Graphene Nanoplatelets Research Articles

Investigating the potential of powder metallurgy for fabricating graphene nanoplatelets reinforced copper nanocomposites

Copper (Cu) is highly sought for its excellent electrical and thermal conductivity. However, its limited mechanical strength hinders its wider application in demanding fields. This work explores the potential of graphene nanoplatelets (GNPs) as a strengthening agent for Cu. Cu-GNP composites with varying GNP content (0.1–1.5 wt%) were fabricated using a combined ball milling and powder metallurgy approach. The microstructure and mechanical properties of the composites were comprehensively analyzed using field emission scanning electron microscopy (FESEM), energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), and Raman spectroscopy. Compared to pure Cu, the Cu-GNP composites showcased significantly improved mechanical performance. Notably, the Cu-1.0 wt% GNP composite exhibited a remarkable ∼27% and ∼53% enhancement in compressive strength and micro-hardness, respectively. This improvement is attributed to the effective load transfer between Cu and well-dispersed GNPs, which act as reinforcement elements and inhibit dislocation movement. These findings demonstrate the promising potential of Cu-GNP composites for applications requiring high strength.

Ionic Organic Network-based C3-symmetric@Triazine core as a selective Hg+2 sensor

ABSTRACT The C3-symmetry ionic polymer PPyTri has been designed with multi-walled carbon nanotubes (MWCNTs) or graphene nanoplatelets (GNPs) and studied as an ultrasensitive electrochemical sensor for trace Hg(II) detection. The synthesis approach incorporated attaching three pyridinium cationic components with chloride anions to the triazine core. The precursors, BPy, were synthesized using a condensation process involving 4-pyridine carboxaldehyde and focused nicotinic hydrazide. The polymer PPyTri was further modified with either MWCNTs or GNPs. The resulting ionic polymer PPyTri and its fabricated nanocomposites were characterized using infrared (IR), nuclear magnetic resonance (NMR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and powder X-ray diffraction (XRD). The analysis revealed that both the polymer and its nanocomposites have semi-crystalline structures. The electroactivity of the designed nanocomposites toward Hg + 2 ions revealed that among the nanocomposites and bare copolymer, the glassy carbon electrode (GCE) adapted with the PPyTri GNPs-5% exhibited the greatest current response over a wide range of Hg + 2 concentrations. The nanocomposite-modified electrode presented an excellent sensitivity of 83.33 µAµM − 1 cm − 2, a low detection limit of 0.033 nM, and a linear dynamic range of 0.1 nM to 0.01 mM (R2 = 0.9945).

A review on cementitious composite incorporating carbon nanomaterials: The self-sensing functionality as an implication for geological CO2 storage monitoring

Ensuring the long-term security and safety of geological CO2 storage relies on the durability of wellbores and cement. Addition of carbon-based nanomaterials (CNMs) have enhanced traditional cement, improving cement properties, and preventing gas migration. Despite these advancements, their potential for self-monitoring in GCS remains understudied. Self-sensing cementitious composites (SSC) are gaining attention for their ability to detect risks and damages, like cracks and corrosion, by monitoring environmental changes. This review first scrutinizes the self-sensing mechanism of SSC, including piezoresistivity, electrical resistivity and conductivity. The commonly used CNMs in SSC, such as carbon nanotubes (CNTs), carbon nanofibers (CNFs), carbon black (CB), and graphene nanoplatelets (GNPs), along with the hybrid nanocomposites, detailing recent advancements. Based on their effects, such as enabling the measurement of electrical response to strain, real-time monitoring of structural integrity, and improvement in cement performance, the implications are made for GCS cases, for instance, structural health monitoring and detecting leakage. Technical challenges, such as balancing electrical properties and mechanical strength, scalability, and environmental sensitivity, are addressed, along with insights on employing machine learning algorithms to optimize SSC usage. Finally, future directions for integrating SSC into GCS initiatives are proposed.

