Green Hydrothermal Synthesis Research Articles

Green hydrothermal synthesis of gallic acid carbon dots: characterization and cytotoxic effects on colorectal cancer cell line

Colorectal cancer (CRC) remains a leading cause of cancer-related deaths worldwide, necessitating the development of novel therapeutic approaches. Carbon dots (CDs) have emerged as promising nanoparticles for biomedical applications due to their unique properties. Gallic acid (GA), an anticancer agent, is effective against various tumor types. This study explores the potential of gallic acid-derived carbon dots (GA-CDs) as an innovative anticancer agent against HCT-116 CRC cells, focusing on apoptosis signaling pathways. GA-CDs were synthesized using a one-pot hydrothermal method. Characterization was conducted using transmission electron microscopy (TEM), Fourier transform infrared (FT-IR) spectroscopy, and ultraviolet-visible (UV-vis) absorption spectroscopy. The cytotoxicity of GA and GA-CDs on HCT-116 cells was evaluated using the MTT assay at various concentrations over 24 and 48 h. Cellular uptake was assessed via fluorescence microscopy, and apoptosis was analyzed using acridine orange/propidium iodide (AO/PI) staining. Total RNA extraction followed by complementary DNA (cDNA) synthesis via reverse transcription-PCR was performed, and real time-PCR (Q-PCR) was conducted to examine the expression of apoptosis-related genes includingCaspase-3,Bax, andBcl-2. Characterization confirmed the successful synthesis of spherical GA-CDs. GA-CDs exhibited dose- and time-dependent cytotoxicity, with IC50 values of 88.55 μg ml-1for GA-CDs and 192.2 μg ml-1for GA after 24 h. Fluorescence microscopy confirmed the efficient uptake of GA-CDs by HCT-116 cells. AO/PI staining showed a significant increase in apoptotic cell numbers after treatment with GA-CDs. Q-PCR analysis revealed overexpression ofCaspase-3 andBaxgenes in GA-CD-treated cells, though no significant changes were observed in the expression ofBcl-2 or theBax/Bcl-2 ratio. GA-CDs demonstrated potent anticancer properties by inducing apoptosis and reducing cell viability in HCT-116 cells. These findings suggest the potential of GA-CDs as a novel therapeutic agent for CRC treatment, warranting further investigation into their mechanism of action andin vivoefficacy.

Non-Stoichiometric Cobalt Ferrite Nanoparticles by Green Hydrothermal Synthesis and their Potential for Hyperthermia Applications

Non-Stoichiometric Cobalt Ferrite Nanoparticles by Green Hydrothermal Synthesis and their Potential for Hyperthermia Applications

Salvia officinalis leaf extract-stabilized NiO NPs, ZnO NPs, and NiO@ZnO nanocomposite: Green hydrothermal synthesis, characterization and supercapacitor application

AbstractIn this study, NiO nanoparticles (NiO NPs) and NiO@ZnO nanocomposite were synthesized for the first time using a Salvia officinalis (S. officinalis) extract-assisted hydrothermal process. The S. officinalis leaf extract served as a natural reducing and capping agent. The synthesized NiO NPs, ZnO NPs, and NiO@ZnO nanocomposite were thoroughly characterized using various techniques, including Fourier-transform infrared spectroscopy (FT-IR), ultraviolet–visible spectroscopy (UV–Vis), powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), energy-dispersive spectrometry (EDS) mapping, vibrating sample magnetometer (VSM), and cyclic voltammetry (CV) analysis. The direct and indirect band gap energies of NiO NPs, ZnO NPs, and NiO@ZnO were found to be 3.00, 2.28, and 2.71 eV, and 2.63, 1.91, and 2.23 eV, respectively. The crystallite sizes were analyzed using PXRD spectra through Scherrer and Williamson–Hall (W–H) methods. TEM analysis revealed that the average particle sizes of NiO NPs, ZnO NPs, and NiO@ZnO were 16.0, 207.5, and 31.0 nm, respectively. The magnetic properties of all nanomaterials were assessed via the VSM technique. Specific capacitance (Cs) values, determined from CV voltammograms, were 196.8, 632.4, and 785 Fg-1 at a scan rate of 25 mVs-1 for NiO NPs, ZnO NPs, and NiO@ZnO, respectively. These findings suggest that the green-synthesized NiO@ZnO nanocomposite holds significant potential as a high-performance electrode material for supercapacitor applications.

