Gravity Cores Research Articles

Evaluation of radioactivity levels and hazard indices of Th-232, Ra-226 and K-40 in sediment and water samples of Lake Victoria, Jinja, Uganda

This study evaluates the levels of natural radioactivity in sediment and water samples from Lake Victoria in Jinja, Uganda, with a focus on the radionuclides potassium-40 (40 K), radium-226 (226Ra), and thorium-232 (232Th). We investigated four distinct zones around the lake: fishing (Zone A), farming (Zone B), domestic/livestock (Zone C), and a control zone (Zone D). A total of 15 sediment samples and 15 water samples were collected and analyzed. Sediment samples were obtained using a gravity corer, with a maximum penetration depth of 50 cm. 40 K ranged from 170.479 to 524.883 Bqkg−1 across all zones, 226Ra ranges from 1.51 to 56.78 Bqkg−1 across all zones, and 232Th ranges from 18.18 to 73.10 Bqkg−1 across all zones. 40 K concentrations were highest in the farming zone, likely due to the use of nitrogen, phosphorus, and potassium (NPK) fertilizers. 226Ra and 232Th levels were also elevated in the farming zone, suggesting potential contributions from phosphate fertilizers. Absorbed dose rates varied across the zones, ranging from 28.33 to 58.17 nGyh-1. The measured absorbed dose rates across all zones were within the global average of 59 nGyh−1. The effective annual dose rate ranged from 0.35 to 0.91 mSvy−1 across all zones. Effective annual dose rates did not exceed the United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR) recommended limit of 1 mSv y−1, indicating low risks to public health from sediment radioactivity. The external index was below the safety threshold, suggesting minimal health risks. In water samples, gross alpha and beta activity concentrations were analyzed. Zone B had the highest average alpha activity concentration (0.64 BqL−1) and beta activity concentration (0.72 BqL−1), while Zone A had the lowest for both alpha (0.16 BqL−1) and beta (0.25 BqL−1) activity concentrations. Gross beta activity was generally higher than gross alpha activity, reflecting potential anthropogenic influences. Most water samples were within the UNSCEAR recommended limits for drinking water quality, except in areas affected by agricultural runoff. This study demonstrates that while the sediments of Lake Victoria in Jinja, Uganda, exhibit varying levels of naturally occurring radionuclides influenced by farming practices, the overall radiation exposure remains within safe limits. Continuous monitoring and regulatory measures are essential to maintain these safety levels and mitigate potential risks from increasing agricultural activities.

Recent sedimentology at the grounding zone of the Kamb Ice stream, West Antarctica and implications for ice shelf extent

Sediment accumulating beneath floating ice contains a record of ice dynamics in polar regions where in situ observations are rare. In 2019 a hole was melted through a 590m-thick region of the Ross Ice Shelf ∼5 km seawards of the Kamb Ice Stream (KIS) grounding line (82.7841°S, 155.2626°W) to access the seafloor. Imagery from a remotely operated vehicle (ROV, Icefin) shows ocean current-generated ripples likely formed by tidal flow parallel to the grounding line (GL). Observed current speeds <0.15 m s−1 suggest these bedforms may be relict. Larger, dm-scale, ‘furrows’ parallel to the former direction of KIS flow may relate to past grounding line processes. A 0.49 m-long gravity core collected from the seafloor contains weakly stratified diamicton. The sediment matrix comprises variable mixtures of reworked Tertiary biogenic silica, predominantly diatoms, and arkose material. Sediment εNd values of ∼7 are consistent with derivation from the WAIS, as is the U-Pb age distribution and modelled late Holocene ice flows. Ramped pyrolysis 14C analysis shows all fractions are either >30 ka or 14C dead. By contrast, 210Pb-210 activity of >30 Bq Kg−1 indicates deposition within the last 120 years. The combination of features suggests rapid rainout deposition from melting of a sediment-laden basal debris layer as the GL retreated, followed by some reworking by ocean currents and little modern accumulation. Although Tertiary diatoms are abundant, unambiguously Late Quaternary forms are absent and we speculate on the implications for Ross Ice Shelf stability. [239 wds]

Tracing rate and extent of human-induced hypoxia during the last 200 years in the mesotrophic lake, Tiefer See (NE Germany)

