Ultralight and flexible aerogel sensors have garnered significant interest, yet challenges persist in developing their high elasticity and exceptional piezoresistive properties. In this work, laminated porous composite aerogels have been successfully prepared by a composite of sodium alginate (SA) and antimony-doped SnO2 coated titanium dioxide whiskers (ATO@TiO2) via directional freezing technique. The resulting SA and ATO@TiO2 (SAT) aerogels with laminated porous structure demonstrate lightweight with low-density (0.06 g·cm−3), good compressive properties, superplastic, and conductive properties. The incorporation of small amounts of rod-like ATO@TiO2 whiskers into SAT aerogels not only enhances its electrical conductivity and thermal insulation, but also imparts a light-colored appearance to the aerogel. The assembled SAT aerogel sensors exhibit high sensitivity within 1.0 kPa (225 kPa−1, 17.86 kPa−1) and maintains excellent fatigue resistance even over 1000 cycles. The temperature-responsive properties of SAT aerogel sensors presented superior thermal insulation properties, and it can operate properly even at a high temperature of 100 °C. More importantly, SAT piezoresistive sensors facilitated real-time monitoring and human-computer interactive activities related to human movement and health, showcasing significant potential in diverse fields.
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