Highly stable mesoporous-controlled corncob biochar confined paraffinic material with exceptional latent heat retention performance

Bio-based composites fabricated from bio-sourced waste feedstocks have attracted increasing interest and have shown potential applications in sustainable energy infrastructure development. Thermal management using phase-change materials (PCMs) has appeared as an innovative approach for energy storage and cooling, where pure PCMs that lack thermal stability are encapsulated in solid matrices to ensure the charge/discharge of the latent heat of the composite. However, their energy storage density, thermal stability, and durability are reduced after multiple thermal cycles, besides the complicated and expensive nonrenewable fossil feedstock utilization. Biochar, mostly used for soil remediation, can be redirected and repurposed for the encapsulation of PCMs in renewable energy storage infrastructures. In this study, a “greener” biochar-based composite was fabricated from agricultural corncob-derived biochar (88.9 % mesopore proportion) and a commercially available paraffinic PCM (n-hexadecane) following vacuum impregnation strategies. Corncob biochar combined with hexadecane exhibited an efficient energy per unit mass of 250.6 kJ kg−1 and a latent heat retention of 110.3 % after 500 consecutive thermal cycles. In addition, the corncob biochar/hexadecane composite demonstrated high fractional crystallinity and relative latent heat efficiency (98.9 %). The composite exhibited promising chemical compatibility with composite components, stability, and competitive energy density even compared with a composite made of nonrenewable fossil-based materials, like exfoliated graphene nanoplatelets, which demonstrated reduced latent heat retention after multiple heating-cooling cycles. Intermolecular interactions, such as hydrogen bonding, between the guest molecular chains and host materials played a significant role in the thermal performance of the as-synthesized composite materials. This approach will contribute to overcoming the complexities and costs of composite PCM development in thermal management and thermal energy storage applications and support and advance the UN's sustainable development goal (affordable and clean energy).

Enhancing Wear Resistance and Mechanical Behaviors of AA7020 Alloys Using Hybrid Fe3O4-GNP Reinforcement

This study investigates the effect of graphene nanoplatelets (GNPs) and milling duration on the microstructure, mechanical properties, and wear resistance of the AA7020 alloy reinforced with Fe3O4 and GNP. The composites were prepared with a fixed 10 wt.% Fe3O4 and varying GNP contents (0.5 and 1 wt.%) using high-energy ball milling for 4 and 8 h, followed by hot pressing. The aim was to enhance the performance of the AA7020 alloy for potential use in defense, automotive, aviation, and space applications, where superior mechanical properties and wear resistance are required. The results showed that the incorporation of 0.5 wt.% GNP and optimized milling significantly improved the composite’s performance. The AA7020 + 10 wt.% Fe3O4 + 0.5 wt.% GNP composite achieved the highest density (99.70%) when milled for 4 h. Its hardness increased with both the inclusion of GNP and extended milling duration, with the composite milled for 8 h exhibiting the highest hardness value (149 HBN). The tensile strength also improved, with the composite milled for 4 h showing a 28% increase (292 MPa) compared with the unreinforced alloy. Additionally, the friction coefficient decreased with GNP content and milling duration, with the composite milled for 8 h showing a 26% reduction. Wear resistance was notably enhanced, with the composite milled for 8 h exhibiting the lowest specific wear rate (7.86 × 10−7 mm3/Nm).

Conductive recycled PETg additive manufacturing filament for sterilisable electroanalytical healthcare sensors

