Gold Endowment Research Articles

Contribution of bismuth melts to gold endowment in the Baolun gold deposit, Hainan Island, South China

Bismuth (Bi) melts and related polymetallic alloys can efficiently scavenge gold (Au) from Au-unsaturated aqueous solutions, contributing to the Au endowment in many hydrothermal deposits. However, original evidence for Au–Bi melts is often poorly preserved due to post-precipitation alteration. This complicates investigation of the liquid bismuth collector model in hydrothermal Au deposits. Here we present primary evidence for the occurrence of Au–Bi melt in hydrothermal systems through an examination of the Au–Bi phases and textures in the Baolun Au deposit (Hainan Island). This study found that maldonite, native bismuth, Au–Bi symplectite and Au–Bi melt blebs appeared successively following the precipitation of native gold. Notably, large Au–Bi melt blebs were well preserved in natural systems due to the rapid cooling of fluids. The mineral assemblages and their corresponding fluid physiochemical conditions suggest that the evolution of the ore fluids at Baolun was characterized by a continuous reduction in Au and Bi concentrations and Au/Bi ratios alongside decreasing fluid temperatures and sulfur fugacity (fS2). These observations offer direct evidence for Au scavenging by Bi melts in a mesothermal (275–450 °C), low-fS2 and reduced hydrothermal system, aligning well with the Au–Bi binary phase evolution established in metallurgy. As the fluid cooled further, the Au–Bi phases were subsequently overprinted by later Te–S-rich fluids, as evidenced by the formation of bismuthinite, jonassonite, and joséite-A around the Au–Bi phases. Importantly, our study reveals that the Baolun Au deposit ischaracterizedby a Au–Bi–Te hydrothermal system and that the metamorphic country rocks at Baolun are the major source of Au, Bi, and Te.

LA-ICP-MS Analyses of Sulfides from Gold-Bearing Zones at the Perron Deposit, Abitibi Belt, Canada: Implications for Gold Remobilization through Metamorphism from Volcanogenic Mineralizations to Orogenic Quartz–Carbonate Veins

The Perron deposit, located in the northern part of the Archean Abitibi belt, bears some of the highest gold-grade mineralization for orogenic-vein-type deposits worldwide (High-Grade Zone: HGZ). More than 13 gold-bearing zones with different sulfide assemblages, hydrothermal alterations, and gold grades have been recently outlined, and they range from volcanogenic to orogenic in origin. In addition, seven zones are hosted in a restricted volume of ~1 km3, which is called the Eastern Gold Zone. Pyrite, sphalerite, pyrrhotite, and chalcopyrite—each from a different gold-bearing zone—were analyzed with LA-ICP-MS to decipher their genetic links, mineralizing processes, and temperature of formation. The temperatures calculated with the sphalerite GGIMFis thermometer range from 348 to 398 °C. All gold-bearing zones recorded volcanogenic hydrothermal inputs at different intensities, manifested by pyrrhotite. Pyrite was late-metamorphic and related to the orogenic gold system induced by the contact metamorphism of amphibolite facies. The pyrrhotite grains had very homogeneous trace element signatures in all zones, which is a characteristic of metamorphic recrystallization, exhibiting a loss of mobile elements (Au, Te, Bi, Tl, Sn, W, In) but high concentrations of Ni, Co, and As. Conversely, the pyrite was systematically enriched with all elements depleted from pyrrhotite, bearing five specific signatures of element enrichments: W, Tl, Sn, In-Cd-Zn, and Bi-Te-Au. For gold-rich zones (e.g., the HGZ), gold was linked to the Bi-Te-Au signature of pyrite, with Bi enrichment occurring at up to 72,000 times the background level in Archean shale pyrite. It was concluded that gold was transported, at least in part, as Bi-Te melts in the previously documented non-aqueous orogenic fluids, hence accounting for the very-high-grade gold content of the HGZ. Genetically, the metamorphism of primary gold-bearing volcanogenic mineralizations was the main source of gold during the overprinting of amphibolite (600 °C) in a metamorphically induced orogenic mineralizing event. A strong volcanogenic pre-enrichment is considered the main factor accounting for the gold endowment of the Eastern Gold Zone.

Gold concentration during polyphase deformation: Insights from Boulanger Project, French Guiana

The Boulanger gold deposit is hosted within the Rhyacian greenstone belts from the Guiana shield located within the North Guiana Through, French Guiana. The Boulanger deposit is characterized by a complex polyphase deformation and mineralization history involving a coaxial shortening phase, D1, followed by a transcurrent deformation event, D2. The main ore bodies consist of a series of quartz-tourmaline-pyrite-carbonate extension and shear veins in response to NNE-SSW shortening event (D1), and adjacent altered host-rocks. The proximal alteration bordering the vein system is characterized by pyrite-tourmaline (main ore assemblage). This shortening event is followed by transcurrent deformation, D2. Locally, D2 is expressed by the formation of N020-030 narrow zones (F2 axial trace) along which D1 structures are reoriented. The structural analysis performed on both S1/0 foliation and on geophysical data interpretation highlights the presence of Type-1 interference patterns. These zones are associated with significant gold enrichment and the presence of a new ore assemblage dominated by pyrrhotite-pyrite. Quantitative structural analysis approach, based on measured foliations (S1/0) and gold grade demonstrates that D2-related folding is associated with important gold endowment. These findings suggest that the characterization of the exact fold interference pattern is fundamental for the targeting of favorable enriched zones at the deposit scale.

