Goethite Content Research Articles

Characterization and detailed mapping of C by spectral sensor for soils of the Western Plateau of São Paulo

Soil mineralogy and texture are directly related to soil carbon due to the physical properties of the clay surface. Traditional techniques for quantifying carbon in soil are time-consuming and expensive, making large-scale quantification for mapping unfeasible. The alternative is the use of soil sensors, such as diffuse reflectance spectroscopy (DRS), an economical, fast, and accurate technique for predicting carbon stocks. In this sense, this study aimed to (a) investigate the relationship of C with different soil mineralogical, chemical, and physical attributes for different geological and geomorphological compartments; (b) understand which spectral bands are most important for estimating C content; (c) estimate C content from diffuse reflectance spectroscopy using different mathematical techniques and indicate which one is the best for tropical soil conditions; and (d) map C contents in detail. The study area was the Western Plateau of São Paulo (WPSP), which covers approximately 13 million hectares (~ 48% of the State of São Paulo, Brazil). A total of 265 samples were collected in this area. The attributes clay, silt, sand, crystalline and non-crystalline iron, base saturation, soil density, total pore volume, total C, C stock, kaolinite/(kaolinite + gibbsite) and hematite/(hematite + goethite), hematite and goethite contents, and spectral curves were evaluated. The spectra were recorded at 0.5-nm intervals, with an integration time of 2.43 nm s−1 over the 350 to 2500-nm range (350–800 nm—visible—VIS and 801–2500 nm—near-infrared—NIR). The data were subjected to descriptive statistics, Spearman correlation, stepwise analysis, and cluster grouping for characterization purposes; partial least squares regression (PLSR) and random forest (RF) for estimation purposes; and geostatistics analysis for creation of spatial maps. Our results indicate that the highest C contents are associated with more clayey soils, oxidic mineralogy, higher total pore volume, and lower soil density in highly dissected basalt compartments. The random forest algorithm associated with the Vis–NIR spectral range is more efficient for estimating and mapping C contents. This suggests that integrating diffuse reflectance spectroscopy with machine learning techniques holds promise for shaping public policies related to land use, mitigating CO2 emissions, and facilitating the implementation of carbon credit policies in a rapid and economically efficient manner.

Batch Sintering of FeO·OH and Fe2O3 Blends: Chemical and Metallurgical Characterization

A sample of goethite iron ore sinter feed (G_SF) was employed as a raw material in a sintering bed. This sample partially replaced hematite sinter feed (H_SF), which is currently used as raw material in a sintering plant in the state of Minas Gerais, Brazil. This substitution did not adversely affect the chemical and metallurgical proprieties of the sinter mix product, provided that the utilization of G_SF was kept below 30% in weight. Despite the higher proportion of fines in G_SF, the presence of argillaceous minerals in the sample led to an improvement in the granulation index (GI) of the sinter mix product. The GI value increased from 68.4 to 82.7% for the experiments conducted without the presence of goethite ore and with 40% of goethite ore in the sintering mix, respectively. Consequently, the qualities of both the process and the produced sinter product were not compromised. The raw materials and the various sinters produced were characterized through X-ray fluorescence (XRF) and X-ray diffraction (XRD), as well as thermal gravimetric analysis (TGA). The XRD results were used to perform a quantitative assessment of the mineral phase using the Rietveld method (RM). This technique allowed for the determination of goethite content in the studied sample, which was 35.5%. Finally, the incorporation of G_SF in the sintering bed led to a 20% reduction in the cost of raw materials.

