Gold Content Research Articles

Crystal structural perfection and the associated properties of quartz as an indicator of vein vertical zoning: Example of the Verkhnealiinskoye gold deposit in Transbaikalia, Russia

Research subject. A section of the V ore zone in the Verkhnealiinskoye gold deposit in Transbaikalia. Materials and methods. Samples of host rocks and ores from the core of exploratory wells, which cut the ore zone at depth intervals of 27–34; 57–104; 153–168; 285–293 m, were studied by the methods of chemical analysis, as well as determination of crystal structural perfection, phase α→β transition temperatures, and electrical resistivity of vein quartz. Results and conclusions. An increase in the degree of crystal structural perfection (CSP) of vein quartz in cross sections in the direction from the quartzification zone at the contacts to the axial parts of the vein from 59 to 73 (average 63) in the upper section, from 54 to 79 (average 67.2) in the lower-middle section, and from 86 to 93 (average 89.2) in the section below the wedging of the conductor was established. Over the entire depth range from 27 to 168 m, the average CSP value degree increases from 63 to 89.2. Similarly, although less clearly, phase (α→β) transition temperatures in quartz undergo changes; their connection with the CSP value was revealed. The electrical resistivity of vein quartz increases during the transition from the quartz zone to the quartz vein due to a decrease in the number of inclusions and impurities of hydromica and chlorite. The possibility of using the СSP value in combination with data on the content of gold, silver, and bismuth to assess the level of an erosion section of newly discovered gold manifestations is confirmed, both in individual undercuts by boreholes and in the form of dumps or bedrock outcrops of quartz veins.

Thiocoumarin-based Au(I) Complexes and Au(0) Systems over TiO2 as Hybrid Photocatalysts for Hydrogen Generation under UV-Vis Light.

This work focuses on the photocatalytic production of hydrogen from the photodehydrogenation of ethanol using several gold(I) complexes and gold(0) systems over titanium dioxide (P90 TiO2) as hybrid photocatalysts. The photocatalytic systems are composed of at least one coumarin-based ligand, which can enhance the photocatalytic activity by its photon-absorbing capacity due to its chromophore properties. The photocatalytic behavior for hydrogen generation of the studied samples is compared under UV-vis light setting the total gold-based co-catalyst loading at 1 wt% onto the TiO2 photocatalysts and when the gold content is maintained at 0.25 wt%. The incorporation of gold co-catalysts results in an enhancement of hydrogen production up to 2.7 times compared to a conventional Au/TiO2 reference sample. The results show an increase in the total hydrogen production under UV-vis light due to the combined presence of coumarin chromophore, gold-based co-catalysts, and gold plasmonic nanoparticles. A deep characterization of the samples from each group is performed by UV-vis spectroscopy, XPS, HRTEM, and HAADF-STEM, observing the presence of plasmonic gold nanoparticles for sample "AuL1NPs" and the reduction of the gold present in sample "AuL1a," which explains the highest observed hydrogen production rates of this study.

In-situ trace element and sulfur isotope compositions of Multi-Stage sulfides in the Buzhu orogenic gold (Antimony) Deposit, southern Tibet: Implications for the metallogenic process

