Composition Gradient Research Articles

3D Hydrodynamic Simulations of Massive Main-sequence Stars. III. The Effect of Radiation Pressure and Diffusion Leading to a 1D Equilibrium Model

We present 3D hydrodynamical simulations of core convection with a stably stratified envelope of a 25 M ⊙ star in the early phase of the main sequence. We use the explicit gas-dynamics code PPMstar, which tracks two fluids and includes radiation pressure and radiative diffusion. Multiple series of simulations with different luminosities and radiative thermal conductivities are presented. The entrainment rate at the convective boundary, internal gravity waves in and above the boundary region, and the approach to dynamical equilibrium shortly after a few convective turnovers are investigated. We perform very long simulations on 8963 grids accelerated by luminosity boost factors of 1000, 3162 and 10,000. In these simulations, the growing penetrative convection reduces the initially unrealistically large entrainment. This reduction is enabled by a spatial separation that develops between the entropy gradient and the composition gradient. The convective boundary moves outward much more slowly at the end of these simulations. Finally, we present a 1D method to predict the extent and character of penetrative convection beyond the Schwarzschild boundary. The 1D model is based on a spherically averaged reduced entropy equation that takes the turbulent dissipation as input from the 3D hydrodynamic simulation and takes buoyancy and all other energy sources and sinks into account. This 1D method is intended to be ultimately deployed in 1D stellar evolution calculations and is based on the properties of penetrative convection in our simulations carried forward through the local thermal timescale.

Elevational patterns of species richness and phylogenetic diversity in a Mediterranean island

Understanding the abiotic factors influencing biodiversity patterns on Earth is a crucial task for conservation scientists. At the regional level, meso-climate factors, primarily associated with elevational gradients, are of great importance. However, disentangling these factors can be challenging due to the influence of other variables, such as geological substrata. To address this issue and better understand elevational gradients, it is essential to study geologically homogeneous terrains, particularly in Mediterranean islands where such research is lacking. In this study, we investigated the distribution of plant species richness along the elevational gradient of the Limbara massif, which consists predominantly of granite rocks and ranks as the third-highest peak in Sardinia at 1,359 meters a.s.l. We employed generalized linear models to analyze richness patterns, considering various factors, including all plant species, functional species groups categorized by Raunkiær life forms, chorological groups of species, alien species and phylogenetic diversity. Our findings revealed a hump-shaped model of species richness along the elevational gradient, with lower elevations exhibiting the highest species richness. Additionally, endemic species richness increased with higher elevations, while alien species were predominantly found at lower elevations. These results indicate that the Limbara massif possesses a significant elevational gradient in species composition, likely reflecting a unique plant evolutionary history. Furthermore, we emphasize the importance of published floras as valuable sources of biodiversity data for such studies.

Biomimetic Structural Hydrogels Reinforced by Gradient Twisted Plywood Architectures.

Naturally structural hydrogels such as crustacean exoskeletons possess a remarkable combination of seemingly contradictory properties: high strength, modulus, and toughness coupled with exceptional fatigue resistance, owing to their hierarchical structures across multiple length scales. However, replicating these unique mechanical properties in synthetic hydrogels remains a significant challenge. This work presents a synergistic approach for constructing hierarchical structural hydrogels by employing cholesteric liquid crystal self-assembly followed by nanocrystalline engineering. The resulting hydrogels exhibit a long-range ordered gradient twisted plywood structure with high crystallinity to mimic the design of crustacean exoskeletons. Consequently, the structural hydrogels achieve an unprecedented combination of ultrahigh strength (46±3MPa), modulus (496±25MPa), and toughness (170±14MJ m-3), together with recorded high fatigue threshold (32.5kJ m-2) and superior impact resistance (48±2kJ m-1). Additionally, through controlling geometry and compositional gradients of the hierarchical structures, a programmable shape morphing process allows for the fabrication of complex 3D hydrogels. This study not only offers valuable insights into advanced design strategies applicable to a broad range of promising hierarchical materials, but also pave the ways for load-bearing applications in tissue engineering, wearable devices, and soft robotics.