Facile and green hydrothermal synthesis of MgAl/NiAl/ZnAl layered double hydroxide nanosheets: a physiochemical comparison

Abstract Layered double hydroxide (LDH) exhibits a remarkable trait referred to as the ‘memory effect,’ demonstrating its capacity to reconstruct its layered structure from calcined oxides through hydrothermal treatment. Its uniqueness has garnered significant interest from researchers in both industrial and academic domains. Various methods have been utilized to synthesize LDH but most LDH studies still utilize alkali precipitants which might taint the final LDH product. Thus, in this study, layered double hydroxides involving MgAl/NiAl/ZnAl were synthesized via an alkali-free hydrothermal approach in which the formed precipitates of LDH were thermally destroyed via calcination at 450 °C before undergoing a rehydration treatment at 110 °C for 24 h to restore its original structure. Particularly, the physiochemical properties of MgAl/NiAl/ZnAl LDH have been undertaken by multiple techniques such as Powder X-ray Diffraction (PXRD), thermogravimetric analysis (TGA), Brunauer-Emmett-Teller (BET), Field Emission Scanning Electron Microscope (FESEM) and Fourier-transform infrared spectroscopy (FTIR). The resultant products exhibited exceptional crystallinity, accompanied by notably larger crystallite sizes and crystallinity index, particularly post-hydrothermal treatment. Among the fresh and calcined products studied, those subjected to HTM (4:1) treatment demonstrated the highest specific surface area and crystallinity surpassing both the fresh and calcined samples. In essence, this research showcased how utilizing the hydrothermal approach resulted in the most substantial increase in crystallite size and specific surface area.

Development of a new nanosensor for the determination of food coloring Sunset Yellow in powder drinks using L-cysteine coated copper nanoclusters.

Sunset Yellow (SY), which is an artificial azo dye, is preferable for its high stability and low cost. The determination of SY in foods is extremely important for human health because excessive consumption of SY has harmful effects, such as hyperactivity disorder and cancer. In this method, L-cysteine coated copper nanoclusters (CuNCs) were used as a fluorescence probe. L-cysteine has been used as both a reducing and stabilizing agent. One-step green hydrothermal synthesis of CuNCs was made. L-cysteine-coated CuNCs have been characterized using several of methods. CuNCs quenching mechanism is static and inner filter effect (IFE). The linear range is 0.65-14 μg.ml-1 at optimum conditions. LOD and LOQ values were calculated as 0.1 and 0.35 μg.ml-1, respectively. The proposed method was used for the determination of SY in different type of powder drinks. The developed nanosensor is environmentally friendly, easy, fast, reproducible, and low cost.

Commercial Wheat and Oat Flour Derived Fluorescent Carbon Quantum Dots through Sustainable Hydrothermal Synthesis and Their Biological Activities

AbstractIn this study, we utilized processed edible commercial wheat and oat flours to synthesize highly fluorescent carbon dots using green hydrothermal synthesis. The as‐synthesized carbon quantum dots (CQDs) were characterized using UV‐vis spectrophotometry, photoluminescence spectrophotometry, high‐resolution transmission electron microscopy, and Fourier transform infrared spectroscopy. The synthesized wheat‐CQDs (W‐CQDs) and oat‐CQDs (O‐CQDs) had monodispersed spherical shapes with average sizes of 3–8 and 5–10 nm, respectively, and exhibited strong fluorescence intensity and excitation‐dependent photoluminescence. The W‐CQDs and O‐CQDs were highly dispersed in aqueous solutions and exhibited bright green and blue fluorescence, respectively, under UV light (λex=380 and 370 nm). Both CQDs contained abundant functional groups, including amino, hydroxyl, and carboxyl groups, which may play a major role in biological applications. The W‐CQDs and O‐CQDs showed good free‐radical scavenging capacity in the 2,2‐diphenylpicrylhydrazyl (DPPH) and H2O2 assays. The anti‐inflammatory activities of W‐CQDs and O‐CQDs were more effective than that of the standard, with EC50 values of 1.8 and 1.3 mg/mL, respectively, in the protein denaturation assay. Additionally, the CQDs exhibited low cytotoxicity toward NIH3T3 fibroblast and human HeLa cervical cancer cells when treated with a 5‐mg/mL concentration. Therefore, green‐synthesized W‐CQDs and O‐CQDs are easily available, less cytotoxic, and applicable to therapeutic and cell nanocarrier purposes.

