Gneiss Bedrock Research Articles

Rapid groundwater assessments in gneissic settings using transient electromagnetics – examples from Togo

Towed transient electromagnetics (tTEM) is applied in the Plateau Region of Togo for rapid and high-resolution characterization of groundwater systems surrounding six villages. Past drilling efforts in the region often resulted in unsuccessful or low-yielding boreholes, due in large part to sparse hydrogeological data at the scale relevant for borehole siting surrounding each village. Towed TEM systems are shown to be well-suited to addressing this data sparsity issue, enabling the mapping of large regions surrounding each village in relatively short field times (two days per village in this work). Comparison with borehole lithology logs reveals that a towed electromagnetic system can accurately characterize the thickness of the weathered zone in gneissic settings, as well as to delineate elevated saturation fractured zones within the gneissic bedrock in several cases. Boreholes drilled based on tTEM surveys were able to intercept fresh groundwater resources in each of the investigated villages.

Biotic-Abiotic Radial-Acicular Crystal Fan Fabrics with Rosickýite at the Angel Springs Tufa-Travertine Deposit in Southern British Columbia

Abstract The tufa-travertine deposit at Angel Springs developed through the interaction of thermal waters with bedrock of the Proterozoic Okanagan Gneiss, which extends along the eastern margin of the Okanagan Valley fault system in south-central British Columbia. This warm spring is proximal to Miocene plateau basalt flows that cut the Okanagan Gneiss bedrock eastward of the Okanagan Valley. The carbonate deposit, which is widely referenced as tufa, consists of a tufa and an overlying travertine. These texturally and petrographically different deposits developed in response to a shift in the groundwater pathway wherein the surface discharge transitioned from multiple vents of the tufa to a single downslope vent pool of the overlying travertine. Lower interval tufa fabrics are characterized by networks of fenestral-type porosity supported by a framework of curvilinear stromatolitic sheets of calcite that resulted from the partial coalescence of sub-horizontal arrays of calcite-encrusted cyanobacteria. These tufa fabrics aligned with the strong stream flow emanating from multiple vents. In contrast, radial crystal fan fabrics of the upper interval travertine developed with the transition from biotic calcite encrustations of upward branching cyanobacteria to the abiotic development of radial crystal fans. Length-long mouldic porosity tubules were occluded as the abiotic sheaf- and fan-shaped crystal growth surfaces expanded radially with rapid degassing. Core areas of the radial crystal arrays coalesced and were partially recrystallized, resulting in spheroidal crystalline fabrics that preserve inclusion-delineated concentric growth surfaces. Syntaxial overgrowths of radially aligned acicular crystals rapidly expanded from these core areas of coalesced calcite, resulting in the formation of abiotic radial-acicular and starburst crystal arrangements. The biotic–abiotic transition resulted in the rapid growth of abiotic crystal fans as the dominant deposition process of the upper interval travertine fabrics, but not in the lower interval tufa fabrics. Activities of sulfate-reducing bacteria in the sulfate-rich thermal water of both intervals resulted in precipitation of rosickýite, the monoclinic polymorph of S, as nanocrystalline globular protuberances on surfaces of calcite crystals. This is the first recorded occurrence of rosickýite in a tufa-travertine deposit and the first recognition of this mineral in Canada.

Use of stable Mg isotope ratios in identifying the base cation sources of stream water in the boreal Krycklan catchment (Sweden)

The knowledge of the sources of base cations in stream water is a prerequisite to assess potential effects of changing environmental conditions such as changing rainfall, weathering or groundwater flows on cation export with stream water. This study use stable Mg isotopes to identify potential sources in the well-studied catchment of Krycklan located on gneissic bedrock covered by quaternary sediments in Sweden. Samples were collected from open filed rain, throughfall, stream, soil, rock and litterfall. The δ26Mg values of these samples was determined and the contributions of different sources to Mg fluxes in the stream were determined from the variation of the Mg isotope and Sr / Mg ratios.The results show an overall variation of 1.10‰ between all samples. In addition, Magnesium isotope ratios varied little in the streamwater and in soil solution, except during snowmelt periods during which a large portion of the annual runoff occurs. Magnesium in the streamwater is explained as a mixture of three pools (open field rain, soil solution and groundwater) with the latter two influenced by catchment processes. Outside the snowmelt period, Mg in streamwater mainly derived from the groundwater, assumed to be mineral weathering signature in this catchment, with a contribution ranging from 12 to 63% to Mg fluxes. Open field rain dominates Mg fluxes in streamwater during spring flood (0 to 78%) and may contribute significantly during larger summer and autumn rainfall events. Soil solution input to streamwater range from 16 to 59% of Mg fluxes in streamwater. Our results demonstrate that δ26Mg values together with Mg concentrations and Sr/Mg ratios can be used to constrain the Mg sources of stream water and quantify weathering release rates.

