Gradual Decrease In Temperature Research Articles

Performance analysis of solar-assisted ground source heat pump in severe cold regions

ABSTRACT Long-term operation of a ground source heat pump (GSHP) in severe cold regions leads to a gradual decrease in subsurface soil temperature, affecting system performance. This paper proposes a solar assisted ground source heat pump (SAGSHP) system consisting of solar photovoltaic thermal (PV/T) and GSHP. Through TRNSYS software, the system was analyzed for 10 years of dynamic simulation in a severe cold region. The results are listed below: (1) The SAGSHP system is capable of effectively lessening the maximal temperature of photovoltaic (PV) modules in Changchun, Shenyang, and Harbin, China, by 21.73%, 13.67%, and 19.10%, respectively. The power generation efficiency of PV modules in these three locations can be maintained at about 22% year-round. (2) After ten years of operation, the coefficients of performance (COP) of the heat pumps have increased by 5.70%, 6.80%, and 5.01%, respectively, relative to the first year, showing good stability. (3) The soil temperatures at all three locations were stabilized during the ten years of operation. This study provides a theoretical basis for devising and installing SAGSHP in severe cold regions.

The effect of local hardware hypothermia on microcirculation in vivo

Purpose. Demonstrate microcirculatory changes and justify the effectiveness of controlled hardware hypothermia in an experiment Material and methods. To study microcirculatory changes during local instrumental hypothermia, everted cheek pouches of 20 hamsters were used. Local hardware hypothermia (LHH) was carried out using the ViThermo device in a mode with a target temperature of 18°C for 60 minutes. Optical coherence tomography (OCT) was performed for intravital monitoring of microcirculatory changes. Results. At an interval of up to 5 min. There was an increase in vascular density to a value of 5.31% and a decrease to 4.76%. At the same time, the peak vascular system density (VSD) was reached at 3 minutes of LHH (5.31%). After 5 minutes of LHH application, and subsequently until 60 minutes, VSD decreased in steps from 0.1% to 0.02% per 1 minute per step. The lowest VSD was achieved at 57-60 minutes of VSD. The temperature of the outer surface of the golden hamster’s cheek pouch decreased slowly and gradually in increments of 1°C to 0.1°C in 1-10 minutes. After 60 minutes of LHH, the temperature of the golden hamster’s cheek pouch began to increase: at step 61 minutes, 19.80°C and 62 minutes, 21.40°C. VSD at 61-62 minutes stabilized to values of 3.62% and 4.43%, respectively. Conclusions. The effect of LHH on the microvascular bed of the hamster buccal mucosa revealed a number of characteristic physiological changes. With a gradual decrease in tissue temperature, a slow decrease and then an increase in vascular VSD was detected on OKT scans. This substantiates the hypothesis that the use of “soft” tissue cooling in the form of PAH is more rational in relation to the microcirculation.

Near-surface ocean temperature and air-sea heat flux observed by a buoy array during summer to autumn in year 2014 in the northern South China Sea

The observational data of the air-sea interface and upper ocean elements from a buoy array deployed in the northern South China Sea from June to November 2014 is analyzed. The COARE 3.0 algorithm was adopted to examine the variability of air-sea heat fluxes and their contributions to near-surface ocean temperature changes. During the observation period, air-sea heat exchange in the northern South China Sea is primarily determined by solar shortwave radiation and latent heat flux, with net heat flux mostly negative, indicating that the ocean predominantly loses heat. In autumn, net heat flux loss significantly increased by an average of 34.4 W/m2, primarily due to enhanced latent heat loss driven by stronger winter monsoon. During typhoon period, net air-sea heat flux was significantly suppressed, mainly due to reduced solar shortwave radiation, with minimal contribution from sensible heat flux. Near-surface ocean temperature exhibited a seasonal cooling trend, averaging 29.7°C in summer and 28.4°C in autumn. The maximum cooling during typhoon reached 3.1°C, with minimal contribution from air-sea heat flux. During the monsoon transition period, weaker winds led to a slight increase in near-surface ocean temperature, with air-sea heat flux contributing 70.2% and 56.3% to this process. During winter monsoon, more uniform water column mixing resulted in a gradual decrease in near-surface ocean temperature, with air-sea heat flux contributing over 60% to this process.