A New Perspective on the Applicability of Diffuse Reflectance Spectroscopy for Determining the Hematite Content of Fe-Rich Soils in the Tropical Margins of China

Hematite and goethite are widely occurring chromogenic iron oxides in soils and sediments that are sensitive to climatic dry/wet shifts. However, only by accurately quantifying the content or ratio of hematite and goethite can they be applied reliably to palaeoclimate reconstruction. Compared to the Loess Plateau of China, hematite in the soils of southern China has not been sufficiently studied. We used diffuse reflectance spectroscopy (abbreviation DRS, including the first-derivative curves and the second-derivative curves of the Kubelka–Munk remission functions), combined with ignition at 950 °C, and X-ray fluorescence (XRF) to quantify the hematite content of four tropical-margin iron-rich soil profiles with different matrix compositions in the Leizhou Peninsula, China. We also examined the application of hematite quantification parameters in soils with different matrix compositions under the same climatic conditions. Our main findings are as follows: (i) DRS first-derivative curves can reflect the presence of goethite and hematite in soils, and their relative contents can be compared within the same profile. (ii) The second-derivative curve of the Kubelka–Munk remission functions can reflect the relative proportions of goethite and hematite and provide information about the degree of Al substitution. (iii) Combined with calibration equations, soil redness can reliably quantify the hematite content, but it is necessary to consider the effect of mucilage envelopes in the process of hematite formation. Additionally, we summarize various methods used for quantifying hematite, and the influence of soil matrix compositions, with the aim of providing a reference for hematite quantification elsewhere. We also propose a new indicator (ΔHmRed/HmRed) to help detect iron hydroxide/iron oxide changes in soils.

Goethite in the Red Clay sequences on the western Chinese Loess Plateau and its responses to the middle Miocene Climate Transition

The middle Miocene Climate Transition (MMCT, ca. 14 Ma), with a sharp drop in temperature, is a key transition period in the Earth’s climatic and biotic evolution. However, our knowledge of how arid-monsoon environments were coupled during the middle Miocene Climate transition remains limited, due to the lack of robust proxies from well-dated sedimentary sequences covering the MMCT in monsoon areas. Goethite is an abundant iron oxide in soils, which is sensitive to persistent wet and cold environments. However, aluminium (Al) substitution is ubiquitous in the pedogenic process, and the Al substitution for goethite in the Red Clay sequence is unclear. In this study, we combined the rock magnetic and DRS methods to assess the Al substitution level of goethite and quantify the goethite content in the Zhuanglang (ZL) Red Clay deposits from the western Chinese Loess Plateau. Our results show that Al substitution in the ZL Red Clay sequence is relatively stable, facilitating the quantification of goethite using this approach. Goethite content displays an increasing trend from approximately 0.2% at 18 Ma to 0.5% at 14 Ma, and then gradually decreased towards the late Miocene in the ZL Red Clay deposits. The maximum goethite production at around 14 Ma indicates a cold and wet climate condition during MMCO at this location. Together with other palaeoenvironmental proxies of this sequences and other sedimentary sequences in the Tianshui Basin, we suggest that climate conditions during the MMCT in the monsoonal western CLP were relatively cold and wet, which was different from the cold and dry climate in the central Asian. Global cooling and the uplift of the Tibetan Plateau might be predominantly responsible for the cold and wet climate during the MMCT.

Effects of chloride on corrosion scale compositions and heavy metal release in drinking water distribution systems

Variations in water chemistry may lead to the release of harmful heavy metals in drinking water distribution systems (DWDSs). In this study, the effects of chloride on the release of heavy metals such as Fe, Mn, As, Cr, Mo, V, Sr, and Co were examined using steel and cast iron pipe loops. After chloride was added, the relative contents of goethite (α-FeOOH), lepidocrocite (γ-FeOOH), and siderite (FeCO3) in pipe scales increased, but the contents of magnetite (Fe3O4) decreased. The most prevalent compounds were α-FeOOH and γ-FeOOH. When the chloride levels were increased, the effluent concentrations of Fe, Mn, As, Cr, Mo, V, Sr, and Co significantly increased. These heavy metals were released presumably because of the destabilization and dissolution of corrosion scales induced by chloride and adsorption site competition. Strong positive correlations were also observed between Fe&Mn, Fe/Mn&As, Fe/Mn&Cr, Fe/Mn&Mo, Fe/Mn&V, Fe/Mn&Sr, and Fe/Mn&Co, indicating the co-release of Fe, Mn, and other metals. This study may be helpful for the potential strategies on avoidance of heavy metal release and improvement of water supply security.

