay mud, and natural levee sediment units selected from the eastern Basrah side at the lower Mesopotamian plain, southern Iraq. The matching between particle size distribution (PSD) curves of simulated sediment units (SSU) and target sediment unit (TSU) was verified by applying a developed slope proximity ratio. For the three tested sediment units (marsh, buy mud, and natural levee), the ratios of slope proximity were 1.0, 0.93, and 0.99, respectively, which are well matched. For the mineralogy, the consistency limits were used as a proxy. The Casagrande plasticity chart was modified to reveal two empirical functions linking the plasticity indices to the clay mineral groups. The two predictions are reliable means to proxy the mineralogy of the fine-grained sediments. Reconstructing procedure allows the non-available sediment samples to be practically presented and it better characterizes the sediment for forensic geoscience applications; for instance, engineering geology and sedimentology applications concerning with studies of the physical and mechanical behaviors of sediments and the depositional conditions interpretations, respectively.

REEVALUATION OF KAOLINITE OCCURRENCE IN SOME TORRIFLUVENTS IRAQI SOIL

Clay fraction of Torrifluvents Iraqi soils contained different clay mineral groups. Usually, samples with limited number of clay minerals, can be defined mainly by x-ray diffraction analysis. Whereas poly-mineralized soil needs additional techniques to clarify its mineral composition accurately. Kaolinite which is characterized by reflection peaks at 7.2 Aº and (3.55-3.57 Aº), are normally overlapped with those of chlorite peaks. This work was carried out to reevaluate the occurrence of kaolinite in some Iraqi soils with the presence of chlorites. Clay fractions from four Torrifluvents Iraqi soils were used in this study. X-ray diffraction analysis with different heat treatments is referred to the presence of kaolinite and soil chlorite. Intercalation with dimethylsulfoxide, after saturation with Li (Li-DMSO) showed the presence of a peak at 11.3 Aº, which confirmed the presence of trace amount of kaolinite. However, the continuous occurrence of the peaks at 7.2 and 14.4 Aº are referred to the presence of chlorites. Reduction the intensity of 7.2 Aº peaks by heating at temperature below 500o C confirmed the presence of soil chlorite which overlap with kaolinite. There was no difference among the four soils with regard to the presence of soil chlorite and kaolinite.

Mineralogical and physico-chemical characterization of gypsiferous semi-arid soils in the north of Urmia, Iran

Gypsiferous soils contain sufficient gypsum to influence soil physico-chemical, mineralogical, mechanical properties and geotechnical conditions and as a consequence, affect plant growth and crop production. So physico-chemical and mineralogical properties of 6 soil profiles located on the gypsiferous parent material with semi-arid climate in north of Urmia, West Azerbaijan province, Iran, were investigated. Based on standard methods, morphological, physico-chemical and mineralogical properties of these soils were determined. Soils with higher gypsum content had lighter color, lighter texture, lower values of organic carbon and cation exchange capacity and higher values of electrical conductivity. These parameters were reversely changed with decreasing gypsum content of soils. Semi-quantitative analysis of clay minerals indicated the presence of smectite, illite, chlorite, kaolinite and palygorskite were as major clay minerals with decreasing order from smectite to palygorskite. The origin of illite, chlorite and kaolinite were related to the inheritance from parent material. Smectite group of clay minerals has been resulted from three origins of inheritance from parent material, transformation of illite and palygorskite and neoformation, but the transformation and neoformation are the main pathways for its formation. Palygorskite has pedogenic origin and has been formed via neoformation. The comparison of clay mineralogy of soils with different gypsum values revealed the presence of higher smectites in soils with higher gypsum. Palygorskite was identified just in soils with higher gypsum. In soils with lower values of gypsum, illite and chlorite were the predominant clay minerals and palygorskite did not identified.