Underwater temperature and pressure monitoring for deep-sea SCUBA divers using optical techniques

The safety of SCUBA divers remains at high risk in deep-sea owing to multiple factors such as dangerous surrounding, rely upon technical equipment necessary for life support, decreased underwater navigation, and communication infrastructure. Gradual decrease and increase in water temperature and pressure corresponding to depth are among the most common problems that cause most of the fatalities in deep-sea diving. Therefore, different gadgets for accurate measurement of vital parameters, reliable navigation, and seamless communication are of prime importance. In this paper, we propose an all-optical technique for local and remote monitoring of underwater temperature and pressure for deep-sea SCUBA divers based on fiber Bragg grating (FBG) sensors and underwater optical communication-single mode fiber (UWOC-SMF) integrated transmission system. The proposed technique is implemented using two FBG temperature and pressure sensors fixed over diver’s suit and UWOC-SMF integrated transmission system for simultaneous local and remote monitoring of underwater temperature and pressure. Remote monitoring of underwater temperature and pressure is achieved at ship station through a remotely operated underwater vehicle (ROV) and UWOC-SMF integrated transmission system by means of shifts in the original Bragg wavelengths of sensors due to temperature and pressure variations. The performance of the sensors is analyzed for pressure and temperature in the range of 0 to 6.4 MPa (≈0 to 655 mH2O) and 40 to −2°C, respectively corresponding to different depths. The results show that the proposed technique can work well in the deep ocean over a range of pressures and temperatures of 0–7 MPa and 40 to −2°C while achieving a temperature sensitivity of 4.3 p.m./°C and a pressure sensitivity of 30.5 p.m./MPa. Clear spectra of reflected signals from FBG sensors at ship station are achieved after signal transmission over UWOC-SMF hybrid link.

Ore-forming process of the Xiaoyuzan gold deposit in the Western Tianshan, Northwest China: Constraints from mineralogy and S isotopes of sulfides

The Xiaoyuzan deposit is a typical intermediate-sulfidation epithermal Au deposit in the Boluokenu metallogenetic belt. The orebodies are hosted by the Lower Carboniferous Dahalajunshan Formation volcanic rocks and controlled by the NW- and NNW-striking faults. The metal minerals present in the ores mainly include pyrite, sphalerite, galena, chalcopyrite, and tetrahedrite. The non-metallic minerals are primarily composed of quartz, calcite, and sericite. Three ore-forming stages are distinguished based on mineral assemblages, wall-rock alteration, and vein crosscutting relationships, including the quartz-pyrite stage (I) with silicification and propylitization, quartz-sulfide stage (II) with phyllic alteration, and quartz-carbonate stage (Ⅲ) with carbonatization. Three different types of pyrite are classified: coarse-grained PyI with cubic from the wall rock, fine-grained PyII with a crystal form of pentagonal dodecahedron in the quartz-sulfide veins, and coarse-grained cubic PyⅢ in the quartz-carbonate veins. The in-situ δ34S value range of sulfides from stage I, stage II and stage Ⅲ are 5.0 ‰ to 5.5 ‰, 4.3 ‰ to 6.5 ‰ and 5.7 ‰ to 6.2 ‰, respectively. The composition of S isotopes indicates that the source of the sulfur is magmatic in origin, with main contribution from the host rock. All the types of pyrite are relatively enriched with Sb, Cu, Ag, Pb, Bi, and As. The composition of pyrite suggests that the Au in the pyrite present as lattice gold (Au+1). The gradual decrease in Co contents from in PyⅠ, PyⅡ to PyⅢ indicates a gradual decrease in temperature during fluid evolution. The contents of trace elements in sphalerite are relatively low, with Fe, Mn, Cd, and Cu being relatively enriched. Using the sphalerite geothermometer (GGIMFis), the calculated temperature falls within the range of 303.0 to 334.3 °C. Pyrite II is characterized by the occurrence of oscillatory zones, suggesting rhythmic changes in fluid physicochemical conditions and compositions. Although coexisting of liquid-rich and vapor-rich aqueous inclusions were locally observed in stage II quartz according to previous studies, the absence of crustiform/colloidal/lattice bladed quartz in the main stage suggests that slight or gentle fluid boiling has occurred. In summary, it is proposed that fluid-rock reactions made great contribution for the precipitation of gold and sulfides in the Xiaoyuzan deposit.

