Gold-bearing Pyrite Research Articles

Genetic link between the Kangjiawan gold deposit and late Jurassic granitic magmatism, South China: Constraints from in situ calcite U-Pb dating, sulfur isotope and trace elements of pyrite

(Meta)sedimentary rock-hosted gold (Au) deposits are globally important Au resources, of which ore genesis and mineral exploration have been attracted considerable attention. However, the precise dating of Au mineralization of those Au deposits remains challenging due to the absence of suitable dating minerals, thus impeding a comprehensive understanding of their genesis. The Kangjiawan Au deposit, situated in the southern Hunan Province, South China, is one of representative (meta)sedimentary rock-hosted Au deposits. Due to the lack of mineralization age, the genesis of Kangjiawan Au deposit is still a matter of debate. Here we report the data of in situ calcite U-Pb dating, in situ trace elements and sulfur isotope analysis of pyrite, to further constrain the mineralization timing and the sources of ore-forming materials of the Kangjiawan Au deposit. Based on the detailed field investigation and petrographic observations, three mineralization stages have been identified: pyrite (Py1) + quartz (Stage I), gold-bearing pyrite (Py2) + polymetallic sulfides + quartz + calcite (Stage II), and gold-bearing pyrite (Py3) + calcite (Stage III). The results of mineralogical and trace elemental analyses indicate that Au are mainly hosted in Py2 (average 14.19 ppm) and Py3 (average 4.80 ppm), primarily as the form of “invisible gold”. In situ LA-ICP-MS U-Pb dating on calcite intergrowth with the gold-bearing pyrite (Py3) yields a Tera-Wasserburg lower intercept age of 151.7 ± 5.4 Ma. This age is well consistent with the published zircon U-Pb age (158.3 ± 1.2 Ma) of the nearby Shuikoushan granodiorite, the molybdenite Re-Os age (157.8 ± 1.4 Ma) of the Laoyachao skarn Pb-Zn deposit in the Shuikoushan ore field, and the garnet U-Pb age (159.1 ± 1.9 Ma) of the skarn Pb-Zn ore in depth of the Kangjiawan Au deposit. These suggested that the Au mineralization of the Kangjiawan deposit is coeval with the emplacement of the Shuikoushan granodiorite and Laoyachao Pb-Zn mineralization, which are important parts of the large-scale Middle-Late Jurassic Cu-Au-Pb-Zn Metallogenic event of the Qin-Hang Metallogenic Belt, South China. In addition, trace elemental contents, such as relative low Co, Ni, and Se (i.e., <0.01 to 100 ppm), and a narrow δ34S range of −2.94 ‰ ∼ +3.03 ‰ of pyrite, indicate that ore-forming materials were mainly derived from granitic magmas. Integrated with previous studies, it is suggested that the Au mineralization in the Kangjiawan deposit is genetically associated with the late Jurassic granitic magmatism and is probably as the distal products of the deep-seated concealed granitic intrusions and related proximal skarn Pb-Zn ore.

The mineralogical evidence for the formation of gold-bearing pyrite through the metasomatism of siderite by the Au-As-S multicomponent fluids

The mineralogical evidence for the formation of gold-bearing pyrite through the metasomatism of siderite by the Au-As-S multicomponent fluids

In-Situ Geochemical and Rb–Sr Dating Analysis of Sulfides from a Gold Deposit Offshore of Northern Sanshandao, Jiaodong Peninsula, North China: Implications for Gold Mineralization

The gold deposit offshore of Northern Sanshandao is an ultra-large-scale gold deposit discovered in the Jiaodong ore area in recent years. This deposit is a fractured-zone altered-rock-type gold deposit; however, its ore genesis and precise mineralization processes are still highly controversial. Based on petrographical observation, the trace elements, sulfur isotopes, and rubidium–strontium isotopes of the gold-bearing pyrite were analyzed using LA-MC-ICP-MS to obtain the source of the ore-forming fluids and ore genesis. The results show that Au has a good positive correlation with Ag, As, and Cu. It is speculated that the As in the pyrite of the gold deposit offshore of Northern Sanshandao is in the form of As−, replacing S− and entering the pyrite, causing its lattice defects, and thus promoting the entry of Au+ into the gold-bearing pyrite. The Co/Ni ratios mainly range between 0.1 and 10, indicating that the mineralization process has experienced different forms of hydrothermal evolution and the mixing of different fluids. The results of the in-situ sulfur isotope analysis show that pyrite δ34S in the mineralization period is characterized by a high sulfur value. The authors of this study believe that the initial sulfur isotope composition has mantle-derived components. The large-scale, deep cutting, and high degree of fragmentation in the Sanshandao fault zone are conducive to the interaction between fluids and rocks, as well as the mixing and addition of seawater, resulting in the characteristic high δ34S value. The Sr isotopic compositions indicate a crust–mantle mixing attribute of the mineralized material source. The Rb–Sr isochron age of the pyrite is 118.5 ± 0.65 Ma, which represents the age of gold mineralization. According to the characteristics of the trace elements and sulfur isotopes, it is inferred that the gold deposit minerals offshore of Northern Sanshandao originated from deep magmatic-hydrothermal reservoirs, and the mixing of seawater and Au–As-rich hydrothermal fluids was the formation mechanism of huge amounts of gold precipitation.