Polyphased gold enrichment as a key process for high-grade gold formation: Insights from the 10 Moz Jundee-Bogada camp (Yilgarn Craton, Western Australia)

High-grade (> 10 g/t) gold mineralization in orogenic gold deposits is of significant economic importance. Understanding the formation of such enriched ore zones is critical for gold exploration success. The world-class Jundee-Bogada gold camp in the Yilgarn Craton of Western Australia comprises both high-grade (avg. > 10 g/t, Jundee deposit) and low-grade (avg. < 3 g/t, Bogada prospect) lodes, despite shared host stratigraphy. The paragenetic framework established for the Jundee gold deposit suggests that the overall gold endowment developed over three deformation events. An early episode of low-grade gold mineralization is associated with colloform-crustiform veins that formed during extensional deformation (DJB2A). A switch to transtensional deformation (DJB2B) resulted in brecciation of the colloform-crustiform veins and coeval deposition of native gold. Late reverse faults record evidence for a third mineralization stage resulting from a NE-SW-directed shortening (DJB3). Mineralization during this late stage was dominantly low-grade, with local occurrences of ultra-high-grade ore zones (> 100 g/t). Each event records transient changes in fluid chemistry during continued hydrothermal activity that spanned local deformation histories. We argue that at the Jundee gold deposit, protracted gold enrichment during three polyphased mineralization episodes resulted in the formation of high-grade gold ores. Whereas the complete metallogenic history is recorded at the Jundee deposit, gold within the Bogada prospect was introduced solely during the late contractional stage (DJB3), resulting in a bulk low-grade endowment. We hypothesize that gold enrichment in high-grade orogenic gold deposits is a direct consequence of the spatial superimposition of protracted ore-forming events.

Polyphase formation of a Neoarchean auriferous fault zone network in the Michipicoten greenstone belt, southern Superior craton

Correlating structurally distinctive fault zones for understanding an unknown deformation system at the regional scale remains a challenge for understanding orogenic evolution and gold endowment. The current study deals with this challenge in the southern Michipicoten greenstone belt (MGB) of the Superior craton focusing on a Neoarchean auriferous fault zone network. Three deformation events associated with episodic gold mineralization are revealed in the ca. 2745 Ma host granitoid: (1) NW‒SE shortening recorded by the subvertical Grace and Minto B fault zones and locally the inclined Jubilee and Hornblende fault zones; (2) top-to-NNE strike-slip to oblique faulting indicated primarily by the dominant structures of the Jubilee and Hornblende fault zones; and (3) top-to-NE extension demonstrated by the northeast-dipping Parkhill #4 and Cooper fault zones. Fault zone lithologies and mineral assemblages suggest that the localization of deformation for the formation of these fault zones was controlled by rheological heterogeneities and syn-deformation fluids. The first and second events are correlated with two shortening events in a gold-endowed, structurally and kinematically distinctive deformation zone of the northern MGB. This correlation based on deformation processes suggests a larger footprint of gold mineralization associated with a regional deformation in the MGB and has implications for investigating structural evolution of orogens and orogenic gold mineralization in general.

Formation of a late-orogenic conglomeratic sequence in the Neoarchean western Wabigoon terrane, Superior craton