Ultralong Compositional Gradient Perovskite Nanowires Fabricated by Source-Limiting Anion Exchange.

Anion exchange in halide perovskites offers prospective approaches to band gap engineering for miniaturized and integrated optoelectronic devices. However, the band engineering at the nanoscale is uncontrollable due to the rapid and random exchange nature in the liquid or gas phase. Here, we report a source-limiting mechanism in solid-state anion exchange between low-dimensional perovskites, which readily gives access to ultralong compositional gradient nanowires (NWs) with lengths of up to 100 μm. The exchanged NWs remain single-crystalline with intact morphology, while the halogen content exhibits an apparent gradient distribution, leading to a tapered energy band profile along a NW. In the dynamic study of anion behavior, it is shown that the spatial stoichiometric composition can be precisely tuned following Fick's law of diffusion. In addition, self-powered, spectrally resolved photodetectors incorporating multiple detection units within a single gradient NW are demonstrated. This work provides a feasible strategy for the realization of perovskite-based ultracompact optoelectronics, imaging sensors, and other miniaturized semiconductor devices.

The invasion of Japanese hop (Humulus japonicus) in a restored floodplain forest

Abstract Japanese hop (Humulus japonicus Sieb. & Zucc.) is an emerging invasive plant that has been observed to invade and spread throughout wetlands. As an annual vine, H. japonicus can smother native vegetation, forming dense stands and reducing biodiversity. At a restored floodplain forest in Joslin, Illinois, formerly used as an experimental site to test the effectiveness of different reforestation methods, H. japonicus has invaded stands of the previously dominant invasive, reed canarygrass (Phalaris arundinacea L.). We conducted an observational field study to examine the spatio-temporal dynamics of H. japonicus invasion relative to gradients in canopy cover and species composition. Ten transects, with half the transect extending into and half extending beyond H. japonicus patches, were established in October 2022. Seven quadrats per transect were surveyed for vegetation cover and canopy cover in October 2022, June 2023, and October 2023. Transects were evenly split between forested and open areas based on the reforestation treatments. H. japonicus cover significantly increased from October 2022 to October 2023, which has resulted in a slight decrease and replacement of P. arundinacea across the site. Shade reduced H. japonicus cover, indicating its preference for sunlit conditions. Species richness was higher in forested transects compared to open ones, most likely due to the absence of both P. arundinacea and H. japonicus in shaded transects. Along transects, quadrats that had been invaded by H. japonicus differed in species composition from quadrats that had not been invaded in both October 2022 and October 2023. H. japonicus cover was much lower in June than October, suggesting that temporal niche partitioning may allow P. arundinacea to persist, and indicating that monitoring for H. japonicus should occur late in the growing season. Both invasive species are shade intolerant, suggesting that planting fast-growing trees should be an effective long-term solution for controlling invasion.

Hybrid additive manufacturing of ceramic/aluminum-titanium gradient composites via arc and laser cladding eutectic pools

ABSTRACT There is a great deal of interest in improving the efficiency of arc-directed energy deposition (Arc-DED) of aluminium matrix composites and the uniform introduction of reinforcing particles. In this work, ceramic/aluminum-titanium gradient composites were manufactured by hybrid additive manufacturing with arc and laser cladding eutectic pools. The results show that the laser cladding powder feed method can have a higher powder capture rate compared to bypass feeding. Coupling the laser and powder changed the pulsed base-arc characteristics and increased the peak arc length. After the addition of the powder mixture, the aluminium matrix formed an Al3Ti reinforced phase, which evolved from needles to rods as the amount of powder increased. As the content of ceramic particles and the Al3Ti phase increased, the average hardness of the AMC components increased from 55.5–126 HV0.1 and the wear rate decreased from 6.16 × 10−3–1.25 × 10.−3 mm3·N−1·m−1.