Glaciers Control the Hydrogeochemistry of Proglacial Streams During Late Summer in the Wind River Range, Wyoming, United States

Glaciers alter the geochemistry of sensitive alpine streams by exposing freshly weathered bedrock and releasing atmospherically deposited trace metals from melting ice. Changes in the timing and quantity of glacial melt also affect discharge and temperature of alpine streams. To investigate the effects of glacier meltwater on the geochemistry and hydrology of proglacial streams in the western US, we sampled supraglacial meltwaters and proglacial streams in the Dinwoody Creek watershed in the Wind River Range, Wyoming during a one-week period in 2015. The upper watershed contains Gannett Glacier ( ∼ 5 km2) and Dinwoody Glacier ( ∼ 4 km2) at elevations between 3,300–4,000 m asl. Samples were collected during late summer (27 August–4 September) when the contributions of glacier meltwater were highest. Supraglacial meltwater was enriched in a suite of trace metals (Cd, Co, Cu, Hg, Mn, Pb, Zn) relative to proglacial streams, suggesting an atmospheric source of metals to the glaciers. Concentrations of major ions and the remaining 30+ analyzed trace elements were enriched in proglacial streams relative to supraglacial meltwater, reflecting weathering of granite and gneiss bedrock. To evaluate the diurnal effects of glacier meltwater inputs, we deployed loggers to monitor water levels, temperature, and specific conductance at 15 min intervals over a one-week period and collected hourly water samples from Dinwoody Creek for a 24 h period. The influx of glacial meltwater during the daytime diluted major ion and rare earth element concentrations and caused increased concentrations for a subset of trace metals. Stable water isotopes (δD and δ18O) in Dinwoody Creek were more depleted during peak flow relative to baseflow due to contributions from isotopically depleted meltwater. The combination of multiple hydrologic tracers (solute concentrations, high frequency logger data, water isotopes) shows strong potential to improve estimates of glacier meltwater contributions to proglacial streams. Changes in water chemistry and discharge need to be monitored as glaciers recede across the Wind River Range and other midlatitude mountain ranges for mitigating negative impacts on alpine ecosystems and downstream water resources.

Tracking denudation and sediment production and transport with cosmogenic 10Be in arid, high‐altitude Himalayan half‐grabens, Zanskar, northern India

AbstractUnderstanding the extent to which local factors, including bedrock and structure, govern catchment denudation in mountainous environments as opposed to broader climate or tectonic patterns provides insight into how landscapes evolve as sediment is generated and transported through them, and whether they have approached steady‐state equilibrium. We measured beryllium‐10 (10Be) concentrations in 21 sediment samples from glaciated footwall and hanging wall catchments, including a set of nested catchments, and 12 bedrock samples in the Puga and Tso Morari half‐grabens located in the high‐elevation, arid Zanskar region of northern India. In the Puga half‐graben where catchments are underlain by quartzo‐feldspathic gneissic bedrock, bedrock along catchment divides is eroding very slowly, about 5 m/Ma, due to extreme aridity and 10Be concentrations in catchment sediments are the highest (~60–90 × 105 atoms/g SiO2) as colluvium accumulates on hillslopes, decoupled from their ephemeral streams. At Puga, 10Be concentrations and the average erosion rates of a set of six nested catchments demonstrate that catchment denudation is transport‐limited as sediment stagnates on lower slopes before reaching the catchment outlet. In the Tso Morari half‐graben, gneissic bedrock is also eroding very slowly but 10Be concentrations in sediments in catchments underlain by low grade meta‐sedimentary rocks, are significantly lower (~10–35 × 105 atoms/g SiO2). In these arid, high‐elevation environments, 10Be concentrations in catchment sediments have more to do with bedrock weathering and transport times than steady‐state denudation rates. © 2020 John Wiley & Sons, Ltd.