The Buzhu gold (antimony) deposit, located within the gold-antimony polymetallic belt of southern Tibet in the Tethys Himalayan belt, is a recently discovered medium-sized gold polymetallic deposit. The orebody consists primarily of gold-bearing quartz sulfide veins. Currently, the metallogenic mechanism of the deposit remains largely unexplored. Utilizing results from the mineralogical observation of principal ore minerals, LA-ICP-MS trace element analysis, and in-situ sulfur isotope analysis of pyrite, investigations reconstruct the evolution process of pyrite-arsenopyrite and constrain the metallogenic process of the Buzhu gold (antimony) deposit. It has been discovered that the gold-bearing sulfides in the Buzhu gold (antimony) deposit are primarily pyrite and arsenopyrite. Pyrite can be categorized into six generations: framboidal pyrite Py0, dissolution cavity pyrite Py1a (some exhibiting oscillatory zoning), disseminated pyrite Py1b, euhedral pyrite Py2a, irregular pyrite Py2b, and Py3. Arsenopyrite, on the other hand, can be classified into three generations: early arsenopyrite Apy0, disseminated arsenopyrite Apy1, and euhedral Apy2. The analysis of δ34S in pyrite throughout the ore-forming process indicates sulfur derives from multiple sources, with Py0 indicative of a biological sulfur source. The evolutionary process of pyrite, supported by trace element analysis, suggests that the remaining pyrite derives from sedimentary fluid transformation, with sulfur primarily sourced from metamorphic sediments. Elemental spectrum analysis and BSE observations indicate that the Buzhu gold (antimony) deposit primarily undergoes two distinct stages of mineralization: the initial stage is the gold-antimony mineralization phase, during which antimony precipitates in the fissures of Py1a as stibnite, while gold is primarily found in Py1-Apy1 as invisible gold, with the highest gold content in Apy1 (28.20–60.13 ppm, average 40.51 ppm). The subsequent stage of mineralization is characterized by gold mineralization, with gold primarily residing in the internal fissures of Apy2 as micron silver gold ore. The evolution characteristics of gold-bearing sulphide and the solubility curve of Au indicate that gold mainly derives from gold-bearing unsaturated fluid, rather than from early framboidal pyrite Py0 (0.52–1.06 ppm, average 0.79 ppm). Only a minor fraction of gold (originating from early sediments) in Py0 was liberated and integrated into subsequent pyrites. The content of antimony in Py0 significantly reduces after dissolution, suggesting that antimony predominantly originates from Py0 (206–440 ppm, average 335 ppm). Throughout the genesis of the Buzhu gold (antimony) deposit, the gold constituent underwent a sequence of pre-enrichment, re-enrichment, liberation, and precipitation. The processes of coupled dissolution-reprecipitation (CDR) and boiling fostered the reactivation and reenrichment of gold. The recrystallization into cubic pyrite led to the expulsion of gold from the pyrite lattice, and fluid oxidation resulting from multistage fluid boiling, coupled with a decrease in sulfur fugacity, led to gold precipitation.

Prediction, modeling, and optimization studies of eco-friendly gold extraction using alpha-cyclodextrin and the RSM and CCD methods

In the Democratic Republic of the Congo, gold extraction from ore in South Kivu utilized alpha-cyclodextrin (α-CD) as an eco-friendly method to replace harmful methods. Analysis of variance and response surface methodology were employed for prediction, modeling, and optimization studies. Atomic absorption spectroscopy revealed a 0.06% gold content in a randomly taken ore sample. Leaching with modified aqua regia was optimized with the following parameters: 7.27 h, 50 g/L HBr concentration, pH 1, and 200 rpm stirring speed, resulting in 98.5% removal. Neutralization tests with potassium hydroxide (KOH) followed leaching to prepare the solution medium with appropriate pH for extraction test, by varying parameters such as time, KOH concentration, and pH. Following neutralization, extraction tests with α-CD were carried out and optimized with the following parameters: 40 min, α-CD concentration of 11.6166 g/L, and a pH of 5, resulting in a percent removal of 98.9%. α-CD’s eco-friendly nature, cost-effectiveness, and high percent removal make it a promising and sustainable alternative for gold recovery, appealing to the mining industry.

Native gold from alluvial deposits of the Kyvvozhsky district and its probable primary sources (Volsko-Vymskoe rise, Middle Timan)

