Global Network Of Isotopes In Precipitation Research Articles

The Effect of Convective/Advective Precipitation Partitions on the Precipitation Isotopes in the Monsoon Regions of China: A Case Study of Changsha

Abstract Convective/advective precipitation partitions refer to the divisions of precipitation that are either convective or advective in nature, relative to the total precipitation amount. These distinct partitions can have a significant influence on the stable isotope composition of precipitation. This study analyzed and compared the effect of precipitation partitions on δ18O in precipitation (δ18Op) by using daily precipitation stable isotope data from Changsha station and monthly precipitation stable isotope data from the Global Network of Isotopes in Precipitation (GNIP), under different time scales, time intervals (i.e., annual, warm season, and cold season), and precipitation intensities. The results showed that the correlation between the convective precipitation fraction (CPF) and total precipitation amount was influenced by the intensity of convection in different time intervals. On both the daily and monthly scales, the CPF decreased as the precipitation amount increased in the warm season, while it increased with increasing precipitation amount in the cold season. Regardless of the season, daily δ18Op at Changsha station consistently increased with an increase in daily CPF. On a daily scale, the effect of convective activity on δ18Op was stronger than that of the “precipitation amount effect” in the cold season, as compared to the situation in the warm season. As a result, the regression line slope between δ18Op and CPF increased with increasing precipitation intensity in the warm season, meaning that as the CPF increased, the δ18Op increased at a faster rate under higher precipitation intensity. Similarly, the slope increased with increasing precipitation intensity in the cold season. This suggests that precipitation intensity and convection intensity can affect the relationship between δ18Op and CPF. Our findings shed light on how different precipitation partitions affect stable isotope composition of precipitation, thus enhancing our understanding of the variability of precipitation stable isotopes in the monsoon regions of China. Significance Statement This study aims to better elucidate the influence of different precipitation partitions on precipitation stable isotopes. In the eastern monsoon region of China, stable isotopes in precipitation showed a robust positive relationship with convective precipitation faction. On a daily scale, the convective activity enhanced the influences of the “precipitation amount effect” on precipitation stable isotopes in the warm season and reduced such influences in the cold season. These results improve our understanding of stable isotopic variability of precipitation in the eastern monsoon region, China.

VARIATIONS OF δ18О AND δ2H VALUES OF PRECIPITATION IN MOSCOW FROM 2017 TO 2019

To reveal variations in the iso topic composition of O and H in the atmospheric precipitation in Moscow and the processes influencing the isotope composition, all events of precipitation in 2017-2019 were sampled at the Meteorological Observatory of the Moscow State University: 158 samples in 2017, 119 samples in 2018 and 143 samples in 2019. The study is a prolongation of continuous measurements of the isotope composition of precipitation, started by authors in 2014. The study of the isotope composition of precipitation at the MSU Meteorological Observatory was supported by the IAEA and became a part of the Global Network of Isotopes in Precipitation (GNIP) database. It has been found that the intra-annual variability of the isotop e composition of precipitation has a pronounced seasonality. The most isotopically heavy precipitation falls from May to August, and the most isotop ically light precipitation at December-February, mainly due to seasonal air temperature variations. The ratio of the average monthly δ18O values in precipitation and air temperature for the study period varied from 0.34 to 0.39‰/°C, which is consistent with the previously obtained data for precipitation in Moscow. The δ2H-δ18O ratio in precipitation was clos e to that of the Global Meteoric Water Line, pointing to the equilibrium conditions during precipitation formation. It was established that in the summer months isotopic composition is significantly influenced by undercloud evaporation. The deuterium excess va lues in precipitation are not markedly seasonal; however, lower dexc values (below the 3-year average of 11‰) are typical for the summer months (July-August). It is most likely due to undercloud evaporation in conditions of low relative humidity and high air temperatures. Higher dexc values (above 11‰) prevailed from October to April.