Abstract. The global spread of lake hypoxia, [O2] &lt; 2 mg L−1, during the last 2 centuries has had a severe impact on ecological systems and sedimentation processes. While the occurrence of hypoxia was observed in many lakes, a detailed quantification of hypoxia spread at centennial timescales remained largely unquantified. We track the evolution of hypoxia and its controls during the past 200 years in a lake, Tiefer See (TSK; NE Germany), using 17 gravity cores recovered from between 10 and 62 m water depth in combination with lake monitoring data. Lake hypoxia was associated with the onset of varve preservation in the TSK and has been dated by varve counting to 1918 ± 1 at 62 m water depth and reached a lake floor depth of 16 m in 1997 ± 1. This indicates that oxygen concentration fell below the threshold for varve preservation at the lake floor (&gt; 16 m). Sediment cores at 10–12 m depth do not contain varves indicating good oxygenation of the upper-water column. Monitoring data show that the threshold for hypoxia, and the intensity and duration of hypoxia which are sufficient for varve preservation, is a period of 5 months of [O2] &lt; 5 mg L−1 and 2 months of [O2] &lt; 2 mg L−1. Detailed total organic carbon (TOC), δ13Corg, and X-ray fluorescence (XRF) core scanning analyses of the short cores indicate that the decline in dissolved oxygen (DO) started several decades prior to the varve preservation. This proves a change in the depositional conditions in the lake, following a transition phase of several decades during which varves were not preserved. Furthermore, varve preservation does occur at seasonal stratification and does not necessarily require permanent stratification.

Diverse glacial ventilation in deep Pacific: An integrated record from Mariana Trench and Magellan Seamounts over the last 1.2 Myr [Global and Planetary Change, volume 230, November 2023, 104279]: Comment

Yi (2023) proposed a new deep Western Pacific ventilation hypothesis using beryllium (10Be/9Be) and 230Thex dates, magnetostratigraphy, and element-based tuning data from two box cores and one gravity core. However, given the low sedimentation rates of these cores and uncertain stratigraphy, we suggest that some interpretations require further clarifications and corrections. The low sedimentation rates cast doubt on the validity of the millennial-scale western Pacific bottom-water oxygenation variability. The lack of unsupported explanations about the newly found periodicity in the Mariana Trench and Magellan Seamounts records raises concern about the confidence of the age models. The phasing between the North Atlantic deep water and Antarctic bottom water formation and atmospheric pCO2 in the deep Western Pacific setting is unclear.

Direct measurements of sediment geoacoustic properties in the New England Mud Patch and shelf breaka).

This paper reports on an original set of direct sound speed measurements collected with the acoustic coring system in the New England Mud Patch (NEMP) and shelf break area to the south. Cores collected within the NEMP show range-dependence of the mud with slower sound speed and lower attenuation on the west side. In the shelf break region, the highest sound speeds are observed between the 200- and 350-m isobaths. The depth-dependence of the mud layer in the NEMP includes a surficial layer with a negative sound speed gradient of 28 s-1. The remainder of the mud column has a weak positive sound speed gradient of 6.2 s-1 over an isovelocity layer. Comparison between in situ and ex situ sound speed measurements provides an assessment of the effects of sediment disturbance from gravity coring operations. Small differences in the upper 2.5 m were attributed to the changes in the geoacoustic properties caused by disturbance from the coring process. Below 2.5 m, the average difference is close to zero, suggesting that these sediments were minimally disturbed. Finally, an in situ measurement of shear speed was obtained near the depth of maximum penetration. The shear speed was well correlated with sound speed from approximately the same depth interval.

Late Pleistocene–Holocene palynology and paleoceanography of İmralı Basin, Marmara Sea: Pollen-spore, dinoflagellate cyst and other NPP zonations