Age and fluid source constraints of the Haoyaoerhudong orogenic gold deposit, North China: Evidence from geochronology and noble gas isotopes

The Haoyaoerhudong gold deposit, located in the northwestern part of the North China craton (NCC), has produced over 120 metric tonnes (t) of gold since 2007. It has a total reserve of > 240 t at average gold grade of 0.62 g/t, making it one of the largest open pit gold mines in China. The steeply dipping, large-tonnage, low-grade, vein- or veinlet-type gold orebodies are hosted in strongly-deformed Mesoproterozoic carbonaceous schist of the Bayan Obo Group. The laminated/boudinaged veins/veinlets in the sinistral ductile–brittle shear zones are dominated by quartz, biotite, gold-bearing löllingite, pyrrhotite, (arseno)pyrite, with minor native gold, titanite and xenotime. In this paper, we present new in situ U–Pb geochronological data on magmatic zircon from the pre-ore dikes, on metamorphic and hydrothermal xenotime, and on hydrothermal titanite from the hydrothermally altered carbonaceous schist and auriferous quartz–sulfides veins/veinlets, as well as He-Ar isotopic analysis on gold-bearing (arseno)pyrite in the syn-ore stage. The metamorphic xenotime U–Pb age of 426 ± 6.0 Ma (2σ) records a regional metamorphic event, possibly related to the accretion of the Bainaimiao arc onto the NCC. Two pre-ore andesitic dikes yielded similar emplacement ages at ∼ 278 Ma constrained by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U–Pb zircon data. Hydrothermal xenotime grains from the altered carbonaceous schist and auriferous quartz–sulfides veins yielded U–Pb ages of 256.0 ± 4.1 Ma (2σ) and 254.4 ± 2.1 Ma (2σ), respectively, overlapping with that of the hydrothermal titanite at 255.4 ± 0.8 Ma (2σ) from the laminated quartz–sulfides veinlets. This indicates that the gold mineralization occurred at ca. 255 Ma. The ∼ 255 Ma gold mineralization age is much younger than the previously reported Early–Middle Permian regional magmatic activity (ca. 291 Ma to 268 Ma), and may be associated with the regional sinistral strike-slip event in the late orogenic cycle related to the collision between the Siberian craton and the NCC. The 3He/4He (R/Ra) and 40Ar/36Ar values of the gold-bearing (arseno)pyrite are 0.04 to 0.09 (average = 0.07) and 375.8 to 2023 (average = 1045), which reveal the ore-forming fluids dominantly originated from the crustal rocks, with limited involvement from the mantle. Collectively, our new geochronological data, noble gas isotopic analyses, and geological evidence support a typical orogenic gold deposit model at Haoyaoerhudong.

Textures and trace element geochemistry of pyrite in Gaoloushan ore section of the Yangshan gold belt, West Qinling: Implications for ore genesis

The Devonian Sanhekou Group phyllite in the Yangshan gold belt includes multiple stages of pyrite development, and Au is mainly distributed within the pyrite. Bodies within the Gaoloushan ore section of the gold belt are located in the broken and altered carbonaceous phyllite and granitic rock dykes, where quartz vein-type gold ores are more common as compared to other ore sections (Anba, Getiaowan). Studying the trace element distribution characteristics of gold-bearing and non-gold-bearing pyrite can constrain the evolution of ore-forming fluids and the types of ore deposit genesis. Based on detailed fieldwork and microscopic identification, 48 pyrite samples from the 69th exploration line of the Gaoloushan ore section were analyzed in situ by LA-ICP-MS. The following conclusions were drawn: (1) The gold-bearing pyrite formed during the ore-forming stage while the non-gold-bearing pyrite formed during the sedimentary and metamorphic period. The morphology of the pyrites differs, with gold-bearing pyrite mainly characterized by medium-fine grains, impregnation, fine veins, and reticulate structure, with crystal morphology mainly pentagonal dodecahedra or pentagonal octahedra, whereas non-gold-bearing pyrite is mainly characterized by a medium or medium-coarse grains, with stellate, strawberry, or cluster structures, and crystal morphology mainly in the form of cubes or pentagonal octahedra; (2) The As and Te content of the sedimentary pyrite is low, locally below the detection limit, and the Co and Ni contents and ratios vary greatly, with a distribution of 117–945 ppm and ratio distribution of 0.11–1.92. Pyrite from the ore-forming stage is primarily characterized by high As, Pb, Co, Ni, Cu, Sb, Zn, and Se concentrations, with Bi, Au, and trace amounts of Tl, Te, and Sn observed in later formations; (3) Au and As are positively correlated. The average Au content of 60.53 ppm in pyrite from granite dykes is higher than the average Au 15.97 ppm in carbonaceous phyllite. Pyrite particles with Au contents below the detection limit are sourced in carbonaceous phyllite. In addition, the higher As enrichment is observed in pyrite from granite dykes, averaging 35 770.60 ppm with a maximum value of 72 930.19 ppm. In comparison, the average As content in carbonaceous phyllite is 8974.66 ppm, with a maximum of 69 800.50 ppm, and the Au-As diagram indicates that gold in the Gaoloushan ore section is mainly in the form of solid solution gold within the pyrite lattice; (4) Statistical analysis of the Co/Ni ratio variation in the different lithologies and pyrite stages reveals an initial increase followed by a decrease. The median Co/Ni ratio variations during the mineralization stages of Py1s (0.51–0.7), Py1m (1.35–2.25), Py2 (1.43–1.87), Py1-2 m (1.53), Py2a (1.59), Py2b (1.4), Py2s (1.2), Py2m (1.63), and Py3 (0.19–1.40) suggest that magmatic-hydrothermal fluids dominated during the early stage of mineralization in the gold belt and metamorphic fluids during the main mineralization stage, with deep-seated metamorphic fluids playing a significant role in the late mineralization stage. The varying proportions of ore-forming fluids are likely to have been crucial in controlling gold mineralization in the Yangshan gold belt.