The Neoarchean conglomeratic Timiskaming assemblage is considered to be one of the most gold-endowed rock associations in the Abitibi greenstone belt of the southern Superior craton. Identifying Timiskaming-like basins, therefore, may facilitate new discoveries of gold deposits in other Archean greenstone belts. This study focuses on the conglomeratic Ament Bay assemblage (ABA) in the Neoarchean Sturgeon Lake greenstone belt of the western Wabigoon terrane of the western Superior craton. Geologic mapping and petrographic analysis show that the ABA consists of a ≥1000 m thick conglomerate-arenite lithofacies and a conformably overlying ≥200 m thick greywacke-mudstone lithofacies, which are interpreted to indicate a sub-aerial fan delta that transitioned into subaqueous turbidites. The depositional age is constrained to be between 2697.5 ± 1.2 and 2693.2 ± 0.9 Ma by the statistically defined minimum age of the ABA detrital zircons and igneous zircons of an alkalic intrusion within the ABA, respectively. Detrital zircons from seven ABA samples are characterized by ca. 2930, 2780–2770, and 2750–2690 Ma age populations along with minor zircons of ca. 3300–3000 Ma, which are consistent with proximal sources mostly in the western Wabigoon terrane and secondarily in the adjacent Winnipeg River terrane. Petrography of conglomerate clasts and sandstone supports these provenances and reveals additional sources from proximal mafic volcanic rocks. The ABA is interpreted to result from uplift and erosion associated with the late-stage convergence between the western Wabigoon and Winnipeg River terranes and to be partially controlled by a regional fault zone and accompanied by broadly coeval alkalic magmatism. Overall, the ABA is similar to the typical Timiskaming assemblage in lithofacies, depositional environments, structural setting, and syn-depositional alkalic magmatism, but dissimilar to the latter in gold endowment. The apparent lack of gold in the ABA is likely due to assimilation of crustal components into the coeval alkalic melts and a shallow-penetrating fault zone, in contrast to the juvenile nature of alkalic magmatism and deep-penetrating fault zones associated with the Timiskaming assemblage. This study suggests that Timiskaming-like basins similar in geology are not necessarily equivalent to the typical Timiskaming assemblage in gold endowment.

Combined Effect of Organic Carbon and Arsenic on the Formation of Sediment-Hosted Gold Deposits: A Case Study of the Shahuindo Epithermal Deposit, Peru

Abstract Sediment-hosted gold deposits represent a significant portion of the world’s gold resources. They are characterized by the ubiquitous presence of organic carbon (Corg; or its metamorphosed product, graphite) and the systematic occurrence of invisible gold-bearing arsenian pyrite. Yet the role played by these features on ore formation and the distribution of gold remains a long-standing debate. Here, we attempt to clarify this question via an integrated structural, mineralogical, geochemical, and modeling study of the Shahuindo deposit in northern Peru, representative of an epithermal gold deposit contained in a sedimentary basin. The Shahuindo deposit is hosted within Lower Cretaceous fluvio-deltaic carbon-bearing sandstone, siltstone, and black shale of the Marañón fold-and-thrust belt, where intrusions of Miocene age are also exposed. The emplacement of the auriferous orebodies is constrained by structural (thrust faults, transverse faults) as well as lithological (intrusion contacts, permeable layers, anticlinal hinge in sandstone) features. The defined gold reserves (59 tons; t) are located in the supergene zone in the form of native gold grains. However, a primary mineralization, underneath the oxidized zone, occurs in the form of invisible gold in arsenian pyrite and arsenopyrite. Here, four subsequent pyrite generations were identified—namely, pyI, pyII, pyIII, and pyIV. PyI has mean Au concentrations of 0.3 ppm, contains arsenic that is not detectable, and is enriched in V, Co, Ni, Zn, Ag, and Pb compared to the other pyrite generations. This trace element distribution suggests a diagenetic origin in an anoxic to euxinic sedimentary basin for pyI. Pyrite II and pyIV have comparable mean Au (1.1 and 0.7 ppm, respectively) and As (2.4 and 2.9 wt %, respectively) concentrations and precipitated under conditions evolving from lower (pyrrhotite, chalcopyrite, sphalerite) to higher (enargite, digenite, chalcocite) sulfidation, respectively. The pyIII generation is the major gold event in the primary mineralization, with pyrite reaching 110 ppm Au (mean ~7 ppm) and 5.6 wt % As (mean ~1.8 wt %), while coeval arsenopyrite attains 460 ppm Au. Pyrite III is also enriched in other trace elements such as Se, Ge, Mo, In, Ga, and Bi compared to the other pyrite generations, which is indicative of a magmatic source. Bulk analyses of the surrounding unmineralized rocks show only parts per billion levels of Au and less than 25 ppm As. These data, combined with mass balance considerations, demonstrate that the sedimentary rocks could not be the sole source of gold, as they could only contribute a minor portion of arsenic and sulfur (and iron) to the deposit. Conversely, fluids exsolved from a pluton crystallizing at depth likely provided the great part of the gold endowment. Equilibrium thermodynamics simulations, using geochemical constraints established in this study, demonstrate that interaction between Au-As-S-Fe–bearing fluids and organic carbon-bearing rocks strongly enhanced the fluid ability to transport gold by maximizing its solubility as AuI hydrosulfide complexes via a combined increase of pH and aqueous sulfide concentration. This finding challenges the traditional qualitative view of organic matter acting exclusively as a reducing agent for AuI that should promote gold deposition in its native state (Au0) rather than enhance its solubility in the fluid. Our results have significant implications for the exploration of carbonaceous sedimentary environments. Such settings may provide a very effective mechanism for focusing gold transport. Subsequent scavenging of AuI from solution in a chemically bound form is promoted by the precipitation of arsenian pyrite in permeable structural and lithologic traps, bound by more impermeable units, similar to what occurs in petroleum systems. Our integrated study underlines the important potential of sedimentary Corg-bearing rocks in the formation and distribution of gold and associated metal resources.