Characteristic and distribution of grain sizes and minerals in sediments from the Vietnamese Gulf of Tonkin

Grain sizes and minerals of sediments from the Gulf of Tonkin were evaluated from 30 surface samples and 50 samples from two cores. The distribution of grain sizes and minerals from these samples were determined to help understand sediment characteristics, origins, and environmental dynamics. There were five sediment types: fine and very fine sands, very coarse, coarse, and medium silts. Minerals in the sediment were identified as decreasing in terms of the content of quartz, illite, kaolinite, chlorite, feldspar, goethite, halite, calcite, gibbsite, aragonite, and montmorillonite. Contents of major minerals such as quartz, illite, kaolinite, and chlorite varied from nearshore to offshore; quartz was higher nearshore than offshore; illite, kaolinite, and chlorite from nearshore were lower than offshore; calcite and aragonite were low nearshore and higher in the offshore; goethite was lower offshore and higher nearshore; and, finally, halite was high offshore and low nearshore. Surface sediments were divided into three groups based on sedimentary environment characteristics: Group 1 was distributed nearshore with strong dynamics, Group 2 in bays and nearshore with weak dynamics, and Group 3 was distributed offshore with quiet dynamics. The origin of the sediments was weathering and erosion from the mainland and islands under the river and sea processes in the Gulf of Tonkin with quartz, illite, kaolinite, feldspar, chlorite, and montmorillonite found present in the sediment. Geochemical processes produced goethite, gibbsite, halite, and pyrite in the sediments while biological substances produced calcite and aragonite.

The Color Formation of “Lumu Stone” in the Weathering Processes: The Role of Secondary Hematite and Goethite

Rocks and minerals buried in the earth’s surface usually undergo weathering processes and change color in the burying environment. A kind of yellow Chinese stamp stone named “Lumu stone”, which is buried in a yellowish weathering crust (yellowish soil), was selected to investigate its color changes in the weathering processes. In this study, the appearance features, mineral components, micromorphology, spectroscopy characteristics, and color causation of the “Lumu stone” were studied by using X-ray powder diffraction (XRD), scanning electron microscopy (SEM), an electron probe microanalyzer (EPMA), a laser ablation inductively coupled plasma mass spectrometer (LA-ICP-MS), and a UV-Visible (UV-Vis) spectrum. The “Lumu stone” usually exhibits a darker yellow outer layer and a lighter yellow core, suggesting that yellow color permeated into the stone from the surface to the core gradually and the color is secondary forming. The results from XRD and SEM show the studied samples are mainly composed of dickite and illite. The individual particles of the dickite and illite are about 2–5 μm, randomly distributing in the three-dimensional space and constituting voids among the particles. The acid pickling experiments using HCl coupled with KSCN confirmed that the mineral phases that caused the yellow color of the matrix are iron oxide and hydroxide. On the other hand, goethite and hematite were observed gathering in the yellow and brown-red cracks on the “Lumu stone” by SEM study. However, iron oxide and hydroxide in the matrix were difficult to observe and detect among the dickite and illite aggregates by SEM and XRD methods. It indicates that they may be nanoscale in size and very low in content. According to the calculation of the second derivative of Kubelka-Munk (K-M) transformed diffuse reflection spectroscopy (DRS) curves obtained from UV-Vis, the characteristic peaks of goethite and hematite were found in the yellow matrix, and their contributions to the color were confirmed. The concentrations of goethite and hematite were calculated to be 0.32 to 1.87 g/kg and 0.22 to 0.93 g/kg in the studied samples, respectively. In this study, a series of methods were employed to detect very low levels of goethite and hematite in the samples undergoing weathering processes. Additionally, nanoscale goethite and hematite were considered newly formed minerals when buried in the weathering processes and may gradually move into the voids among phyllosilicate particles. Therefore, they turned the “Lumu stone” yellow.