Study on Electrochemical Behavior of Oxidized Pyrite in Alkaline Electrolyte

Nowadays, refractory gold ore production around the world accounts for about 30% of total gold production, and the low leaching rate of such gold concentrate seriously limits the efficient utilization of gold resources. The alkaline preoxidation process can improve the leaching rate of this kind of gold deposit and has good development and application prospects. Therefore, it is of great significance to study the oxidation and dissolution behavior of pyrite in an alkaline environment. In this paper, the oxidation process of gold-bearing pyrite in an alkaline electrolyte was studied using electrochemical techniques, and the oxidation products of a pyrite electrode in an alkaline solution were characterized using XPS, SEM, and other analytical methods. The results show that the optimum pH for pyrite electrochemical oxidative dissolution is about 12, and the oxidation potential of pyrite should be above 0.8 V. In the process of alkaline oxidative dissolution of pyrite, part of the S element enters the electrolyte in the forms of Sx2−, S2O32−, SO32−, and SO42−, and a small amount of the S element is adsorbed on the surface of the electrode in the form of S0 and becomes a part of the passive layer. The Fe element is adsorbed on the surface of the electrode in the forms of Fe(OH)2, Fe2O3, and Fe2(SO4)3, which become the main components of the passivation layer. This study provides a theoretical basis and reference data for the chemical preoxidation treatment of gold-bearing sulfide ores.

Early Mesozoic orogenic gold mineralization in the North Qinling Terrane: Insights from rutile U-Pb, mica and K-feldspar 40Ar/39Ar, and H-O-S-Pb isotopes of the Yangxie gold deposit

The North Qinling Terrane is located between China’s second largest, Early Cretaceous gold province (southern North China Craton) to the northeast and the third largest, Triassic gold province (western South Qinling Terrane) to the southwest. However, only several small- to medium-sized Au deposits and occurrences have been found so far in the North Qinling Terrane, and their genesis and possible links with the gold mineralization in the above two large gold provinces remain unclear. In this study, we present a comprehensive geochronology, stable and radiogenic isotope geochemistry study of the Yangxie gold deposit in the North Qinling Terrane to provide new insights into gold genesis in the North Qinling Terrane and its genetic relations to the neighboring gold provinces. The Yangxie gold deposit consists of quartz-sulfides veins that are hosted by NW- and NE-striking brittle faults cutting amphibolite- to granulite-facies metamorphic rocks of the Paleoproterozoic to Neoproterozoic Qinling Group. Gold mineralization is represented by four paragenetic stages consisting of milky quartz-K-feldspar (I), light grey quartz-pyrite (II), light grey quartz-polymetallic sulfides (III), and quartz-calcite (IV). Gold was deposited mainly in stages II and III, forming abundant native gold grains that occur as inclusions in pyrite, microfracture infillings in sulfide minerals, or interstitial growths to other ore and gangue minerals. Ore-related alteration assemblages comprise mainly quartz, sericite, muscovite, K-feldspar, and calcite. Hydrothermal rutile is widely recognized in gold ores and texturally intergrown with gold-bearing pyrite and other alteration minerals, indicating synchronous precipitation of rutile and gold. Laser ablation ICP-MS U-Pb dating on two rutile samples yield reproducible dates of 214.6 ± 5.5 Ma (MSWD = 0.82, 2σ) and 210.1 ± 6.9 Ma (MSWD = 1.3, 2σ), which are interpreted as the time of gold deposition. 40Ar/39Ar dating of sericite, muscovite, and K-feldspar from the alteration assemblages yield more scattered and younger dates ranging from 199.8 ± 1.1 to 119.3 ± 0.6 Ma, which are considered as the cooling ages of the deposit related to later tectonothermal events. Oxygen and hydrogen isotopes of ore-related quartz and extracted fluid inclusion waters are 10.4 ∼ 15.0 and −87.7 ∼ -67.2 per mil, respectively. Pyrite and galena have variable δ34S values ranging from −9.4 to 0.5 per mil. These sulfides have lead isotopic compositions of 17.956–18.067 for 206Pb/204Pb, 15.565–15.621 for 207Pb/204Pb, and 38.045–38.301 for 208Pb/204Pb. The isotope data collectively suggest that the ore-forming fluids and metals were derived from the devolatilization of the early Paleozoic sedimentary rocks distributed in the North Qinling Terrane. The results presented here, combined with independent studies, show that the Yangxie deposit was a product of the Late Triassic orogenic gold mineralization event that formed the western South Qinling gold province. Recognition of the Late Triassic Yangxie gold deposit suggests that faults within and around the metamorphosed Paleozoic sedimentary rocks and subsidiary faults affiliated to the Shangdan Suture in the North Qinling Terrane could be favorable targets for further Triassic orogenic gold exploration.