Origin, nature, and evolution of the northern Pontiac subprovince, Canada: Insights from the intrusive record

The metasedimentary subprovinces of the Superior Province provide critical insights into the tectonic style and thermal state prevailing during its Neoarchean cratonic assembly. The Pontiac subprovince consists of metamorphosed turbiditic sequences with minor interlayered mafic volcanic rocks that are intruded by abundant mafic to felsic plutonic rocks of different geochemical affinities, and for which the source, timing, deformation, and relationship to metamorphism and gold endowment are poorly constrained. Petrological, geochemical, isotopic (Lu-Hf zircon), and geochronological (U-Pb zircon and monazite) data reveal three plutonic events consisting of 1) c. 2764 Ma medium-pressure TTG gneiss, interpreted as the local basement to the Pontiac supracrustal sequences; 2) syn- to late- sedimentary c. 2690–2670 Ma juvenile (mean εiHf = 4.02 ± 1.12) monzonite sanukitoid and highly potassic calc-alkaline sills and plutons; and 3) voluminous c. 2670–2620 Ma S-type granite sourced by protracted partial melting of sedimentary rocks at depth. This succession in the intrusive record combined with syn-depositional volcanism and subsequent Barrovian metamorphism of the metasedimentary host rock is consistent with a transition from a continental rift setting to crustal thickening via terrane assembly and challenges early models of arc accretion.

Case Histories of Orogenic Gold Deposits

This review compares genetic parameters of 12 orogenic gold deposits. The set of examples is considered to represent largely the variability of orogenic gold deposit (OGD) characteristics. The data are presented in tables and include following definitive parameters: regional geologic settings, nature of hosts rocks and mineralization, ore controlling structures, ages of host rocks and mineralization and timing of mineralization relative to metamorphism, hydrothermal alteration mineralogy and ore mineral assemblages, isotopic signatures, physical conditions of ore formation and proposed origin of ore fluids aa well as gold reserves, production, and grades. This allows comparison of deposits from different geologic terrains having different ages and formed under different P-T conditions. The data are further discussed before the background of the orogenic gold system and the crustal metamorphic models that provide different scenarios to explain the source of ore fluids. The orogenic gold system model advocates a metal and fluid source external to the terrain in which mineralization occurred, but the model applies only for 3 of the 12 deposits studied. All other deposits formed most likely from a crustal source, which would favor the crustal metamorphic model. However, the formation of hypozonal OGDs cannot be accounted for by the crustal metamorphic model or by the metamorphic devolatilization model. The data identify a set of coherent signatures in OGDs, but there seem to be no unified model for all possible environmental conditions and facets of ore formation and fluid sources, tectonic and lithologic setting, and scale of gold endowment.

Gold endowment and unloading along pathway for giant gold mineralization: Insights from spatiotemporal variations of in-situ pyrite geochemistry and gold fineness from the Jiaodong gold deposits, north China Craton

Over 5000 tonnes of gold were accumulated in the Jiaodong Peninsula at the early Cretaceous, the sources and critical ore-forming processes of which are still controversial. Here, we conducted comprehensive in-situ textural, elemental and isotopic analyses on pyrite and gold grains from the different mineralization styles, hydrothermal stages and depths for three representative gold deposits (Linglong, Xiadian and Jiangjiayao) from the northwestern Jiaodong Peninsula, with the aim to exactly constrain the sources and ore-forming processes. Three groups of δ34Spyrite were identified in the studied deposits, of which the Group 1 shows stable and low δ34S (4.8–7.6‰) throughout the hydrothermal evolution while the Group 2 has elevated δ34S (6.0–12.8‰) coupled with increasing As and Au concentrations. The Group 3 shows moderate δ34S (5.2–9.8‰) accompanied by high Al and Si concentrations. The Group 1 suggests a low-δ34S primary auriferous fluid derived from a mantle-related source, whereas the Group 2 indicates the primary auriferous fluid leaching additional S, As and Au from the Precambrian metasedimentary rocks along pathway. The Group 3 is petrographically coupled with numerous silicate inclusions, indicating enhanced fluid-rock interaction between the auriferous fluids and the granitic wallrcoks. Gold fineness decreases from the early to the late hydrothermal stages, combined with increasing deposition of polymetallic sulfides, suggesting an increase of pH resulting in efficient Au deposition. Gold fineness and Bi concentrations in pyrite decrease with shallowing, suggesting that cooling affected Au deposition as well. Bismuth-Te-S minerals were identified in the deep depths, combined with the well correlated Bi and Ag, implying that Bi-Te complexes might play a role in transporting Au and Ag at high-temperature conditions. The above results corroborate that multiple sources and ore-forming processes were responsible for the giant gold mineralization, of which the gold endowment from Precambrian wallrocks needs to be further concerned.