Goethite affects phytolith dissolution through clay particle aggregation and pH regulation

Formed in plant tissues as fine silica particles, phytoliths are deposited within plant debris in soils where they can dissolve and feed silicon (Si) fluxes to the biosphere and hydrosphere. Yet, soil phytoliths can be protected from dissolution by entrapment in aggregates, and thus be withdrawn from the global silica cycle. Among clay-sized minerals interacting in stable aggregates, goethite and kaolinite are ubiquitous in soils. We analyzed the impact of goethite-mediated aggregation on the release of aqueous Si from phytoliths entrapped in microaggregates containing organic matter and kaolinite, with quartz and goethite at variable concentrations, simulating a soil sequence with increasing contents of clay and iron oxide, as it can commonly occur in terrestrial ecosystems. The microaggregates stored sizable amount of organic carbon, the release of which decreased with increasing goethite concentration. Aqueous Si was assessed through a kinetic extraction with dilute CaCl2, while pH, aluminum (Al) and germanium (Ge) concentrations were measured in the CaCl2 extracts. Our experimental data showed that phytoliths were the source of aqueous Si. They also showed that the process of phytolith dissolution prevailed over Si adsorption on goethite. As mediated by goethite, aggregation protected phytoliths from dissolution at goethite concentrations above 20 g kg−1. Increasing goethite concentration enhanced aggregation on the one hand, but increased pH from 5.5 to 7.5 on the other. Thus, while aggregation significantly reduced the release of aqueous Si by 1.7- to 3-fold at a given pH, the increase in pH enhanced it. Overall, at common soil solution pH (5–6), aggregation reduced Si release by 2–3 times. Thus, preservation of phytoliths in aggregates can be widespread in well-aerated soils and more effective than Si adsorption on secondary oxides in retaining Si.

UVA and goethite activated persulfate oxidation of landfill leachate

In this study, UVA and goethite activated persulfate oxidation was applied to treat a synthetic (SLL) and a real landfill leachate (RLL) spiked with sulfamethoxazole (SMX). Initially, SLL was used to find the optimum landfill leachate (LL) treatment conditions in terms of total organic carbon (TOC) and SMX removal. The screening experiments were conducted using a two-level, four-factor Plackett-Burman design (PBD) to investigate the effects of UVA irradiation, time, concentrations of persulfate (PS) and goethite, on the removal of TOC and SMX. Dark experiments (PS/Goethite) yielded only a 2% TOC removal. Therefore, further experiments were conducted under UVA (365 nm) using a three-factor Box-Behnken design (BBD) in conjunction with response surface methodology (RSM). Analysis of variance (ANOVA) indicated high regression coefficients for the BBD-RSM model in the case of TOC removal (R2 = 0.9755, adjusted R2 = 0.9314 and predicted R2 = 0.7956). In the case of SLL, RSM predicted an 84.4% TOC removal at the reaction time of 5.33 h, PS concentration of 477.4 mM, and goethite dosage of 755 mg/L under UVA. Experimentally, an 81.8% TOC removal and 100% removal of SMX were obtained under these conditions. Finally, the obtained optimum conditions were recalculated using RLL from the local municipal solid waste landfill, and 87% TOC and 100% SMX removals were obtained for PS concentration of 419.3 mM and goethite dosage of 663 mg/L after 4.68 h under UVA irradiation. Air stripping of RLL at pH 11 was complementarily applied to completely remove ammonia nitrogen after 3 hours. The results demonstrated the efficiency of the UVA/PS/Goethite system for the removal of organic matter from the LL for the first time.

Study of Mineralogy and Metallurgical Properties of Lump Ores

The ironmaking process in blast furnaces using iron lumps is an energy-efficient and low-carbon initiative that helps lower the cost of the ironmaking process. The physical and chemical properties of raw materials, process mineralogy, and metallurgical properties of three Malaysian iron ore lumps were researched in this paper, with the goal of showing the relationship between metallurgical qualities and mineralogy. The results show that lump ore A has a better decrepitation index, with a DI−6.3mm of only 0.2%; lump ore J has better reducibility and low-temperature reduction disintegration index, with RI and RDI+6.3mm values of 88.39% and 87.55%, respectively; and the three lump ores have excellent softening and melting properties and a high permeability index. The metallurgical properties of lump ore and mineralogical characterizations are generally correlated, the decrepitation performance of lump ore is mostly determined by the presence of goethite, and the original porosity is unrelated. The higher the content, the worse the decrepitation performance; lump ore’s reducibility is mostly determined by the open porosity and the content of newly generating hematite at high temperatures, which has no relationship to its original porosity. The higher the open porosity, the higher the goethite content, the higher the newly generated porous hematite content, and the better the lump ore’s reducibility; the higher the original hematite content in the lump ores, the lower the open porosity at high temperatures and the worse the reduction degradation characteristics.

