Gold Orebodies Research Articles

Advanced soil-gas geochemical exploration methods for orogenic gold deposits: A case study of Chalapu deposit, Xizang

Orogenic gold deposits play a significant role in the world’s gold reserves, and their distinctive characteristics pose challenges for exploration. The low sulfide content and narrow, fault-controlled sulfide-quartz veins hinder the use of traditional mineral exploration methods to locate deeply buried ore bodies, particularly in regolith-covered areas. Enhanced methods are required to detect deposits at greater depths. Soil gas composition shows promising potential for mineral exploration by conveying information about sulfur-rich and carbon-rich gases related to deep-seated mineralization into surface soils. However, the prospects of this method for gold deposits remain uncertain. In this study, a novel method was introduced to perform an integrated H2S, SO2, CH4, and CO2 soil-gas geochemical survey on gold ore bodies of different scales at the Chalapu deposit in Tibet. The results unveiled notable gas geochemical anomalies of H2S, SO2, CH4, and CO2 above the multi-layered or thick gold ore bodies. For instance, on exploration line 16 at point A1607, H2S reached the regional maximum value of 1.064 ppm, coinciding with the surface exposure of the thickest gold ore body, measuring 19.81 m. While the presence of CH4 and CO2 anomalies alone may not signify potential mineralized zones, the combined presence of anomalous H2S and SO2 values along with CH4 and CO2 concentrations appears to be effective in identifying mineralization. These combinations of geochemical anomalies not only uncover concealed ore bodies, but also delineate the trend and extension direction in strike and dip of ore bodies. Gas intensity may provide insights into the scale of the ore bodies, with stronger gas anomalies observed in areas with thicker ore bodies at similar depths. Thus, the study reveals that soil-gas exploration shows great promise as an exploration technique for orogenic gold deposits, especially in areas with regolith cover hindering traditional methods from detecting mineralized zones for gold exploration.

The Application of Dual Frequency IP Survey to Identify the Concealed Ore Body in Pilbara Craton, Australia: A Case Study from Calvert Gold Deposit

The Mallina Basin in Western Australia, situated in the central part of the Pilbara Craton which is one of the world's oldest cratons, is a structurally deposited basin subjected to multiple episodes of deformation and magmatic intrusion. The Calvert gold deposit in Mallina Basin is heavily covered by Quaternary, thus, it is hardly to identify any distinct mineralization indicators, and there is no any significant progress in exploration so far. The SQ-3C dual frequency induced polarization facility that is developed by China is introduced to carry out the dual frequency IP survey, the author’s team have tested all the types of different rock samples to collect the geophysical parameters in the Calvert area, and the selection of suitable facility and working frequency is based on the geological characters of the Calvert deposit and the geophysical parameters of rocks, and some processes are undertaken to weaken the interference triggered by the electromagnetic coupling, and an IP anomaly zone was delineated. Through the drilling program in the IP anomaly zone, a gold ore body that has the same orientation with the IP anomaly zone was controlled; this result demonstrated the dual frequency IP survey is effective in the local area and provide an efficient technical method for the mineralization prospecting, and this geophysical survey project sets an example for the familiar type of gold deposit in the local area.

Metallization characteristics and gold ore controlling factors in the south region of Tra Nu - Phuoc Thanh, Quang Nam Province

The gold mineralization in the southern region of Tra Nu-Phuoc Thanh was initially discovered and assessed by the Central Geological Division. However, mineralization characteristics and ore-controlling factors in the Tra Nu-Phuoc Thanh area remain inadequately understood. To assess the gold mineralization potential in this research area, this study conducts a comprehensive synthesis of prior research findings, complemented by the analysis of an additional 50 thin sections, 100 thick sections, SEM scanning electron microscopy, and 10 ICP-MS samples. The research results reveal the presence of gold deposits within the study area, including native gold and electrum. The identified gold-bearing minerals in the deposits encompass quartz, pyrite, galena, sphalerite, pyrrhotite, and goethite. The ore formations predominantly exhibit disseminated, vein, and breccia structures, along with granular, semi-granular, spherical, and solid inclusions. It has been ascertained that the gold ore in the study area belongs to the gold-quartz-sulfur formation and can be categorized into two types: gold-quartz-pyrite ore and polymetallic gold-quartz-sulfur ore. The ore is primarily situated within ancient metamorphic sedimentary rocks of the Kham Duc formation and young granitoid rocks of the Ba Na complex. Typically, the gold ore body occurs in a single-vessel form, with less common branched, vascular zone, and infiltrative vascular forms. All gold ore bodies are aligned along the fault systems, primarily oriented in the northeast-southwest direction. These sub-meridian fault systems serve as conduits for hydrothermal solutions carrying gold ore in the study area.