Current reports of healthcare sensors within literature that use additive manufacturing electrochemistry all utilise conductive PLA, which is unsuitable for widespread use within the industry. Poly(ethylene terephthalate glycol (PETg) is a polymeric material with proven attributes for additive manufacturing due to its thermal and mechanical properties. Likewise, its excellent chemical stability transforms PETg into a desirable alternative for developing healthcare sensing devices. In this work, we report the production, physicochemical and electrochemical characterisations, as well as the electroanalytical performance of an enhanced electrically conductive additive manufacturing filament made with recycled poly(ethylene terephthalate glycol (rPETg) and a combination of carbon black, multi-walled carbon nanotubes and graphene nanoplatelets as conductive fillers. The post-print activation of additive manufactured electrodes from this material is optimised and shown to produce enhanced electrochemical performance compared to non-activated electrodes, with a k0 of 1.03×10−3 cm s−1. The sterilisation for the real application of sensors in the biomedical field is a critical point, the electrodes were submitted to standard UV light treatment showing to be reliable compared to PLA in the determination of uric acid (30–500 µM) and sodium nitrite (0.1–5 mM) within synthetic urine using differential pulse voltammetry and chronoamperometry techniques. A sensitivity and LOD for uric acid of 25.7 µA µM−1 and 0.27 µM, and 52.6 µA mM−1 and 2.69 µM for nitrite were obtained within synthetic urine, respectively. The re-useability of the electrodes was also tested for the detection of uric acid, showing that the electrode could be used up to 10 times before a significant decrease in the results was observed. We demonstrate that a new conductive rPETg with superior electrochemical performance has a prominent place within the development of additive manufactured-printed healthcare sensors due to its ability to be sterilised and re-used, low solution ingress, and its potential to tackle rising costs and plastic waste problems within the healthcare sector.

Determination of nano-graphene content for improved mechanical and tribological performance of Zn-based alloy matrix hybrid nanocomposites

The primary objective of this study is to explore the fabrication of a hybrid nanocomposite (HNC) composed of ZnAl40Cu2 alloy, graphene, and B4C particles, while also determining the optimal graphene reinforcement ratio for enhanced properties. Our methodology entails the production of HNC powders (HNPs) through mechanical milling, where we combine graphene nanoplatelets with B4C microparticles into ZnAl40Cu2 alloy powders. Throughout this process, we maintain a constant B4C content of 1.5 wt%, while varying the graphene content at 1.5 wt%, 3 wt%, and 4.5 wt%. Following the characterization of all produced powders, which includes an assessment of powder morphology, powder size distribution, and powder microhardness, we proceed to hot-press the HNPs to create bulk HNC samples. After consolidating the specimens, a comprehensive series of tests are carried out to determine microstructural, mechanical (hardness and tensile strength) and tribological properties. Our results reveal that the HNC specimen with graphene content of 3 wt% (referred to as A2) displays the most notable enhancements in properties. Specifically, A2 exhibits an impressive hardness of 163 HB, surpassing the hardness of the ZnAl40Cu2 matrix alloy, which measures at 133 HB. Furthermore, its ultimate tensile strength significantly outperforms the ZnAl40Cu2 matrix alloy, with a remarkable value of 223 MPa compared to 157 MPa. However, it is worth noting that the improvement in wear resistance for HNCs is most pronounced up to a certain threshold of graphene content, which is 3 wt%.

Synergistic reinforcement of Cu/Ti3SiC2/C laminated-like composites with the bimodal and highly oriented graphite flake and graphene nanoplatelets

This study describes the preparation of bimodal reinforced Cu/Ti3SiC2/C laminated-like composites using flake powder metallurgy and vacuum hot-press sintering process. The objective was to accurately modulate the formation of oriented reinforcement network in two-dimensional carbon materials. The powders used in the five designed composites were flake Cu powder (45–60 μm), Ti3SiC2 (1–5 μm), graphite flakes (GFs, 120 μm) and graphene nanoplatelets (GNPs, 15 μm). Among them, the proportions of Ti3SiC2 (10 wt %) and GFs (3 wt %) remained unchanged, GNPs accounted for 0 wt %, 0.5 wt %, 1.0 wt %, and 1.5 wt %, and Cu powder accounted for a decreasing proportion. Formation mechanisms of GFs and GNPs in oriented networks were quantitatively analyzed using the alignment model. Additionally, the related strengthening and failure mechanisms were investigated. According to the study, the bimodal laminated-like Cu/Ti3SiC2/C composites with 0.5 wt% GNPs added showed the best overall performance. Specifically, it exhibited a hardness of 125.7 HV, tensile strength of 276.3 MPa, thermal conductivity of 207.8 W m−1 K−1, and electrical conductivity of 23.6 MS/m. The network enhanced by the two-dimensional carbon material achieves efficient and orderly load transfer and dissipation mechanisms, optimizing stress distribution and enhancing fracture resistance, resulting in improved mechanical properties. In addition, the formation of the oriented reinforcement network optimizes the orientation arrangement of the reinforcing particles, which somewhat mitigates the scattering of thermoelectric carriers by structural defects in the composites, and the enlarged mean free-range improves the migration efficiency of electrons and phonons. Therefore, the erection of bimodal laminated-like structure achieves the goal of optimizing the properties of the composites.