Thermodynamic analysis and in situ powder X-ray diffraction investigation of the formation and transformation of mineral phases during pressure oxidation of pyrite

Acid oxidative pressure leaching is a cost-effective way for recovering gold from refractory gold ores such as gold-bearing pyrite, yet our knowledge of the dissolution, crystallization, and phase transformation during pressure leaching is still controversial. This is partially due to the lack of thermodynamic data and in situ studies of the leaching process. Here, we combine thermodynamic modelling and in situ powder X-ray diffraction (PXRD) to investigate mineralogical phase changes during oxidation of pyrite. The polyhedron method has been utilised to estimate the standard Gibbs free energy of formation (∆Gfo) and enthalpy of formation (∆Hfo) of 31 sulphate minerals from 25 °C to 300 °C. The calculated thermodynamic data for the sulphate minerals agree well with the literature, with an average relative error of 0.23% for both ∆Gfo and ∆Hfo demonstrating the reliability of the polyhedron method. Some new thermodynamic data for the mineral phases at elevated temperature was calculated and used to construct the Eh-pH diagrams for the Fe-S-H2O system at 225 °C, which were used to predict phase transformations and chemical reactions during oxidation of pyrite. Based on the analysis of thermodynamic diagrams, the formation of basic ferric sulphate (BFS: Fe(OH)SO4) is favoured at stronger acidic and higher solution redox potential conditions, while hematite and FeSO4∙H2O occur at low solution redox potential conditions. These predictions agreed with the results from laboratory-based in situ PXRD experiments, in which the mineralogical phase transformations were studied during acid pressure treatment of pyrite in a capillary. The influence of initial concentration of ferric ions on the change of mineral phase was revealed. The results confirmed the formation of FeSO4∙H2O and Fe(OH)SO4 phases during the heating (24–225 °C) and annealing stages. These phases may passivate pyrite surface and hence slow down further pyrite oxidation but were re-dissolved during the annealing and/or cooling stages, depending on the initial concentration of ferric ions.

Coupling and decoupling of Au and As in pyrite from Carlin-type Au deposits, southwest China

The low-temperature geochemistry of gold (Au) and arsenic (As) in pyrite from Carlin-type Au deposits is significant for understanding the enrichment mechanisms of Au in pyrite, but remains poorly understood due to the complex processes that lead to the precipitation of micron-scale pyrite grains. This paper concerns the geochemical behaviors of Au and As during the precipitation of pyrite from six Carlin-type Au deposits (the Nibao, Shuiyindong, Banqi, Jinya, Yata, and Zimudang deposits), southwest China. These deposits are located in different locations and ore-bearing horizons of the Youjiang Basin. Arsenian pyrite and/or arsenopyrite are the dominant Au-bearing minerals. Gold-bearing pyrite grains are typically zoned (core, intermediate, and rim), with multiple, oscillatory banded sub-zones. In situ analysis demonstrates that invisible Au exists mainly as cationic Au+ in the growth zones of pyrite. Gold and As are positively correlated (i.e., coupled) in the Nibao and Shuiyindong deposits, negatively correlated in the Banqi, Jinya, and Yata deposits, and poorly correlated in the Zimudang deposit. Arsenic and S substitution in pyrite and the presence of a reduced fluid promoted the incorporation of Au, resulting in the coupling of Au and As. The Au precipitation was affected by changes in the physicochemical conditions of the hydrothermal systems, independent of the As concentration, resulting in decoupling of Au and As. As such, invisible Au precipitation is controlled by the extrinsic physicochemical conditions of the ore-forming fluids and microscopic reactions at the fluid–mineral interface, and also the episodic incursion of Au-rich hydrothermal fluids. High As contents in pyrite favor Au incorporation, but are not solely responsible for Au enrichment. Gold and As contents in pyrite in Carlin-type Au deposits may be coupled or decoupled.

Gold mineralized diorite beneath the Linglong ore field, North China craton: New insights into the origin of decratonization-related gold deposits