Resistivity imaging for identification of fracture zones in crystalline bedrock in Brazil

Geophysical methods have been extensively used in fractured rocks water prospection, with varying success levels. The objective of this article is to improve the understanding of the electrical response in 2D surveys for fractures zones mapping in crystalline rocks. 2D resistivity models simulated several types of crystalline rock fractures influenced by fracture dipping, soil coverage, and topography effects. Numerical simulations show that conceptual models are useful in evaluating the expected electrical response and planning the field survey. Field surveys were conducted on areas where fractures and faults are known from geological mapping and groundwater wells: crystalline gneissic bedrock (Louveira), diabase sill from Serra Geral Formation (Tiete), and basalt from Serra Geral formation with sediments coverage (Bebedouro). Fractures and faults were identified by resistivity values lower than 250 Ω m, confirmed by well drilling.

Impact of the Former Vineyard Land Use on the Productivity of Secondary Forest Herb Layer in the Little Carpathians (SW Slovakia)

Abstract The Little Carpathians Mountains include a vineyard region with long tradition that dates back up to the Roman Empire period (and according to some opinions, even earlier). In the late 19th century, it was strongly impacted by the phylloxera epidemic, and the vineyard area has significantly reduced here. Large areas of the former vineyards are covered by forests, which mostly have formed spontaneously, but some of them were also planted. This contribution is focused on the impact of the former vineyard land use on the productivity (aboveground, belowground, and total biomass) of such forest herb layer. Research included also the forests, which occupy rocky mounds formed by rock gathering and their placement on the vineyard borders. There were sampled by following four stands, mostly differed by tree composition, origin, age, and succession stage: (i) up to 100 years old spontaneously formed thermophilous acidophilous oak forest on the former vineyard on the granite substrate, (ii) up to 100 years old spontaneously formed oak-dominated forest on the rocky (granite) mounds (borders between the former vineyards formed by rock gathering), (iii) 40–60 years old planted ash stands on the gneiss bedrock, and (iv) 40–60 years old planted ash-dominated stands on the rocky (gneiss) mounds. According to our results, the former land use modified original relief, where the former vineyards have modified soil profile and new relief forms rocky mounds were created. These mounds with no or just shallow soils are usually much less covered by vegetation, thus production of herb layer biomass is lower here than in the adjacent former vineyards. Moreover, rocky mounds show a higher ratio of synanthropic species and apophytes than the adjacent former vineyards, and same as for ratio of therophytes. The younger the stands on the former vineyards, the higher is the ratio of synanthropic species, apophytes, and therophytes. On the other hand, when estimating the production quantity, the values of herb layer production on the former vineyards are similar to those in natural oak-hornbeam forests found in the Little Carpathians Mts. and the adjacent regions, except for the rocky mounds covered by old oak forests, which are less productive. In other words, the former vineyard land use affects the herb layer production quality rather than quantity.

Fluoride content of minerals in gneissic rocks at an area of endemic dental fluorosis in Sri Lanka: estimates from combined petrographic and electron microprobe analysis

A mass balance of the mineralogical sources of fluoride in charnockitic gneiss bedrock and regolith (weathered rock) in Sri Lanka has been undertaken, using optical petrography and Scanning Electron Microscopy (SEM) with energy dispersive X-ray spectrometry (EDX) to support development of a conceptual model of fluoride release to groundwater. Bedrock and regolith samples were collected in Polonnaruwa where there is a widespread occurrence of dental fluorosis attributed to excessive fluoride (up 5.25mg/L) in groundwater, while primary minerals of the gneissic bedrock are identified as the ultimate source of fluoride. Fluoride leaching related to long-term weathering of the bedrock and development of the regolith, control the occurrence of F in the groundwater system which is yet unresolved. In the study area, the charnockitic gneiss bedrock is mantled by a few meters thick regolith within which the groundwater table fluctuates seasonally. Mineral abundance and mineral fluoride content were estimated using petrographic and SEM analysis. Plagioclase, hornblende, pyroxene, K-feldspar, quartz, biotite and titanite (sphene) were the major minerals of the rock though the mineral proportions vary widely over the area. Apatite and magnetite were present as accessory minerals. Fluoride concentrations obtained from SEM-EDX analysis were combined with the volume percentage of minerals from petrography to estimate the total rock fluoride concentration. The order of fluoride abundance was apatite (highest), biotite, titanite, and hornblende. Plagioclase, K feldspar, pyroxene and magnetite did not have any noticeable fluoride concentrations. Loss of fluoride from the rock mass upon weathering was clearly evident and hornblende appeared to be the most significant fluoride releasing agent through weathering. Apatite, though present in accessory amounts, is distributed evenly in the rock and hence may be considered as a steady fluoride donor causing elevated and uniform fluoride distribution in groundwater. On the other hand, hornblende and biotite though of irregular occurrence (area wise), may cause high fluoride anomalies in groundwater in areas of high abundance.