Advancements in Wire Arc Additive Manufacturing of Functionally Graded Materials: Optimizing Compositional Gradients and Mechanical Performance: An Overview

Advancements in Wire Arc Additive Manufacturing of Functionally Graded Materials: Optimizing Compositional Gradients and Mechanical Performance: An Overview

Correction: Botanical composition gradients in silvopastoral systems on temperate native grasslands of Uruguay

Correction: Botanical composition gradients in silvopastoral systems on temperate native grasslands of Uruguay

Multi-Gradient Bone-Like Nanocomposites Induced by Strain Distribution.

The heterogeneity of bones is elegantly adapted to the local strain environment, which is critical for maintaining mechanical functions. Such an adaptation enables the strong correlation between strain distributions and multiple gradients, underlying a promising pathway for creating complex gradient structures. However, this potential remains largely unexplored for the synthesis of functional gradient materials. In this work, heterogeneous bone-like nanocomposites with complex structural and compositional gradients comparable to bones are synthesized by inducing strain distributions within the polymer matrix containing amorphous calcium phosphate (ACP). Uniaxial stretching of composite films exerts the highest strain in the center, which ceases gradually toward the sides, resulting in the gradual decrease of polymer alignment and crystallinity. Simultaneously, the center with high orientation traps most ACP during stretching due to the nanoconfinement effect, which in turn promotes the formation of aligned nanofibrous structures. The sides experiencing the least strain have the smallest amounts of ACP, characteristic of porous architectures. Further crystallization of ACP produces oriented apatite nanorods in the center with a larger crystalline/amorphous ratio than the sides because of template-induced crystallization. The combination of structural and compositional gradients leads to gradient mechanical properties, and the gradient span and magnitude correlate nicely with strain distributions. Accompanying bone-like mechanical gradients, the center is less adhesive and self-healable than the sides, which allows a better recovery after a complete cutting. Our work may represent a general strategy for the synthesis of biomimetic materials with complex gradients thanks to the ubiquitous presence of strain distributions in load-bearing structures.

Shaping the mechanical properties of a gelatin hydrogel interface via amination.

Injuries to musculoskeletal interfaces, such as the tendon-to-bone insertion of the rotator cuff, present significant physiological and clinical challenges for repair due to complex gradients of structure, composition, and cellularity. Advances in interface tissue engineering require stratified biomaterials able to both provide local instructive signals to support multiple tissue phenotypes while also reducing the risk of strain concentrations and failure at the transition between dissimilar materials. Here, we describe adaptation of a thiolated gelatin (Gel-SH) hydrogel via selective amination of carboxylic acid subunits on the gelatin backbone. The magnitude and kinetics of HRP-mediated primary crosslinking and carbodiimide-mediated secondary crosslinking reactions can be tuned through amination and thiolation of carboxylic acid subunits on the gelatin backbone. We also show that a stratified biomaterial comprised of mineralized (bone-mimetic) and non-mineralized (tendon-mimetic) collagen scaffold compartments linked by an aminated Gel-SH hydrogel demonstrate improved mechanical performance and reduced strain concentrations. Together, these results highlight significant mechanical advantages that can be derived from modifying the gelatin macromer via controlled amination and thiolation and suggest an avenue for tuning the mechanical performance of hydrogel interfaces within stratified biomaterials.

Bio‐Based Gradient Composites for 3D/4D Printing With Enhanced Mechanical, Shape Memory, and Flame‐Retardant Properties

Bio‐Based Gradient Composites for 3D/4D Printing With Enhanced Mechanical, Shape Memory, and Flame‐Retardant Properties

High-temperature oxidation resistance and wear properties of functionally graded CrHfNbTaTiN high-entropy nitride coating on Ti alloy