Spatial variability in stable isotopes from Lesotho surface waters: insights into regional moisture transport

AbstractPrecipitation in Lesotho is highly spatially variable, a feature of the high altitude and rugged topography. The hydroclimate dynamics, despite being critical to the water security of Lesotho and adjacent South Africa, are poorly understood. Ratios of oxygen and hydrogen isotopes in meteoric water are excellent tracers of hydroclimatic processes. This study presents the first analysis of stable isotopes from surface waters in Lesotho, and an investigation into the moisture sources. Our results demonstrate considerable variability in isotope values. There are statistically significant relationships between both oxygen and hydrogen isotopes and the altitude of the site and source of rivers sampled, and with hydrogen isotopes and longitude. The meteoric water line for the Lesotho samples is most closely aligned with that of the Global Network of Isotopes in Precipitation (GNIP) station at Harare, in Zimbabwe. The meteoric water line for Windhoek is more closely aligned to the Lesotho samples than the more proximate Cape Town or Pretoria meteoric water lines, which would more closely represent the South African winter- and summer-rainfall zones respectively. HYSPLIT back-trajectory air parcel analysis supports these findings, demonstrating a frequent continental anticyclonic track through southern Zimbabwe. Deuterium excess values vary widely, although are most likely related to processes during moisture transport rather than differences in moisture source. These findings are of particular importance in the context of the future water security of both Lesotho and South Africa, especially as the poleward displacement of the westerly moisture corridor has raised concerns for winter precipitation in the region.

Role of stable isotopes in revealing moisture sources and rainfall variability in India

Precipitation is a crucial component of the water cycle and is essential for the livelihood of people and ecosystems; therefore, understanding precipitation parameters is vital. Stable isotopes in precipitation can provide important information on precipitation sources, atmospheric circulation patterns, and hydrological processes. In this study, stable isotopes in precipitation for four cities in India were analyzed, namely New Delhi, Hyderabad, Shillong, and Calicut, using data from the International Atomic Energy Agency (IAEA) Global Network for Isotopes in Precipitation (GNIP). The GNIP data were supplemented with in-situ measurements. Results showed the correlations between climate-related factors such as surface air temperature and precipitation levels with the stable isotope composition of precipitation. The relationships critically explore interannual variations in the isotope data over the last three decades. The Local Meteoric Water Line (LMWL) for New Delhi and Hyderabad had intercepts less than 10‰, implying a higher evaporation effect over precipitation, consistent with arid and semi-arid regions with increased altitude. The weighted average value of d-excess for southern and Himalayan points were 10.7 and 12.7, respectively, and the average value of δ¹⁸O were − 3.65 and − 5.84, and δ²H were − 16.8 and − 35.8. The d-excess value was significantly lower in the Northern part (New Delhi), with an average weighted value of 6.6. The key values include the isotopic composition of rainfall in different regions of India, the LMWL for different stations, the d-excess value, and the consistency of meteoric water lines with regional and global values. The results of this study provide valuable information on the variability of stable isotopes in precipitation in India. The study's outcomes can be compared with the isotopic composition of surface water and groundwater. This discovery offers more understanding of the isotopic differences that occur on a smaller scale during organized convection and the factors that affect them. As a result, it enhances our ability to decipher the paleoclimate data in arid, semi-arid, and subtropical monsoon regions.

Global and local meteoric water lines for δ17O/δ18O and the spatiotemporal distribution of Δ′17O in Earth’s precipitation

Recently, δ17O and its excess (Δ′17O) have become increasingly significant “triple-oxygen-isotope” indicators of distinctive hydrological processes in hydrology and climatology. This situation mirrors the research regarding δ18O and δ2H in the 1960s towards a solid theoretical base and a surge in application examples and field studies worldwide. Currently, systematic global measurements for δ17O in precipitation are still lacking. As a result, attempts have been made to define a Global δ17O/δ18O Meteoric Water Line (GMWL), often by using regional or local datasets of varying systematicity. Different definitions of the global reference slope (λref) for determining Δ′17O values have been proposed, by ongoing debate around a proposed consensus value of 0.528. This study used worldwide samples archived in the IAEA Global Network of Isotopes in Precipitation (GNIP) to (a) derive a δ17O/δ18O GMWL based on four-year monthly records from 66 GNIP stations, (b) formulate local δ17O/δ18O meteoric water lines (LMWL) for these stations’ areas, and (c) evaluate regional and seasonal variations of Δ′17O in precipitation. The GMWL for δ17O/δ18O was determined to be δ′17O = 0.5280 ± 0.0002 δ′18O + 0.0153 ± 0.0013, in keeping with the consensus value. Furthermore, our results suggested that using a line-conditioned 17O-excess is a viable alternative over the global λref in the context of regional hydrology and paleoclimatology interpretations; however, without challenging the global λref as such.