Effect of graphene nanoplatelets and nano zinc oxide on gas barrier and antibacterial properties of thermoplastic nanocomposites

AbstractGraphene‐loaded thermoplastic nanocomposite films must be evaluated for antibacterial activity, mechanical, and barrier properties before being utilized as food packaging. Herein, economically feasible linear low‐density polyethylene (LLDPE)‐based flexible packaging materials were developed via the melt compounding technique at 170°C temperature by taking advantage of both graphene nanoplatelets (GNP) and nano zinc oxide (ZnO) fillers. Morphological studies reveal that in composites loaded with GNP/ZnO hybrid fillers, ZnO nanoparticles form a network‐like structure throughout the polymer matrix. Simultaneously, GNPs are uniformly dispersed. The inclusion of hybrid nanofiller considerably reduces both the oxygen transmission rate and the water vapor transmission rate (WVTR) in LLDPE nanocomposites. A maximum decrease of 36% and 67%, respectively, in both oxygen transmission rate and WVTR is observed for 3 wt% of hybrid filler loading in a thermoplastic matrix containing 1 wt% of nano ZnO. The antibacterial efficacy of the derived nanocomposite films is obvious against gram‐positive (Bacillus subtilis) and gram‐negative (Escherichia coli) bacterial strains. These nanocomposite films have the potential to be successfully utilized as flexible packaging materials owing to their improved thermal, barrier, and antibacterial effectiveness.Highlights GNP/ZnO was used as a hybrid reinforcing filler in the LLDPE matrix. ZnO nanoparticles establish a network‐like morphology. LLDPE nanocomposite films exhibited excellent antibacterial activity. Oxygen and water vapor barrier properties were significantly improved. The thermoplastic composite films could be used as food packaging materials.

Ultrastrong Graphene Sheets Assembled with Nanoconfined Water.

Highly ordered assembly of two-dimensional (2D) nanoplatelets plays a key role in enhancing the mechanical properties of layered nanocomposites. Layer-by-layer (LbL) assembly, vacuum-assisted filtration, and blade coating have been used to fabricate layered nanocomposites. However, the intrinsic wrinkles of 2D nanoplatelets and defects derived from assembling approaches make it difficult to align 2D nanoplatelets. Recently, the team of Prof. Qunfeng Cheng at Beihang University and their collaborator, Prof. Ray H. Baughman at the University of Texas at Dallas developed a novel approach for aligning graphene and Ti3C2Tx MXene nanoplatelets by nanoconfined assembly through continuous vacuum-assisted filtration. The resultant MXene-bridged sheet has ultrastrong mechanical properties and low porosity, providing a new concept for assembling 2D nanoplatelets into aligned and compact high-performance layered nanocomposites.

Ultrastrong Graphene Sheets Assembled with Nanoconfined Water

AbstractHighly ordered assembly of two‐dimensional (2D) nanoplatelets plays a key role in enhancing the mechanical properties of layered nanocomposites. Layer‐by‐layer (LbL) assembly, vacuum‐assisted filtration, and blade coating have been used to fabricate layered nanocomposites. However, the intrinsic wrinkles of 2D nanoplatelets and defects derived from assembling approaches make it difficult to align 2D nanoplatelets. Recently, the team of Prof. Qunfeng Cheng at Beihang University and their collaborator, Prof. Ray H. Baughman at the University of Texas at Dallas developed a novel approach for aligning graphene and Ti3C2Tx MXene nanoplatelets by nanoconfined assembly through continuous vacuum‐assisted filtration. The resultant MXene‐bridged sheet has ultrastrong mechanical properties and low porosity, providing a new concept for assembling 2D nanoplatelets into aligned and compact high‐performance layered nanocomposites.