High-entropy nitrides have emerged as promising alternatives to traditional protective coatings due to their excellent comprehensive properties. However, there is still a long-standing technical challenge in the design and manufacture of hard and high-temperature stable high-entropy nitride coatings. This study utilized first-principles calculations to evaluate the thermodynamic stability between high-entropy nitrides and corresponding high-entropy metals, as well as titanium alloy substrates, confirming the rationality of the structural design of the functional gradient high-entropy ceramic coating. Subsequently, a double-glow plasma surface alloying technique were conducted to prepare a CrHfNbTaTiN functional gradient high-entropy ceramic coating on titanium alloy, followed by high-temperature cyclic oxidation experiments and high-temperature ball-on-disk wear tests. The research demonstrates that the gradient composition coating exhibits strong interfacial bonding, with an adhesion strength of around 40 N. It maintains excellent oxidation resistance in environments below 700 °C and displays good high-temperature wear resistance. This study contributes to providing insights and guidance for the further development of high-temperature, high-hardness, and wear-resistant materials.

Tensile Properties and Coefficient of Thermal Expansion of Laser Powder Bed Fusion Fabricated IN718‐YSZ Compositionally Graded Composite

The microstructure, tensile properties, and thermal expansion characteristics of a laser powder bed fusion (LPBF) manufactured compositionally graded composite with 0.5–8 wt% yttria‐stabilized zirconia (YSZ) reinforced Inconel 718 are investigated. Along the composition gradient, which is perpendicular to the build direction, in all cross sections, the YSZ segregates at the melt‐pool boundaries and the IN718 matrix has randomly oriented equiaxed grains. Cross sections with >2 wt% YSZ contain significant porosity (>2%) and solidification cracks, which reduces their strength and ductility significantly. In the section with 1.5 wt% YSZ, the YS, UTS, and ductility are 819 ± 30, 1008 ± 40, and 7.4 ± 0.4 MPa, which matches well with that of LPBF fabricated YSZ‐free IN718. Dilatometry measurements on sections with 0.5–1.5 wt% YSZ in the temperature range of 25–1200 °C indicate that their coefficient of thermal expansion (CTE) is intermediate to that of IN718 and YSZ. Finally, the variations in CTE with temperature are discussed in detail by considering the microstructural evolution in the composite with changes in temperature.

Time, temperature and concentration resolved Yb3+ luminescence study in co-sputtered Cu2-xGaxS2 (0.1 < x < 1.6) thin films with a Cu–Ga composition gradient

The broad class of Cu(Al,Ga,In) (S,Se,Te)2 solar absorber materials when doped with Yb3+ are interesting for thin film based luminescent solar concentrator (LSC's) application. In this work the strong and broad absorption properties of co-sputtered CuGaS2 (CGS) thin films combined with the luminescent properties of Yb are reported. Energy-dispersive x-ray spectroscopy (EDS), x-ray diffraction, transmission, excitation, and temperature dependent emission as well as radiative lifetime measurements are performed on thin films with varying Cu:Ga ratios and Yb3+ concentrations. It is found that Yb3+ emission can be broadly sensitized by the host in the range of 200–600 nm. A lower Cu:Ga ratio, crystallinity and post annealing in air provides a positive impact on the sensitization of Yb3+ emission. The temperature dependent time integrated decay curves show a clear thermal energy barrier of about 0.2 eV. Because the exponential tail, with a lifetime of 110 μs, is constant with temperature, we conclude that the barrier is connected to the thermal release of electrons trapped at the Yb2+ ground state. The low energy transfer efficiency from the host to the Yb dopant is attributed to efficient non-radiative electron-hole pair recombination. The prospects and design criteria of Cu(Al,Ga,In) (S,Se,Te)2 solar absorber materials for LSC applications is the further subject of the discussion.