Genesis of the Yu'erya gold deposit, East Hebei, China: Insights from geology and fluid inclusions

The Yu'erya gold deposit is a large‐scale gold deposit in eastern Hebei. However, the ore genesis is controversial because the gold orebody is closely related to biotite granite in time and space. The hydrothermal processes of the Yu'erya gold deposit can be divided into early quartz (Q1)‐pyrite stage, middle quartz (Q2)‐sulphide stage and late quartz (Q3)‐calcite stage. The Q1 is subdivided into Q1‐1 and Q1‐2 generations by SEM‐CL images, and Q2 is subdivided into Q2‐1 and Q2‐2 generations. Three types of fluid inclusions (FIs), including aqueous‐carbonic type (C‐type), aqueous‐rich type (W‐type) and vapour‐rich type (V‐type), were observed in the Yu'erya gold deposit. The Q1‐1 is dominated by C‐type inclusions, and the other quartz is dominated by W‐type inclusions. Laser Raman analysis shows that the initial ore‐forming fluids mainly belong to the CO2‐H2O‐NaCl system and gradually transferred to the H2O‐NaCl system. The C‐type inclusions of Q1‐1 show the salinity of 3.1–10.1 (av. 6.9 ± 1.7) wt.% NaCl eqv., and the total homogenization temperature (Th) of 305–391°C. The homogenization temperature decreases gradually from the early to the late stage, with insignificant change in salinity, indicating that fluid cooling is the main precipitation mechanism. Trapping pressures of C‐type FIs are estimated at 206–284 MPa and 203–211 MPa for the early and middle stages, corresponding to the mineralization depths of 7.2–9.9 km and 7.1–7.4 km, respectively. The FIs in the early stage indicate that the initial ore‐forming fluids are characterized by low salinity and CO2 richness, which are different from those of the intrusion‐related gold deposits, but consistent with the orogenic gold deposits.

Ore-forming material sources of the Pakbeng gold deposit, Laos: Evidence from fluid inclusions, H-O-S isotopes, and trace elements

The Pakbeng gold deposit, located at the junction of the eastern Tethys and western Pacific tectonic domains, is part of the Phôngsali-Luang Prabang-Sayaboury polymetallic metallogenic belt. Its gold ore bodies are predominantly governed by fault structures, being vein-like and short-axis-veined in shape. The Pakbeng gold deposit primarily exhibits two types of mineralized alterations: the quartz-vein type and the schistositized altered rock type. The ore bodies are primarily distributed within cataclastic granites and altered andesite plutons, near their contact zone. The ore-forming process can be divided into four stages: quartz + rutile + pyrite (stage I), quartz + pyrite + coarse-grained arsenopyrite (stage II), quartz + polymetallic sulfides + native gold (stage III), and calcite + quartz (stage IV). Native gold primarily occurs as invisible gold in the quartz and pyrite of stages I and II, and as enclosed, intergranular, and interstitial gold within the quartz, pyrite, and other metal sulfides of stage III. The ore-forming materials of the Pakbeng gold deposit primarily originate from plagioclase granites and altered andesites, as indicated by investigations of gold-bearing quartz fluid inclusions, hydrogen and oxygen isotopes, the trace-element composition of pyrite, and in situ sulfur isotopes. The sulfur in the deposit is mainly derived from metamorphic sources, supplemented by late magmatic sulfur. The ore-forming fluids in the deposit were dominated by metamorphic fluids in the early stage, with magmatic fluids participating in the late stage. While ascending, the temperature of the ore-forming fluids decreased due to fluid boiling and mixing, but their salinity increased slightly. The ore-forming fluids exhibited a consistent decrease in homogenization temperatures from stages I to IV, with salinity initially increasing and then decreasing. This suggests that the ore-forming fluids are low-temperature, medium to low-salinity and low-density fluids.

Age and fluid source constraints of the Haoyaoerhudong orogenic gold deposit, North China: Evidence from geochronology and noble gas isotopes

The Haoyaoerhudong gold deposit, located in the northwestern part of the North China craton (NCC), has produced over 120 metric tonnes (t) of gold since 2007. It has a total reserve of > 240 t at average gold grade of 0.62 g/t, making it one of the largest open pit gold mines in China. The steeply dipping, large-tonnage, low-grade, vein- or veinlet-type gold orebodies are hosted in strongly-deformed Mesoproterozoic carbonaceous schist of the Bayan Obo Group. The laminated/boudinaged veins/veinlets in the sinistral ductile–brittle shear zones are dominated by quartz, biotite, gold-bearing löllingite, pyrrhotite, (arseno)pyrite, with minor native gold, titanite and xenotime. In this paper, we present new in situ U–Pb geochronological data on magmatic zircon from the pre-ore dikes, on metamorphic and hydrothermal xenotime, and on hydrothermal titanite from the hydrothermally altered carbonaceous schist and auriferous quartz–sulfides veins/veinlets, as well as He-Ar isotopic analysis on gold-bearing (arseno)pyrite in the syn-ore stage. The metamorphic xenotime U–Pb age of 426 ± 6.0 Ma (2σ) records a regional metamorphic event, possibly related to the accretion of the Bainaimiao arc onto the NCC. Two pre-ore andesitic dikes yielded similar emplacement ages at ∼ 278 Ma constrained by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U–Pb zircon data. Hydrothermal xenotime grains from the altered carbonaceous schist and auriferous quartz–sulfides veins yielded U–Pb ages of 256.0 ± 4.1 Ma (2σ) and 254.4 ± 2.1 Ma (2σ), respectively, overlapping with that of the hydrothermal titanite at 255.4 ± 0.8 Ma (2σ) from the laminated quartz–sulfides veinlets. This indicates that the gold mineralization occurred at ca. 255 Ma. The ∼ 255 Ma gold mineralization age is much younger than the previously reported Early–Middle Permian regional magmatic activity (ca. 291 Ma to 268 Ma), and may be associated with the regional sinistral strike-slip event in the late orogenic cycle related to the collision between the Siberian craton and the NCC. The 3He/4He (R/Ra) and 40Ar/36Ar values of the gold-bearing (arseno)pyrite are 0.04 to 0.09 (average = 0.07) and 375.8 to 2023 (average = 1045), which reveal the ore-forming fluids dominantly originated from the crustal rocks, with limited involvement from the mantle. Collectively, our new geochronological data, noble gas isotopic analyses, and geological evidence support a typical orogenic gold deposit model at Haoyaoerhudong.