Solanum tuberosum tuber-driven starch-mediated green-hydrothermal synthesis of cerium oxide nanoparticles for efficient photocatalysis and antimicrobial activities

In this study, we are reporting for the first time the utilization of Solanum tuberosum tuber-driven, starch-mediated, green-hydrothermally synthesized cerium oxide nanoparticles (G-CeO2 NPs) for the antibacterial activity and photodegradation of cationic (methylene blue, MB) and anionic (methyl orange, MO) dyes separately and in combination, aimed at environmental remediation. The XRD analysis confirms the fluorite structure of G-CeO2 NPs, displaying an average crystallite size of 9.6 nm. Further, XPS confirms the existence of 24% of Ce3+ oxidation states within G-CeO2 NPs. Morphological studies through FE-SEM and TEM reveal that starch-driven OH− ion production leads to a high percentage of active crystal facets, favoring the formation of Ce3+-rich CeO2 NPs. Photocatalytic experiments conducted under UV-A illumination demonstrate the superior degradation performance of G-CeO2 NPs, with MB degradation reaching 93.4% and MO degradation at 77.2% within 90 min. This outstanding catalytic activity is attributed to the mesoporous structure (pore diameter of 5.63 nm) with a narrow band gap, a large surface area (103.38 m2g-1), and reduced charge recombination, as validated by BET, UV–visible, and electrochemical investigations. The identification of photogenerated intermediates is achieved through LCMS, while the mineralization is monitored via total organic carbon analysis. Moreover, the scavenging experiments point towards the involvement of reactive oxygen species in organic oxidation, demonstrating efficiency over five consecutive trials. Additionally, G-CeO2 NPs exhibit potent antibacterial activity against both gram-positive and gram-negative bacteria. This study presents an innovative, and efficient approach to environmental remediation, shedding light on the potential of G-CeO2 NPs in addressing environmental pollution challenges.

Powerful drying and doping strategies for enhancing the thermoelectric performance of tellurium nanostructures prepared via green hydrothermal synthesis

An effective freeze-drying and solution-based In doping approach was developed to enhance the thermoelectric properties of Te nanostructures via green hydrothermal synthesis.

Green hydrothermal synthesis of multifunctional carbon dots from cassava pulps for metal sensing, antioxidant, and mercury detoxification in plants

Carbon dots (CDs) have been attracted to nanocarbon materials for metal ion sensing, biological activity, and plant phytotoxicity due to their excellent photophysical properties, such as low cytotoxicity, high quantum yield, tunable fluorescence emission, and biocompatibility. Cassava pulp, which consists mainly of starch, has been identified as a low-cost biomass waste from the cassava starch industry. Therefore, this research developed CDs and nitrogen-doped CDs (NCDs) from cassava pulp using a one-step hydrothermal process in deionized water at 200 °C. The effects of the synthesis conditions, including reaction time (6–24 h) and the nitrogen doping derivatives, were also investigated. CDs and ethylenediamine doped-NCDs exhibited tunable fluorescence emission, strong quantum yield, high photostability, and tolerance to photobleaching. Furthermore, the potential applications of CDs-12 h were demonstrated such as fluorescent sensors for metal ion sensing, antioxidant activity, and mercury detoxification in plants. Fluorescence quenching of the CDs-12 h via both static and dynamic quenching mechanisms was observed in the presence of several metal ions such as Hg2+, Cu2+, and Fe3+ with the detection limit in micromolar levels and further applied to real water samples with good recovery and acceptable relative standard derivation. The paper test strip coated with CDs-12 h could also detect these metal ions under UV light. CDs and NCDs-EDA also showed potential DPPH radical scavenging activity and alleviated mercury toxicity in the Chinese cabbage seedlings with the incubation of CDs-12 h and NCDs-EDA-12 h (30 mg/L).