Investigation of the nonlinear dynamics of thin sandwich shells composed of functionally graded materials with double curvature in thermal environments

Double curvature structures play a crucial role as load-bearing components across various engineering fields. Functionally graded materials, blending metals and ceramics, boast superior material characteristics, fueling their expanding applications. This study pioneers the non-linear dynamic analysis of sandwich shells that feature functional gradient compositions in thermal settings. We assume that both the upper and lower shells of these double curvature structures are crafted from functionally graded materials, with a ceramic core. This variation in material exhibits a ceramic layer on the inner surface and a metallic layer on the outer surface, showing properties that vary along the shell thickness in a power-law gradient. Non-linear dynamic equations are derived using third-order shear theory, encompassing geometric non-linearity and shear deformation. Employing the Galerkin method, we discretize the equations of motion into a non-linear dynamic system with five degrees of freedom, and subsequently give an analytical expression for the nonlinear naturalfrequency by means of multiscale analysis. Our discussion examines the impacts of structural parameters, porosity volume fraction, volume fraction index, and temperature differences on the non-linear/linear frequency ratio of doubly curved sandwich shells. Calculations reveal a sharp rise followed by a rapid decline in the non-linear/linear frequency ratio with increasing structural aspect ratio b/a. Conversely, it decreases with increasing thickness-to-length and radius-to-length ratios, with temperature differences initially reducing and later increasing it. These findings offer practical insights for designing functional gradient double curvature sandwich shells.

Influence of climate, weather and floral associations on pollinator community composition across an elevational gradient

Insect pollinators, which are ectothermic, are especially sensitive to abiotic conditions, which often drive predictable patterns of pollinator species turnover along environmental gradients. However, pollinator activity is also reliant on suitable biotic conditions, such as the presence of host plants. High‐elevation environments provide a useful setting to examine the relative contribution of abiotic and biotic factors in shaping species interactions as they are often characterised by strong environmental gradients over short geographic distances. Here, we examined pollination interaction networks across an elevational gradient from 930–2000 m a.s.l. in southern Australia, to determine the underlying patterns of pollinator activity and their interactions with flowers. Interaction frequency of Diptera increased at high elevations, while interaction frequency of Hymenoptera and Coleoptera decreased. We provide evidence that this elevational pattern of activity is partly driven by floral associations, with interactions dominated by Hymenoptera‐attracting plant families at lower elevations (Proteaceae, Fabaceae) and a Diptera‐attracting family at high elevation (Asteraceae). Pollinator activity was also influenced by weather conditions, with reduced activity for all three orders at lower temperatures, and Diptera active across the broadest range of temperature, humidity and wind conditions. We suggest that changes across elevation gradients in pollinator community composition are driven by both direct responses to abiotic conditions such as temperature, as well as the elevational distribution patterns of associated flowering plants. Despite these distinct shifts in composition of the pollinator assemblage with elevation, pollination network structure was stable across the elevational gradient, with moderate levels of specialisation and low levels of connectance and nestedness present across the gradient. By considering both abiotic conditions and biotic processes, our results provide insight for predicting the impacts of upslope vegetation shifts on pollinator communities in the face of climate change.

Stand composition and development stage affect fuel characteristics of quaking aspen forests in UT, USA

In western North America, quaking aspen stands (Populus tremuloides Michx.) have predominantly been described as low flammability, “fireproof” forests, but the specific relationship between aspen stand composition, fuel characteristics, and potential fire behavior is not fully understood. We investigated surface and canopy fuel characteristics in 80 aspen stands in Utah, U.S. that spanned gradients of tree species composition from aspen to conifer dominance and stand development from early to late stages. We quantified fuel type and load, measured fuel moisture content in representative stands across two summer seasons, and modeled flame lengths in each stand. Fuel type and load varied greatly across stands, though late development, conifer-dominated stands had significantly higher (~2-5 times) fine dead woody and litter load and significantly lower (~2-5 times) live understory herbaceous load compared to pure aspen stands. Fuel moisture content did not vary by stand type. Modeled flame lengths were lowest in pure aspen stands, and flame lengths increased linearly with decreasing aspen composition, suggesting that potential surface fire behavior increases as a seral aspen stand progresses through succession to conifer dominance.