Gold mineralisation by pyrite recrystallisation and arsenopyrite sequestration in the Jiaochong Au deposit, Tongling ore district, eastern China: Implications for the formation of stratabound ore deposits

The Middle–Lower Yangtze River Valley metallogenetic belt (MLYRB) is a large and economically valuable porphyry–skarn Cu–Au ore belt in China with a total reserve of >600 tonnes of gold. Orebodies in the MLYRB are commonly stratabound and extend for several tens of metres in length and locally for more than 1000 m. However, the origin of the stratabound orebodies is uncertain, with proposals including a magmatic or sedimentary genesis, and the specific processes by which these gold deposits were formed are also unclear. Here we report a study of the representative stratabound Jiaochong Au deposit in the Tongling ore district, where stratified gold orebodies are hosted at the Triassic -Permian strata boundary. A detailed field survey, petrologic observations, in situ sulfur isotopic analysis, and major and trace element compositional analysis of gold and sulfide grains were carried out to determine how the gold was enriched. Field survey shows that precipitated sulphides exhibit obvious mineral and textural zonation from wall-rock to orebody centres as follows: Zone 1, colloform pyrite (Py1) ± sphalerite ± chalcopyrite → Zone 2, euhedral pyrite (Py2) ± pyrrhotite + arsenopyrite ± colloform pyrite (Py1) → Zone 3, pyrrhotite + arsenopyrite. From zone 1 to zone 3, the sulphides were progressively phase-transformed, with the earlier Py1 being gradually consumed and converted into Py2, which finally became pyrrhotite. The gold deposition occurs in Zones 2 and 3 and forms two generations of gold grains, one group being completely enclosed within euhedral Py2 with low As contents (<0.1 wt%) and another group infilling fractures between arsenopyrite and pyrrhotite or occurring as inclusions within arsenopyrite with high As contents (0.4 to 1.4 wt%). The comparable S-isotope compositions of the ore sulfides to those of Mesozoic intermediate-felsic intrusions and the veining characteristics of colloform pyrite in the Tongling ore district suggest that Mesozoic magmatic-hydrothermal fluids, rather than Carboniferous sedimentary rocks as usually thought, provided the principal ore-forming materials. The gold precipitation in this study followed two continuous processes: recrystallisation and arsenopyrite sequestration; in the first process, Au is remobilised from the pyrite structure at higher temperatures up to recrystallisation of fine-grained, colloform morphologies into euhedral crystals and formation of Au-bearing metallic particles (Au1); with the ongoing recrystallisation more As is released and accumulated into the equilibrated fluids, forming As-rich pyrite or arsenopyrite and a second period of gold deposition (Au2). The continuous sulphide zonation texture and phase transformation, similar to Jiaochong, have been observed in other gold deposits in the MLYRB, and our gold enrichment processes may also give an explanation for the formation of these stratabound gold deposits.

A study of Au-bearing-nanoparticle-enriched plants from the concealed gold deposits and their prospecting significance

This study analyzes Au-bearing nanoparticles in five plant species (Anemone vitifolia, Taraxacum mongolicum, Artemisia argyi, Larix gmelinii, and Equisetum arvense) from the Yangshan gold deposit. Numerous Au-bearing nanoparticles were discovered in the five predominant plants within the ore deposit. It was found that plants differ in terms of their absorption and tolerance of Au-bearing nanoparticles. Among the five dominant plant species, Anemone vitifolia exhibits the highest absorption and accumulation capacity for Au-bearing nanoparticles, making it an Au-bearing-nanoparticle-enriched plants. The Au-bearing-nanoparticle-enriched plants which can super enrich Au-bearing nanoparticles store more abundant and intuitive information about deeply concealed gold ore bodies. Nanoparticles with similar composition and morphology were found in both the root and stem specimens of the Anemone vitifolia. It is shown that the Au-bearing nanoparticles in the stem cells were probably transported from the root. Furthermore, we discuss the relationship between Au-bearing nanoparticles in plants and deep concealed gold deposits and the process whereby Au-bearing nanoparticles migrate from gold orebodies to plants. The Au-bearing nanoparticles can carry information from the concealed gold ore body to the surface medium, and then be absorbed by the roots of Au-bearing-nanoparticle-enriched plants, gaining access to the aboveground parts of the plants. Therefore, this paper advances a new technology for gold deposit exploration using Au-bearing nanoparticles for the enrichment of plants.