An insight into the co-doping effect of d-d transitions of transition metal ions and hypersensitivity of rare-earth ions in multicomponent glass-system

A multicomponent glass system with composition (70B2O3-22.5Bi2O3-5SeO2-2CuO-0.5Sm2O3) was synthesized via the conventional melt-quench technique. X-ray diffraction analysis confirmed the amorphous nature of this glass. The co-doping of transition and rare-earth metal ions results in the gradual decrease in glass transition temperature and improvement in thermal stability as observed from differential scanning calorimetry. The addition of CuO has increased non-bridging oxygens in multicomponent glass system. The increase in non-bridging oxygens results in a decrease in the optical band gap energy of the glass. Various results reveal that the hypersensitive nature of rare-earth ions has been suppressed by the d-d transition. A decrease in the energy band gap upon co-doping of transition and rare earth ions, suggests its applications in the fields of optoelectronics.

Investigating the influence of Joule-Thomson cooling on hydrate reformation near the wellbore

Hydrate reformation, caused by the Joule-Thomson effect (JTE) during depressurization, poses a major obstacle to efficient gas production. This study examines the impact of the JTE on hydrate reformation near the wellbore during depressurization, focusing on the influences of gas-to-water ratio, depressurization range, and permeability. The results indicate that JTE significantly contributes to a gradual temperature decrease, leading to hydrate reformation. Reformed hydrates, potentially saturating up to 80%, initially appear near the wellbore then move away due to intense depressurization that eroded their inner surface, creating a moving low-permeability barrier that obstructs fluid flow and reduces gas-water production rates. Formations with higher permeability and gas saturation experience intensified JTE, leading to faster temperature drops, shorter hydrate reformation times, and quicker expansion of secondary hydrate bands. The study also evaluates the effectiveness of wellbore heating to mitigate hydrate reformation. Wellbore heating is found to be more effective in low-permeability formations, but only within a 0.5 m radius near the wellbore in high-permeability formations. This research suggests narrower depressurization ranges to prevent hydrate reformation and indicates the limited impact of wellbore heating on enhancing gas production. The findings have significant implications for preventing hydrate reformation near the wellbore and improving hydrate production efficiency.

Finite element analysis of thermal sensitivity of copper nanorods, nanoellipsoids, nanospheres and core-shells for hyperthermia application

Hyperthermia is a cancer treatment strategy that involves raising the temperature of the afflicted tissues without disrupting the surrounding tissues. This study is focused on finite element analysis of copper, nanoellipsoids, nanorods, nanospheres and core-shells for potential hyperthermia application. The temperature of copper nanostructures was elevated using an external source to the desired temperature to destroy the cancerous cell. The COMSOL Multiphysics package was used to calculate how long it would take to achieve the desired temperature using different nanostructures of copper. Thermal sensitivity of the tested nanostructures was checked by putting them in a spherical domain of tissue. It was observed that copper nano-rod attained the highest temperature of 43.3 °C compared to other geometries. It was also found that these geometries attained thermal equilibrium just after 0.5 μs. However, the copper nano-ellipsoid had a higher core volume, which is utilized to determine the thermal sensitivity of the nanostructures. Noble metal (Au) coating was first found to be better than PEG polymer coating for investigating core–shell structures. The Au coating on the surface of the copper core resulted in a gradual decrease in temperature with an increasing volume coverage ratio. These results conclude that copper nanostructures can be suitable candidates for hyperthermia.

Integration of Active Clothing with a Personal Cooling System within the NGIoT Architecture for the Improved Comfort of Construction Workers

Intense physical activity and high ambient temperature cause construction workers to be exposed to an increased risk of overheating, especially in the summer season. Personal cooling systems have great potential to support workers’ thermoregulation and reduce this risk. In particular, solutions based on the thermoelectric effect can provide high cooling effectiveness and ergonomics at the same time. In this paper, a newly developed active clothing solution with flexible thermoelectric modules intended for outdoor activities is presented. The active clothing was subjected to utility tests on a treadmill under laboratory conditions with the participation of potential end users. A comparison of results from cooled and uncooled places indicated a reduction in local skin temperature of as much as 2.7 °C. Moreover, a gradual decrease in temperature in the uncooled place during the experiment was observed. Based on the positive results from this evaluation, the personal cooling system was integrated into active clothing within the ASSIST-IoT NGIoT reference architecture. This allows contextual and personalized adjustment of the cooling power to be provided using AI techniques and, additionally, by using data from a weather station and a smartwatch. Training procedures and models for the AI system are proposed, with special attention paid to the privacy aspect.