Combined effect of montmorillonite Cloisite 30B and graphene nanoplatelets on high‐density polyethylene matrix under high strain rate dynamic compression

AbstractLaminated polymer composites are widely used in ballistic barriers where polyethylene can be applied. The mechanical properties of polymers can be improved with the addition of nanofillers. Therefore, this work evaluates the effect of the combination of montmorillonite Cloisite 30B (OMt) and graphene (Gr) on the dynamics compression properties obtained from a split‐Hopkinson pressure bar (SHPB) test for nanostructured maleinized high‐density polyethylene (HDPE). The nanofillers are incorporated into the polymeric matrix in its molten state, and their dispersion is evaluated through x‐ray diffraction and transmission electron microscopy analyses. Thermal analysis, including differential scanning calorimetry and thermogravimetric analysis are performed. Additionally, the viscoelastic behavior of the materials is studied from the results of storage and loss modulus obtained by dynamic‐mechanical analysis. Under the SHPB test conditions, it is possible to evaluate the material stress–strain curve, identifying its yield point, compressive strength, and deformations to calculate the elastic stiffness and toughness of the material. The nanocomposite with 3% OMt and 0.75% Gr (wt.%) shows the highest average compressive strength and toughness values. Furthermore, this sample shows similar Tpeak temperature, improved crystallinity index, storage, and loss modulus, with similar glass transition temperature compared to the HDPE sample.

Thermal behavior of polypropylene composites with segregated graphene nanoplatelet network

AbstractThree‐dimensional architecture of segregated network can significantly influence thermal behaviors of polymer composites, such as the melting temperature (Tm) and degradation temperature. However, there have been few systematic studies on the thermal behaviors of polypropylene (PP) composites with a segregated network that the fillers were selectively located in the polymeric particle interfaces. In this study, we found that introduction of the segregated graphene nanoplatelet (GNP) network induced the maximum Tm of 177.6°C, extending the operating temperature by 11.5°C compared to the Tm of composites with randomly dispersed GNPs. In contrast, the thermal degradation temperature of polymer composites varied insignificantly regardless of introduction of the segregated network because the thermal degradation of the polymer matrix occurred after the PP chains melted and the segregated GNP network collapsed at temperatures above the Tm. Therefore, the incorporation of a segregated network can be an effective option for enhancing the Tm and extending the operating temperature of the polymer composites.Highlights Segregated network induced the remarkable increase in melting temperature. Meanwhile, the segregated network had little effect on decomposition temperature. Segregated composite was efficient strategy for expanding operating temperature.

Simultaneous Manufacture of Magnetic and Locally Conductive Millimeter Scale Bifunctional Devices via Single‐Material Projection‐Based Stereolithography

AbstractThe development of projection‐based stereolithography 3D printing techniques has provided a powerful approach to fabricate millimeter scale functional devices with complex structures. However, the current processes face challenges in frequent switching between multiple materials or processes, resulting in low efficiency and accuracy during the fabrication of bifunctional devices. To address these challenges, chemical deposition is utilized to modify graphene nanoplatelets (GNs) with Fe3O4 magnetic particles and incorporate them into the photosensitive resin, resulting in the development of a novel bifunctional printing material with magnetic and locally conductive properties. Furthermore, the localized conductivity of devices is controlled by an electric‐field‐assisted alignment process of the magnetic GNs (mGNs) during the printing process. Herein, this single‐material projection‐based stereolithography allows for the simultaneous fabrication of magnetic and locally conductive millimeter scale bifunctional devices without switching between multiple materials or processes. A magnetically driven circuit switch and signal coding gear are fabricated as demonstrations. This work significantly improves the efficiency and accuracy of fabricating millimeter scale bifunctional devices, thereby facilitating their application in the fabrication of miniaturized and integrated devices.