The 27 July 2011 debris flows at Umyeonsan, Seoul, Korea

On 27 July 2011, a total of 33 debris flows occurred in Umyeonsan, Seoul, Korea, resulting in 16 fatalities and extensive damage to houses, roads, and other properties. The debris flows originated during an intense rainstorm with a peak intensity of 112.5 mm/h and a cumulative rainfall of 306.5 mm over 16 h. The debris flows were triggered by a combination of two processes: (1) shallow translational landslides in colluvium at the ridge crest along a fault plane associated with the Chugaryeong Fault Zone and (2) the progressive entrainment of loose material due to surface water runoff in the channel. The ensuing debris flows extensively eroded the colluvial deposits overlying the bedrock along their paths and transported large quantities of soil and woody debris. Two watersheds with catastrophic debris flows in the study area were chosen for a forensic investigation to analyze the geomorphological features of the debris flow gullies and to study several factors influencing the debris flows. The debris flow activity was found to be primarily related to rainfall, as well as to the loose, compressible colluvium overlying the gneiss bedrock, the watershed topography with >30° slopes, and the vegetation.

Site response assessment of an urban extension site using microtremor measurements, Ahud Rufeidah, Abha District, Southwest Saudi Arabia

Microtremor horizontal-to-vertical spectral ratio (HVSR) method has been conducted at 33 sites in Ahud Rufeidah urban expansion zone in order to assess the fundamental frequency and the corresponding amplitude of the sediments. Clear HVSR peaks have been identified in the majority of the surveyed area. The eastern and northern parts of the area are characterized by two well-separated peaks which indicate distinct shallow and deep impedance contrasts. The frequency map of sediments shows a distribution in the range of 0.86–3.13 Hz. The observed frequencies can be related to the total thickness of Quaternary alluvial sediments (sand, gravel, and shale) deposited over the gneiss bedrock. Lower resonance frequencies are attained at sites in the northern part, while the higher values are attained at sites in the southern part. The amplitudes of HVSR peaks are in the range 3–15. In general, the higher peak amplitudes are identified at lower frequencies. Since low fundamental frequencies are related to bedrock, this can be an indication of high-impedance contrast between alluvial sediments and gneiss bedrock. The results of this study represent one step for seismic hazard assessment and risk mitigation of this urban area where great damage can be attained in case of strong earthquakes. Hence, these results should be taken into consideration before establishing the new urban constructions in the area of study.

Subglacially precipitated carbonates record geochemical interactions and pollen preservation at the base of the Laurentide Ice Sheet on central Baffin Island, eastern Canadian Arctic

The mineralogy and isotopic compositions of subglacially precipitated carbonate crusts (SPCCs) provide information on conditions and processes beneath former glaciers and ice sheets. Here we describe SPCCs formed on gneissic bedrock at the bed of the Laurentide Ice Sheet (LIS) during the last glacial maximum on central Baffin Island. Geochemical data indicate that the Ca in the crusts was likely derived from the subglacial chemical weathering Ca-bearing minerals in the local bedrock. C and Sr isotopic analyses reveal that the C in the calcite was derived predominantly from older plant debris. The δ18O values of the SPCCs suggest that these crusts formed in isotopic equilibrium with basal ice LIS preserved in the Barnes Ice Cap (BIC). Columnar crystal fabric and the predominance of sparite over micrite in the SPCCs are indicative of carbonate precipitation under open-system conditions. However, the mean δ18O value of the calcite crusts is ~10‰ higher than those of primary LIS ice preserved in the BIC, demonstrating that SPCCs record the isotopic composition of only basal ice. Palynomorph assemblages preserved within the calcite and basal BIC ice include species last endemic to the Arctic in the early Tertiary. The source of these palynomorphs remains enigmatic.