Low‐Temperature Thermochronology for Defining the Tectonic Controls on Heterogeneous Gold Endowment Across the Jiaodong Peninsula, Eastern China

AbstractThis study presents a low‐temperature thermochronological data set from the Jiaodong Peninsula in eastern China, including new zircon U‐Th/He and apatite fission‐track data from the Sulu Terrane in the eastern side of the Jiaodong Peninsula and published data from the Jiaobei Uplift to the west. These data reveal differential tectonic evolution between the Jiaobei Uplift and the Sulu Terrane, which is responsible for their heterogeneous gold endowment. Thermal history inverse modeling and structural analysis indicate three broad periods of cooling in the Sulu Terrane. These include: (a) slow cooling from 114 to 50 Ma; (b) rapid cooling from 50 to 40 Ma; and (c) tectonic stability after 40 Ma with little cooling. This thermotectonic evolution pattern shows that the local tectonic evolution of Sulu Terrane and Jiaobei Uplift are relatively independent, although they share identical far‐field geodynamic controls. The critical characteristic is the Early Cretaceous extension within the Sulu Terrane was much weaker than that in the Jiaobei Uplift that underwent a rapid period of uplift in the Aptian. The differential tectonic evolution of the two areas induced variation in structural architecture and consequential differences in degree of extension that are important factors in defining the heterogeneous gold endowment rather than simply suggested differences in ore‐forming fluid chemistry, metal precipitation mechanism, and/or exhumation levels. The intense extension in the Jiaobei Uplift was conducive to voluminous fluid migration and gold precipitation. In contrast, the much weaker extensional setting in the Sulu Terrane was not conducive to large‐scale fluid migration from deep.

Vein-type gold formation during late extensional collapse of the Eastern Desert, Egypt: the Gidami deposit

Orogenic gold deposits, though construed to focused fluid flow during orogenesis, commonly post-date the main accretionary events. Several lines of evidence indicate that orogenic gold formation in the Arabian–Nubian Shield continued through the orogen collapse stage and associated rapid exhumation and thermal re-equilibration. The Gidami gold deposit in the Eastern Desert of Egypt is associated with post-foliation, brittle-ductile shear zones that deformed a weakly foliated tonalite-trondhjemite massif dated as ~ 704 Ma (U–Pb zircon age). Gold-sulfide quartz veins exhibit textural features indicative of repeated mylonitization, recrystallization, and muscovite crystallization. New 40Ar/39Ar ages of muscovite flakes from the auriferous quartz veins and from the altered wallrock overlap within analytical uncertainty at ~ 583 Ma, which corresponds to the climax of extension-related wrenching and rapid exhumation in the region (~ 596 to 582 Ma). Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) data coupled with microtextural characteristics suggest that early formed pyrite generations experienced substantial fluid-mediated recrystallization, and that a set of metals was remobilized by later fluids. A late generation of fibrous pyrite, ubiquitous in microfractures, deposited while the veins re-opened and deformed. The occurrence of free gold particles along with a late-paragenetic assemblage of galena-sphalerite-chalcopyrite(± hessite ± cervelleite) was related to influx of low salinity, metalliferous H2O-NaCl-CO2-CH4 fluids as indicated by the fluid inclusion laser Raman spectroscopy and microthermometry results. Au-mobilization and redeposition at T ≤ 350 °C and P ~ 1 to 1.7 kbar, triggered by intermittent fluid pluses and thermal re-equilibration, were most likely stimulated by extensional structures and within-plate magmatism. Coincident province- and deposit-scale pressure–temperature-time data highlight the pivotal role of the orogenic collapse tectonics in gold endowment in the Central Eastern Desert’s crust.

Tectonic-magmatic setting for Early Cretaceous low-sulfidation epithermal gold deposits in the Xing–Meng Orogenic Belt: Constraints from zircon U–Pb and Hf isotopic data of wulaga deposit, NE China