The Marmara Sea is the oceanographic gateway that links the hypersaline Eastern Mediterranean Sea with the hyposaline Black Sea via Straits of Dardanelles and Bosphorus, respectively, and also occupies a transitional vegetation and climatic regime between the Mediterranean and Euxinic phytogeographic ecosystems. Recent palynological studies of long cores from the shallow İmralı Basin perched on the southeastern slope of the Marmara Sea reveal that major paleoecological changes accompanied the isolation and reconnection of the Marmara Sea during the last two Pleistocene glacial–interglacial cycles. Here, we use data primarily from two İmralı Basin cores to determine new quantitative zonations for the pollen-spore, dinoflagellate cyst (dinocyst) and other non-pollen palynomorph (NPP) assemblages in sediments representing the last ∼30 cal ka. A gap in one core is closed using data from three short gravity cores. Twenty-four radiocarbon ages and 20 correlation-ties for sapropel and ash layers from these five cores provide an essentially complete record for the past 30 cal ka. Use of a full suite of palynomorph data (pollen and spores, fungal spores, dinocysts and other phytoplankton, aquatic parasites/saprophytes, zoo-planktonic and zoo-benthic NPPs) shows for the first time that fluctuations in aquatic palynoassemblages during the glacial periods are more complex than simple salinity or temperature responses. The changes involve food web-level turnovers in trait- and size-based food web components in which potential parasites/saprophytes appear critically important.Pollen stratigraphies reveal a significant loss of Euxinic tree taxa by MIS 3c, with only partial recovery in MIS 1. The Euxinic forest elements are replaced by cultivars and other indicators of anthropogenic influences during the MIS 1 that is also marked by a dry interval and corresponding in part with the 4.2 cal ka Eastern Mediterranean Drought Event. The dinocyst zones for the last ∼30 cal ka show a clear turnover from assemblages dominated by brackish Ponto–Caspian taxa to marine assemblages at ∼11.7 cal ka. This phytoplanktonic signal lags slightly behind (a) the vegetation and shift in the other NPP commencing ∼13.2 cal ka, the initial marine incursion at 13.8 cal ka, and the arrival of coccolithophores at ∼13 cal ka. Comparison to published MIS 6 and 5 data reveals higher MIS 2–1 species diversity, reappearance of the MIS 6 marker Impagidinium inaequalis, and the emergences of Pyxidinopsis psilata f. quadrata, cf. Boreadinium breve, and Peridinium spp. of Brenner 2005. The pre-reconnection microbiota is dominated by the unicellular alga Sigmopollis, spikes of colonial Pediastrum algae, the saprophytes/parasites cf. Multiplicisphaeridium and Chytridiomycota. This microbiota is displaced by the post-reconnection assemblage dominated by Botryococcus coenobia, various Platyhelminth egg capsules and ostracod lining-types that persist through the Holocene. A distinctive transitional microbiota with Discocotyle-type turbellarian egg capsules marks the Bølling–Allerød warming, followed at ∼13.3 ka by a marine assemblage with micro-foraminiferal linings and crustacean eggs. The interglacial marine phase of MIS 1 in İmralı Basin has much higher dinocyst species diversity than MIS 5e, reflecting Neolithic impacts (agriculture, land clearance) and expanded shipping trade. Initial marine flooding in the Marmara Sea during both interglacials are marked by sapropel deposition but variations of ravinement surface erosion, and marine deep water residence time in a stratified Marmara Sea are potentially important factors underlying hypoxia/anoxia and sapropel deposition.

Modified Gravity Corer: Advantages and Offshore Testing

Modified Gravity Corer: Advantages and Offshore Testing

Sedimentary signatures of large earthquakes along the submerged Enriquillo–Plantain Garden transpressional plate boundary, northern Caribbean

Abstract The Enriquillo–Plantain Garden fault (EPGF), the southern branch of the northern Caribbean left-lateral transpressional plate boundary, has ruptured in two devastating earthquakes along the Haiti southern peninsula: the Mw 7.0, 2010 Haiti and the Mw 7.2, 2021 Nippes earthquakes. In Jamaica, the 1692 Port Royal and 1907 Great Kingston earthquakes caused widespread damage and loss of life. No large earthquakes are known from the 200-km-long Jamaica Passage segment of this plate boundary. To address these hazards, a National Science Foundation Rapid Response survey was conducted to map the EPGF in the Jamaica Passage south of Kingston, Jamaica, and east of the island of Jamaica. From the R/V Pelican we collected &amp;gt;50 high-resolution seismic profiles and 47 gravity cores. Event deposits (EDs) were identified from lithology, physical properties, and geochemistry and were dated in 13 cores. A robust 14C chronology was obtained for the Holocene. A Bayesian age model using OxCal 4.4 calibration was applied. Out of 58 EDs that were recognized, 50 have ages that overlap within their 95% confidence ranges. This allowed for their grouping in multiple basins located as much as 150 km apart. The significant age overlap suggests that EDs along the Enriquillo–Plantain Garden plate boundary resulted from large and potentially dangerous earthquakes. Most of these earthquakes may derive from the EPGF but also from thrust faulting at this strain-partitioned transpressional boundary. The recent increase in Coulomb stress on the EPGF from the Mw 7.2 Nippes earthquake in southwestern Haiti and the discoveries reported here enhance the significance for hazard in the Jamaica Passage.