Низкотемпературная сверхпластическая деформация никелевого сплава ЭК79 с ультрамелкозернистой структурой смешанного типа

One of the most effective ways to increase the processing plasticity of advanced superalloys (heat-resistant nickel-based alloys) is the formation of an ultrafine-grained (UFG) microstructure in bulk semi-finished products. Such a microstructure is a necessary condition for the manifestation of the structural superplasticity effect in the technological processes of manufacturing products from such superalloys. One of the most promising methods for producing UFG microstructures is thermomechanical treatment (TMT) according to the multiple isothermal forging scheme. It has been shown that the EK79 superalloy after TMT, with a gradual decrease in the processing temperature from 0.88 to 0.62 Ts (where Ts is the strengthening phase dissolution temperature) leads to the transformation of the initial microduplex fine-grained microstructure into a mixed UFG microstructure. Such a mixed UFG microstructure consists of: 1) relatively coarse (inherited from the fine-grain microstructure) particles – γ'-phase with a size of 3.0±0.8 μm; 2) γ-grains, and incoherent γ'-phase particles with a size of 0.3–0.5 μm; 3) strengthening coherent intragranular γ'-phase particles with a size of 0.05–0.1 μm, released upon cooling from the TMT temperature to room temperature. During uniaxial compression tests, the EK79 superalloy with such microstructure, demonstrates low-temperature superplasticity in the temperature range of 800–1000 °C. It has been found that an increase in the deformation temperature up to 1000 °C, leads to the increase of γ-phase grains to micron size. The maintenance of superplastic properties in the presence of relatively coarse incoherent particles in the microstructure of the second phase (γ'-phase) is apparently related to the fact that the deformation is localised in the UFG component.

Algama Gold Ore Cluster (Aldan–Stanovoi Shield): Mineralogy, Formation Conditions, Sources of Ore Matter, and Age of Mineralization

Abstract —The paper presents results of research into the conditions of formation of ores in the poorly studied Algama ore cluster (Bodorono deposit and Dyvok ore occurrence) located at the junction of the Aldan Shield and the Stanovoi area. We have established that Bi and Se minerals (bismuthinite, lillianite, native bismuth, tellurobismuthite, tetradymite, hedleyite, pilsenite, and laitakarite) are present in the ores of the Bodorono deposit. Two successive productive stages of mineral formation have been distinguished: Au–polymetallic and Au–Bi–Te. The corresponding minerals are products of the evolution of a hydrothermal system, during which a gradual decrease in fluid temperature (from 300 to 145 °C) and salinity (from 5 to 1.9 wt.% NaCl equiv.) took place. The fineness of native gold gradually increases from early (~840‰) to late (~940‰) stages and changes in passing from simple sulfides to sulfosalts. The evolution of the ore system is accompanied by a change in the composition of the vapor phase of fluid inclusions from CH4–CO2 to CO2 with an impurity of N2 and CH4. The results of 40Ar/39Ar dating of pre-ore metasomatites point to ore-forming processes at the Bodorono deposit ca. 150 ± 1.8 Ma. Analysis of the isotopic composition of lead in galena shows the leading role of the ancient crustal source of ore matter. The calculated isotopic composition of oxygen (δ18OH2O) in ore-bearing quartz varies from 1.0 to 7.3‰, which corresponds to an aqueous fluid of a mixed source. The Dyvok ore occurrence differs from the Bodorono deposit in the mineral composition of ores and the physicochemical parameters of ore formation. Four mineral stages have been established within the ore occurrence: gold–arsenopyrite–pyrite–quartz, pyrite–chalcopyrite–sphalerite, quartz–boulangerite, and telluride. The telluride stage is represented by hessite, altaite, volynskite, merenskyite, melonite, and rucklidgeite. Gold-bearing mineralization formed from a fluid of medium salinity (0.9–9.2 wt.% NaCl equiv.) with a predominance of CO2 and an impurity of CH4 in the vapor phase at moderate temperatures (310–360 °C). The calculated values of δ34S and δ18O varied from 2.2 to 3.0‰ and from 0.6 to 12.0‰, respectively. The 40Ar/39Ar age of gold mineralization is 124.0 ± 1.5 Ma, which corresponds to the stage of tectonomagmatic activity in the Aldan Shield.