Quantifying Raindrop Evaporation Deficit in General Circulation Models from Observed and Model Rain Isotope Ratios on the West Coast of India

Raindrop evaporation is an important sub-cloud process that modifies rainfall amount and rainwater isotope values. Earlier studies have shown that various general circulation models (GCMs) do not incorporate this process properly during the simulation of water isotope ratios (oxygen and hydrogen). Our recent study has demonstrated that an inadequate estimation of this process for the Indian Summer Monsoon (ISM) results in significant biases (model-observed values) in the simulation of various GCMs on a monthly scale. However, a quantitative estimation was lacking. The magnitude of raindrop evaporation depends upon ambient humidity and temperature, which vary considerably during the ISM. Consequently, the isotope biases would also vary over various time scales. The present study aims to investigate the magnitude of the monthly scale variation in raindrop evaporation in the simulations and its causal connection with the corresponding variation in isotope biases. Towards this, we compare an 11-year-long (1997–2007) dataset of rain isotope ratios (both oxygen and hydrogen) from an Indian station, Kozhikode (Kerala), obtained under the Global Network of Isotopes in Precipitation (GNIP) programme of the International Atomic Energy Agency (IAEA) with the corresponding outputs of two isotope-enabled nudged GCMs—ISOGSM and LMDZ4. The raindrop evaporation fractions are estimated for 44 ISM months (June–September) of the study period using the Stewart (1975) formalism. Using a simple condensation–accretion model based on equilibrium fractionation from vapour, obtained from two adopted vapour isotope profiles, we estimate the liquid water isotope ratios at the cloud base. Considering this water as the initial rain, the raindrop evaporation fractions are estimated using the observed oxygen and hydrogen isotope ratios of Kozhikode surface rain samples. The estimated fractions show strong positive correlations with the isotope biases (R2 = 0.60 and 0.66). This suggests that lower estimates of raindrop evaporation could be responsible for the rain isotope biases in these two GCMs.

Stable Isotope Signatures in Tehran’s Precipitation: Insights from Artificial Neural Networks, Stepwise Regression, Wavelet Coherence, and Ensemble Machine Learning Approaches

This study investigates the impact of precipitation on Middle Eastern countries like Iran using precise methods such as stable isotope techniques. Stable isotope data for precipitation in Tehran were obtained from the Global Network of Isotopes in Precipitation (GNIP) station and sampled for two periods: 1961–1987 and 2000–2004. Precipitation samples were collected, stored, and shipped to a laboratory for stable isotope analyses using the GNIP procedure. Several models, including artificial neural networks (ANNs), stepwise regression, and ensemble machine learning approaches, were applied to simulate stable isotope signatures in precipitation. Among the studied machine learning models, XGboost showed the most accurate simulation with higher R2 (0.84 and 0.86) and lower RMSE (1.97 and 12.54), NSE (0.83 and 0.85), AIC (517.44 and 965.57), and BIC values (531.42 and 979.55) for 18O and 2H compared to other models, respectively. The uncertainty in the simulations of the XGboost model was assessed using the bootstrap technique, indicating that this model accurately predicted stable isotope values. Various wavelet coherence analyses were applied to study the associations between stable isotope signatures and their controlling parameters. The BWC analysis results show coherence relationships, mainly ranging from 16 to 32 months for both δ18O–temperature and δ2H–temperature pairs with the highest average wavelet coherence (AWC). Temperature is the dominant predictor influencing stable isotope signatures of precipitation, while precipitation has lower impacts. This study provides valuable insights into the relationship between stable isotopes and climatological parameters of precipitation in Tehran.