Dismantling of an isolated tropical carbonate platform through flank collapse and canyon erosion, Coral Sea, Northeast Australia

The steep slopes of carbonate platforms frequently display large-scale sediment destabilization features like rockfalls, mass transport complexes, and slope erosion. The processes and factors triggering such instabilities and how they interact are a matter of ongoing discussion. We use hydroacoustic, sedimentological, and seafloor imaging data to map and characterize slope instabilities and potential controlling factors at the flank of the isolated Tregrosse carbonate bank in the Coral Sea, northeast Australia. Erosion of gullies and submarine valleys is concentrated in slope segments with the platform rim at several 10s of meters of water depth, i.e. where there is potential for sediment transfer from the bank interior to the slope. Gravity core data indicate that most sediment export from the platform occurs during sea-level fall. The toe of slopes neighboring segments with a shallower platform rim are mostly characterized by mass-transport complexes of platform rim and upper slope rocks forming extended block fields. Distal slope areas are dismantled through submarine landslides resulting in scalloped head scarps. The basal detachment surface of these submarine landslides appears to be rooted in several 100 s of meters in the subsurface at a lithological heterogeneity, which is documented by a gamma-ray peak in the downhole logging data from Ocean Drilling Program Site 817. Our findings show that (1) canyon erosion, (2) platform rim and upper slope destabilization as well as (3) lower slope dismantling, largely act independently of each other to destabilize the flanks of the carbonate bank. The complexity of the carbonate platform dismantling processes and the corresponding controlling factors shown in this study should also be considered when interpreting seismic morphological data.

Carbon budget of methane seepages in the Haiyang 4 Area in the northern slope of the South China sea

Methane seepage records information of the local carbon cycle with respect to the generation, consumption and sequestration of carbon. Here presents the investigation of 7 gravity cores retrieved in 2004 during cruise SO-177 in the Haiyang 4 Area at the northern slope of the South China Sea. Porewater solutes, sulfate, methane, total alkalinity, sulfide and calcium demonstrate currently the weak seep activity. Local carbon cycling and sequestration is also revealed, that dominates by anaerobic oxidation of biogenic methane to dissolved bicarbonate inducing calcium carbonate and iron sulfide minerals (mainly pyrite) precipitation. A reactive transport model was employed to quantify the carbon cycle and budget. Model results show that current methane fluxes contribute to less than 2 wt % of authigenic carbonates and 2 wt % iron sulfide minerals being precipitated in 600–800 cm sediment depth. The sequestration of carbon could be > 50 mmol C cm−2 yr−1 under in situ condition. The observed increase of carbonate and iron sulfide minerals at ∼100 cm, however, require higher methane fluxes to shift the zone of anaerobic oxidation of methane upwards to around 1 m below the seafloor, which have occurred during sea level low stands in the geological past. The oscillation of seepage flux contributed to the formation of multiple layers of authigenic carbonates and pyrite, which indicates the high capability of carbon sink and is speculated to be induced by the dissociation of the underlying hydrates triggered by sea level drop and or temperature increase.