Based on the study of typomorphic features of gold from alluvial deposits of the Kyvvozh region of Middle Timan, including industrial placers, the most probable genetic types of primary sources were determined. The size of gold particles varies widely, reaching the size of small nuggets; along with rounded ones, there are weakly rounded and unrounded particles. Many of them have undergone repeated deformations in the form of envelope-shaped bends, dents and tears. Most gold coins have high-fineness rims. Gold always contains Ag, sometimes Cu, Pd and Cu. Gold particles with a block structure with high-silver vein zones are often found. In intergrowths with gold and in the form of inclusions are noted in it pyrite, galena, and occasionally minerals of the cobaltine-gersdorfite series, ankerite, galenobismutite, native bismuth, aurostibite, and also sudovikovite (PtSe2), which was first identified in the region. Three types of gold have been identified: 1 – homogeneous silver-containing, 2 – block with highly silvery vein-like zones, 3 – rare silver-containing with impurities of Cu, Pd. The morphology, composition and structure of placer gold indicate its entry into placers from various sources, including nearby sources. Of greatest interest are the zones of development in Riphean rocks of hydrothermal veinlet-disseminated sulfide mineralization, oriented in the northwest direction, partially exposed during the development of placers. Gold with Cu and Pd impurities is most likely associated with derivatives of mafic magmatism. The Volsko-Vymskoe, as well as the Tsilemskoe and Chetlasskoe uplifts of Middle Timan can be considered promising in terms of primary gold content and deserve further study and prospecting.

Genesis of high-grade lode gold shoot dominated by ore fluid overprinting during a ductile-brittle shear event

Lode gold deposits hosted by ductile-brittle shear zones account for more than one-third of the world’s gold production. High-grade ore shoots from this type of deposit are the most critical exploration targets. The ore shoots can form through the post-depositional deformation of auriferous sulfides or overprinting of ore fluids accompanied by coupled dissolution-reprecipitation (CDR) reactions. However, the mechanism that dominates ore shoot genesis remains unknown, primarily due to the controversial single progressive or polyphase nature of ore-bearing shear zones. Here, we report on geological and geochemical analyses we conducted at the large Hetai goldfield, South China, to construct an accurate gold upgrading model for the formation of ore shoots. Stages 1−3 of mineralization at Hetai show features typical of ductile shearing, while Stage 4 is characterized by quartz-sulfide veinlets in brittle fractures. 40Ar/39Ar ages of ca. 184 Ma and 157 Ma for the mineralization of stages 1 and 4 overlap with the regionally dextral ductile-brittle shear that occurred during ca. 210−162 Ma. Thus, the gold event at Hetai should have been controlled by a single progressive ductile-brittle shear episode, rather than polyphase structural events. The auriferous fluids at Hetai precipitated minor invisible gold in pyrites (mean 0.173 ppm) produced during stages 1−4 through fluid-rock interaction. The systematic increase of elements Au, As, Sb, Bi, Ag, and Cu and δ34S values in ductile-deformed pyrites from stages 1−3 indicate that early invisible gold upgrading should be the result of the post-depositional remobilization of auriferous sulfides during the long-lived ductile-brittle transition. Cataclastic pyrites hosting invisible gold from Stage 4 have zoned and porous mantles with elevated invisible gold (mean 0.503 ppm) and Sb, Bi, Pb, Co, Ni, and Ti contents. These pyrites are further replaced by chalcopyrite and pyrrhotite with increasing invisible gold, Co, and Ni contents. In addition, numerous visible native gold grains in Stage 4 are included in sulfides formed by replacement and develop along the microfractures and grain boundaries of these sulfides. We suggest the late invisible and visible gold upgrading events in Stage 4 can be attributed to the auriferous fluid superposition and subsequent replacement of pyrite via CDR reactions in a brittle regime. Therefore, the gold upgrading process at Hetai is jointly caused by the early remobilization induced by ductile-brittle deformation and the late ore fluid superposition with accompanying CDR reactions within a brittle domain. As the ore fluid superposition and CDR reactions in Stage 4 produce a significant amount of visible gold, they exert a first-order control on the genesis of ore shoots at Hetai. The refined model may be widely applicable to lode gold deposits elsewhere and can be used to identify regions with promising exploration targets.