Late Holocene sediment provenance change in the Red River Delta: A magnetic study

Holocene climate change and human activities can lead to sediment composition variations. In this study, two drilled cores (VN and GA) from the Red River Delta, Vietnam, were subjected to magnetic measurement, as well as particle size, diffuse reflectance spectroscopy (DRS), and geochemical analyses, to infer Holocene sediment provenance changes. Both cores VN and GA cover estuarine, shallow marine, delta front slope, delta front platform, and delta plain facies in ascending order, with the former covering the whole Holocene while the latter covering the late Holocene. In the younger core GA, the clay content has a significant positive correlation with magnetic grain-size indicators (χARM/SIRM and χfd%) and a negative correlation with demagnetization parameters (S-100 mT and S-300 mT), reflecting the enrichment of fine-grained ferrimagnetic minerals and antiferromagnetic minerals in finer sediments. On the contrary, the relationship between the above-mentioned magnetic properties and clay content is not significant in core VN, reflecting the impact of stronger post-depositional diagenesis. In addition, diagenesis in the shallow marine and delta front slope facies of two cores is more pronounced, which is due to the fact of higher input of marine-sourced organic carbon. A magnetic comparison of the upper parts of two cores indicates that there are sediment source changes within the last 2000 years, which is supported by DRS analysis. Sediments in delta front slope and delta front platform of two cores have similar goethite content, but core GA contains higher hematite content indicating a drier condition. Such a sediment source change can be interpreted by variations of monsoon climate and reworking of soil due to human disturbance. Surface soil erosion due to human activities over the last 0.5 ka is supported by the presence of ultra-fine grained magnetite. Our study demonstrates that magnetic properties together with DRS analysis can provide insights into paleoclimate and paleoenvironmental change in deltaic environments.

Controlling factors and palaeoclimatic significance of colour reflectance in the Late Tertiary red clay on the Chinese Loess Plateau

The colour of soil is one of its most striking features, and records the palaeoenvironment conditions when the soil is formed; however, the controlling factors and palaeoclimatic significance of colour reflectance in the Late Tertiary red clay are poorly understood. In this study, the Jiaxian section, on the northern edge of the Chinese Loess Plateau, was selected to explore the aforementioned issue using colour reflectance, diffuse reflectance spectroscopy (DRS), geochemical, and magnetic approaches. In the red clay sequence, (1) the concentration of iron oxides (mainly haematite and goethite) and the intensity of pedogenesis were significantly positively correlated with redness (a*) and yellowness (b*). (2) a*, b*, and a*/b* can be used as proxy indicators of haematite concentration, goethite concentration, and temperature, respectively. (3) The parameters derived from colour reflectance and DRS measurements were proven to be better than magnetic susceptibility (χ) in recording palaeoclimatic evolution, and Ca*b* was better than the chemical weathering index in recording soil development.

Abatement of Naphthalene by Persulfate Activated by Goethite and Visible LED Light at Neutral pH: Effect of Common Ions and Organic Matter