South Georgia marine productivity over the past 15 ka and implications for glacial evolution

Abstract. The subantarctic islands of South Georgia are located in the Southern Ocean, and they may be sensitive to future climate warming. However, due to a lack of well-dated subantarctic palaeoclimate archives, there is still uncertainty about South Georgia's response to past climate change. Here, we reconstruct primary productivity changes and infer Holocene glacial evolution by analysing two marine gravity cores: one near Cumberland Bay on the inner South Georgia shelf (GC673: ca. 9.5 to 0.3 cal. kyr BP) and one offshore of Royal Bay on the mid-shelf (GC666: ca. 15.2 cal. kyr BP to present). We identify three distinct benthic foraminiferal assemblages characterised by the dominance of Miliammina earlandi, Fursenkoina fusiformis, and Cassidulinoides parkerianus that are considered alongside foraminiferal stable isotopes and the organic carbon and biogenic silica accumulation rates of the host sediment. The M. earlandi assemblage is prevalent during intervals of dissolution in GC666 and reduced productivity in GC673. The F. fusiformis assemblage coincides with enhanced productivity in both cores. Our multiproxy analysis provides evidence that the latest Pleistocene to earliest Holocene (ca. 15.2 to 10.5 cal. kyr BP) was a period of high productivity associated with increased glacial meltwater discharge. The mid–late Holocene (ca. 8 to 1 cal. kyr BP), coinciding with a fall in sedimentation rates and lower productivity, was likely a period of reduced glacial extent but with several short-lived episodes of increased productivity from minor glacial readvances. The latest Holocene (from ca. 1 cal. kyr BP) saw an increase in productivity and glacial advance associated with cooling temperatures and increased precipitation which may have been influenced by changes in the southwesterly winds over South Georgia. We interpret the elevated relative abundance of F. fusiformis as a proxy for increased primary productivity which, at proximal site GC673, was forced by terrestrial runoff associated with the spring–summer melting of glaciers in Cumberland Bay. Our study refines the glacial history of South Georgia and provides a more complete record of mid–late Holocene glacial readvances with robust chronology. Our results suggest that South Georgia glaciers were sensitive to modest climate changes within the Holocene.

Litho- and chronostratigraphy of the Upper Quaternary sediments from the Piedra Buena Terrace, Patagonian Continental Margin (SW Atlantic)

This paper presents a detailed description of the lithostratigraphy of mostly contouritic deposits from the Piedra Buena Terrace (PBT), collected at water depth of 2–2.5 km. It is based upon a multi-proxy investigation of five gravity cores, including visual description and scanning, grain size distributions, microfossils and sand fraction study, supported by the analysis of high-resolution sub-bottom profiles. Two older seismic units were identified in addition to those previously described in the area. The defined lithostratigraphic units were correlated to the upper seismic units, while the age of the younger units was confirmed using AMS-14C dating. In terms of the sedimentary facies, the dark quartz-glauconitic sands, which seem to be a fingerprint of the Piedra Buena Terrace, were investigated by applying the X-ray diffraction and performing grain SEM - SE images. The sandy facies correspond to sea-level low-stands during cold glacials (MIS 2 and MIS 4), when glauconite and terrigenous material were transported from the emerged shelf down and along the Patagonian continental slope by vigorous bottom currents. The latter is confirmed by an occurrence of parts of bi-gradational sequences reported from the grain-size distributions in lithostratigraphic units 2 and 4. Units 1 and 3, represented by mostly hemipelagic calcareous ooze, were formed during warm high sea-level stages (MIS 1 and 3). Unlike Unit 1, Unit 3 also demonstrates clear contourite features, similar to Units 2 and 4. They include common bioturbation, occurrence of mottles, lenses, irregular thin layers of sand, erosional boundaries and hiatuses between and within the units, good sorting of fine sands, and microfossil reworking. Together with our previous data from canyons on the Perito Moreno Terrace and the Ameghino segment, supported by available publications from the PBT and Mar del Plata areas, this study demonstrates that the Patagonian Continental Margin could be used as a natural laboratory to investigate and better understand contourite systems.

Methanooceanicella nereidis gen. nov., sp. nov., the first oceanic Methanocellaceae methanogen, isolated from potential methane hydrate bearing area offshore southwestern Taiwan.