Combined study of Au-bearing arsenopyrite of orogenic gold deposits (NE Asia): High resolution 3D X-ray computed tomography, LA-ICP-MS, and EMPA data

The distribution of gold in small acicular arsenopyrite of a pyrite-arsenopyrite association from Suzdal (Eastern Kazakhstan), Olympiada (Yenisei Ridge, Russia) and large pseudorhombic arsenopyrite crystals from Bazovskoe (Yakutia, Russia) orogenic-type deposits were investigated. On orogenic gold deposits in NE Asia, occurring mainly in black shales, two productive stages of ore deposition are distinguished, which correspond to two morphological varieties of arsenopyrite. At the early stage, fine-grained acicular-prismatic arsenopyrite with invisible gold was deposited; at the late stage, tabular arsenopyrite in association with free visible gold was formed. The samples of gold-bearing arsenopyrite were analyzed using Scanning Electron Microscopy, Electron Microprobe Analyses, Atomic Absorption and Laser Ablation Inductively Coupled Plasma Mass Spectrometry in combination with High Resolution 3D X-ray Computed Tomography (HRXCT). HRXCT does not destroy the studied mineral during the investigation. That technique permits to do an estimation of the amount of gold inclusions in minerals or host rocks and draw reasonable conclusions about the gold content of the ores, to study in detail the distribution patterns of metal inclusions (associated with certain minerals, cracks, crystal growth faces, etc.) and to determine the form of the gold. It can be used to understanding of the genesis of productive mineral associations, and to developing optimal technological schemes for gold extraction.

Contrast-to-noise ratio comparison between X-ray fluorescence emission tomography and computed tomography.

We provide a comparison of X-ray fluorescence emission tomography (XFET) and computed tomography (CT) for detecting low concentrations of gold nanoparticles (GNPs) in soft tissue and characterize the conditions under which XFET outperforms energy-integrating CT (EICT) and photon-counting CT (PCCT). We compared dose-matched Monte Carlo XFET simulations and analytical fan-beam EICT and PCCT simulations. Each modality was used to image a numerical mouse phantom and contrast-depth phantom containing GNPs ranging from 0.05% to 4% by weight in soft tissue. Contrast-to-noise ratios (CNRs) of gold regions were compared among the three modalities, and XFET's detection limit was quantified based on the Rose criterion. A partial field-of-view (FOV) image was acquired for the phantom region containing 0.05% GNPs. For the mouse phantom, XFET produced superior CNR values ( , 21.6, and 3.4) compared with CT images obtained with both energy-integrating ( , 4.6, and 1.5) and photon-counting ( , 7.7, and 2.0) detection systems. More generally, XFET outperformed CT for superficial imaging depths ( ) for gold concentrations at and above 0.5%. XFET's surface detection limit was quantified as 0.44% for an average phantom dose of 16mGy compatible with in vivo imaging. XFET's ability to image partial FOVs was demonstrated, and 0.05% gold was easily detected with an estimated dose of to a localized region of interest. We demonstrate a proof of XFET's benefit for imaging low concentrations of gold at superficial depths and the feasibility of XFET for in vivo metal mapping in preclinical imaging tasks.

Paleotectonic setting of basaltoid volcano-plutonic belts with porphyry copper deposits

The article considers geotectonic position and geological features of basaltoid volcano-plutonic belts (VPBs) associated with porphyry copper and gold-copper deposits. Three types of the belts, the oceanic, perioceanic, and riftogenic ones, are distinguished among these VPBs. The oceanic and peri-oceanic belts were incorporated into the composition of ensimatic island arcs and formed at a late stage of their development, after inversion of the basaltoid troughs. The riftogenic belts appeared in island-arc oceanic settings at a late stage of filling the spreading zones. VPBs of the first two types with porphyry gold-copper deposits are located over the convergent boundaries of tectonic plates in an above-subduction position, while belts of the third type form extended linear zones within individual rift structures and contain smallscale porphyry copper objects with poor gold and molybdenum contents. As examples of the structures, the Sunda, Philippine archipelago, New British, Solomon, Alaska, and Antilles ensimatic island arcs and the Irendyk and Novoalekseevsky belts of rift zones of the Southern Urals are described. Volcanic-plutonic associations participating in the structure of these VPBs (including those productive for porphyry copper mineralization), as well as structural-lithological complexes of their basement, are characterized. It is noted that repeated magmatism manifestations during the long-term development of the ensimatic island arcs lead to appearance of several basaltoid VPBs with porphyry gold-copper deposits, while basaltoid belts with porphyry copper objects in the rift settings are formed only once.