Stable isotopic composition of fog and rainfall in a Macaronesian cloud forest

Stable isotopes of water are commonly used to investigate the role of fog in cloud forests. This first requires the characterization of the isotopic signatures of both fog and local rainfall. The isotopic composition of rain and fog water and their variability were analysed for a Macaronesian cloud forest in Tenerife, Canary Islands, from samples collected over 5 years within the Global Network of Isotopes in Precipitation (GNIP) project. The results showed little differences in the isotopic signature of fog and rain with the former being slightly higher with respect to the latter (differences in absolute value of 1‰ in δ18O, 7‰ in δ2H and 0.7‰ in d-excess, on average) and with a similar statistical variability. Their meteoric lines, LMWL (local meteoric water line for precipitation): δ2H = 6.56 δ18O + 11.56 and FWL (fog water line): δ2H = 5.57 δ18O + 9.98, which are very close to each other and above the GMWL (Global Meteoric Water Line), reveals that rain and fog may originate from water evaporated from the same water sources and under moisture conditions typical of semi-arid regions. Different slopes and interception in LMWL and FWL point to seasonal processes affect fog and rain differently, i.e. summer evaporation of small fog droplets and autumn-winter rainfalls isotopically depleted from frontal or low-pressure systems that are decoupled from fog formation processes. Both isotopic signatures showed low correlation with temperature and total rainfall (R2 <0.3 in all cases). However, the high anticorrelation observed (R2 values >0.6) between the isotopic composition of rain and fog with rainfall totals with values between 100 and 150 mm for both fog and rain, associated with a well-defined synoptic rainfall pattern affecting the Canary Islands, supports the hypothesis that the “amount effect” is related to the moisture source region and transport patterns. Annual variability of the isotopic signatures showed a marked pattern, typical of these latitudes, with enriched values in summer and more depleted in winter for both rainfall and fog. The high amplitude observed in the seasonal pattern of d-excess for both rain and fog, point to the Mediterranean Sea as a potential source of moisture in the winter months or to a mixing process when the moist air mass trajectories pass over North Africa. Despite the similarities observed in these seasonal patterns, some anomalies were found in the summer d-excess, indicating the participation of some local processes to which d-excess is sensitive, such as sub-cloud evaporation or moisture recycling.

Environmental drivers of precipitation stable isotopes and moisture sources in the Mongolian Plateau

Τhe absence of precipitation-isotope stations in the wide flatland of the Mongolian Plateau (MP) hinders the analysis of precipitation processes. For this reason, a precipitation-isotope station was established in Erenhot in 2015. Based on precipitation samples collected during all precipitation events between January 2015 and December 2019, we analyzed the temporal variations of stable isotopes (δ2H, δ18O) in precipitation and their influencing factors, including meteorological factors, sub-cloud evaporation, and moisture sources. Oxygen and hydrogen isotopes in precipitation in Erenhot are richer than those in Ulaanbaatar, which is situated close to the mountains and depleted compared to, e.g., Baotou. In Erenhot, oxygen and hydrogen isotopes in precipitation are controlled by the temperature effect, similarly to Ulaanbaatar, but also by the amount effect in summer. The low slope of the local meteoric water line indicates that raindrops have undergone sub-cloud evaporation. The annual mean sub-cloud evaporation fraction was 5.2% from 2015 to 2019, while sub-cloud evaporation fraction was highest in summer (7.5%). Sub-cloud evaporation is mainly correlated by relative humidity, precipitation amount, regional (pan) evaporation, and air temperature. Relative humidity has the greatest effect and masks the effect of air temperature. The study area is mainly controlled by the west wind and winter monsoon, which brought 75.6% of the total precipitation with −7.75‰ δ18O. During summer, the Pacific monsoon resulted in 13.5% precipitation with −10.34‰ δ18O in the study area, while the Indian monsoon had negligible impact. Except for moisture advection, the moisture recycling fraction accounted for 11.1% of local precipitation, with −10.32‰ δ18O. This study compensates for the lack of global network of isotopes in precipitation (GNIP) stations in the MP, reveals the MP precipitation-isotope signatures and their influencing factors, and provides basic precipitation-isotope information for researching the distribution of precipitation-isotope signatures in Asia and the water cycle in the MP.

Investigating the potential for Southern Hemisphere climate reconstruction using stable isotopes in Tasmanian tree rings