The Xing–Meng Orogenic Belt hosts an amount of low-sulfidation epithermal gold deposits. However, the tectonic-magmatic setting remains problematic, which hinders understanding the factors that control the gold endowment in the region. Wulaga deposit is the largest low-sulfidation epithermal gold deposit in the northeastern Xing–Meng Orogenic Belt. Gold mineralization occurs in the crypto-explosive breccia zone of subvolcanic granodiorite porphyry. Zircon U–Pb ages of three granodiorite apophyses and previous pyrite Rb–Sr dating (113.8 ± 4.4 Ma) indicate granodiorite porphyry and gold mineralization was coeval. The ore-related granodiorite porphyry is moderate SiO2, high-K calc-alkaline, and metaluminous, suggesting an I-type granite. Moreover, Wulaga granodiorite porphyry displays low initial 87Sr/86Sr ratios and positive εNd(t) values with TDM2(Nd) of 799.7–897.4 Ma and εHf(t) values with TDM2(Hf) of 652–785 Ma, indicating that it was derived from partial melting of the Neoproterozoic juvenile mafic lower crust. Ti-in-zircon thermometry, medium–high Sr/Y ratio, high Ba/La, and fO2 value indicate that Wulaga granodiorite porphyry formed at relatively low temperatures (∼700 °C), rich water, and high fugacity within the stability field of garnet in the juvenile lower crust. Combined with ore-related tectonic-magmatic activities in the Wulaga, Dong'an, and Sandaowanzi gold deposits, the Early Cretaceous low-sulfidation epithermal gold deposits in the Xing–Meng Orogenic Belt were formed from magmatic-hydrothermal events triggered by mutual interaction between post-orogenic lithospheric extension related to the closure of the Mongol-Okhotsk Ocean and arc-back extension associated with rollback of the Paleo-Pacific Ocean plate. These data indicate the potential existence of the Early Cretaceous epithermal gold deposits that are related to the contemporaneous igneous activity.

Fluid sources and mineralizing processes in greenstone belts: a stable isotope (O, H) comparison between the weakly mineralized Moly-Desgagné–Guercheville system and Val-d’Or orogenic gold deposits, Canada

In orogenic gold systems, the source of the fluids and the processes leading to mobilization, transport, and deposition of gold remain debated. Most studies focus on endowed rather than on gold-poor orogenic systems to unravel the “key” parameters of gold mineralizing processes. Here, we present stable isotope (O, H) data from the Moly-Desgagné–Guercheville fault system (gold-free to low gold endowment) in the Chibougamau area, Abitibi greenstone belt, Canada. The gold-free Moly-Desgagné showing and nearby poorly endowed Hazeur showing and Monster Lake deposit share similar features typical of orogenic systems. The stable isotope compositions of tourmaline and quartz from the Moly-Desgagné–Guercheville fault system also display similar characteristics, such as (1) temperature of vein formation of 345 ± 86 °C (1σ); (2) fluid mixing between an upper crustal reservoir (low T – high δD – low δ18O) and a metamorphic water reservoir (high T – low δD – high δ18O); and (3) positive δDfluid values consistent with multiple boiling-condensation cycles related to fault-valve processes. These characteristics are similar to those from the gold-endowed Val-d’Or vein field. The difference in gold endowment between the Moly-Desgagné–Guercheville and Val-d’Or vein fields may be related to the nature of the fault system (i.e., terrane-bounding or “intragreenstone belt”) and the volume and (or) composition (i.e., gold, its ligands, CO2) of the fluid source rocks.

Genesis of orogenic gold systems in the Daduhe belt: Evidence of long-lived fertile mantle lithosphere as a source of diverse metallogeny on the western margin of the Yangtze Craton, China

The poorly documented Daduhe gold belt on the western margin of the Yangtze Craton, an important metallogenic belt in southwest China, is characterized by typical orogenic gold systems against a highly anomalous geodynamic setting. A synthesis of regional and deposit geology, mineralization ages, and S-O isotopic compositions of 33 gold deposits from the Danba-Kangding-Shimian-Mianning area of the belt reveals regional metallogenic patterns, establishes a consistent genetic model, and demonstrates a source equivalent to other diverse mineral systems on the western margin of the Yangtze Craton. The Daduhe orogenic gold deposits are controlled by the lithosphere-scale Xianshuihe and Anninghe strike-slip faults in the northern and southern segments of the belt, respectively. The alteration and ore mineral assemblages of the Daduhe orogenic gold deposits define a wide range of hypozonal, mesozonal, and epizonal sub-types. They formed during two episodes: 1) Early Jurassic gold mineralization related to closure of the Paleo-Tethys Ocean, with a large hypozonal gold deposit on the margin of the Danba dome in the northern segment; 2) Cenozoic gold mineralization associated with continental collision on the Tibetan Plateau, with small mesozonal and epizonal gold deposits in shear zones in migmatite basement and at contacts with cover sequences in both the northern and southern segments. At the belt and deposit scales, the ore-controlling structures for both mineralization episodes are NNE-trending second-order extensional faults or their intersections with the dominant NW-trending compressional faults. The three deposit sub-types have overlapping δ34S of 0 ∼ 10‰, δ18Ofluid of 6 ∼ 11‰, and low He-Ar isotope ratios, all consistent with derivation of ore fluids from metasomatized mantle lithosphere. Importantly, the Daduhe orogenic gold deposits have similar S-O-He-Ar isotope compositions to the giant IOCG, Cu-Ni-PGE, Fe-V-Ti, anomalous porphyry Cu-Mo-Au, and carbonatite-related REE deposits in the Panxi region on the shared margin of the western Yangtze Craton. This suggests that these diverse mineral systems have a common source of ore fluids and metals derived from fertile mantle lithosphere during different geodynamic and metallogenic events. Such a widespread hydrous metal-rich deep source with lithosphere-scale faults as ore fluid pathways, and a depth continuum of orogenic gold deposits in the Daduhe belt suggest a high prospectivity and a higher future gold endowment for the belt. This study adds to an increasing awareness of the diversity of mineral systems on specific craton margins globally.