A novel mesophilic, hydrogenotrophic methanogen, strain CWC-04T, was obtained from a sediment sample extracted from a gravity core retrieved at station 22 within the KP-9 area off the southwestern coast of Taiwan during the ORIII-1368 cruise in 2009. Cells of strain CWC-04T were rod-shaped, 1.4-2.9 µm long by 0.5-0.6 µm wide, and occurred singly. Strain CWC-04Tutilized formate, H2/CO2, 2-propanol/CO2 or 2-butanol/CO2 as catabolic substrates. The optimal growth conditions were 42 °C, 0.17 M NaCl and pH 5.35. The genomic DNA G+C content calculated from the genome sequence of strain CWC-04T was 46.19 mol%. Phylogenetic analysis of 16S rRNA gene revealed that strain CWC-04T is affiliated with the genus Methanocella. The 16S rRNA gene sequences similarities within strains Methanocella arvoryzae MRE50T, Methanocella paludicola SANAET and Methanocella conradii HZ254T were 93.7, 93.0 and 91.3 %, respectively. In addition, the optical density of CWC-04T culture dropped abruptly upon entering the late-log growth phase, with virus-like particles (150 nm in diameter) being observed on and around the cells. This observation suggests that strain CWC-04T harbours a lytic virus. Based on these phenotypic, phylogenetic and genomic results, we propose that strain CWC-04T represents a novel species of a novel genus in the family Methanocellaceae, for which the name Methanooceanicella nereidis gen. nov., sp. nov. is proposed. The type strain is CWC-04T (=BCRC AR10050T=NBRC 113165T).

Major ion pore-water chemistry evolution in Lake Michigan benthic sediments: Evidence for direct input from Michigan Basin saline groundwater

The Michigan Basin is composed of geological formations that contain brines and evaporites, and solutes from these geological sources have affected benthic sediment pore-water chemistry in Saginaw Bay (Lake Huron). We hypothesize that there exists similar potential for upward solute transport directly from the Michigan Basin into other Great Lakes areas. To test our hypothesis, we present here previously unpublished pore-water chemistry analyses from sediment cores collected during multiple Lake Michigan sampling events (spanning 1991−1999) and a new evaluation of previously published data. In several box cores, pore-water chloride concentrations increase with depth, and Cl:Br ratios are consistent with a geological formation brine source. In all gravity cores we collected from southern Lake Michigan, pore-water sodium concentrations increase with sediment depth. At one sample station, pore-water sodium concentrations exceed 2000 mg L−1 within 2 m of the sediment-water interface. Given the pore-water chemistry changes reported here, combined with information from previous studies of Lake Michigan bedrock geology, a Devonian formation brine is a plausible solute source. The presence of saline pore water within glaciolacustrine sediments underlying Lake Michigan indicates that this solute flux has been active during the past 10 k.y. However, the origins of this solute flux, including timing (onset) and contributions from advective and/or diffusive transport, are unknown. The specific geological source and solute transport process are important to resolve in order to evaluate potential effects of these Michigan Basin solute sources on the Great Lakes’ sediment biogeochemistry and water quality.

Biogeochemical impact of historical submarine mine tailings on benthic ecosystems in the Repparfjord (Northern Norway)

Historical copper mine tailings deposited in the Repparfjord, Northern Norway, provided new insight into the biogeochemical impact of submarine tailings disposals on high-latitude coastal ecosystems. The submarine tailings disposal in the Repparfjord represents a product of mining activities between 1972 and 1979. Their environmental impact has been extensively studied during the last decade, but geochemistry of the sediment pore water, which is crucial to assess and monitor the in-situ metal leaching and bioavailability, has never been analysed. The actual impact on the benthic fauna remains poorly known. Therefore, this study couples the pore water chemistry and the foraminiferal analysis obtained from selected sediment cores (gravity core, multicore, box cores) to examine metal stability and the past and current status of the foraminifera community. We measured down-core sulfate and trace metal concentrations and Eh-Ph and applied the Shannon index, the AZTI's Marine Biotic Index (F-AMBI) index and the foraminiferal abnormality index. This study confirms the ongoing leaching of Cu from the underlying mine tailings and release across the sediment-water interface. Leaching of Ni, Zn and Pb have been attributed to weathering of natural bedrock lithologies. The original benthic foraminiferal community disappeared almost entirely during the disposal period, and now it is dominated by stress-tolerant and opportunistic species like Bulimina marginata and Spiroplectammina biformis. Anyhow, against previous assumptions, the community composition changed, while the overall diversity and abnormalities (FAI) shell formation is unaffected by elevated Cu concentrations.