Few annually dated stable isotope records exist across Oceania. Stable carbon and oxygen isotope ratios have the potential to enhance climate reconstructions currently reliant on tree ring width chronologies. The purpose of this study is to explore the sources of variability in a stable oxygen isotope chronology derived from A. selaginoides from Mount Read, Tasmania. This high elevation site receives abundant rainfall throughout the year and is ∼130 km from the Global Network of Isotopes in Precipitation (GNIP) site at Cape Grim. We crossdated 10 new tree core samples against an existing ring width chronology (954–2011 CE) and analyzed the δ18O from the individual rings for the period 1960–2018. Using high resolution (0.25 degrees) climate data and ECMWF ERA5 reanalysis data, we disentangled the effects of local climate and source region on the isotopic signatures recorded in the annual rings. In addition, we used HYSPLIT backward trajectory analysis to characterize the source region of precipitation to Mount Read and whether the source region has influence over the δ18OTR series. Median δ18OTR (n = 10) is correlated with local temperature and vapor pressure deficit in the early growing season. In addition, spatial correlations reveal that median δ18OTR is positively correlated with temperature and negatively correlated with precipitation in the source region. However, measurements of δ18OTR exhibit high inter-tree variation, particularly between 1960 and 1990. Our results indicate that this δ18OTR proxy may provide additional information about past moisture conditions during the growing season, potentially contributing to more robust reconstructions of the Southern Hemisphere climate dynamics; however, additional sampling may be necessary to resolve inter-tree variation in δ18OTR.

Defining a Precipitation Stable Isotope Framework in the Wider Carpathian Region

The eastern part of Europe is very poorly represented in the Global Network for Isotopes in Precipitation (GNIP) database, mainly because the monitoring of the stable isotopes in precipitation started only recently compared with other regions. In this respect, the main objective of this article is to fill the gap in the GNIP database over the eastern part of Europe and show the temporal variability and potential drivers of an extended network of δ18O values in precipitation collected from 27 locations in Romania and the Republic of Moldova. We also present the first high-resolution map of the spatio-temporal distribution of δ18O values in precipitation in Romania and the Republic of Moldova, according to an observational dataset. According to our results, the stations from western and northern Romania tend to have LMWLS with higher values than those from southwestern Romania. The monthly variation of the δ18O and δ2H showed a clearly interannual variation, with distinct seasonal differences, following the seasonal temperatures. The analysis of the spatial distribution of stable isotopes in precipitation water was made on the basis of both observational data and modeled data. This allowed us to study the origin of the air moisture and the interaction with regional and local patterns and to analyze the link between the spatial δ18O variations and the large-scale circulation patterns on a seasonal scale.

Validation and Bias Correction of Monthly δ18O Precipitation Time Series from ECHAM5-Wiso Model in Central Europe

Simulated stable oxygen isotopic composition (δ18O) of precipitation from isotope-enabled GCMs (iGCMs) have gained significant visibility nowadays. This study evaluates bias correction techniques to reduce the systematic and dispersion biases of the modelled δ18O by the ECHAM5-wiso model compared to the Global Network of Isotopes in Precipitation (GNIP) observations over Central Europe. mean bias error (MBE) and Root Mean Square Error (RMSE) are substantially reduced by more than 70% and 10%, respectively, depending on the bias correction scheme, with better results for Generalized Additive Model (GAM) and linear scaling approach (SCL) methods. The bias-corrected δ18OECHAM5-wiso values successfully describe the long-term isotopic composition of precipitation and the isotopic amplitude with the best performances for the EQM method. The necessity of applying bias correction algorithms is verified by the excellent agreement between the corrected δ18OECHAM5-wiso with GNIP in high-altitude areas where ECHAM5-wiso fails to reproduce the observed isotopic variability. The results are expected to bring valuable insights into the utilization of iGCMs’ relationships in climate studies for understanding the present and past water cycle under the isotopic perspective.

Building an isoscape based on tooth enamel for human provenance estimation in Brazil

In this study, we present a correlation between δ18OC values of carbonate in tooth enamel samples from the modern Brazilian population and the available δ18ODW data for the meteoric water from the Global Network of Isotopes in Precipitation (GNIP). Tooth enamel from 119 Brazilian individuals from five different regions of the country were analyzed. The δ18OC isoscape obtained is in good agreement with the isoscape based on regional meteoric and drinking water. The regression matrix obtained for the δ18O values of the carbonate tooth enamel and meteoric water was used to build an isoscape using the regression-kriging approach. Our data show that Brazil can be divided in two main regions with respect to the δ18O values of the carbonate tooth enamel: (1) the most easterly part of the northeast region, which is characterized by a warm and dry climate and (2) the remainder of the country, stretching from the Amazon rain forest to the more southernly regions. The data herein reported can be used for forensic purposes related to human identification.