Penerapan Metode Enhanced Phytoremediation pada Lahan Bekas Tambang Emas Desa Tirta Kencana Kecamatan Bengkayang

Community gold mining activities using the amalgamation method cause soil pollution due to the use of mercury (Hg) to extract gold content which causes a decrease in soil quality and environmental damage. Enhanced phytoremediation is a method that can be applied to remove mercury levels with using the Cyperus kyllingia plant and adding supporting elements in the form of bacterial isolates that are resistant to mercury. This research aimed to determine the effectiveness of Cyperus kyllingia plants and bacterial isolates for removing mercury levels in mercury-contaminated soil, as well as observing the bacterial population and plant morphology during the research. Based on the research results, it is known that the best efficiency value for removing mercury levels is found in phytoremediation with the addition of bacterial isolates, namely 86.88%. The largest bacterial population was found in the phytoremediation reactor with the addition of bacterial isolates, namely 73.3 × 106 CFU/mL. The mercury content in polluted soil causes changes in plant morphology, namely the color of green plants changes to yellow, but plants can reproduce as indicated by an increase in the number of leaves and plant stems

Remote sensing and magnetic characterization of the Au mineralization and its structural implications: Meatiq dome, Eastern Desert, Egypt

This article examines hydrothermally altered ophiolitic ultramafic rocks (HAOU), specifically Listvenite, which are thrust over the Meatiq dome in the context of gold mineralization. These rocks represent gneissic complexes located in Egypt's eastern desert. The analyses presented herein are essential for understanding the distribution of sheared serpentinite on and beneath the surface and the underlying domal structure. This study offers critical insights into the distribution of serpentinite at Meatiq. It combines remote sensing, aerial and ground magnetic data with petrological, geochemical, and geological analyses to create precise geological maps of potential subsurface igneous structures commonly linked to gold mineralization. Remote sensing is used to test for rock differentiation; intensive field geological investigations were conducted along several traverses. Petrographic and geochemical analysis of selected samples confirmed Au content in some localities. Additionally, tomographic inversion of the collected magnetic land profiles has unveiled previously unidentified subsurface distributions of magnetic susceptibilities, which are essential for explaining the observed surface magnetic anomalies and for understanding the subsurface arrangement of various rock units. Results show that the HAOU rocks have a lower magnetic susceptibility signature relative to the adjacent serpentinites, the serpentinite from South Meatiq shows relatively high gold content, and the gold content decreases with carbonation and alteration of the serpentinite into talc-carbonate, as detected geochemically. The procedure followed in the present study can be regionally applied to studying HAOU rocks of similar geologic conditions. The novelty of this study, beyond the introduction of a novel workflow, lies in the revelation that the rocks forming the Meatiq dome are in thrust contact with steeply dipping suprastructure units.

Antioxidant and anti-inflammatory activity of gold nanoparticles synthesized employing fruit peel extract of Citrus sinensis L.Osbeck

Abstract Nanoparticle biosynthesis has attained a lot of attention because of its cost-efficiency and eco-friendly process. Only limited studies are available which explain the interrelationship between physical parameters (pH, gold concentration, extract concentration, and temperature) and biological synthesis mechanism. The goal of this study was to predict the antioxidant as well as anti-inflammatory activity of biosynthesized gold nanoparticles utilizing Citrus sinensis peel extract. The initial colour shift from yellow to ruby red served as proof that nanoparticles had been successfully synthesized. The nanoparticles that were synthesized underwent various characterization techniques such as AFM (Atomic Force Microscope), FTIR (Fourier Transform Infrared Spectroscopy), FESEM (Field Emission Scanning Electron Microscope), XRD (X-Ray Diffraction), and UV–vis spectroscopy to examine their properties. Further, the synthesis method was optimized for different pH, various gold concentrations, extract concentrations, and temperatures. The nanoparticles displayed good activity as a powerful antioxidant and anti-inflammatory agent. Advanced studies are necessary to explore their therapeutic property.