Glass-Containing Matrices Based on Borosilicate Glasses for the Immobilization of Radioactive Wastes

Glass-containing materials are widely considered among the most reliable materials for the immobilization of radioactive waste materials. The present work considers the synthesis of glass–ceramic and glass crystalline composite materials based on borosilicate glasses. The synthesis of glass–ceramic materials was carried out by a gradual temperature decrease, followed by crystallization for several hours. Sintering of crushed samples with crystalline components was carried out as an alternative procedure. Porous glasses were produced from glass melts by quenching. After impregnating the resulting porous materials with aqueous solutions of cesium nitrate, compaction of the glass was carried out to form glass crystalline composites. The thermochemical characteristics of the parent glasses were determined using the differential scanning calorimetry method. The phase composition and structure of the glass-containing materials were determined using X-ray phase analysis, X-ray spectral microanalysis, and Raman spectroscopy.

Experimental and numerical investigations on operation characteristics of seasonal borehole underground thermal energy storage

To investigate operation characteristics of seasonal borehole underground thermal energy storage (SBUTES) with different operational strategies, a model test platform with reduced size was established based on similarity principle. The test results show that the larger the start-stop time ratio, the smaller the average heat exchange rate per unit depth (HERPUD) of borehole, and the lower the energy storage efficiency, but the thermal energy storage and extraction capacity increase. For the time ratio of thermal energy storage to extraction (TROSE), the larger the TROSE, the larger the thermal imbalance rate of energy storage body, which will lead to the gradual increase or decrease of temperature of energy storage body and is not conducive to the operation of energy storage. Compared with the asynchronous mode of storage and extraction, the synchronous mode of storage and extraction can effectively reduce the average temperature of energy storage body and increase the heat exchange efficiency of boreholes during the thermal energy storage. The focused energy storage mode can improve the energy storage efficiency and soil temperature recovery rate, balance the thermal energy storage and extraction capacity, and thus the performance of SBUTES can be optimized. A 3-D CFD model of borehole energy storage was established to further find the influences of borehole layout forms, layout spacing and depths on characteristics of the SBUTES. It can be found that for the energy storage efficiency, the hexagonal layout is the highest, the rectangular layout is the lowest, and the circular layout is slightly higher than the square one. Under the same volume of boreholes group, increasing the spacing of inner boreholes can effectively alleviate thermal interference of inner boreholes during the thermal energy storage, and the heat exchange capacity undertaken by inner boreholes can be improved. But it is not conducive to thermal energy extraction. Although increasing borehole depth can increase thermal energy storage and extraction capacity and system operation efficiency, the increase degree is decreasing with the increase of borehole depth, and the greater the borehole depth, the smaller the influence of borehole depth on characteristics of SBUTES.

Effect of thermal management system parameters on the temperature characteristics of the battery module

In the present inquiry, a novel electric-thermal coupled model is devised to delve into the battery module's temperature distribution characteristics at different ambient temperatures and discharge rates. The accuracy of temperature prediction accuracy is contingent upon the experimental determination of the entropy heat coefficient and convective heat transfer coefficient. In the absence of a thermal management system for the battery module, an escalation in the discharge rate correlates with an increase in the average temperature, average temperature rise, and maximum temperature difference, while a decline in the initial ambient temperature relates to a decrease in these values. Under typical vehicle driving cycle conditions, the average temperature curves show peaks before the end of the cycle. The wider speed range, longer testing time, and reduced regularity of the driving cycles cause both the average temperature and maximum temperature difference to increase. Further research is done into the effects of coolant flow rate and temperature, and contact thermal resistance on the efficiency of thermal management systems. Gradual decrease in the average temperature transpires as the coolant flow rate increases, but excessively high flow rates engender a larger maximum temperature difference. As the coolant temperature decreases, both the average and maximum temperature difference decrease, but temperature uniformity is worsened. The average and maximum temperature difference generally rise when the thermal contact resistance increases, and a low thermal contact resistance leads to a more uniform low-temperature distribution.