Applying an isotope-enabled regional climate model over the Greenland ice sheet: effect of spatial resolution on model bias

Abstract. In order to investigate the impact of spatial resolution on the discrepancy between simulated δ18O and observed δ18O in Greenland ice cores, regional climate simulations are performed with the isotope-enabled regional climate model (RCM) COSMO_iso. For this purpose, isotope-enabled general circulation model (GCM) simulations with the ECHAM5-wiso general circulation model (GCM) under present-day conditions and the MPI-ESM-wiso GCM under mid-Holocene conditions are dynamically downscaled with COSMO_iso for the Arctic region. The capability of COSMO_iso to reproduce observed isotopic ratios in Greenland ice cores for these two periods is investigated by comparing the simulation results to measured δ18O ratios from snow pit samples, Global Network of Isotopes in Precipitation (GNIP) stations and ice cores. To our knowledge, this is the first time that a mid-Holocene isotope-enabled RCM simulation is performed for the Arctic region. Under present-day conditions, a dynamical downscaling of ECHAM5-wiso (1.1∘×1.1∘) with COSMO_iso to a spatial resolution of 50 km improves the agreement with the measured δ18O ratios for 14 of 19 observational data sets. A further increase in the spatial resolution to 7 km does not yield substantial improvements except for the coastal areas with its complex terrain. For the mid-Holocene, a fully coupled MPI-ESM-wiso time slice simulation is downscaled with COSMO_iso to a spatial resolution of 50 km. In the mid-Holocene, MPI-ESM-wiso already agrees well with observations in Greenland and a downscaling with COSMO_iso does not further improve the model–data agreement. Despite this lack of improvement in model biases, the study shows that in both periods, observed δ18O values at measurement sites constitute isotope ratios which are mainly within the subgrid-scale variability of the global ECHAM5-wiso and MPI-ESM-wiso simulation results. The correct δ18O ratios are consequently not resolved in the GCM simulation results and need to be extracted by a refinement with an RCM. In this context, the RCM simulations provide a spatial δ18O distribution by which the effects of local uncertainties can be taken into account in the comparison between point measurements and model outputs. Thus, an isotope-enabled GCM–RCM model chain with realistically implemented fractionating processes constitutes a useful supplement to reconstruct regional paleo-climate conditions during the mid-Holocene in Greenland. Such model chains might also be applied to reveal the full potential of GCMs in other regions and climate periods, in which large deviations relative to observed isotope ratios are simulated.

δ2H and δ18O in Precipitation and Water Vapor Disentangle Seasonal Wind Directions on the Loess Plateau

In many areas of the Loess Plateau, groundwater is too deep to extract, making meteoric water (snow and rain) the only viable water resource. Here we traced the rainwater and water vapor sources using the δ2H and δ18O signature of precipitation in the northern mountainous region of Yuzhong on the Loess Plateau. The local meteoric water line in 2016 and 2017 was defined as δ2H = 6.8 (±0.3)∙δ18O + 4.4 (±2.0) and δ2H = 7.1 (±0.2)∙δ18O + 1.5 (±1.6), respectively. The temperature and precipitation amount are considered to be the main factor controlling the δ2H and δ18O variation of precipitation, and consequently, relationships were first explored between δ18O and local surface air temperature and precipitation amount by linear regression analysis. The temperature effect was significant in the wet seasons but was irrelevant in the dry seasons on daily and seasonal scales. The amount effect was significant in the wet seasons on a daily scale but irrelevant in the dry seasons. However, based on the data of the Global Network of Isotopes in Precipitation (GNIP) (1985–1987, 1996–1999) of Lanzhou weather station, the amount effects were absent at seasonal scales and were not useful to discriminate either wetter or drier seasons or even wetter or drier decades. Over the whole year, the resulting air mass trajectories were consistent with the main sources of water vapor were from the Atlantic Ocean via westerlies and from the Arctic region, with 46%, 64%, and 40% of water vapor coming from the westerlies, and 54%, 36%, and 60% water vapor from the north in spring, autumn and winter, respectively. In the summer, however, the southeast monsoon (21%) was also an important water vapor source in the Loess Plateau. Concluding, using the δ2H and δ18O signatures of precipitation water, we disentangled and quantified the seasonal wind directions that are important for the prediction of water resources for local and regional land use.