Gold deposits in Precambrian cratons were mostly generated during the formation and stabilization of the cratons, but the North China craton is unusual in that its gold deposits were mainly formed ∼1.7 b.y. after its stabilization. A magmatic-hydrothermal origin or mantle-derived fluid source has been proposed for the giant gold deposits of the Jiaodong District in the eastern North China craton, but direct evidence is sparse, and the mineralization processes remain controversial. Here, we present the results of a comprehensive geological, geochronological, and geochemical study of the gold mineralized Xiejia diorite beneath the Linglong ore field at Jiaodong to link the gold mineralization to underlying magmatism. Magmatic zircon and titanite grains from the Xiejia diorite have laser ablation−inductively coupled plasma−mass spectrometry (LA-ICP-MS) U-Pb ages of 121.3 ± 0.9 Ma to 120.8 ± 1.1 Ma and 121.7 ± 3.9 Ma, respectively, which are indistinguishable from the time of gold deposition throughout the Jiaodong District as constrained by previous studies. The diorite has a shoshonitic composition and is characterized by strong enrichment in large ion lithophile elements (LILEs) and light rare earth elements (LREEs) along with significant depletion in high field strength elements (HFSEs) and heavy rare earth elements (HREEs). Samples of the diorite have high initial 87Sr/86Sr ratios, but low εNd(t) and ɛHf(t) values and low Pb isotope ratios. These geochemical characteristics are akin to those of contemporaneous mafic dikes in most gold mines at Jiaodong, indicating that the Xiejia diorite was most likely derived from an enriched lithospheric mantle source. The upper part of the diorite intrusion is pervasively altered and mineralized, containing an average of 0.32 g/t Au, but locally up to 7.59 g/t. Hydrothermal titanite from the mineralized diorite has a LA-ICP-MS U-Pb age of 122.3 ± 4.3 Ma, which is consistent with the gold-bearing pyrite Re-Os isochron age of 122.5 ± 6.7 Ma. Ore-related sericite aggregates from the Dongfeng gold deposit above the Xiejia diorite have a 40Ar/39Ar plateau age of 122.6 ± 1.3 Ma. Pyrite from the mineralized diorite yielded δ34SCDT values of 2.1‰−9.7‰, which are comparable with those of pyrite (δ34SCDT = 5.8‰−8.1‰, where CDT indicates the Canyon Diablo troilite standard) from gold ores of Dongfeng. Pyrite grains from both groups also have similar Pb isotope compositions. The S and Pb isotope data are consistent with values of mafic dikes that are spatially and temporally associated with gold veins in the Linglong ore field. The results presented here thus indicate a possible genetic link between gold mineralization in the Xiejia diorite and underlying magma presumably represented by the Xiejia diorite. The auriferous fluids exsolved from that magma and migrated upward along the Potouqing fault to form the Dongfeng gold deposit above the Xiejia diorite. The mineralized diorite thus links shallow gold mineralization to deep-seated mantle-derived magmatism generated during the extensive destruction of the North China craton induced by the rollback of the subducted paleo-Pacific plate.

Trace Element and Sulfur Isotopic Analysis of Pyrite from the Luyuangou Gold Deposit, Xiong’ershan Au-Ag Polymetallic District, Central China: Implications for The Origin and Evolution of Ore-Forming Fluids

The Luyuangou gold deposit is located in the eastern section of the Xiong’ershan Au-Ag polymetallic district (XESPMD) and consists of a few gold-bearing veins found in the EW-striking faults located in the Archean Taihua and Mesoproterozoic Xiong’er Groups. The gold deposits contain numerous gold-bearing pyrites in thin quartz veins, representing an ideal tool for explaining the enigmatic genesis of gold deposits in the XESPMD. The distributions of trace elements and the sulfur isotopes of gold-bearing pyrite in the Luyuangou gold deposit were investigated to define the origin and evolution of ore-forming fluids. Five generations of pyrite have been identified: coarse-grained euhedral pyrite cores (Py1-1) and margins (Py1-2) in milky quartz veins, fine-grained pyrite (Py2) in quartz veins and host rocks, pyrite (Py3) in quartz + polymetallic sulfide veins, and pyrites (Py4) in quartz calcite veins. The distributions of trace elements indicated that Py2 and Py3 represented the main gold-bearing minerals and contained high concentrations of As, Au, Ag, Pb, Zn, and Cu, and the distributions were controlled by the micro/nanoinclusions. The δ34S values in the five pyrite generations ranged from −19.5 to 3.4‰. Py2 (−15.4 to −6.1‰) and Py3 (−19.5 to −12.4‰) had the lowest δ34S values, indicating that the sulfur originated from an oxidizing fluid. Py1 showed δ34S values (−0.3 to 1.9‰) corresponding to a magmatic origin. Py4 (1.1–3.4‰) displayed the highest δ34S values, indicating that the sulfur originated from the host rock under the action of meteoric water cycles. Analyses of the pyrite’s trace elements and sulfur isotopes, in combination with geological evidence, indicated that magmatic ore-forming fluids contributed to the formation of the Luyuangou gold deposit. The magmatic ore-forming fluids interacted with meteoric water during the main mineralization period. The changing physicochemical conditions of the mineralized fluids caused the precipitation of a large amount of gold and other mineralized elements.

Hydrothermal evolution and gold precipitation mechanism of the Hekou gold deposit, North China Craton: Insights from pyrite texture, composition and in situ S isotope