A Late Triassic gold metallogenic event within the extended tectonic evolution of the West Qinling Orogen, central China: Constraints from U-Pb and Ar-Ar geochronology in the Yangshan gold district

The West Qinling Orogen in central China resulted from Late Devonian to Triassic collisional orogenesis involving accreted terranes along the southwestern margin of the North China Block with subsequent ocean closure and collision of the South China Block with those terranes. The Yangshan gold district, with a pre-mining resource of more than 308 t gold, is situated along the Mianlue Suture Zone on the southern margin of the orogen. The gold orebodies are mainly controlled by the ENE-trending Anchanghe-Guanyinba Fault and its subparallel second-order faults. The relatively low pressure–temperature mineralization is dominated by disseminated pyrite, arsenopyrite, and stibnite hosted in phyllite and granite dikes, accompanied by intense muscovite-silica-carbonate alteration.Four major phases of deformation related to collisional tectonics are recorded in the Yangshan gold district. Early N-S-oriented compressional deformation (D1) is characterized by an alignment of muscovite, overgrowths on framboidal pyrite, and quartz veinlets. D2 is characterized by a series of continuous ENE-trending reverse faults and folds at multiple scales related to SSE-NNW-oriented compression. D3 is related to gold mineralization and is characterized by a series of ENE-trending, largely normal faults, formed during transtensional tectonics. D4 post-dates gold mineralization and is associated with the development of nearly N-S-trending, low-displacement normal faults.New high-precision SHRIMP zircon U-Pb dating of three types of granite dikes in the Yangshan gold district yields broadly coincident ages of 216 ± 3.0 Ma to 210 ± 9.7 Ma, which is a range identical to that of existing dates of 217–211 Ma for more regional granite magmatism in this district. New Ar-Ar dating of gold-related muscovite gives an age of 210.9 ± 1.6 Ma for the Yangshan gold deposit, indicating that hydrothermal activity overlapped or post-dated the final stages of granite intrusion. Pre-226 Ma peak metamorphism of the ore-hosting rocks occurred prior to extensional ductile shear deformation that is constrained by a published 40Ar/39Ar muscovite cooling age of 223 ± 2 Ma. In good agreement, U-Pb constrained ages of retrograde metamorphism and associated late magmatism of around 215 Ma are reported for rocks along the Mianlue Suture Zone.These geological and geochronological data suggest that relatively shallow-level gold mineralization was broadly coeval with Late Triassic transtensional, orogen-parallel deformation along the regional-scale fault system, late in the tectonic evolution of the West Qinling Orogen. This is consistent with its classification as epizonal orogenic gold mineralization.

Multi-Phase Hydrothermal Fluid Events in the Giant Lannigou Gold Deposit, SW China: Insights from Calcite Sm–Nd Age, Trace Elements, and C-O-Sr Isotopes

The Nanpanjiang basin hosts the world’s second-largest concentration of Carlin-type gold deposits. To decipher the origin and evolution of hydrothermal fluid, this study conducted Sm–Nd dating, in-situ trace element, and C-O-Sr isotopic analyses on three types of calcite samples from the giant Lannigou gold deposit in the Nanpanjiang basin, SW China. The type-I calcite, intergrown with Au-bearing arsenian pyrite, has an Sm–Nd isochron age of 213 ± 7 Ma (MSWD = 0.81), indicating that gold mineralization occurred in Late Triassic. The type-II calcite, which coexists with high-maturity bitumens and cut through the main-stage gold orebodies, yields an Sm–Nd age of 188 ± 14 Ma (MSWD = 0.34), representing a post-ore hydrocarbon accumulation event. The type-I and type-II calcite samples have low REE contents (5.28–51.6 ppm) and exhibit MREE-enriched and LREE-/HREE-depleted patterns. Combined with their identical C-O-Sr isotopes, we suggest that hydrothermal fluids responsible for the precipitation of type-I and type-II calcite samples were derived from a mixed metamorphic fluid and meteoric water source. In contrast, the type-III calcite samples, associated with realgar and orpiment, have distinct Mn, Sr, and As contents, REE patterns, and C-O-Sr isotopic composition from the type-I and II calcites, suggestive of different fluid sources. Based on our and previously published data, we propose that the fluid evolution, gold mineralization, and hydrocarbon accumulation in the Nanpanjiang basin are closely related to the Indosinian and Yanshanian orogenies in South China.