Heat transfer inside annular passages: A comparison of non-circular and fully circular passages using eco-friendly graphene nanofluid

This research investigates the thermal performance of an annular passage using eco-friendly nanofluids as substitutes for conventional working fluids. Specifically, the study focuses on the utilization of covalently functionalized Graphene Nanoplatelets (GNPs) dispersed in an aqueous medium, with Gallic acid as the functionalizing agent. Nanofluids were synthesized at different weight concentrations (0.1 wt%, 0.05 wt%, and 0.025 wt%) and exhibited an excellent long-term colloidal stability for 39 days, with a relative concentration of 94.4% at 0.025 wt%. Thermophysical property evaluations revealed significant enhancements of 18.25% and 8.23% in thermal conductivity and viscosity, respectively at 0.1 wt%. The nanofluids exhibited average enhancements of convection heat transfer coefficient evaluations indicating improved thermal performance for GaGNPs/DW nanofluids, with the highest average enhancement of approximately 12.11% achieved at 0.1 wt%. To investigate the impact of different annular geometries, a numerical study (CFD) was conducted. Various inner rod shapes, including circular, rectangular, square, triangular, and pentagonal, were considered. The pentagonal cross-section exhibited the highest average increase in convection heat transfer coefficient at 13.9%, followed by rectangular and triangular shapes. In a numerical case study with different thermal boundary conditions, the circular inner rod shape demonstrated the highest thermal performance at 0.1 wt%.

A Study on the Mechanism and Properties of a Self-Powered H2O2 Electrochemical Sensor Based on a Fuel Cell Configuration with FePc and Graphene Cathode Catalyst Materials.

Conventional electrochemical sensors use voltammetric and amperometric methods with external power supply and modulation systems, which hinder the flexibility and application of the sensors. To avoid the use of an external power system and to minimize the number of electrochemical cell components, a self-powered electrochemical sensor (SPES) for hydrogen peroxide was investigated here. Iron phthalocyanine, an enzyme mimetic material, and Ni were used as a cathode catalyst and an anode material, respectively. The properties of the iron phthalocyanine catalyst modified by graphene nanoplatelets (GNPs) were investigated. Open circuit potential tests demonstrated the feasibility of this system. The GNP-modulated interface helped to solve the problems of aggregation and poor conductivity of iron phthalocyanine and allowed for the achievement of the best analytical characteristics of the self-powered H2O2 sensor with a low detection limit of 0.6 µM and significantly higher sensitivity of 0.198 A/(M·cm2) due to the enhanced electrochemical properties. The SPES demonstrated the best performance at pH 3.0 compared to pH 7.4 and 12.0. The sensor characteristics under the control of external variable load resistances are discussed and the cell showed the highest power density of 65.9 μW/cm2 with a 20 kOhm resistor. The practical applicability of this method was verified by the determination of H2O2 in blood serum.

The influence of graphene nanoplatelet content on the mechanical properties and microstructure of sustainable concrete

The effects of the content of graphene nanoplatelets (GNPs) on the mechanical properties and microstructure of sustainable concrete were investigated. Aqueous solutions were prepared, using a wet-dispersion technique to disperse GNPs in the mixing water. Concrete batches were prepared using different GNP fractions (0.05, 0.1, 0.25, 0.5, 1 and 2% by weight of cement), and their compressive, flexural and tensile strengths were determined at 28 days. Qualitative microstructural analyses were performed using scanning electron microscopy and energy dispersive X-ray analysis. The results obtained were analysed using analysis of variance (Anova), which demonstrated improvements in all strength properties when using GNP filaments regardless of their weight fraction. The batch containing 0.5% GNPs showed the largest strength improvements, with improvements in compressive, flexural and tensile strength properties of 22.6%, 23.9% and 255.4%, respectively. Microstructural analysis showed a good dispersion of nanofilaments inside the concrete matrix through the dispersion technique used in this study. Finally, Anova revealed statistically significant relationships between the GNP content and the compressive, flexural and tensile strengths of the concrete specimens. The results highlight the importance of the GNP content in influencing the concrete's mechanical properties.