Naphthalene (NAP) has received particular attention due to its impact on the environment and human health, mandating its removal from water systems. In this work, the abatement of NAP in the aqueous phase was achieved using persulfate (PS) activated by Fe (III) and monochromatic LED light at a natural pH. The reaction was carried out in a slurry batch reactor using goethite as the Fe (III) source. The influence of the PS concentration, goethite concentration, irradiance, temperature and presence of organic matter, chloride, and bicarbonate on the abatement of NAP was studied. These variables were shown to have a different effect on NAP removal. The irradiance showed a maximum at 0.18 W·cm−2 where the photonic efficiency was the highest. As for the concentration of goethite and PS, the influence of the first one was negligible, whereas for PS, the best results were reached at 1.2 mM due to a self-inhibitory effect at higher concentrations. The temperature effect was also negative in the PS consumption. Regarding the effect of ions, chloride had no influence on NAP conversion but carbonates and humic acids were affected. Lastly, this treatment to remove NAP has proved to be an effective technique since minimum conversions of 0.92 at 180 min of reaction time were reached. Additionally, the toxicity of the final samples was decreased.

An Overview of Late Quaternary Studies and Status of Mineral Magnetism from the Konkan Coast: Constrains on Degradation of the West Coast of India

We present here an overview of textural, sedimentological, magnetic, and remote sensing studies from different sectors of the west coast along with new mineral magnetic results. The emerging coastal erosion and growing incidences of extreme events with an increase in cyclones in the Arabian Sea are affecting these beaches at higher rates of dynamics. The sand characteristics, textures, sorting and clast composition have been studied to correlate them with energy conditions and interpret the transportation dynamics. Heavy mineral analyses delineated provenances and detrital pathways, the morphological and volumetric vicissitudes of beaches helped characterize western coast beaches into stable, eroding or depositing regimes aided by time elapsed satellite images. The multi-parametric studies unravel the relationship of hydrodynamics over a range of geomorphic features. The predominant controls of longshore and rip currents in altering the land-sea interfaces at less than decadal scales were observed. New mineral magnetic results from the Vengurla Beach of the Sindhudurg district are evaluated in above context and to establish semiquantitative relations amongst depositional and erosional patterns that can be further linked to the effects of degree and intensity of local monsoon. The beaches record systematic changes in the concentration of magnetite, haematite, maghaemite, and goethite as a result of a combination of the above beach processes. The studies from Vengurla beach successfully demonstrate mineral magnetism as a suitable quantitative approach to depict the quasi-decadal effects of long shore currents that are further governed by the shoreline changes resultant of increasing competitiveness between coastal erosion and depositional conditions in recent years. The status of studies over the west coast depicted an alarming increase in the rates of erosion at several beaches demanding quantitative monitoring using the integrative approach of mineral magnetism and satellite data. Keywords: West Coast, Magnetic Susceptibility, Curie Temperature, Provenance, Sindhudurg.

Quantitative Study on Colour and Spectral Characteristics of Beihong Agate

The Beihong agate from the southern section of the Xing’an Mountains in northeastern China is a kind of cryptocrystalline agate with a yellow to orange-red colour. However, it has been less studied in previous research, and there is a lack of quantitative study on the cause of its colour. In this study, the colour of Beihong agate was quantified by a colourimeter, and the quantitative relationships between colour and spectral characteristics of Beihong agate were studied by XRF, Raman spectra, UV-VIS spectra, and a heat treatment experiment. The results show a high correlation between the lightness and the hue angle of the Beihong agate. The change of total Fe content can significantly affect the lightness and the hue of the Beihong agate. The first derivative curve can effectively distinguish the relative contents of goethite and hematite in the Beihong agate, and the position of a primary trough is related significantly to the colour of the Beihong agate.

Colorimetric characterization of ochres in a Palaeolithic flint pebble from Maschio dell’Artemisio, Latium, Italy

The flint pebble from Maschio dell’Artemisio, a mountain near Velletri (South-East of Rome), is one of the earliest complex artefacts from the Upper Palaeolithic of the Colli Albani possibly displaying a symbolic/artistic value. It has been used as a stone-striker and retoucher, to create or modify lithic implements. It shows a diffuse and intense ochreous colour on almost half of its surface. Here we discuss the results of an innovative colorimetric approach to define the use of pigments in the area during the Upper Palaeolithic and eventually compare the raw materials with local supplies. Second-derivative diffuse reflectance spectroscopy, a data treatment on colorimetric data used since the 1980s in the characterization of soils, for the first time is here applied to the lithic industry, to characterize and quantify the presence of yellow and red ochres, found in mixture on the surface. We used both a colorimeter and a fibre optic reflectance spectrometer (FORS) and then compared the results to assess their efficiency and define a protocol useful for future investigations on lithic tools. Colorimetric results can lead to an easier estimation of the redness rating, which represents the relative content of hematite and goethite, independently on the level of expertise of the operator. FORS data were more suitable to determine the variation of the inflection point in the reflectance curves. Both techniques showed that in all the points analysed on the flint pebble there is a mixture of yellow and red ochre, possibly reflecting the exploitation of the surrounding area during the Final Pleistocene.