Lake water based isoscape in central-south Chile reflects meteoric water

Warming across the globe is expected to alter the strength and amount of regional precipitation, but there is uncertainty associated with the magnitude of these expected changes, and also how these changes in temperature and the hydrologic cycle will affect humans. For example, the climate in central-south Chile is projected to become significantly warmer and drier over the next several decades in response to anthropogenically driven warming, but these anthropogenic changes are superimposed on natural climate variability. The stable isotope composition of meteoric water provides significant information regarding the moisture source, pathways, and rain-out history of an air mass, but precipitation samples suitable for stable isotope measurements require long-term placement of field equipment making them difficult to obtain. The International Atomic Energy Agency (IAEA) Global Network of Isotopes in Precipitation (GNIP) stations generate isotopic and ancillary data of precipitation from many locations around the world, but remote areas of developing countries like Chile typically have sparse networks of meteorological stations, which inhibit our ability to accurately model regional precipitation. Central-south Chile, in particular, has a sparse network of GNIP stations and, as a result, the isotopic composition of meteoric water is underrepresented in the global database complicating efforts to constrain modern day hydroclimate variability as well as paleohydrologic reconstruction for southern South America. In this study, we measured the stable isotope compositions of hydrogen (δ2H) and oxygen (δ18O) in surface lacustrine waters of central-south Chile to determine what physical and/or climatic features are the dominant controls on lacustrine δ18O and δ2H composition, assess whether or not the isotopic composition of the lakes record time-averaged isotope composition of meteoric water, and determine whether an isoscape map based on lake surface waters could predict the H and O isotope compositions of precipitation at the few GNIP stations in the region.

Paleotemperature reconstructions using speleothem fluid inclusion analyses from Hungary

The combined use of the stable isotope compositions of speleothem carbonate and inclusion-hosted water presents great potential in paleotemperature reconstructions, due to the various temperature-dependent isotope fractionations detected in cave systems and their environment. This paper evaluates the applicational possibilities of hydrogen and oxygen isotope measurements of inclusion-hosted water and its host calcite, in three different approaches: i) direct determination of calcite-water oxygen isotope fractionation by measuring inclusion water and carbonate compositions, ii) calculation of water oxygen isotope composition from hydrogen isotope data and of temperature from the inferred calcite-water fractionation, and iii) calculation of formation temperature from measured hydrogen isotope data and its temperature dependence in the modern precipitation water. Fluid inclusion oxygen and hydrogen isotope compositions as well as calcite oxygen isotope compositions were determined for five speleothem occurrences in Hungary. Although the background processes are not resolved, calculations involving measured calcite and water oxygen isotope compositions yielded unrealistic paleotemperatures, likely because of syn-formation isotope fractionation processes and diagenetic alterations. The hydrogen isotope data may yield realistic temperatures, provided that long-term isotopic composition - temperature relationships are known and the stable hydrogen isotope composition of the precipitation waters in the study area is temperature-controlled. Winter half-year and annual isotope-temperature relationships (δ2H/T gradients) were calculated using multidecadal isotope composition records from the Global Network of Isotopes in Precipitation (GNIP), gridded surface temperatures, and precipitation amounts from the E-OBS 21.0e database. The calculations yielded a paleotemperature record for the last ~250 ka, with average precisions ranging from ±0.6 °C for interglacial to ±2.4 °C for glacial periods. Clumped isotope analyses of cave-hosted flowstones support the inferred formation temperatures based on gradients, while detection of kinetic fractionations by combined hydrogen and oxygen isotope analyses of calcite and inclusion water lead to filtering clumped isotope (Δ47) data and more coherent Δ47-temperature relationships.

Linking the karst record to atmospheric, precipitation, and vegetation dynamics in Portugal