Rapid hydrothermal green synthesis of core-shell-shaped NiCo2O4@MoS2/RGO ternary composites for high-performance electrode materials

RGO-based composites possess great potential as materials for supercapacitors owing to their remarkable properties such as high specific surface area and electrical conductivity. Herein, this work presents an investigation on ternary composite electrode materials composed of RGO, NiCo2O4, and MoS2. The chemical insertion method was employed to overcome the issue of RGO layer repacking. By means of a rapid green hydrothermal synthesis approach, conductive MoS2/RGO substrates were successfully fabricated, and subsequently, NiCo2O4@MoS2/RGO core–shell-shaped composites were prepared using the MoS2/RGO substrates. The ternary NiCo2O4@MoS2/RGO composites were composed of uniformly distributed conductive MoS2/RGO substrates embedded with NiCo2O4 core microspheres. Remarkably, the NiCo2O4@MoS2/RGO composites, used as electrode materials in supercapacitors, exhibited an exceptional specific capacitance of 946 F g-1 at 1 A g-1, improved rate capacity, and demonstrated outstanding electrochemical stability while maintaining 87.3 % retention after 5000 consecutive charge–discharge cycles. The exceptional integrated performance of these composites renders them promising electrode materials for electrochemical supercapacitors.

Green synthesis of elephant manure-derived carbon dots and multifunctional applications: Metal sensing, antioxidant, and rice plant promotion

Carbon dots, the carbon nanomaterials, have been greatly developed for several applications including fluorescent sensors for metal ion detection, antioxidant activity, and plant growth promotion due to their excellent photophysical properties, non-toxicity, and high quantum yield. Therefore, this research focused on the synthesis of multifunctional carbon dots from elephant manure via green hydrothermal synthesis owing to its chemical composition of cellulose, hemicellulose, and lignin. The as-synthesized carbon dots exhibited blue fluorescence emission under UV light and the excitation wavelength-dependent fluorescence enhancement. Carbon dots could be further used as a “turn-off” fluorescence sensor for Hg2+ detection as a part of environmental monitoring. Furthermore, the as-synthesized carbon dots containing high phenolic content showed the antioxidant activity and promoted rice growth with an increase in the characteristic aroma compound (2-acetyl-1-pyrroline), confirmed by GC–MS analysis.

Hydrothermal Synthesis of Highly Crystalline Zwitterionic Vinylene-Linked Covalent Organic Frameworks with Exceptional Photocatalytic Properties.

Ionic covalent organic frameworks (COFs) featuring both crystallinity and ionic characteristics have attracted tremendous attention in recent years. Compared with single anion- or cation-containing ionic COFs, zwitterionic COFs possess unique functionalities beyond single ionic COFs such as tunable charge density and superhydrophilic and highly ion-conductive characteristics, endowing them with huge potential in various applications. However, it remains a considerable challenge to directly synthesize robust, highly crystalline zwitterionic COFs from the original building blocks. Herein, we report a green hydrothermal synthesis strategy to prepare highly crystalline zwitterionic vinylene-linked COFs (ZVCOFs) from the predesigned zwitterionic building block by utilizing 4-dimethylaminopyridine (DMAP) as the high-efficiency catalyst for the first time. Detailed theoretical calculations and experiments revealed that both the high catalytic activity of DMAP and the unique role of water contributed to the formation of highly crystalline ZVCOFs. It was found that the participation of water could not only remarkably reduce the activation energy barrier and thus enhance the reaction reversibility but also enable the hydration of zwitterionic sites and facilitate ordered layered arrangement, which are favorable for the ZVCOF crystallization. Benefiting from the highly π-conjugated structure and hydrophilic characteristic, the obtained ZVCOFs achieved an ultrahigh sacrificial photocatalytic hydrogen evolution rate of 2052 μmol h-1 under visible light irradiation with an apparent quantum yield up to 47.1% at 420 nm, superior to nearly all COF-based photocatalysts ever reported. Moreover, the ZVCOFs could be deposited on a support as a photocatalytic film device, which demonstrated a remarkable photocatalytic performance of 402.1 mmol h-1 m-2 for hydrogen evolution.

3D Covalent Polyoxovanadate‐Organic Framework as an Anode for High‐Performance Lithium‐Ion Batteries

AbstractPolyoxometalates (POMs), as a unique class well‐defined metal‐oxo clusters with excellent multielectron redox properties, have attracted extensive attention in the field of energy storage and conversion, but it is still challenging to achieve their highly uniform and stable monodispersed. In this study, for the first time, polyoxovanadate (POV) is used, (NH4)2[VIV3VV3O10{NH2C(CH2O)3}3] (tris‐V6O19), as nodes and successfully obtain a 3D covalent polyoxovanadate‐organic framework through a green hydrothermal synthesis method, termed POF‐1. Total scattering atomic pair distribution function analysis confirms that POF‐1 has a noninterpenetrated diamond‐like framework, fully exposing the monodispersed tris‐V6O19, effectively utilizing the active components of VIV/VV and enhancing surface mass transfer. Notably, POF‐1 demonstrates exceptional performance in lithium‐ion batteries, achieving a high reversible capacity of 887.4 mAh g−1 at 0.1 A g−1 and retaining over 92% capacity at 1 C during 1000 cycles. Electrochemistry mechanism and density functional theory calculations reveal that V centers in tris‐V6O19 and carbonyls (C═O) in BDOEB linkers are the main active sites, with each POF‐1 fragment capable of storing up to 14 Li+. This study opens a new pathway for the efficient and green synthesis of new 3D well‐defined POM‐organic frameworks, and shows great application prospect in the field of energy storage.