Holocene Paleoclimate Records in Equatorial West Africa: Insights Based on the Characterization of Glycerol Dialkyl Glycerol Tetraethers

One gravity core retrieved from the Niger Delta was used to explore the origin of deposited organic matter (OM) and the paleo-climatic and environmental conditions over the Holocene in equatorial West Africa. The geochemical properties of sediments including glycerol dialkyl glycerol tetraethers (GDGTs) and elemental (%OC, %N, C/N) and isotopic (δ13Corg, δ15N) signatures were determined. The determination constrained the age of the column and revealed that the sediment OM was mainly derived from a marine source. The isoprenoid (iso)GDGTs were the dominant GDGTs, with a small amount of branched (br)GDGTs, which led to a low-branched and isoprenoid tetraether index (BIT, 0.02–0.21) and represented a low terrestrial input. Most isoGDGTs and OH-GDGTs were produced in situ by Marine Group I (MG-I) Thaumarchaeota, while the brGDGTs were mainly transported from land. A two-endmember model quantified the contribution of terrestrial OM, as 0.9–19.9% by BIT and 1.1–32.6% by δ13C. Accordingly, the millennium-scale sea surface temperatures (SSTs) were reconstructed based on the cyclopentane ring distribution (TEX86H) and the ring index of OH-GDGTs (RI-OH). The top core SSTs were lower than the modern mean annual SST due to the growth season and habitat depth of Thaumarchaeota. The reconstructed SSTs clearly revealed the four stages of paleoclimate change, in particular, the drought episode of 8.2 kyr and the following humid period. The above research has enhanced our understanding of the paleoclimate change in river outflow during the Holocene at the millennium scale.

Seawater contamination by coring and pore water sampling of marine sediments

Coring of sediments with minimal physical disturbance, and sampling of pore water with minimal contamination from seawater, are critical in marine geochemistry and microbiology. Yet, sediment coring generally causes smearing of sediment down along the inside of the core liner and leaves seawater and fluid mud trapped around the core. This seawater is a source of diffusive or advective exchange of solutes with the core, which affects the chemistry of retrieved pore water. The exchange depends on the time elapsed between coring and the end of pore water extraction. The degree of seawater contamination is difficult to determine and has generally been neglected in the geochemical literature. Yet, it is possible to quantify seawater contamination due to the high millimolar concentration of sulfate in seawater and low micromolar concentration in the subsurface methanic zone, where sulfate is largely depleted. Analysis of 540 sediment cores from a global database showed that sulfate concentration data beneath the sulfate-methane transition were often truncated and stated as “0” or “0,0” mM, thereby preventing an evaluation of seawater contamination. Among the 181 sediment cores for which the mM sulfate concentrations were reported with two or three decimal places, concentrations measured in methanic sediments were up to an order of magnitude higher than the estimated in situ concentrations in gravity cores and two orders of magnitude higher in cores recovered by scientific ocean drilling. A comparison between pore water extraction by Rhizon suction samplers and by high-pressure squeezers in cores from Baltic Sea Expedition 347 of the IODP (International Ocean Discovery Program) showed no systematic difference in the degree of contamination. A comparison with a perfluorocarbon (PFC) tracer injected by IODP coring into the drilling fluid showed a seawater contamination similar to that based on sulfate in the methanic zone. In IODP cores, where the true in situ sulfate concentration is generally unknown, we calculated the theoretical sulfate concentration that corresponded to equilibrium between SO42−, Ba2+ and barite (BaSO4) to show that the equilibrium sulfate concentrations in the methanic zone are much lower than the sulfate concentrations measured in pore water samples, again indicating seawater contamination. We used a time-resolved diffusion model to calculate how contaminating seawater ions penetrate from the external liner fluid into sediment cores before pore water is extracted. We conclude that nearly all published pore water samples retrieved from subsurface sediments are contaminated by seawater to some degree. We also conclude that sensitive sulfate analyses in methanic sediments constitute a unique opportunity to quantify this contamination and thereby provide a better possibility to control it.