Gold removal from e-waste using high-intensity focused ultrasound

The demand for rare and precious metals (RPMs), e.g. gold, is increasing, as these are used in the ever-increasing amount of electronics needed for technological development and digitalization. Due to their rarity, virgin mining of RPMs is becoming more difficult and expensive. At the same time, over 62Mt of e-waste is created globally each year. The high concentration of gold and other RPMs in e-waste makes it an excellent source for recycling. Unfortunately, current recycling methods need to separate the different metals and the current pyrometallurgical and hydrometallurgical processes also create toxic pollutants, large amounts of wastewater and require highly corrosive substances. Here we present a new method for gold removal for the purpose of recycling, using only water and high-intensity focused ultrasound to induce material erosion through cavitation. An 11.8 MHz ultrasonic transducer is used to first image the sample to locate gold-coated pads on discarded printed circuit boards (PCBs) and subsequently to remove only the gold layer. We demonstrate that the gold removal can be controlled by the number of transmitted ultrasonic bursts and that the energy efficiency is optimal when only minute amounts of the nickel layer beneath are also removed. Removing solely the gold layer also decreases the need for further processing steps. This greener gold removal method for e-waste is therefore well aligned with, and contributing to, the United Nations Sustainable Development Goal 12: Ensure sustainable consumption and production patterns.

Arsenopyrite from the Low-sulphidation Sedefche Au-Ag deposit, Eastern Rhodopes: Mineral Association and Gold Potential

The Sedefche Au-Ag deposit is located in the eastern Rhodopes, Bulgaria and is part of the Zvezdel-Pcheloyad ore field. The deposit is of low-sulphidation epithermal type, hosted in Oligocene highly silicificated intermediate volcanic tuffs, which lie above shallow marine sediments of organogenic limestones. The orebody has stratiform shape partly outcroping onto the surface. The ore mineralization is represented by small crystals and fine grained aggregates of sulphides (mainly pyrite, arsenopyrite, marcasite, chalcopyrite, galena, sphalerite) and associated sulphosalts (tetrahedrite, pyrargyrite, freibergite, and miargyrite) within matrix of quartz, formed in several stages of deposition. Gold in the deposit is detected in significant amounts in bulk ore samples, while native gold (a single < 1 μm gold nugget) and gold-bearing phases were sporadically discovered. The form of gold presence in the deposit is nevertheless debatable. Using combined SEM-EDS, EPMA and LA-ICP-MS approach, the highest concentrations of gold have been established in the arsenopyrite – the gold content there is up to hundredfold higher than in other ore minerals being potential concentrators of gold such as pyrite, marcasite and chalcopyrite. The presence of gold in arsenopyrite predominantly as nanoparticles, irregularly disseminated in the crystals as clusters of inclusions is suggested.

Synthesis of sodium 1,3-propanebis(dithiocarbamate) and study of its flotation properties

Development and selection of a suitable reagent for efficient flotation is of great importance for ore beneficiation processes. Dithiocarbamates represent a class of organic compounds that are widely used as reagent-collectors in ore flotation. In this work, we conducted an analytical review of the methods currently used for obtaining this class of compounds and established the main method for obtaining dithiocarbamate salts to be the interaction of primary or secondary amines with carbon disulfide (CS2) in the presence of potassium or sodium hydroxide. The aim of the reviewed work was to synthesize sodium 1,3-propanebis(dithiocarbamate), as well as to study its flotation properties in the beneficiation of gold-bearing sulfide ores. A simple and effective method for sodium 1,3-propanebis(dithiocarbamate) synthesizing was proposed. Its structure was confirmed using physicochemical methods (infrared spectroscopy, 1H, 13C nuclear magnetic resonance spectroscopy). A set of studies found that the combined use of potassium butyl xanthate and sodium dialkyl dithiophosphate (BTF-1552) with sodium 1,3-propanebis(dithiocarbamate) led an increase in the efficiency of extraction of the target component of up to 81.63%, as well as an increase in its content in the concentrate of up to 7 g/t. In addition, the combination of sodium 1,3-propanebis(dithiocarbamate) with potassium butyl xanthate was shown to enable an extraction efficiency of 80.51%, as well as a valuable component content in the concentrate of up to 6.5 g/t with a low gold content in flotation tailings of 0.07 g/t. The proposed synthesis method and the results of flotation tests of gold-bearing ores are of interest for further research in the field of organic synthesis and practical application.