Delineation of groundwater potential zones in the crystalline basement terrain of SW-Nigeria: an integrated GIS and remote sensing approach

Due to complex and erratic nature of groundwater occurrences in crystalline basement terrains, groundwater development in form of boreholes/wells without the necessary pre-drilling hydrogeological investigations usually results in failure. Therefore, there is the need for adequate characterization of aquifers and delineation of groundwater potential zones in such crystalline basement setting. This study employed the integration of multi-criteria decision analysis (MCDA), remote sensing (RS) and geographical information system (GIS) techniques to delineate groundwater potential zones in crystalline basement terrain of SW-Nigeria and validation of the result with existing borehole/well yield data. The study approach involved integration of nine different thematic layers (geology, rainfall geomorphology, soil, drainage density, lineament density, landuse, slope and drainage proximity) based on weights assignment and normalization with respect to the relative contribution of the different themes to groundwater occurrence using Saaty’s analytic hierarchy approach. Following weigh normalization and ranking, the thematic maps were integrated using ArcGIS 10.0 software to generate the overall groundwater potential map for the study area. The result revealed that the study area can be categorized into three different groundwater potential zones: high, medium and low. Greater portion of the study area (84,121.8 km2) representing about 78 % of the total area, fall within the medium groundwater potential zone which are generally underlain by medium-porphyritic granite, biotite-hornblende granite and granite gneiss bedrock settings. About 18,239.7 km2 (17 %) fall under high groundwater potential zone which are characterized by weathered/fractured quartzite, quartz-schist, amphibolite schist and phyllite bedrock settings. However, areas of low groundwater potentials constitute only 3 % (3,416.54 km2) of the total study area and are mostly underlain by migmatite, banded and augen gneiss bedrock settings. Subsequent validation with boreholes/well yield data revealed a good correlation with respect to the observed groundwater potential zonation. Wells/boreholes with yields greater than >150 m3/day are generally characteristic of areas with high groundwater potential while those with yields of 75–150 and <75 m3/day are typical of areas with medium and low groundwater potentials, respectively. The validation clearly highlights the efficacy of the integrated MCDA, RS and GIS methods employed in this study as useful modern approach for proper groundwater resources evaluation; providing quick prospective guides for groundwater exploration and exploitation in such crystalline basement settings.

우면산의 지질 특성과 사면지형 변화

This study is conducted as a part of the Collective Academic Research of Mt. Umyeon in Seocho-gu, Seoul 2012. The purpose of this study is to understand the changing conditions of the slope landform and geological characteristics of the Mt. Umyeon in the field work. Aspect of slope landform changes of Mt. Umyeon revealed in this study is divided into human factors and natural factors. Slope landform change due to natural factors, most influential rainfall amount and properties of the bedrock. In order to form a thin weathered layer, the clay component in many cases, moisture content is high, gneiss bedrock of Mt. Umyeon is very vulnerable to landslides during heavy rain. The slope landform changes due to human factors, the impact of landslide recovery facility is the largest. And, road of the valley and surrounding mountain trail made of wood stepped affected the change in slope landform. In order to prevent damage such as Mt. Umyeon, it must make a legal systematic approach for the conservation and management of the mountain area. In addition, various studies for disaster prevention and prediction of landslides must be carried out.

Anthracological analysis of fuel wood used for firesetting in medieval metallic mines of the Faravel district (southern French Alps)

This anthracological study of fuel wood used in the Faravel mines is part of a doctorate research programme conducted on the interrelationship between mines and forests of the Southern Alps during the Middle Ages. The study area is situated in the upper Durance valley, a major mining region from the 11th to the end of the 13th century. Man sought and extracted silver-bearing ore from the valley bottoms to the summit of the mountains. He employed firesetting to attack the hard gneiss bedrock. The study of residual charcoal has been used to measure the impact of the mining economy on the development of mountain forests. The example of the small district of Faravel situated in an upper mountainous region (1900–2150 m altitude), illustrates a supply anchored at subalpine level with a gradual extension of the source area towards the timberline. The anthracological spectra document extinction of Pinus cembra L. at subalpine level and the lowering of the upper limit of the dense forest dominated by Larix decidua Mill. These changes are the result of agropastoral and mining pressure, as testified by both surviving manuscripts and archaeology.