Layered Magnesium Phosphate as an Environmentally Friendly Solid Lubrication Additive: Morphology Control and Tribological Properties

To develop a new type of environmentally friendly solid lubricant and expand the high-value utilization of salt lake resources, we prepared a layered magnesium phosphate (MgHPO4·1.2H2O) eco-friendly lubricant using an improved green hydrothermal synthesis route in which particle size and morphology were controlled. The tribological properties of the layered magnesium phosphate samples as additives in PAO8 calcium-based grease were evaluated using an Optimol SRV-V oscillating reciprocating tester (hereafter referred to as SRV tester). Products exhibited excellent friction behavior when added to grease. When added at 3.0 wt %, the tribological properties of the grease were improved significantly; the highest operating load was raised from 400 to 600 N, the wear volume was decreased from 44.98 to 7.50 (10–4 mm3), and friction curves became more stable and smooth. A possible lubricating mechanism was proposed. Macro to micro analysis of rubbing surfaces showed that the MgP materials had a protective effect on the PAO8 calcium-based grease matrix, and lubricating films were clearly formed on the friction pair surface.

Low-oxidation-state Ru sites stabilized in carbon-doped RuO2 with low-temperature CO2 activation to yield methane

The generation of methane fuel using surplus renewable energy with CO2 as the carbon source enables both the decarbonization and substitution of fossil fuel feedstocks. However, high temperatures are usually required for the efficient activation of CO2. Here we present a solid catalyst synthesized using a mild, green hydrothermal synthesis that involves interstitial carbon doped into ruthenium oxide, which enables the stabilization of Ru cations in a low oxidation state and a ruthenium oxycarbonate phase to form. The catalyst shows an activity and selectivity for the conversion of CO2 into methane at lower temperatures than those of conventional catalysts, with an excellent long-term stability. Furthermore, this catalyst is able to operate under intermittent power supply conditions, which couples very well with electricity production systems based on renewable energies. The structure of the catalyst and the nature of the ruthenium species were acutely characterized by combining advanced imaging and spectroscopic tools at the macro and atomic scales, which highlighted the low-oxidation-state Ru sites (Run+, 0 < n < 4) as responsible for the high catalytic activity. This catalyst suggests alternative perspectives for materials design using interstitial dopants.

Green hydrothermal synthesis of carbon dot-silver nanocomposite from Chondrococcus hornemanni (marine algae): an application of mosquitocidal, anti-bacterial, and anti-cancer (MDA-MB-231 cells)

Green hydrothermal synthesis of carbon dot-silver nanocomposite from Chondrococcus hornemanni (marine algae): an application of mosquitocidal, anti-bacterial, and anti-cancer (MDA-MB-231 cells)

Cobalt‐Nickel Ultrathin Hexagonal Nanosheets for High‐performance Asymmetric Supercapacitors

AbstractIn this work, uniform ultrathin hexagonal nanosheets of Co−Ni bimetallic hydroxides are synthesized using a simple green hydrothermal synthesis method. By tuning a Co/Ni mole ratio of 1 : 2, a special nanosheet structure of Co0.32Ni0.68(OH)2 was obtained with high interlayer spacing and large pore size. This nanosheet exhibits an enhanced specific capacity as high as 1021.96 C/g at 0.5 A/g, 12 times higher than Co(OH)2 (83.23 C/g). The high electrochemical performance is attributed to the interfacial interaction between Co2+ and Ni2+, as well as its special nanosheet structure. The advantages of the composition and structure are further confirmed by density functional theory (DFT) calculations. Besides, the energy storage process was visually observed by in situ Fourier transform infrared (FTIR) spectroscopy. Furthermore, an asymmetric supercapacitor (ASC) is assembled by Co0.32Ni0.68(OH)2 and activated carbon electrodes. The ASC delivers a high energy density of 54.97 W h/kg at a power density of 1.68 kW/kg and maintains 33.52 W h/kg at 32.66 kW/kg. These results highlight the promising applications of ultrathin Co0.32Ni0.68(OH)2 nanosheets as a high‐performance electrode material in supercapacitors.