The Mineral Chemistry of Magnetite and Its Constraints on Ore-Forming Mechanism in the Sandaozhuang Skarn-Type W-Mo Deposit in East Qinling, China

The Sandaozhuang super-large W-Mo deposit is located in the southern margin of the North China Craton, within the well-known East Qinling Mo mineralization belt, and is one of the typical skarn-type W-Mo deposits in China. Based on EMPA and LA-ICP-MS analyses, major and trace elements were presented, and the mineral chemistry of magnetite at various mineralization stages was discussed. Combining field observations, petrography, and geochemical characteristics, the magnetite at the Sandaozhuang deposit can be classified into three types, namely early-magmatic-stage high-temperature magnetite (Mag1), potassic-alteration-stage magnetite (Mag2), and retrograde-alteration-stage magnetite (Mag3). The Mag1 and Mag2 magnetites primarily occurred in granites in association with potassium (K) feldspar and biotite, whereas Mag3 is associated with metallic sulfide minerals that occurred mainly in vein-like structures in skarn. The three magnetites Mag1, Mag2, and Mag3 can be distinguished as having magmatic, magmatic–hydrothermal transition, and hydrothermal origins, respectively. All three types of magnetite exhibit a depletion of high-field-strength elements (HFSEs) such as Zr, Hf, Nb, Ta, and Ti, and large-ion lithophile elements (LILEs) including Rb, K, Ba, and Sr, compared to the mean continental crust composition. Conversely, they are enriched in elements such as Sn, Mo, V, Cr, Zn, and Ga. Mag3 showed no significant depletion of Co, Ni, Cu, and Bi, indicating that the influence of coexisting sulfides on the composition of magnetite at the Sandaozhuang deposit is limited. There are systematic variations in major and trace elements from Mag1 to Mag3, which exhibited similar patterns in trace element spider and rare earth element diagrams, and Y/Ho ratio, indicating a consistent source for the three types of magnetite. The changes in V and Cr contents and (Ti + V) vs. (Al + Mn) diagram of magnetite at the Sandaozhuang deposit reflected the evolution of ore-forming fluids with an initial increase in oxygen fugacity and a subsequent decrease, as well as a gradual decrease in temperature during skarn mineralization. The early high-temperature and high-oxygen-fugacity magmatic fluids became W and Mo enriched by hydrothermal fluid interaction. The rapid change in fluid properties during the retrograde alteration stage led to the precipitation of scheelite and molybdenite.

Linear water column stratification and euphotic depth determine the number of phytoplankton taxa that create biomass peaks in a hypertrophic oxbow lake

The mixing regime, the spatial distribution of nutrients and light determine the distribution of phytoplankton in lakes to a large extent. Linear stratification is a unique phenomenon among the various forms the lakes can stratify, representing a continuous and gradual water temperature decrease with depth. Here, we aimed to understand how mixing, nutrient and light affect the vertical distribution of phytoplankton in the case of linear water column stratification using the taxonomic and functional group approaches. We sampled phytoplankton and physical and chemical variables in the Malom-Tisza oxbow lake (Hungary) monthly from May to September between 2007 and 2009. Our results revealed that multiple biomass peaks of taxa belonging to distinct phytoplankton functional groups could develop in response to the strong linear stratification of the water column. Although several different species represented the functional groups, only one or two species developed the peaks. Light irradiance did not influence the vertical distribution of biomass and taxonomic richness of phytoplankton, but the depth of the euphotic zone determined the number of distinct biomass peaks. We found that diversity indices could not reflect the phytoplankton compositional differences well in the case of linear stratification, but similarity indices calculated among water column layers.

Study on the thermal release characteristics and the correlation transformation mechanism of microscopic active groups of oxidized coal combustion in a deep mined-out area

With the normalization of deep mining, the risk of residual coal spontaneous combustion (CSC) in deeply mined areas has gradually increased. To investigate the thermal characteristics and microgroup transformation mechanisms during the secondary oxidation of deep-well oxidized coal, a deep-well oxidation process was simulated in a synchronous thermal analyzer, and the thermal parameters of the oxidized coal were tested. The correlated transformation pathways of microscopic active groups was studied by electron paramagnetic resonance (EPR) and in situ diffuse reflectance (in situ FTIR) experiments during the reoxidation of oxidized coal. The results showed that with increasing deep-well ambient temperature and oxidation temperature, the characteristic temperature of coal gradually decreased, exothermic heat release gradually increased, and active aliphatic structures and -OH, -CHO and other active functional groups gradually accumulated and became distributed more uniformly. When the thermal conditions and oxidation temperature were very high (> 160 °C), the active free radicals in the oxidized coal were rapidly consumed, resulting in a gradual decrease in the characteristic temperature and heat release during the secondary oxidation process, while the contents of peroxy and carboxyl groups continued to increase. In the slow oxidation stage of oxidized coal, methyl groups were mainly transformed with hydroxyl and peroxide groups (r > 0.96), and the associated oxidative consumption of -CHO and -COOH mainly occurred in the rapid oxidation stage (r > 0.99). Geminal diols and peroxy groups are important intermediates in the coal–oxygen composite reaction process. With an increase in the deep-well temperature and initial oxidation temperature, the reoxidation tendency and heat release capacity of residual coal in the goaf gradually increased, and the risk of CSC intensified. The research results provide a theoretical reference for the prevention and control of coal fires in deep mines and play an important role in guiding environmental management and gas emissions reduction measures in mining areas.