Precipitation‐runoff processes in Shimen hillslope micro‐catchment of Taihang Mountain, north China

AbstractPrecipitation runoff is a critical hillslope hydrological process for downslope streamflow and piedmont/floodplain recharge. Shimen hillslope micro‐catchment is strategically located in the central foothill region of Taihang Mountains, where runoff is crucial for water availability in the piedmont corridors and floodplains of north China. This study analyzes precipitation‐runoff processes in the Shimen hillslope micro‐catchment for 2006–2008 using locally designed runoff collection systems. The study shows that slope length is a critical factor, next only to precipitation, in terms of runoff yield. Regression analysis also shows that runoff is related positively to precipitation, and negatively to slope length. Soil mantle in the study area is generally thin and is therefore not as critical a runoff factor as slope length. The study shows a significant difference between overland and subsurface runoff. However, that between the 0–10 and 10–20 cm subsurfaces is insignificant. Runoff hardly occurs under light rains (&lt;10 mm), but is clearly noticeable under moderate‐to‐rainstorm events. In the hillslope catchment, vertical infiltration (accounting for 42–84% of the precipitation) dominates runoff processes in subsurface soils and weathered granite gneiss bedrock. A weak lateral flow (at even the soil/bedrock interface) and the generally small runoff suggest strong infiltration loss via deep percolation. This is critical for groundwater recharge in the downslope piedmont corridors and floodplains. This may enhance water availability, ease water shortage, avert further environmental degradation, and reduce the risk of drought/flood in the event of extreme weather conditions in the catchment and the wider north China Plain. Copyright © 2011 John Wiley &amp; Sons, Ltd.

Labraunda 2009. A preliminary report on the Swedish excavations

The 2009 campaign in Labraunda accomplished three goals: the termination of the excavations in the Byzantine fort on the Acropolis and in the Late Roman Tetraconch and the complete excavation of the impressive marble chamber tomb along the Sacred Way. In the Acropolis Fortress, evidence was found to support the military character of the Byzantine establishment: the rooms along the fortification wall were paved and had a rectangular shape, suggesting defensive rooms. In these rooms sling stones were found. Structures dating from the Hekatomnid period were further investigated this year, and a well cut into the gneiss bedrock was excavated. In the Tetraconch, the north apse was excavated down to bedrock and a coin from Constantius II (348–357/8) suggests an ante quem dating for this unique and sophisticated structure. The geophysical investigations indicated that a church is located on the terrace below the Tetraconch and a first sondage was conducted here. The large marble chamber tomb was completely excavated and emptied of its content. Small pieces of pottery indicate a date in the middle of the fourth century BC. The extensive geophysical survey was carried out at five different areas around the Sanctuary, in order to achieve a better picture of the entire Sanctuary, as the early excavations had involved only its central part. Evidence for several previously unknown structures came to light: possibly a temple on the East Stoa terrace and further bath buildings at the East Bath, as well as several unexcavated tombs.

Characterizing aquifers when using magnetic resonance sounding in a heterogeneous geomagnetic field

ABSTRACTIt has previously been reported that the heterogeneity of the geomagnetic field disturbs the currently‐measured free induction decay signal of magnetic resonance sounding (MRS). To overcome the limitation of MRS in a non‐homogeneous geomagnetic field, we adapted the spin‐echo methodology usually used at the laboratory scale and in boreholes. We present examples of measurements carried out in a sandy aquifer in southern India. The 15–25 m thick sand deposit overlays a gneissic basement. Two sources of geomagnetic field heterogeneity have been identified at this site, both affecting the geomagnetic field within the sandy aquifer: the gneissic bedrock and an intruded dyke into the bedrock. Spin‐echo and free induction decay signals have been recorded at six locations. We found that the groundwater content, the thickness of the saturated aquifer and its transmissivity calculated with free induction decay measurements are underestimated compared to those derived from spin‐echo measurements. The closer to the dyke the higher the underestimation. Time‐domain electromagnetic measurements indicate that the aquifer is rather homogeneous at the site scale, as suggested by spin‐echo results. We also found that a small heterogeneity of the geomagnetic field can go unnoticed, thus leading to an unknown mis‐estimate of aquifer properties when using free induction decay measurements. Thus spin‐echo measurements can be used to improve the accuracy of aquifer characterization when using MRS in geological contexts where geomagnetic field heterogeneity exists.