Fluid-rock interaction modeling to constrain Au enrichment: Implication for the giant Jiaodong Au mineralization, eastern North China Craton

The devolatilization model of the metasomatized lithospheric mantle without pre-enriched gold has been proposed to account for the giant gold mineralization. An excellent example is the world-class Jiaodong gold province with >5000 tonnes Au resources in the eastern North China Craton. The auriferous fluid transport and gold enrichment during wallrock alterations are two vital processes to determine the giant gold mineralization formation in this province. However, the effects of the fluid-rock interaction with alterations on the auriferous fluid transport and gold enrichment still keep poor understanding, which leads the above model to be imperfect. The giant Jiaojia goldfield in this province recorded a wallrock alteration evolution from K-feldspar alteration to pyrite-sericite-quartz alteration, and some parts of the latter can become gold orebodies when the gold grade is >1 ppm. This study conducts thermodynamic fluid-rock interaction modeling to reveal auriferous fluid transport and coupled relationship between gold enrichment and alteration mineral assemblage based on the alteration-mineralization and ore fluid characteristics of the goldfield. The modeling of fluid-rock interaction with cooling indicates the transformation of Au-Cl complexes to Au-S complexes combined with the total sulfur concentration decrease by pyrite precipitation when cooling from ∼460 °C can trigger the dispersive gold precipitation, which should hinder the gold long-range transport to lower ambient temperature. The high oxygen fugacity at >400 °C can enhance Au-Cl complexes stability, and the low pH can maintain high total sulfur concentration in the auriferous fluid, both of which facilitate the long-range gold transport to a lower-temperature environment. The auriferous fluid would acquire higher pH by the buffering of feldspars or sericite, which was beneficial for the high-efficiency precipitations of pyrite and gold. The ankerite-siderite assemblage without pyrophyllite in the pyrite-sericite-quartz alteration zone indicates that a cumulative fluid to rock mass ratio (f/r) of 3.8–4.8 should be needed for the transformation from K-feldspar alteration to pyrite-sericite-quartz alteration according to the fluid-rock interaction modeling at 300 °C and 2000 bar. In the case of auriferous fluids with ≤200 ppb Au concentration, the single fluid-rock interaction can only elevate the gold grade to ≤0.69–0.87 ppm in the pyrite-sericite-quartz alteration zone at f/r 3.8–4.8. Therefore, the fracture-induced fluid flow coupled with fluid-rock interaction is proposed to the prerequisite to elevate the gold grade to >1 ppm in the pyrite-sericite-quartz alteration zone. The metasomatized lithospheric mantle volume for the required ore fluid and Au in the Jiaodong province is estimated according to the modeling results and alteration-mineralization characteristics, which provides a link between the mantle without abnormal Au enrichment and the alteration-mineralization processes.

Geochronology, pyrite trace elements, and sulfur isotope geochemical characteristics of the Saibagou gold deposit in the eastern part of the northern Qaidam Basin

Introduction: The Saibagou gold deposit, located in the eastern part of the tectonic belt of the northern Qaidam Basin in western China, has its gold ore bodies strictly controlled by the regional fault system. Despite this understanding, there remain controversies surrounding the deposit’s metallogenic epochs, sources of ore-forming materials, and properties of ore-forming fluids. To address these controversy, the metallogenic process of the Saibagou gold deposit can be further determined by analyzing the U-Pb ages of hydrothermal zircons in the gold-bearing quartz veins and investigating the trace element and sulfur isotope compositions of pyrite in the gold deposit.Methods: This study does not focus on the mineral characteristics susceptible to interference by the metallogenic condition in gold ore bodies. Instead, it offers a detailed discussion on stable associated minerals and their indicative markers formed in the process of gold mineralization.Results: The results of this study showed that the metallogenic process of the gold deposit can be categorized into the following stages: 1) quartz–pyrite veins, 2) milky-white quartz—pyrite—native gold veins, 3) hoary quartz—native gold—polymetallic sulfide veins. As indicated by the U-Pb ages of hydrothermal zircons in the gold-bearing quartz veins, the Saibagou gold deposit has two metallogenic ages, namely, 423.91 ± 4.5 Ma (the Silurian) and 470.18 ± 4.92 Ma (the Ordovician).Discussion: The Silurian metallogenic age, predominates and nearly aligns with the expansion of the regional NWW-trending brittle-ductile shear zone, followed by the Ordovician metallogenic age. Data on the trace elements and sulfur isotopes of pyrite, show that the Saibagou gold deposit has similar pyrite compositions in the three metallogenic stages. Gold in the deposit primarily occurs as native gold or minor petzite inclusions and has a very low lattice gold concentration. As indicated by the concentrations of elements such as Co, Ni, and as in the pyrite, as well as the variation range of δ34S values, the ore-forming fluids were derived from low-temperature arsenic-bearing acidic magmas. In addition, the primary ore-forming materials appear to encompass mantle-derived materials from the deep earth.