Nanoscale isotopic evidence resolves origins of giant Carlin-type ore deposits

Abstract The western North American Great Basin's Carlin-type deposits represent the largest accumulation of gold in the Northern Hemisphere. The controversy over their origins echoes the debate between Neptunists and Plutonists at the birth of modern geology: were the causative processes meteoric or magmatic? Sulfur isotopes have long been considered key to decoding metal cycling in the Earth's crust, but previous studies of Carlin-type pyrite lacked the spatial resolution to quantify differences among the numerous generations of sulfide mineralization. We developed a new dual-method, nanoscale approach to examine the fine-grained ore pyrite. The δ34S of the ore pyrite varies systematically with Au concentration at the nanoscale, indicating that both magmatic and meteoric fluids contributed during mineralization, but the magmas brought the gold. Repeated oscillations in fluid ratios upgraded the metal content, resulting in high gold endowment. Our results demonstrate that high-spatial-resolution studies are key to elucidate the spatiotemporal evolution of complex hydrothermal systems.

Structural and geochronological constraints on orogenic gold mineralization in the western Wabigoon subprovince, Canada

Some of the world’s largest orogenic gold deposits are hosted within granite-greenstone subprovinces of the Superior Province of Canada. The known gold endowment of the western Wabigoon subprovince is much less than that of the Abitibi subprovince, despite both Neoarchean subprovinces sharing similar structural and metallogenic histories. Further, the relationship between regional deformation and orogenic gold mineralizing events in the western Wabigoon subprovince is poorly constrained in comparison with other greenstone belts within the Superior Province. New structural mapping of the Dryden area of the western Wabigoon subprovince indicates that it experienced a N–S shortening event (D1), circa 2705–2695 Ma, which reactivated, or initiated the formation of, the E–W-trending Wabigoon and Mosher Bay – Washeibemaga deformation zones (Wdz and MBWdz, respectively). Following the D1 event, after 2695 Ma, a protracted period of NNW–SSE shortening (D2) localized transpression along the Manitou Dinorwic deformation zone (MDdz), which is spatially associated with orogenic gold systems, including the Goldlund deposit (∼1.7 Moz Au) and Kenwest prospect (∼0.3 Moz Au). During D2, the MDdz experienced NW-over-SE sinistral transpression, while the Wdz and MBWdz experienced N-over-S dextral-sense movement. U–Pb geochronology of vein-hosted xenotime from the Goldlund deposit and Kenwest prospect indicate that the main hydrothermal event, and likely gold mineralization, occurred syn- to late-D2 deformation around 2664 ± 8.3 Ma. A second population of xenotime, and overgrowths, recorded a younger hydrothermal overprint between ∼2590 and ∼2580 Ma. These ages are comparable with other absolute geochronology data on hydrothermal events in the gold-rich Abitibi subprovince. The structural evolution and timing of orogenic hydrothermal events in the western Wabigoon subprovince are broadly similar to the Abitibi subprovince. Therefore, we propose that the structural evolution and timing of individual greenstone belts is not the primary controlling factor on their bulk gold endowment. Nevertheless, orogenic gold deposits are spatially associated with major D2 deformation zones and linked to widespread hydrothermal event(s), spanning 2680–2660 Ma across the southern Superior Province.

Geochemistry of hydrothermal zircon as a proxy to fingerprint ore fluids in late Mesozoic decratonic gold deposits

Decratonic gold deposits constitute the most important type of gold endowment in the North China Craton (NCC), although the nature and evolution of ore-related fluids in these deposits remain controversial. Here we investigate geochemistry of hydrothermal zircon grains from the Dahu gold deposit in the Xiaoqinling region in the southern margin of the NCC. We also compile the published information on trace elements in hydrothermal zircon from deposits in the other major gold districts of the NCC. The zircon U-Pb data show ages in the range of 101–148 Ma reflecting prolonged hydrothermal alteration that occurred within an extensional tectonic setting. Based on the trace elements, three distinct groups of hydrothermal zircons are recognized. Group 1 shows low La contents (<1 ppm), high Ce/Ce* (>10), and steep positive LREE patterns ((Sm/La)N > 20); Group 2 possesses high La contents (<10 ppm), low Ce/Ce* (<10), and weak positive LREE patterns ((Sm/La)N < 20); Group 3 displays ultra-high La contents (>10 ppm), low Ce/Ce* (<10), and flat LREE patterns ((Sm/La)N < 20). This classification is also applicable to orogenic and porphyry gold deposits. Group 1 grains initially crystallized from magma and underwent subsequent modification by post-magmatic fluids, whereas Group 2 and Group 3 directly crystallized and regrew from zirconium-saturated aqueous fluids. The La-enriched signature in hydrothermal zircons may mainly originate from undetected REE-bearing phases within zircon that formed during the hydrothermal alteration events. The fluid flow has a significant effect on the redox state of gold metallogenic system. The hydrothermal zircons from decratonic gold deposits display higher Ce/Ce* ratios (1–258) and Ce/Nd ratios (0.7–32.2) than those from orogenic and porphyry gold deposits, indicating that the zircon grains formed from a relatively oxidized fluid.