Improving photoelectric characteristics of GaN-based green laser diodes by inserting electron blocking layer with gradient Al composition

This paper proposes four new gradient composition electron blocking layer (EBL) structures to enhance the photoelectric performance of GaN-based green laser diodes (LDs). The optical and electrical properties of new structure LDs are theoretically analyzed by LASTIP. It is observed that the implementation of a gradient composition EBL structure increases the effective barrier height for electrons, thereby better inhibiting the electron current overflow from the active region. In addition, the optical field leakage is effectively suppressed, lower threshold current and higher output power are obtained. The four different new structures have obvious differences in the improvement of the hole current injection and slope efficiency of multiple quantum well (MQW) LDs, and the underlying reasons for these phenomena are explored. Simulation results indicate that adopting a gradually descending Al component EBL structure yields optimal improvements in the photoelectric performance of LDs.

Evaluating the feasibility of using plant‐specific metabarcoding to assess forest types from soil eDNA

AbstractQuestionsAn essential aspect of variation in natural systems is that species respond to complex environmental gradients. Recognizing plant composition gradients associated with abiotic factors (ecoclines) can be foundational for defining habitat types, which, in turn, helps map natural variation. Typically, ecoclinal structures are assessed through visual evaluation of above‐ground vegetation and analysis of covarying abiotic factors. However, the correlation between ecological structures detected by soil eDNA plant assessments and those identified by visual assessment remains largely unexplored.LocationHvaler archipelago, southern Norway.MethodsPlant diversity assessments were conducted using metabarcoding of the trnL (UUA) intron p6 loop and ITS2 from 31 soil samples collected across six forest types. These forest types span gradients related to drought risk and calcium richness.ResultsThe barcode amplicons identified 70 plant taxa, primarily vascular plants (67), with most assigned to the species level (59), representing common forest taxa across the sites. Comparisons between soil eDNA compositions and theoretical forest‐type compositions showed a low to medium correspondence (26% to 76%) between the two. Ordinations of soil eDNA compositions revealed two axes without clear ecological interpretation and correlated poorly with the calcium–richness gradient previously identified by visual assessments.ConclusionsOverall, our results emphasize the necessity for comprehensive sequence reference libraries to conduct thorough plant biodiversity assessments. They also highlight the potential of soil eDNA to assess plant composition, which can aid in ecosystem mapping.

Features of the defect structure of a lithium-gradient nonlinear optical single crystal LiNbO3 and their manifestation in the Raman spectra

LiNbO3 crystal with a lithium composition gradient of Li/Nb = 0.8 wt%/cm (Li0.97..1.01Nb1.03..0.99O3) were obtained. A monotonic change in the edge of the UV absorption edge is observed when scanning the surface of the gradient crystal along the growth direction. Raman spectra from different areas of studied crystal were analyzed in a wide frequency range, which includes the region of fundamental vibrations of the crystal lattice (100–900 cm−1) and the region of overtone processes (900–3000 cm−1). A compositionally homogeneous, congruent LiNbO3 crystal was used as a comparison sample. It was found that in the spectra obtained from different parts of the gradient crystal, there is a significant scatter in the frequency values of the lines corresponding to the fundamental vibrations of the crystal lattice, but at the same time, the number of lines corresponding to the fundamental vibrations of the lattice for the gradient and compositionally homogeneous LiNbO3 crystals is the same. Moreover, in the spectrum of a gradient crystal in the region of overtone processes of fundamental vibrations, significantly more lines (35 lines) are observed than in the spectrum of compositionally homogeneous crystals (15 lines). The data obtained show that the state of the defect structure of compositionally homogeneous crystals and gradient LiNbO3 crystal is significantly different. The discovered differences between the defective structure of a gradient crystal and the defective structure of a compositionally homogeneous crystal may be the reason for compensation (damping) of distortions during nonlinear optical conversion of laser radiation by a gradient crystal due to the uneven temperature distribution along the length of the crystal. In compositionally homogeneous crystals, such temperature distortions significantly limit the efficiency of nonlinear optical conversion.