Fluid evolution and metallogenesis of the Zhangjiapingzi gold deposit in mianning, Sichuan province: constraints from fluid inclusion studies

Introduction: The Zhangjiapingzi gold deposit, located at the western margin of the Yangtze Craton and controlled by the Jinhe-Chenghai deep fault, is a newly discovered super-large gold deposit in the Danba-Mianning metallogenic belt. The gold ore bodies are hosted in the Middle Triassic (T2) altered dolomite (Dm), and have two types of mineralization: altered rock type and quartz vein type. Previous studies on this deposit are rare, especially on the ore-fluid characteristics, which limit the understanding on the ore genesis.Methods: This study focused on fluid inclusions in quartz from altered rocks, and used microthermometry and laser Raman spectroscopy to investigate the properties and sources of ore-forming fluids, and to determine the ore genetic type.Results and discussion: The results show that the fluid inclusions are mainly CO2-H2O-NaCl inclusions, with medium temperature (220–300°C), low salinity (&amp;lt;10%), medium-low density (0.79–1.01 g/cm3) and high contents of CO2 and CH4, resembling typical orogenic gold ore fluids. We suggest that the Zhangjiapingzi is best classified as orogenic type, and our findings provide new insights into the fluid origin and metallogenesis of orogenic gold deposits in the Danba-Mianning metallogenic belt.

Formation–exhumation history of the Carboniferous Axi epithermal gold deposit in the Chinese Western Tianshan based on zircon U–Pb and pyrite Re–Os geochronology and (U–Th)/He zircon–apatite thermochronometry

The Central Asian Orogenic Belt represents a Late Paleozoic archipelago, but crustal growth and the reworking and exhumation of the individual microcontinental massifs remain poorly constrained. Here, we use the Axi epithermal deposit to examine continental preservation and exhumation in the Central Asian Orogenic Belt of the Chinese Western Tianshan region. Zircon U–Pb dating and geochemistry demonstrate that the andesitic host rock formed via the incremental addition of magma in an Andean-type magmatic arc setting at 362, 354 and 342 Ma. Pyrite Re–Os data and textural evidence reveal two mineralization events at 355 and 332 Ma. Zircon (U–Th)/He data reveal temperatures of c. 180°C until 317.8 ± 9.8 Ma, which is interpreted to record the timing of exhumation of the andesite and gold ore bodies prior to their burial by Carboniferous-age sediments. Further sedimentary concealment continued until the Late Mesozoic when the system was re-exhumed between 148.6 ± 8.6 and 120.0 ± 13 Ma at a rate of c. 9.8 m Ma −1 , as shown by apatite (U–Th)/He data. Collectively, the geochronology/thermochronology data show that the Chinese Western Tianshan region records a transition from compressional to extensional tectonism during the Late Paleozoic and Late Mesozoic. The shallow epithermal mineralization was protected from erosion by post-mineralization deposition. Supplementary material: Trace element and zircon U–Pb data for the andesitic host are available at https://doi.org/10.6084/m9.figshare.c.6640014

Application of integrated geological and structural investigations to the discovery of new mineral zones related to the Daping gold deposit, Southwest China

The Daping gold deposit is one of the largest gold deposits in the Ailaoshan gold belt of SW China. It has proven gold reserves of more than 70 tonnes and has been mined for 36 years. Finding new orebodies to extend the mine life has become urgent since the main gold orebodies are almost depleted. Ore deposit types in the Daping area include quartz-vein and porphyry gold types of mineralization. The quartz-vein ores are hosted in late Proterozoic diorite and Silurian limestones and controlled by NW trending faults. We have studied the ore-controlling structures to determine palaeo-stress directions of V1-2-3 and V37 orebodies, and the distribution of gold mineralization in the V1-2-3 orebodies. Based on the field observation, we identified six stages of structure in the Daping gold deposit, i.e., pre-mineralization (stage 1), syn-mineralization (stages 2 to 4), and post-mineralization (stages 5 and 6). The spatial distribution of gold orebodies at Daping is mainly controlled by the compressional faults of stage 1 that is associated with the Ailaoshan orogenic belt, and overprinted by structures of later stages. Orebodies from gold deposits in orogenic belts commonly have greater vertical dimensions than horizontal dimensions, suggesting that V1-2-3 orebodies may extend to deeper area.Our data indicate that higher gold grades and the thickest parts of the orebodies are associated with deeper parts of the V1-2-3 orebodies (up to 800 m in depth), and are likely related to a concealed mineralized porphyry which was intersected in drill core and identified as xenolith in lamprophyre dikes in the underground mine workings. The quartz-vein type gold mineralization at the Daping gold deposit was possibly overprinted by the porphyry gold mineralization, as indicated by the discovery of the new quartz-vein-associated orebodies beneath the current levels of Daping gold deposit and associated porphyry gold orebodies at Daping gold area.