Deconstructing the Iron Boomerang—Quantitative Predictions of Hematite, Ochreous, and Vitreous Goethite Mixtures

The so-called iron boomerang is constructed by using a combination of spectral metrics derived from the 900 nm 6A1→4T1 Fe3+ crystal field absorption. Previous work showed the iron boomerang provides qualitative information about the mineralogical type of spectral datasets of Western Australian iron ore deposits. That work is expanded to demonstrate how the shape of the iron boomerang is driven by a linear mixing regime between hematite and ochreous and vitreous goethite. The iron boomerang enveloping shape is defined by mixing pathways between 3 different 2-endmember systems of hematite–ochreous goethite, hematite–vitreous goethite and ochreous–vitreous goethite and a 3-endmember mixing regime in the interior of the boomerang. This provides a novel methodology of quantifying the relative hematite, ochreous, and vitreous goethite content from spectrally derived data. A combination of 4 spectral metrics as input features to a random forest regression model results in modelling root mean squared errors (RMSE) of approximately 4% when all endmembers are known and in a system where the endmembers are not known the RMSE is approximately 10%. Additionally, a means of identifying potential hematite endmembers from a spectral dataset is presented. Lastly, the regression models are applied to 3 iron ore diamond drillcore from the Hamersley Province in Western Australia and demonstrates that the proportions of hematite, ochreous, and vitreous goethite can be estimated downhole which, in turn, provides ore zone delineation and hardcap and hydrated zone identification.

Inferring iron-oxide species content in atmospheric mineral dust from DSCOVR EPIC observations

Abstract. The iron-oxide content of dust in the atmosphere and most notably its apportionment between hematite (α-Fe2O3) and goethite (α-FeOOH) are key determinants in quantifying dust's light absorption, its top of atmosphere ultraviolet (UV) radiances used for dust monitoring, and ultimately shortwave dust direct radiative effects (DREs). Hematite and goethite column mass concentrations and iron-oxide mass fractions of total dust mass concentration were retrieved from the Deep Space Climate Observatory (DSCOVR) Earth Polychromatic Imaging Camera (EPIC) measurements in the ultraviolet–visible (UV–Vis) channels. The retrievals were performed for dust-identified aerosol plumes over land using aerosol optical depth (AOD) and the spectral imaginary refractive index provided by the Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm over six continental regions (North America, North Africa, West Asia, Central Asia, East Asia, and Australia). The dust particles are represented as an internal mixture of non-absorbing host and absorbing hematite and goethite. We use the Maxwell Garnett effective medium approximation with carefully selected complex refractive indices of hematite and goethite that produce mass fractions of iron-oxide species consistent with in situ values found in the literature to derive the hematite and goethite volumetric/mass concentrations from MAIAC EPIC products. We compared the retrieved hematite and goethite concentrations with in situ dust aerosol mineralogical content measurements, as well as with published data. Our data display variations within the published range of hematite, goethite, and iron-oxide mass fractions for pure-mineral-dust cases. A specific analysis is presented for 15 sites over the main dust-source regions. Sites in the central Sahara, Sahel, and Middle East exhibit a greater temporal variability of iron oxides relative to other sites. The Niger site (13.52∘ N, 2.63∘ E) is dominated by goethite over the Harmattan season with a median of ∼ 2 weight percentage (wt %) of iron oxide. The Saudi Arabia site (27.49∘ N, 41.98∘ E) over the Middle East also exhibited a surge of goethite content with the beginning of the shamal season. The Sahel dust is richer in iron oxide than Saharan and northern China dust except in summer. The Bodélé Depression area shows a distinctively lower iron-oxide concentration (∼ 1 wt %) throughout the year. Finally, we show that EPIC data allow the constraining of the hematite refractive index. Specifically, we select 5 out of 13 different hematite refractive indices that are widely variable in published laboratory studies by constraining the iron-oxide mass ratio to the known measured values. The provided climatology of hematite and goethite mass fractions across the main dust regions of Earth will be useful for dust shortwave DRE studies and climate modeling.