Pyrite, as one of the most important Au carriers, can well document ore-forming processes. In this study, we select the Hekou gold deposit (HKGD), a newly discovered deposit in the North China Craton (NCC), to rebuild its ore-forming process and gold precipitation mechanism with pyrite. The gold-bearing pyrite was used to perform a combined micro-textural petrography, elemental and S isotope analyses. The micro-textural petrography reveals two distinguished generations of pyrite, including coarse-grained euhedral Py1 and fine-grained xenomorphic Py2. The fine-grained xenomorphic Py2 likely results from a fast nuclear rate responding to the rapid thermochemical changes of hydrothermal fluid. Trace elements of pyrite constrained by LA-ICP-MS reveal that the concentrations of metals such as Au, Ag, Cu, and Pb dramatically increase from Py1 to Py2, suggesting that the fluid evolved to oversaturation. The concentrations of As notably decrease from 284.35 to 23.27 ppm from Py1 to Py2, supporting that As escape from the ore solutions. Moreover, the in situ S isotopes by LA-MC-ICP-MS reveal a minor δ34S fractionation between Py1 (6.29±0.22‰, 2SD) and Py2 (5.95±0.22‰, 2SD), which also agree with the isotopic behavior of H2S escape. All of them, together with fluid inclusion observation, we explain that the two-stage pyrite formation in the HKGD records a hydrothermal system evolution from non-immiscibility (Py1) to immiscibility (Py2). Fluid immiscibility likely effectively facilitated the Au precipitation in the HKGD, via significantly destabilizing the Au-HS complex in fluid and incorporating Au into pyrite. Meanwhile, it also led to an unusual decoupling of Au and As in pyrite. This study highlights that the pyrite texture and chemistry can be excellent tools to reveal trace hydrothermal system evolution and gold precipitation mechanism.

Neoproterozoic Aksu Diabase Dyke, Chinese South Tianshan: Magma Sources and Implications for Regional Gold Metallogeny

Tianshan is one of the world’s largest gold provinces; however, the relationship between gold mineralization and metasomatized subcontinental lithospheric mantle (SCLM) remains poorly understood. To improve our understanding, we present new bulk-rock geochemistry and platinum group element (PGE) concentrations of the SCLM-sourced Aksu Neoproterozoic diabase dykes in Chinese South Tianshan. These data, combined with in situ laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analyses of hydrothermal pyrite grains in the diabase dykes, are used to discuss the SCLM source characteristics in the region and their potential links to formation of gold deposits. The diabase dykes exhibit high Th/Yb (0.47–0.62) and low Nb/U (13.4–16.3) ratios, indicating that magma evolution involves subduction-related fluid metasomatism and limited contamination of the continental crust. This is consistent with little variation in whole-rock Pd/Zr, Cu/Zr, and Ni/MgO ratios, suggesting that no sulfide segregation was caused by crustal contamination and magma mixing. In addition, the diabase dykes show low PGE and Au contents, with high Cu/Pd (&gt;105) and low Cu/Zr (&lt;0.5) ratios, indicating that magmas were derived from low-degree partial melting of the SCLM under S-saturated conditions. Such source characteristics indicate residual sulfides and chalcophile elements (e.g., PGEs, Au, and Cu) were concentrated at the SCLM reservoir in South Tianshan. Hydrothermal pyrite in the studied dykes has similar Au/Ag ratios and trace element distribution patterns to gold-bearing pyrite of lode gold deposits in Chinese South Tianshan, indicating that metasomatized SCLM may have contributed ore metals during the formation of these gold deposits. Adding to the available data, our study highlights that the SCLM may be a potential metal source reservoir, and it may have contributed to formation of the lode gold deposits in Chinese South Tianshan.

The Relationship between Fluid Evolution and Hydrocarbon Accumulation and Metallization in the Nanpanjiang-Youjiang Basin: Evidence from Calcite Petrography and Fluid Inclusions

In the process of diagenesis and burial of sedimentary basins, basin fluid activities participate in the process of hydrocarbon accumulation and metal mineralization. Understanding the evolution of basin fluid is of great significance in revealing the related hydrocarbon accumulation and mineralization. Paleo-reservoirs are closely associated with Carlin-type gold deposits in the Nanpanjiang-Youjiang Basin, South China. Calcite, the fluid activity product, is closely related to bitumen and gold-bearing pyrite. By integrating petrographic, cathode luminescence, and fluid inclusion analysis, as well as the relevant chronological results of predecessors, this paper attempts to establish the relationship between fluid evolution, hydrocarbon accumulation, and gold mineralization. Two types of calcite (black/gray and white) developed in the Banqi-Yata-Laizishan area, the Nanpanjiang-Youjiang Basin. Black/gray calcite is symbiotic with bitumen and features dark red colors in cathode luminescence. Many hydrocarbon inclusions developed along with fluid inclusion analysis at low homogenization temperatures (65.7~173.1 °C). Combining the previously reported U-Pb ages (~250–230 Ma) of this kind of calcite with some geochemistry data on the associated reservoir and gold deposit, this calcite records the consecutive hydrocarbon accumulation and Carlin-type gold mineralization from the Late Permian to the Late Triassic periods controlled by Indosinian tectonic movement. The white calcite featuring bright red in cathodoluminescence is symbiotic with gold-bearing pyrite and realgar, and the associated fluid inclusions have high homogenization temperatures (128.2~299.9 °C). Combined with regional tectonic background and isotopic chronology (~140–106 Ma), it seems to record the early Cretaceous Carlin-type gold mineralization controlled by the subduction of the paleo-Pacific plate in the late Yanshanian period.