Petrogenesis of the Granitic Dykes in the Yangshan Gold Belt: Insights from Zircon U-Pb Chronology, Petrography, and In-Situ Hf Isotope Analysis

The Yangshan gold belt is renowned for its igneous rock formations, particularly dykes that form in tectonically weak zones. Some of these rock formations exhibit a close spatial relationship with gold mineralization, and a tiny portion of the granitic dykes serve as gold ore bodies by themselves. In order to investigate the nature of granitic dykes and their association with gold mineralization, we conducted a comprehensive study consisting of zircon U-Pb chronology, petrography, and in situ Hf isotope analysis of 25 granitic dyke samples collected from east to west across the belt. According to LA-ICP-MS zircon U-Pb dating results, the granitic dykes inherited zircon ages that are concentrated between 745.0 and 802.0 Ma, and magmatic intrusion ages that mainly fall between 201.0 and 213 Ma. Moreover, the granitic dykes display a calc-alkaline to high-K calc-alkaline peraluminous series, which is relatively enriched in light over heavy REE, with moderate Eu anomalies. These dykes are rich in large-ion lithophile elements and poor in high-field-strength elements. The zircon Lu-Hf isotope data range from εHf(t) values of −1.5 to 0.1, mantle model (TDM1) ages range from 859 to 937 Ma, and crustal model (TDM2) ages range from 1111 to 1218 Ma. The granitic dykes found in the Yangshan gold belt were formed between 200 and 213 Ma ago, during a period of intracontinental extension following the late collision between the Yangtze plate and Qinling microplates. These dykes originated from the volcanic basement of the Mesoproterozoic Bikou Group, which was formed by the melting of the upper crust under the crustal thickening caused by the subduction and collision of the Qinling microplate. Subsequently, the dykes were transported along a tectonically weak zone, assimilating surrounding rocks and undergoing a transformation from “I”-type to “S”-type granite before finally evolving into granite with specific “A”-type characteristics. Our study provides new insights into the petrogenesis of granitic dykes in the Yangshan gold belt, as well as the relationship between gold mineralization and magmatic activity, which has significant implications for mineral exploration and the geological understanding of gold mineralization in this region.

Mapping of geological complexity and analyzing its relationship with the distribution of gold deposits in the Guangxi Gold Ore Province, Southern China

The Guangxi gold ore province contains >370 gold deposits with total resources of >260 t Au. Factor analysis (FA) of geochemical data, and calculation of lineament density within 10 km, 20 km, and 30 km circular search grids across a geological map, were applied in Guangxi to highlight geological complexity and to analyze its relationships with the distribution of gold deposits. The FA of stream sediment geochemical data for 42 elements, subjected first to center logarithmic transformation (clr), yield several element combinations that allowed distinction of metallogenic signatures from geological backgrounds. The element combinations of the first and second factors were Cd–Co–Cr–Cu–Li–Mn–Ni–P–Sb–Y–Zn–Mg and Be–Bi–La–Nb–Pb–Sn–Th–U–W–Zr–Al, and the spatial distributions of their factor scores overlap the Devonian to Permian strata and granite, respectively. The distribution of factor scores of mineralization-related element combination, Ag–As–Au–Mo, coincides with 70 % of gold deposits. The lineament density mapping can highlight different-scale faults and lithological contacts by using circular search grids with different diameters. The C–A fractal modeling for lineament density has indicated four populations, namely low, moderate-low, moderate-high, and high lineament densities. About ∼80 to ∼90 % of the known gold deposits exist in areas with moderate-low to moderate-high lineament densities. This highlights the importance of distinguishing geological complexity based on faults and lithological contacts, which are commonly the pathways for the focused fluid flow and gold ore formation. The deposit-scale geological complexity mapping has predicted several exploration targets, where high-grade gold orebodies have been prospected successfully by drilling in 2018. The geological complexity mapping is a kind of geochemical and geological complementation for resource potential assessment.

Mechanism and age of gold remobilization in orogenic gold deposit from primary laminated ore to the high-grade ore: A case study from Cenozoic Bangbu gold deposit, Tethyan Himalaya

The formation of high-grade gold ore has always been attractive, mostly located in Precambrian gold deposits with various mechanisms. Yet, in the orogenic Bangbu gold deposit, Tibet, we discovered that the coupled dissolution-reprecipitation (CDR) process and low melting point chalcophile elements (LMCE) -related melting are responsible for the formation of high-grade ore at ca. 38 Ma constrained by in-situ U-Th-Pb dating of hydrothermal monazite. Three generations of pyrite have been recognized, metamorphic barren pyrite (Py I) in the host schist, hydrothermal pyrite (Py II) in the preceding primary laminated ore with an Au grade of ∼8 g/t, and the hydrothermal coarse pyrite (Py III) in later massive ore with a grade of up to 29 g/t. In the primary laminated ore, the Py II in the sulfide ribbons is intergrown with native gold and colloform quartz and carries abundant trace element contents, such as Au, As, Cu, Pb, Zn, Te, Se, and Bi. These suggest that the rapid precipitation and local supersaturation occurred during the episodic crack-seal process. In the later high-grade massive ore, Py III exhibits distinct zonation, ranging from Py III-1 in the core to Py III-3 in the rim. The Py III-1, porous and rich in inclusions, has sharp boundaries and successive lattice orientation with the mantle Py III-2 suggesting a CDR process. Higher Au and As in Py III-2 than the Py III-1, and the close affinity between visible gold and LMCE melt inclusions at the boundary suggest that gold was remobilized and facilitated by the LMCE during the CDR process. The electron backscatter diffraction (EBSD) mapping result shows little crystallographic misorientations of Py III, excluding the deformation process that has significantly contributed to the remobilization of gold. The decrease of the δ34S ratio of pyrite between Py II (δ34S = 2.0‰ to 4.3‰, mean 3.4‰) and Py III (δ34S = −2.5‰ to 3.8‰, mean −0.2‰) most likely reveals a more oxidized condition in the open space which may trigger the CDR process and gold remobilization of the pyrite in the primary ore. Within the zonation of Py III, an increasing trend of the δ34S ratio represent the evolution of the redox state of fluids towards relatively reducing conditions during the healing of quartz veins. The newly obtained ca. 38 Ma age is comparable to regional amphibolite- to granulite-facies metamorphism during the continental subduction, which was considered to trigger the modification of primary gold orebody to form high-grade ore.