Inconel 718 alloy reinforced with nano-sized WC particles and graphene nanoplatelets: Microstructure, wear resistance and electrochemical properties

The coarse columnar grain structure of additively manufactured metals diminishes material performance, hence the transition from columnar grains to equiaxed grains is extensively investigated. The microstructure of composite materials and the properties of Inconel 718 are positively influenced by both nano-sized tungsten carbide (nano-WC) and graphene nanoplatelets (GNPs), which act as reinforcing phases. The study employs directed energy deposition (DED) technology for the fabrication of Nano WC/GNPS-IN718 composite materials. Th emicrostructure, wear resistance, and corrosion resistance properties of both Inconel 718 and its composite materials were systemically investigated. The findings discover the microstructure of the composite material consists of γ/M7C3 phases with precipitation of carbides such as (Nb,Ti)C. Utilizing nano WC and graphene as lubricants, and carbides like (Nb,Ti)C as strengthening phases, the composite material exhibits a grain size refinement of approximately 3.36 % compared to IN718. The grain orientation in the XOY plane predominantly aligns along the <001> direction. The Nano WC/GNPS-IN718 composite material exhibited a 1.264-fold increase in average microhardness compared to the IN718 alloy. Notably, the friction coefficient and wear rate were only 77 % and 18.75 %, respectively, of those observed in the IN718 alloy. Furthermore, the corrosion current density of the Nano WC/GNPS-IN718 composite material was 30.8 % of that observed in IN718, with a polarization resistance 4.08 times higher than that of IN718.

Effect of Torsional Load on Electrical and Mechanical Properties/Behaviour of Stretchable GNP-Ag Conductive Ink

Stretchable conductive inks (SCIs) have gained significant attention in recent years due to their potential applications in flexible and wearable electronics. Graphene nanoplatelet (GNP) hybridization conductive ink is a promising material for stretchable electronics due to its high electrical conductivity and excellent mechanical properties. However, the resistivity of GNP ink on flexible substrates can be affected by various factors, such as the torsion of the substrate. This paper aims to investigate the effect of torsional load in terms of the electrical and mechanical behaviour of hybridization conductive ink between GNP and Ag. The research was carried out on the formulation and performance of GNP hybrids using GNP and silver flakes (Ag). The GNP hybrid ink was printed on a copper substrate using a mesh stencil method and cured at 250 °C for an hour. The resistivity was evaluated at room temperature before and after the torsional tests in terms of electrical characteristics. The finding exposed that the resistivity values for each of the three samples of torsional tests significantly changed after 1000 cycles. Eventually, the resistance value at cycle 5000 rose due to the damaging impact of increasing the number of torsional cycles on the sample. In future work, it is recommended that the evaluation is made under temperature dependence and supported by SEM images.

Production and mechanical characterization of Carbon fiber laminated composites modified by Graphene nano platelets (GnP) for high performance application

Polymeric materials play a pivotal role in diverse high-performance engineering domains, including aerospace, marine, automotive, and defense sectors. Their applications span from essential protective gear to intricate components vital for aircraft missiles, showcasing their versatility and significance in modern technology. The Graphene nano platelets (GnP) have the exceptional properties of a high contact area with the reinforcement material and enhanced synergistic effect, which is highly desired to improve the material performance. The present work describes the production of Carbon fiber laminated composites enhanced by Graphene nano Platelets (GnP) using a cost-effective Hand layup method (HLM). Herein, three different concentrations of GnP at 0.25, 1.0, and 1.75 wt% were used to modify the CFRP laminates. This is primarily performed to examine the viscoelastic and mechanical properties of the proposed GnP/CFRP sample. The findings of mechanical testing reveal that GnP nanofiller addition of 1.00 wt% significantly enhances the tensile and flexural properties by 20.7% and 10.05% respectively in comparison to neat sample. Also, the composites show satisfactory improvement in impact strength by 31.60% and enhanced viscoelastic properties at a 0.25 wt% of GnP loading. The XRD and DMA findings support GnP loading for high performance applications.