Gold Mineralisation and their Lithological Controls at Nagavi Area, Gadag Schist Belt, in Karnataka, India

Dharwar craton is located in southern India is part of the Dharwar-Singhbhum proto-continent and is known for its complex tectonic and structural controls. It’s made up of two distinct parts, Western Dharwar Craton (WDC) and the Eastern Dharwar Craton (EDC) house several schist belts. Many of these schist belts, such as the Kolar schist belt, Hutti schist belt, Chitradurga schist belt and the Gadag schist belt, are auriferous. In such schist belts, gold occurs in association with sulphides such as pyrite, pyrrhotite, arsenopyrite and chalcopyrite. Gold mineralization in these belts is found to occur in different lithologies. The Gadag schist belt is composed dominantly of metabasalt in its western half and meta sediments in the eastern half. Quartz-carbonate veins are observed to cut across these lithologies as well as the Banded Iron Formations (BIFs). This paper aimed to study the gold mineralization in different lithologies of the Gadag schist belt and found that metabasalts and BIFs are the dominant rocks hosting gold. It is also observed that mineralization is strata-bound. Most of the places’ auriferous sheared zones were observed in the study area. In Nagavi area, BIF hosted gold mineralization is observed, and major gold concentration varies from <21 to <26 ppb (parts per billion). Pyrite occurs as characteristic cubic crystals and as clusters of small grains. In carbonated sheared anorthosite, the rock is fine to medium-grained and in-equigranular. It consists of simple to polysynthetically twinned subhedral (100-200 by 400-600 μm) laths (~40-45%) set in a groundmass of irregular anhedral grains of secondary carbonate (~35-40%), chlorite (~8-10%), opaque (~5-7%) and accessory epidote and quartz.

All-solid-state K+ sensing array based on Au@polystyrene nanocomposites.

All-solid-state ion selective electrodes (ASS-ISEs) areeasy to miniaturize and array, meeting the needs of home sensing devices. However, ASS-ISEs still faces challenges in accuracy and stability due to basic potential changes caused by non-specific adsorption of charged background compositions and the complex electrode preparation steps. To this end, our group successfully subtracted the background signal by integrating a self-calibrating channel in the sensing array and simplified the electrode preparation steps by preparing multi-functional PS-Au nanocomposites. However, the uniformity and gold content of PS-Au nanocomposites are difficult to control, so Au@PS nanocomposites are prepared as sensor materials in this paper to further reduce the differences between batches of electrodes. K+ Au@PS sensing array can be obtained by directly dropping Au@PS nanocomposites on the screen-printed carbon electrodes (SPCEs), which shows a near Nernstian behavior in the range 1.0 × 10-3M to 0.3M and good reproducibility in real sample testing. The detection results by K+ Au@PS sensing array for K+ in human morning urine agreed well with that tested by ICP-AES, which make the K+-ASS-ISE suitable for home health monitoring.

Crafting Nanostructured Hybrid Block Copolymer-Gold Nanoparticles by Confined Self-Assembly in Evaporative Droplets.