A facile one-step green hydrothermal synthesis of paramagnetic Fe3O4 nanoparticles with highly efficient dye removal

BackgroundThe aim of this study was the characterization of hydrothermal green synthesized Fe3O4 nanoparticles, as an attractive metal oxide with paramagnetic properties, mediated with Myrtus communis (myrtle) extract. MethodThe effect of myrtle extract and iron sulfate concentration were assessed on the properties of synthesized nanoparticles. Also, the nanoparticles were synthesized without extract to evaluate the extract effect on the reaction. Significant findingsThe obtained results of X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and energy dispersive X-ray (EDX) were in good agreement with each other. The spherical, cubic, and polygonal shapes were created in the chemical method and monodispersed spheres were only observed in green synthesis at all precursor concentrations. The maximum saturation magnetization (Ms) values were obtained about 41 emu.g−1 and 91 emu.g−1 for green and chemically synthesized Fe3O4 nanoparticles, respectively. In addition, green synthesized Fe3O4 nanoparticles indicated high removal capacity for cationic methylene blue (MB), as well as anionic Congo red (CR) dyes compared with chemically synthesized Fe3O4 nanoparticles. The maximum of adsorbed dye per unit mass of adsorbent was 18 mg.g−1 for both dyes. The excellent adsorption capacity, paramagnetic properties, and uniform shape make the green Fe3O4 nanoparticles as an attractive adsorbent.

Green hydrothermal synthesis of Ga doping derived 3D ZnO nanosatellites for high sensitive gas sensors

A green hydrothermal synthesis methodology is employed for the synthesis of Ga3+ doped ZnO 3D nanosatellite structures. XRD technique exposed the hexagonal wurtzite type crystal structure of the 3D Ga3+ doped ZnO nanostructures. Ga3+ induced 3D morphology evolution in accordance to Ga doping concentration is realized via. the FESEM images. The FESEM images indicated one sided capped rod like structures (50–250 nm) in pristine ZnO, whereas 3D satellite kind of morphology (>500 nm) was observed in 5% Ga3+ doped ZnO structures. TEM images revealed physical specifications of 3D nanosatellite structures exposing the central rod of 500 nm length & 250 nm in width and the branch rods grown vertical to the central rod of length 300 nm and width of 50 nm. Further, optical absorbance and photoluminescence spectra confirmed the electron rich state of ZnO with Ga3+ doping. The gas sensing performance has shown selectivity toward CO gas at a working temperature of 250 ⁰C. High CO sensing was recorded for 5% Ga3+ doped ZnO 3D nanosatellites with attractive sensing characteristics such as good response, fast response time & fast recovery time.

In&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;3&lt;/sub&gt;/MoS&lt;sub&gt;2&lt;/sub&gt;/Reduced Graphene Oxide Nanostructure as Composite Electrodes for Supercapacitors

In this study, a novel reduced graphene oxide, indium (III) oxide, and molybdenum disulfide (rGO/In2O3/MoS2) ternary composite for supercapacitor electrode application was developed via green hydrothermal synthesis. The topography, surface morphology, crystalline structure, phase identification and molecular structure of the composites were examined by applying Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDX), Transmission Electron Microscopy (TEM), X-ray Diffraction Spectroscopy (XRD), X-Ray Photoelectron Spectroscopy (XPS), and Raman Spectroscopy. SEM and TEM reveal the uniform dispersion of In2O3 nanoparticles on the rGO and MoS2 sheets. EDX, XRD, and XPS analysis confirm the coexistences of rGO, In2O3, and MoS2, and hence the composite formation. The electrochemical performances of rGO/In2O3/MoS2 ternary composite were evaluated by cyclic voltammetry (CV) in two-electrode configuration in 1 M sodium sulfite (Na2SO3) aqueous electrolyte. The electrochemical results show that the rGO/In2O3/MoS2 composite electrodes possess improved specific capacitance of 77 F/g at a scan rate of 25 mV/s, a modest 29% enhancement over pure In2O3 and In2O3/MoS2 binary composite.