Cave deposits can be valuable sources of paleoclimate data, especially when atmospheric circulation patterns, precipitation variability, vegetation changes, and the chemical evolution of waters moving through the karst environment can be mechanistically linked to speleothem proxies. In particular, an evaluation of the factors that control the isotopic composition of precipitation and the evolution of rainwater during migration from the land surface to the cave are needed to robustly develop speleothems as hydroclimate-sensitive proxies. One area in which precipitation and atmospheric variability are closely linked is western Iberia, where rainfall is strongly influenced by the Azores High, part of the North Atlantic Oscillation (NAO) dipole. Therefore, in order to better characterize the factors that influence the isotopic composition of precipitation in Portugal and to evaluate the potential of using stalagmites from this region as hydroclimate (and NAO-sensitive) proxies, we investigated Global Network of Isotopes in Precipitation (GNIP) data from ten mainland Portugal sites spanning multiple decades. In addition, we use more than one hydrologic year of precipitation amount and isotope data from Buraca Gloriosa (BG), a cave in western Portugal, the site of on-going speleothem analyses, as well as six years of environmental monitoring from BG. We present an integrated analysis of rainfall and vegetation through the normalized difference vegetation index (NDVI) following extremely wet and dry winters. Summer vegetation density, related to the amount of precipitation in the preceding winter wet season, as well as prior calcite precipitation (PCP), would largely control the stable carbon isotopic signature (δ13C) in stalagmites at BG. Cool season recharge is likely the dominant factor for the oxygen isotopic composition (δ18O) of water percolating through the cave system, while amount effects exert the primary control on precipitation δ18O values. Based on HYSPLIT modeling, moisture sources overwhelmingly originate from the Atlantic Ocean as opposed to the Mediterranean or elsewhere; thus, variability in δ18O values in the precipitation (and, thus, by inference, those of the dripwater and stalagmites) are primarily reflecting changes in precipitation amount and not changing temperatures or source regions. Together these data constitute an important analysis of the controls of isotope proxies in Portuguese cave systems.

A Climatological Interpretation of Precipitation δ18O across Siberia and Central Asia

Siberia and Central Asia are located at middle to high latitudes, encompassing a large landlocked area of the Eurasian continent and vast tracts of permafrost, which are sensitive to global climate change. Here, we investigated the data from 15 Global Network of Isotopes in Precipitation (GNIP) stations to clarify the relationship between precipitation δ18O (δ18OP) and the local temperature and precipitation amount on the monthly, seasonal, and annual timescales. Three main conclusions as following: (1) On the monthly time scale, the variation in δ18OP is mainly controlled by the “temperature effect”. (2) The weighted average value of precipitation δ18O (δ18Ow) exhibited “temperature effect” over 60° N–70° N. However, δ18Ow was dominated by multiple factors from 40° N to 60° N (e.g., the North Atlantic Oscillation (NAO) and water vapor source changes). (3) The variations of δ18OW can be attributed to the changes in pathway of the westerly dominated by the NAO at annual timescale. Therefore, it is possible to reconstruct the histories of past atmospheric circulations and water vapor sources in this region via δ18O in geologic archives, e.g., speleothem and ice core records.

High‐Resolution Proxy Records From Two Simultaneously Grown Stalagmites From Zoolithencave (Southeastern Germany) and their Potential for Palaeoclimate Reconstruction

AbstractTwo small annually laminated stalagmites from Zoolithencave (southeastern Germany) grew between CE 1821 and 1970 (Zoo‐rez‐1) and CE 1835 and 1970 (Zoo‐rez‐2), respectively. Trace element concentrations were determined by Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA‐ICP‐MS). Samples for δ13C and δ18O analyses were micromilled on annual and subannual resolution. Soil and host rock samples were analyzed by X‐Ray Diffraction (XRD) and their elemental concentrations determined via inductively coupled plasma optical emission spectrometer (ICP‐OES). Trace element concentrations in the stalagmites show two groups in the principal component analyses: one with Mg, Ba, and Sr and another with Y, P, and Al, respectively. The second group reflects the content of detrital material. Increased weathering of soil minerals seems to have a strong influence on the silicate/carbonate weathering ratio controlling the variability of Mg, Ba, and Sr. Meteorological and Global Network of Isotopes in Precipitation (GNIP) station data were used to calculate the δ18O values of the drip water (infiltration‐weighted, mean annual, and the mean of the winter precipitation δ18O values) as well as the corresponding speleothem calcite. The δ18O values calculated by the infiltration‐weighted model show similar patterns and amplitudes as the measured δ18O values of the two stalagmites. This suggests that the δ18O values of speleothem calcite reflect the δ18O values of infiltration‐weighted annual precipitation, which zis related to mean annual temperature, resulting in a significant correlation between mean annual temperature and the measured δ18O values of stalagmite Zoo‐rez‐2. This relationship could potentially be used for quantitative climate reconstruction in the future by extending the time series back in time with further stalagmites from Zoolithencave.