Hybrid organic-inorganic nanostructures offer significant potential for developing advanced functional materials with numerous technological applications. However, the fabrication process is often tedious and time-consuming. This study presents a facile method for fabricating block copolymer-based photonic microspheres incorporating plasmonic gold nanoparticles. Specifically, the confined self-assembly of poly(styrene)-b-poly(2-vinylpyridine) in emulsion droplets allows the formation of spherical, noniridescent, concentric lamellar structures, i.e., onion-like particles that are subsequently infiltrated with gold salt. Using ethanol as a preferential solvent allows the loading of metal ions exclusively into the poly(2-vinylpyridine) domains, which are subsequently reduced, leading to the in situ, spatially controlled formation of gold nanoparticles. The hybrid structures exhibit a well-defined photonic bandgap and plasmonic resonance at low gold concentrations. These results demonstrate the feasibility of fabricating optically active photonic structures comprising metal nanoparticles in a block copolymer array via a simple two-step fabrication process.

Insight into Limited Recoveries in Printed Circuit Board Leaching: Evidence of Gold Adsorption Loss to Polymeric Particles

AbstractSustainable resource utilization ultimately depends on total recovery during recycling operations. PCB leach pulp for target metal recovery contains ceramic and polymeric particles resistant to reagent attack. The investigation herein shows the physicochemical behavior of five polymeric particles namely green, red, black, white, and blue in gold chloride complex [AuCl4]− solution. Gold concentration change was monitored over time to study how the gold solution interacted with the polymeric particles and how the interaction conforms to known adsorption isotherm and kinetic models. The black and green polymeric particles have the highest adsorption per unit mass to about 1.81 mg/g and 2.18 mg/g, respectively. Four adsorption kinetic models evaluated for insight on the adsorption mechanism observed show Elovich and pseudo-second-order (PSO) models fit the kinetic data best compared to other models with correlation coefficients of 0.9867 and 0.9863, respectively. Of the seven adsorption isotherm models evaluated, Sips model shows best fit for the isotherm data with correlation coefficients of 0.9727 and 0.9328 for green and black particles, respectively. Isotherm and kinetic model analyses of the experimental data indicated physisorption and chemisorption as driving mechanism of the interaction between PCB polymeric particles and gold chloride complex aliquot. Graphical Abstract

Gold nanoparticles for photothermal therapy – Influence of experimental conditions on the properties of resulting AuNPs

Gold nanoparticles (AuNPs)-mediated Photothermal Therapy (PTT) is a minimally-invasive therapeutic approach that uses AuNPs to convert light into heat, leading to the thermal ablation of tumors. Thus, the efficacy of this strategy strongly relies on the photothermal conversion potential of AuNPs. The ability to convert light into heat can be enhanced by tuning the physicochemical and optical properties of AuNPs. This can be achieved by changing the conditions of AuNP's synthesis, such as the order of addition of reagents. The present work entails to explore how varying the order of reagents addition modulates the properties of AuNPs, particularly enhancing the photothermal conversion potential of the resulting AuNPs and consequently, improving PTT efficacy. For this, eleven different AuNPs' nanoformulations were synthetized following different sequences of addition of reagents. These nanoformulations were characterized regarding their physicochemical properties namely size, surface charge, gold concentration, surface morphology and maximum absorbance wavelength. In addition, their thermal activation profiles were determined in vitro. Furthermore, the biocompatibility of different nanoformulations was also assessed. Three nanoformulations, with the most favorable photothermal activation profiles (AuNPs 2, 3 and 7), were then selected for preliminary in vitro safety and efficacy assays using a panel of cell lines. These three nanoformulations were deemed safe in vitro at the tested concentrations. At 250 μM of gold content, and after an incubation period of 4 h, followed by 5 min irradiation with a laser emitting at 808 nm (7.96 W/cm2), AuNPs 7 significantly reduced the cell viability of all cancer cell lines tested (MCF-7, HCT-116 and A375) by ≥ 45 %. However, such cytotoxic effect was not observed for the human keratinocyte cell line (HaCat), thus demonstrating its specificity towards cancer cells. Overall, the results herein presented reinforce that the order of reagents addition is highly important for achieving adequate AuNPs for PTT.