Marine Geological Studies of the Bay of Naples (Southern Tyrrhenian Sea, Italy): Revised Applications of the Seismo-Stratigraphic Concepts and Evolving Technologies to a Late Quaternary Volcanic Area

Marine geological studies of Naples Bay are discussed and reviewed, focusing on the application of the seismo-stratigraphic concepts to a Late Quaternary volcanic area. The Naples Bay represents an active volcanic area in which the interactions between volcanic and sedimentary processes controlled a complex stratigraphic architecture during the Late Quaternary period. While the volcanic processes took place in correspondence with the activity of the Somma–Vesuvius, Campi Flegrei Ischia, and Procida volcanic complexes, the sedimentary processes were controlled by the fluvial processes in the Sarno-Sebeto coastal plain and by the tectonic uplift in correspondence with the Sorrento Peninsula’s structural high Key geophysical and stratigraphic studies of the three active volcanic complexes are revised and discussed. The seismo-stratigraphic concepts applied in the geological interpretation of seismic profiles of Naples Bay are reviewed and discussed: here, the classical concepts of seismic and sequence stratigraphy have been successfully applied, but only partly, due to the occurrence of several buried volcanoes and volcanic seismic units and tephra layers, calibrated by gravity cores.

Enrichment of Smectite in the REY‐Rich Mud of the Clarion‐Clipperton Fracture Zone in the Eastern Pacific and Its Geological Significance

AbstractREY‐rich mud, consisting of deep‐sea sediments with high concentrations of rare‐earth elements and yttrium (REY), holds significant economic potential. Many studies have been conducted on biogenic apatite, ferromanganese micronodule, and phillipsite within these deposits to ascertain the REY enrichment mechanisms. However, the knowledge of clay minerals in REY‐rich mud, which is the predominant component of pelagic sediments, is still limited. In this study, two adjacent gravity cores (core GC02: REY‐rich mud; core GC03: typical sediments of equatorial Pacific) were collected from the Clarion‐Clipperton Fracture Zone (CCFZ) of the Eastern Pacific to study the role of different clay minerals in REY enrichment. The clay minerals in core GC03 and core GC02 are primarily illite (averaging 60%) and smectite (averaging 63%), respectively, and the smectite in core GC02 was mainly Fe‐rich, which was probably formed via the reaction between opal and FeOOH. Moreover, multiple studies have reported similar smectite enrichment in REY‐rich mud, suggesting that it is a common characteristic. The presumed hydrothermal or volcanic origination of smectite in REY‐rich layers of core GC02 indicates the essential role of hydrothermal and volcanic activities in REY‐rich mud formation during the Oligocene in the western CCFZ.

Retreat patterns and dynamics of the former Norske Trough ice stream (NE Greenland): An integrated geomorphological and sedimentological approach

A better understanding of past extent and dynamics of the Greenland Ice Sheet (GrIS) is required to provide context for present-day observations, to constrain numerical climate models and to predict future scenarios of ice-sheet response to recent climatic change. The presence of a grounded GrIS on the NE Greenland shelf during the Last Glacial Maximum (LGM) is supported by high-resolution seismic data combined with multi-proxy analyses of sediment gravity cores from Norske Trough. Our results indicate that an ice stream advanced to the outer shelf during the LGM. Recessional moraines and grounding zone wedges on the seafloor of the outer to middle shelf show that initial retreat was episodic, punctuated by two major stillstands. Pinning points for grounding-zone stabilization were controlled by pre-LGM trough topography. In contrast, preserved large-scale glacial lineations on the seafloor of the inner shelf, formed during the advance, indicate that ice retreat from the inner trough to the coast-proximal position was rapid in order to maintain the former carved morphology. Initial ice retreat was underway before 16.6 cal Kyr BP, earlier than previously known for this sector of the NE Greenland shelf. The inner shelf was free from grounded ice at least by 12.5 cal Kyr BP, and likely before. Retreat occurred in a glaciomarine setting and the ice sheet was fringed by a floating ice shelf. There is no evidence of grounded-ice readvances during the Younger Dryas, although a floating ice shelf with vigorous sea-ice and iceberg rafting production occupied the inner shelf at 11.3 cal Kyr BP. 14C dates reveal initial stepwise ice retreat followed by a fast retreat that coincides with Heinrich Stadial 1 and the Bølling-Allerød interstadial, respectively. During both periods there was increased inflow of warm Atlantic Water, indicating a strong ocean/climate control on the late deglaciation of Norske Trough. Following the late deglaciation, postglacial (Holocene) sedimentation records a change from an ice-distal glaciomarine environment, to an open marine environment and complete ice shelf disintegration. On the innermost shelf of the Norske Trough, the ice shelf disintegrated and reformed once before the final break-up occurred at 9.6 cal Kyr BP.