Эволюция источников золота в процессе формирования золоторудных месторождений (на примере Восточной Якутии)

In contrast to the established ideas about the relationship of gold mineralization with any specific source, a model is proposed for the evolution of different sources during the formation of geological structures in the eastern framing of the Siberian Platform. The model is based on the calculation of regional clarkes of sedimentary, igneous rocks and minerals with the allocation of stratigraphic levels of primary gold enrichment in sedimentary rocks. The poly-stage and multi-stage nature of the evolution of sources is established through the redistribution of gold in the composition of sedimentary rocks and minerals under the influence of various endogenous heat and mass transfer agents, in particular, under the influence of carbonatites. The main condition for the localization of gold mineralization in the region is the presence of levels of primary supraclarke gold concentrations in turbidites R3, C3—P1, T3 of the deltaic facies of submarine slopes. The main gold concentrators in sediments are marcasite and pyrite. Under the influence of various heat and mass transfer agents, gold is redistributed along the heat flow front, forming zones of dispersed mineralization with its high contents in pyrite and arsenopyrite. Then, under the conditions of late superimposed hydrothermal-metasomatic processes, gold-bearing pyrites and arsenopyrites are released from most of the gold, which appears in the composition of ores of the late stage of ore formation in the form of visible gold particles.

Superimposed mineralization in the Tongbai composite orogen, central China: Revealed from geological and geochronological data of the Yindongpo gold deposit

Multi-period mineralizations commonly form superimposed deposits in the orogenic belt, resulting in some disputes about the ore geneses and metallogenic background. Here, we present a comprehensive geological and geochronological study on the Yindongpo super-large gold deposit in the Tongbai composite orogen, central China, to reveal the ages of multi-period gold mineralizations and their links to the complex tectonic evolution framework of the Tongbai orogen. The Yindongpo gold deposit is located in the Weishancheng ore field in the northern segment of the Tongbai orogen and is mainly hosted in the carbonaceous schist of the Waitoushan Formation. Zircon U-Pb dating of leptynite (445 ± 3 Ma) from the Waitoushan Formation shows that it was deposited in the Ordovician, in an island arc or back-arc basin setting during the accretionary orogeny. Orebodies at Yindongpo are strictly controlled by the Zhuzhuang anticline and related fault systems, and are mainly distributed in the turning end, the collapsed part of the dipping end, and the conjugate thrust shear zone of the limbs. Based on field and petrographic observations, two periods of mineralization and four paragenetic stages (stage I to IV) are recognized: the early period consists of the laminated quartz-molybdenite-pyrite stage (I) and laminated-disseminated pyrite stage (II), whereas the late period consists of the quartz-pyrite vein stage (III) and the quartz-polymetallic sulfide vein stage (IV). Molybdenite from stage I has a Re-Os model age of 409 ± 6 Ma, which broadly matches the U-Pb age of intergrown rutile grains (396 ± 4 Ma). These two ages, in combination with the mineralization characteristics, indicate that the early-period gold mineralization was generated by the metamorphism of the accreted terranes during the Early Devonian northward subduction of the oceanic plate. The timing of the late-period mineralization is constrained by the U-Pb age of monazite (127 ± 2 Ma) intergrown with gold-bearing pyrite from stage III and the 40Ar/39Ar ages of ore-related sericite (131 ± 1 Ma) from stage IV and altered sericite (133 ± 1 Ma) from the carbonaceous schist. Combined with the extensive development of coeval granitoids and porphyry Mo deposits in the region, the late-period gold mineralization at Yindongpo belongs to a unified large-scale metallogenic event related to the Early Cretaceous intensive granitic magmatism in an extensional tectonic setting. The results presented here thus reveal two discrete mineralization processes at Yindongpo related to the Tongbai composite orogeny: the early mineralization of Devonian accretionary orogeny and the later mineralization of Cretaceous intracontinental orogeny. Our study contributes to the knowledge of superimposed metallogenesis in composite orogen, and also highlights the decisive role of multi-mineral isotopic dating in revealing the metallogenic epoch of superimposed deposits.

Textures, trace elements, sulfur, lead and He-Ar isotope analyses of pyrite: Implications for ore-forming processes and the origin of the Shenjiayao gold deposit, southern margin of the North China Craton

The Shenjiayao gold deposit (8.50 t Au, average grade of 2.21 g/t), hosted in a Precambrian metamorphic terrane, is located in the Xiaoshan region on the southern margin of the North China Craton. The gold mineralization is characterized by vein ores comprising native gold and gold-bearing pyrite. Paragenesis of the Shenjiayao deposit can be divided into four stages. Stage I is pyrite – milky quartz veins; Stage II consists of grey quartz – pyrite veins; Stage III is characterized by quartz – polymetallic sulfide veins; and Stage IV minor pyrite – carbonate – quartz veins. Native gold and electrum grains are mainly distributed in the fractures of quartz, pyrite, chalcopyrite, and other sulfides. In this study, three types of pyrite were distinguished based on textural and geochemical results. Py1 has silicate inclusions and mainly occurs as euhedral–subhedral grains formed in the Stage I. Py2 within quartz veins from Stage II shows oscillatory zoning and can be distinguished into two subtypes by their distinct textures (Py2a and Py2b). Py3 coexisting with native gold, chalcopyrite, sphalerite, and galena is characterized by sulfide and silicate inclusions and is divided into two subtypes (Py3a and Py3b). The porosity and heterogeneous textures of Au-bearing pyrite indicate a process of dissolution and reprecipitation. The replacement was likely the result of dissolution–reprecipitation. However, Py1 has very low lattice-bound gold contents, indicating that obtaining high-grade gold orebodies through remobilization of lattice-bound gold is unreasonable. We suggest that the deposition of abundant native gold was induced by a new volume of Au-rich ore-forming fluids and triggered by extensive fluid phase separation during Stage II and Stage III. The δ34S values for the sulfides are similar, ranging from +0.9 ‰ to +5.8 ‰, and the lead isotope compositions of Stage II and Stage III sulfides are consistent. Fluid inclusions extracted from gold-bearing pyrite have elevated 3He/4He ratios (0.18–1.13 Ra) and 40Ar/36Ar (329.5–848.5), indicating the presence of mantle-derived fluids in the ore system.