In Situ Study of Peritectic Couple Growth Under Purely Diffusive Conditions

Herein, in a microgravity campaign onboard the International Space Station, peritectic coupled growth (PCG) is studied by solidifying alloys of the peritectic transparent organic system TRIS–NPG under purely diffusive conditions. The experiment reveals that the formation of PCG begins with coagulated lateral bands comprising the peritectic phase at temperatures below the peritectic one. After reaching the growth front of the pro-peritectic phase, growth competition between both solid phases occurs such that the patches of the pro-peritectic phase, lamellae, and fibers/rods grow in the stated order, coupled with the peritectic phase. As the entire solidification process occurs during the initial transient stage, the diffusion coupling between the two solid phases is weak. With the gradual decrease in the interface temperature during the initial transient, the necessary growth conditions for the pro-peritectic phase diminish. Additionally, different concentrations along the inclined solid/liquid interface favor the peritectic phase at the rear window and the pro-peritectic phase at the front window. The corresponding PCG lasts 19 hours while the recoil of the inclined interface continues to a temperature level that makes alterations of the ‘effective’ TRIS–NPG phase diagram necessary.

Heterocene Catalysts and Reaction Temperature Gradient in Dec-1-ene Oligomerization for the Production of Low Viscosity PAO Base Stocks

Hydrogenated oligomers of higher α-olefins (primarily, dec-1-ene) with uniform structure represent high-quality poly-α-olefin oil (PAO) base stocks. High yields of lightweight dec-1-ene oligomers (DPn = 3–4) can be achieved by using 5,10-dihydroindeno[1,2-b]indole-based zirconium ansa-complexes, “heterocenes”. Unusual catalytic behavior of heterocenes served as a starting point for the present study, during which new, more synthetically available and active heterocene precatalysts were synthesized, and a novel oligomerization method, based on a reaction temperature gradient, was developed. A gradual decrease of the oligomerization temperature as dec-1-ene was consumed resulted in decreased dimer formation (down to 10%) and increased oligomer yields (up to 84%). After hydrogenation, low- and medium-viscosity PAO base oils with uniform structure and high viscosity indexes were obtained.

P-T parameters of metamorphism of the rocks of the differentiated body of the Misaelga complex (western slope of the Southern Urals)

The article presents materials on the P-T parameters of metamorphism of the rocks of the differentiated body of the Misaelga complex. Based on the study of metamorphogenic minerals and mineral associations: amphibole, amphibole-plagioclase, amphibole-garnet, epidote-garnet, muscovite, chlorite, ilmenite-titanomagnetite, a gradual decrease in temperature and pressure was established from the final stages of the magmatic stage of formation of rocks of the Misaelga complex to the beginning of the metamorphogenic stage.
 It is shown that the process of amphibolization begins immediately when the temperature of the residual melt drops by ~100°С (from 800°С to 700°С), which indicates the autometamorphic character of rock alteration. At the same time, the decomposition of the solid solution in titanomagnetite and ilmenite begins (766–588°С). Further changes include alteration (albitization) of plagioclase (550–>400°С), sericitization (~ 300°С) and chloritization (333–157°С).
 The association of minerals with garnet, distributed in a narrow interval of the section at a depth of 341.5 m with a horizon thickness of no more than 2–2.5 m, is a zone in which dynamothermal metamorphism manifested itself, due to fluid working out of the substrate of the Taratash complex in shear deformation zones, identified in the interval 1400–1200 Ma. The P-T parameters of dynamothermal metamorphism, determined by the garnet-epidote association, correspond to 550–580°С at a pressure of 2 kbar, and according to the garnet-amphibole geobarometer – 300–400°С. At the same time, it should be emphasized that these associations characterize the regressive stage of metamorphism.