Description and numerical modelling of the October 2000 Nora debris flow, Northwestern Italian Alps

The Nora alluvial fan, which is located in the Orco River valley (Piedmont region, Italy), was affected by a debris flow of approximately 10 000 m3 in October 2000. The event was triggered by heavy rainfall that affected the whole Piedmont region at that time. The mobilization of the water-satured altered gneissic bedrock and colluvium in the upper zone of the Nora basin resulted in the detachment of a debris slide, which rapidly evolved into a channelized noncohesive debris flow. As information from post-event surveys and two pre-event digital elevation models (DEMs), with different resolutions, were available for the study site, the dynamics of the event has been numerically back-analyzed using the numerical code RASH3D. The obtained results have shown both the capability of the code to simulate the dynamics of a noncohesive debris flow, including the final deposit depth distribution, and the importance of on-site surveys and digital elevation model (DEM) resolution in interpreting numerical results and the associated calibrated rheological parameters.

Geochemistry of an acidic chromium sulfate plume

The historical disposal of acidic chromium sulfate solutions into unlined lagoons between 1953 and 1970 at an industrial site resulted in formation of a dense aqueous phase liquid (DAPL) plume [specific gravity 1.11 g/cm 3, pH 3, up to 4700 mg/L Cr(III), and up to 90,000 mg/L SO 4]. The DAPL sank through the shallow glacial till aquifer to an underlying impermeable gneissic bedrock from where it migrated downgradient along buried channels incised in the bedrock. Because of its high density, the plume chemistry is sharply stratified vertically. Chromium(III) predominates in the DAPL because excess Cr(VI) not reduced in the original process has been reduced by Fe(II) derived from silicates, while Cr(OH) 3(am) occurs as surface coatings on silicate minerals and as discrete particles mixed with Fe(OH) 3(am) and Al(OH) 3(am). The solubility of Cr(OH) 3(am) accurately describes Cr(III) concentrations in the plume and nearby groundwater, while Al and Fe in solution are also consistent with solubility-controlling oxyhydroxides. Because of these solubility controls, metal cations are attenuated relative to more mobile Cl and SO 4, resulting in a chromatographic separation of solutes downgradient from the plume origin. The good agreement between predicted and observed solution concentrations illustrates the utility of equilibrium modeling when interpreting metal transport characteristics and in determining the efficacy of natural attenuation in subsurface systems.

The influence of alkaline and non-alkaline parent material on soil chemistry

The gneiss bedrock of Alnö Island, situated at the eastern coastline of central Sweden (62°24′N, 17°30′E), has alkaline intrusions interspersed in narrow dikes. This gives the opportunity to create experimental designs, where the impact of different parent material on the soil solution chemistry can be exclusively investigated. In this study, three alkaline sites and three non-alkaline sites were mineralogically identified within a homogenous spruce stand. Composition of soil, exchangeable cations and soil solution were determined throughout the soil profiles. The soil solution was analysed for pH, dissolved organic carbon (DOC) and inorganic species. The obtained data was statistically evaluated by t-tests, analysis of variance (ANOVA) and principal component analysis (PCA). Results indicate that the alkaline parent materials gave rise to higher content of exchangeable Ca and Mg and a soil solution with higher concentrations of DOC, SO 4, NO 3, and Ca compared to the non-alkaline materials. For the deeper mineral horizons (25–30 cm) F and pH were also higher in the alkaline soil solutions. There were only small differences between the organic horizons at alkaline and non-alkaline sites, presumably explained by the influence of litter and recirculation of nutrients. The multivariate analyses emphasized the correlation between the parent material, exchangeable cations and the soil solution concentrations of Ca, Mg, P and Al.