Weathering events recorded in uppermost Hauterivian\u2013lower Barremian clay-dominated continental successions from the NW Iberian Range: climatic vs. tectonic controls

The facies and clay mineral study of clay/marl-rich levels from the Torrelapaja Formation (latest Hauterivian–early Barremian, NW Iberian Range, NE Spain) allowed to establish the palaeoclimatic and palaeoenvironmental conditions under they were generated. The muddy levels and pisoids contained therein of two logs were sampled and studied by X-ray diffraction and optical and electron microscopy. A similar mineralogical upwards trend is recorded in both logs, with a decrease in calcite coupled with an increase in quartz and orthoclase content and constant proportions in goethite, hematite, diaspore, anatase, rutile, ilmenite, and clay mineral content. The lower muddy levels have higher kaolinite content than the upper levels, where illitic phases are the dominant clay minerals. Smectite and intergrowths of illitic phases and kaolinite are also detected upwards. The kaolinite and smectite textures indicate an authigenic origin, whereas the illitic phases are former phases acting as a substrate for kaolinite crystallization. Pisoids mineralogy and texture show an in-situ origin, but some are fractured, indicating reworking processes. The mineral association found in the muddy levels is characteristic of oxisols formed under warm and humid conditions. The upward decrease in kaolinite content is coeval with an increase in the illitic phases and quartz content, related to siliciclastic input, but is also coeval with the presence of authigenic smectite. This indicates a decrease in chemical weathering, not fully registered due to the siliciclastic contribution, which was possibly associated with a change to colder, drier conditions during the latest Hauterivian–early Barremian in the studied area.

Mars-rover cameras evaluation of laboratory spectra of Fe-bearing Mars analog samples

The cameras on the Pathfinder probe (Imager for Pathfinder) and the rovers Spirit and Opportunity (Panoramic Camera), Curiosity (Mast Camera) and Perseverance (Mast Camera-Z) produce visible-range spectra of limited wavelength resolution but of great target resolution which allows mineralogical analysis of selected areas within martian rocks. Laboratory spectra of relevant specimens were transformed into the spectra corresponding to each of the above cameras to increase our capability to interpret martian spectral data collected in-situ. The focus was on finding spectral features that can be detected by the cameras on Mars and are diagnostic of specific minerals. The samples are a collection of (1) Fe/Mg-phyllosilicates from submarine hydrothermal sites and (2) of rocks from acid alteration environments containing goethite, hematite, jarosite and Fe-bearing chlorite as these minerals are detectable in the extended visible range. Among all the samples, interstratified glauconite-nontronite has the most unique spectral features and should be easily detectable with the rover cameras. The spectral features of talc from Fe-bearing interstratified specimens are described. These data are especially relevant as glauconite and talc have been proposed to be fairly abundant on Mars and their detections are suggested from remote-sensing near-IR data. Several indices are proposed to assess Fe content on the investigated samples as well as mineral concentration of goethite and hematite. Among these indices, the normalized spectral slope in the range 420–600 nm increases with total Fe content for all samples, whether phyllosilicates, oxides or sulphates (R2 = 0.7–0.8). For pure phyllosilicates, the slope from 600 to 1010 nm decreases with increasing octahedral Fe (R2 = 0.75). An index for goethite produced excellent results assessing goethite concentration (R2 = 0.84). Of all cameras, Mast Camera reproduces the spectra with lowest fidelity and generates the poorest correlations between indices and tested variables. The other three cameras perform similarly.