Localization patterns of gold mineralization in the Phuoc Son area, Central Vietnam

Background. In this paper, the authors aim to reveal the localization patterns of gold mineralization in the Phuok Son region of Central Vietnam, which formed a Proterozoic-Cambrian metamorphic complex in the zone of the Late Paleozoic Benzhang–Queshon granite block.Aim. To determine the localization patterns of gold mineralization in the Phuoc Son area, Central Vietnam.Materials and methods. The research was based on geological materials, as well as mine working and appraisal well data. The material composition of the materials was studied using 15 transparent sections and 18 polished sections. In total, 127 samples were subjected to atomic absorption spectroscopy.Results. Within the Phuoс Son gold ore field in Central Vietnam, the site of the Baidat and Baigo mines located in the zone of reverse-shear termination was investigated. Here, the gold ore bodies are represented by quartz-sulfide veins subparallel to schistosity. The ore-bearing zones are layered zones of tectonic faults, which formed at the end of the reverse-shear period and complicated the western limbs and locks of the anticlines. These zones were formed under regional sublatitudinal horizontal stresses. The horizons of carbonaceous quartz-sericite schists are of great importance in ore control. There are steeply dipping post-ore faults that displace ore bodies. Two gold mineralization stages can be distinguished. The early stage was characterized by a wide development of sphalerite and a smaller amount of gold. The later stage was associated with the main precipitation of gold and formation of galena. According to the geochronological data on the argon isotopy in biotite, the gold mineralization at Baidat and Baigo was probably formed in the Triassic (250–200 Ma ago), at the stage of extinction of the regional metamorphism of the Indosinian orogenyConclusion. The results obtained should be used when conducting local forecasting of gold deposits in Central Vietnam.

Origin and evolution of the ore-forming fluids of the Bajiazi gold deposit in the Jiapigou gold ore belt, NE China: Constraints from fluid inclusions, H-O-S isotopes, and pyrite trace element concentrations

The Bajiazi gold deposit, located within the southeastern Jiapigou gold ore belt (JGB) along the northeastern corner of the North China Craton (NCC), contains > 6 tons of gold at an average grade of 24 g/t. More than 20 total auriferous quartz veins are hosted in the Neoarchean basement gneiss and amphibolite and are spatially and temporally associated with Mesozoic intermediate-acid dikes. The distribution of the gold orebodies is mainly controlled by NNE-trending brittle–ductile shear zones and faults. Three hydrothermal stages were identified, namely, quartz–pyrite (stage I), quartz–gold–polymetallic sulfide (stage II), and quartz–carbonate (stage III). Three types of fluid inclusions (FIs) were identified: H2O–NaCl (W-type), CO2–H2O (C-type), and pure CO2 (PC-type) FIs. From stage I to stage III, the FI suite changes from W-type and C-type in stage I to all three types in stage II and to only W-type in stage III. The FIs in the quartz of stages I to III mainly homogenized at temperatures (Th) of 283–395 °C, 183–287 °C and 116–186 °C, respectively, with salinities of 3.87 to 13.01 wt% NaCl equiv, 4.65 to 18.55 wt% NaCl equiv, and 3.83 to 9.68 wt% NaCl equiv, respectively. The ore-forming fluids of the Bajiazi gold deposit evolved from a H2O–NaCl–CO2 system in stages I and II to a H2O–NaCl system in stage III. Fluid immiscibility is an important mechanism leading to rapid precipitation of sulfides and gold. H–O–S isotope signatures indicate that the initial ore-forming fluids and materials were originally derived from magmatic sources. Electron probe microanalysis (EPMA) and laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) data on pyrite grains show that abundant gold mineralization occurred in the middle hydrothermal stage. The high Co/Ni ratios of pyrite are consistent with a magmatic–hydrothermal origin. The results, combined with previous regional studies, indicate that the Bajiazi gold deposit is a mesothermal magmatic–hydrothermal lode gold deposit.