Typomorphic Characteristics of Gold-Bearing Pyrite and Its Genetic Implications for the Fang’an Gold Deposit, the Bengbu Uplift, Eastern China

The Fang’an quartz-vein gold deposit is located in the eastern part of the Bengbu uplift. The eastern part of the Bengbu uplift is considered to be the western extension of the Zhaoyuan gold mineralization zone in the Jiaodong area of Shandong Province and has huge mineralization potential. The Fang’an deposit was a newly discovered, small-sized gold deposit, and the research in the area is relatively weak. In this study, samples of quartz-vein type ore were collected from the ZK141, ZK1549, and ZK1665 drill holes of the Fang’an gold deposit. Based on the study of the geological characteristics, the major and trace elements of pyrite in different stages were analyzed by electron probe microanalyzer (EPMA), to explore the compositional characteristics of pyrite, the occurrence of gold, and the source of ore-forming fluid. The studies indicate that the deposit experienced four ore-forming stages: the quartz stage, the quartz-pyrite stage, the polymetallic sulfide stage, and the carbonate stage. The pyrites are grouped into three stages, corresponding to the first three ore-forming stages. The EPMA analyses showed that the major elements of pyrite were high Fe and low S, indicating that the formation was hydrothermal. The high content of Ni indicated that the metallogenic materials were derived from between the mantle and the lower crust. The general Co/Ni ratio of &gt;1, with an average of 5.34, indicated that the ore-forming fluid was derived from the magmatic–hydrothermal fluid and wall rock. The Fang’an gold deposit mainly contains nano-gold.

The roles of hydrocarbons on the mineralization of Carlin-type gold deposits, Nanpanjiang Basin, South China

The spatial association of hydrocarbons with metalliferous ore deposits, like MVT lead–zinc deposits, sandstone uranium deposits and various type gold deposits (epithermal Au-Ag (-Hg) deposits, orogenic gold deposits and Carlin-type gold deposits) is found worldwide. However, the genetic relationship between hydrocarbon evolution and mineralization is still under controversy. Integrating isotope dates related to timing of petroleum evolution and gold mineralization from published data, as well as high-resolution transmission electron microscopy (TEM) analysis of pyrobitumen, electron probe microanalysis (EPMA) on both pyrobitumen and pyrite, the In-situ S isotope analyses of the gold-bearing pyrite in this study, we consider different type hydrocarbons (liquid oil and gas) played different roles on the mineralization of Carlin type gold deposits. As the residue of liquid oil cracking, the widespread high maturity pyrobitumen within the reservoir indicate both oil and gas has ever accumulated in the Nanpanjiang Basin. The high gold abundance (EPMA: ∼120 ppm; TEM: ∼1500 ppm) within the pyrobitumen in agreement with the metal solubility experiment suggest liquid oils could have acted as gold carrier before metal precipitation. The late Triassic timing overlapping between gas generation and gold mineralization and the δ34S features with gold bearing pyrite ∼ 10 ‰ lighter than the coeval seawater sulfate indicate gas dominated TSR process may play an important role on the supply of gold bisulfide complex (Au(HS)2−) in the ore-forming fluid and directly involved the precipitation of the Carlin-type gold deposit.

The mechanism of microwave-induced phase transformation and sulfur conversion in gold-bearing pyrite under inert atmospheres

Microwave pretreatment of gold-bearing sulfides in an inert atmosphere has served as a promising technique to improve the extraction of gold. However, the complex decomposition mechanism of gold-bearing pyrite under microwave irradiation has not been completely clarified. This study employs in-situ and ex-situ X-ray diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS) to investigate the phase transformation and sulfur conversion during microwave pyrolysis of gold-bearing pyrite. The removal of sulfur from gold-bearing pyrite caused a significant change at about 600 °C with an activation energy of 223.02 kJ·mol−1. The phase transformation during in-situ heating of gold-bearing pyrite occurred at 500–600 °C, and the crystal lattices underwent thermal expansion along the c-axis direction. Under microwave irradiation, iron (Fe) and sulfur (S) atoms in pyrite rearranged themselves to form different types of pyrrhotite in space groups P31 and P63/mmc, and the symmetry of crystal structure became disordered. After microwave pyrolysis, the formation of polycrystalline aggregates consisting of nanoscale pyrrhotite and unreacted pyrite was confirmed in the TEM study. Microwave-induced hot spots should be responsible for the appearance of numerous holes inside mineral particles. Additionally, the sulfur in pyrite (S22− and Sn2−) was converted to monosulfide (S2−) in pyrrhotite and elemental sulfur (S0), potentially reducing air pollution caused by exhaust emissions. This work provides further insights into the decomposition mechanism of gold-bearing pyrite in the microwave field, and it may help advance the application of microwave pretreatment under inert atmospheres in gold extraction.