Magmatic, hydrothermal and ore element transfer processes of the southeastern Archean Superior Province implied from electrical resistivity structure

Although magmatic- and metamorphic- derived fluids are widely recognized mineralizing agents, the role of crustal architecture in defining source and sink zones within the middle to lower crust and upper mantle of ancient orogens remains enigmatic. The globally largest and best-preserved Archean greenstone belts lie in the Superior Province, Canada. They provide an ideal location to investigate the influence of igneous construction and subsequent syn-deformational plutonism and metamorphism on the localization of metal-rich melts and fluids throughout the crustal column. Integration of three-dimensional magnetotelluric modelling and seismic reflection sections across the Abitibi subprovince reveals details of a 'whole-of-crust' magmatic and hydrothermal system. East-west low resistivity structures broadly underlie the surface traces of the major deformation zones that are host to significant gold endowment (>200 Moz), while mid-crustal cross trends suggest mineralized fluids flowed along 'pipes' within fault planes. Most low resistivity structures are inferred to represent domains containing interconnected zones of graphite and/or sulfide. These delineate relict mantle source/transit domains and crustal pathways enriched by the flow of magmas or metamorphic fluids genetically related to a late-stage pulse of ore-bearing magmatism, possibly as a result of slab break-off or delamination. Using the combined MT and seismic data, we develop a 3-D crustal-scale model which highlights how evolving orogenic architecture-controlled mass transfer and metallogenic processes developed.

Gold endowment of the metasomatized lithospheric mantle for giant gold deposits: Insights from lamprophyre dykes

The metasomatized sub-continental lithospheric mantle (SCLM) is increasingly proposed to play a key control in the formation of giant gold (Au) deposits. However, the extent of Au enrichment in metasomatized SCLM and the Au contents of its derivative partial melts remain poorly constrained. Lamprophyres are derived from low-degree melting of metasomatic and fusible components in the SCLM, and could provide fundamental information about the metasomatized source and metal release compared to mantle peridotites and/or pyroxenites. The giant Jiaodong Au province (> 5000 tons, ∼ 120 Ma) in the eastern part of the North China Craton (NCC) is an ideal locality to assess the Au endowment of metasomatized SCLM which may serve as the source of Au, as indicated by the presence of mantle-dominated volatiles in auriferous fluids associated with the deposits. Based on detailed petrological studies, we analyzed Au, S, Cu and platinum-group element (PGE) contents of the SCLM-derived lamprophyres that are temporally (130–121 Ma) and spatially associated with the Jiaodong lode Au deposits. The lamprophyre dykes were emplaced in the deep crust and did not experience significant degassing and sulfide segregation, and the sulfide saturation occurred at a late stage during magma cooling, as demonstrated by sulfide petrography, S contents, Cu/S and Cu/Pd ratios of the lamprophyres. The relatively oxidized (ΔFMQ +1 – +2), hydrous (2–4 wt.% H2O) lamprophyres display variable and generally low Au contents (0.04–3.59 ng/g, mainly 1–3 ng/g, n = 31), as well as low PGE and Cu contents. Their high Au/Cu(N) and Au/Pd(N) ratios together with high Ba/Nb indicate a discernible Au addition to their source, resulting from multi-stage mantle metasomatism related to subduction. However, the average Au contents of the metasomatized SCLM before large-scale Au mineralization are heterogeneous and overall in a range of 0.5–1.5 ng/g. The values are higher than that of depleted SCLM (< 0.5 ng/g) but are still lower than or similar to the fertile upper mantle (1.2–1.7 ng/g). These results indicate that mantle metasomatism related to subduction replenished some amount of Au into previously depleted SCLM, leading to local or regional Au enrichment. However, such processes evidently did not result in remarkable Au enrichment of the mantle source beneath the eastern part of the NCC. We thus propose that the metasomatized SCLM and magmas derived from it, though without anomalously high Au contents, could still provide large amounts of Au for large-scale Au mineralization. Importantly, metasomatic volatiles from the metasomatized SCLM exert a key role, and they enable efficient release of Au from mantle sources, promote Au transportation along trans-lithospheric fault channels and subsequent enrichment and precipitation via magmatic-hydrothermal processes for giant Au deposits.