Glassy Groundmass Research Articles

The influence of temperature (up to 120 °C) on the thermal conductivity of variably porous andesite

The thermal conductivity of volcanic rock is an essential input parameter in a wide range of models designed to better understand volcanic and geothermal processes. However, although volcanoes and geothermal reservoirs are often characterised by temperatures above ambient, laboratory thermal conductivity measurements are often performed at ambient temperature. In addition, there are currently few data on the temperature dependence of thermal conductivity for andesite, a common volcanic rock. Here, we provide elevated-temperature (up to 120 °C) laboratory measurements of thermal conductivity for variably porous (∼0.05 to ∼0.6) and variably glassy andesites from Mt. Ruapheu (New Zealand) using the transient hot-strip method. Our data show that (1) the thermal conductivity of these andesites has little to no temperature dependence and, therefore, (2) there is also no influence of porosity on the temperature dependence of thermal conductivity. We compare our new data with compiled published data to show that the thermal conductivity of volcanic rocks may decrease, remain constant, or increase as a function of temperature. We show that the thermal conductivity of amorphous glass and crystalline material increase and decrease, respectively, as temperature increases. We therefore interpret the temperature dependence of the thermal conductivity of volcanic rock to be dependent on glass content. The thermal conductivity of the studied andesites, the microstructure of which can be characterised by phenocrysts within a variably glassy groundmass, has little to no temperature dependence because the decrease in the thermal conductivity of the crystalline materials, due to decreases in lattice thermal conductivity, is offset by the increase in the thermal conductivity of the amorphous glass. A simple modelling approach, using the temperature dependence of the thermal conductivity of glass and crystalline material, provides a crystal content of 0.26 for a thermal conductivity independent of temperature, a common crystal content for andesite dome rock. Our findings imply that calculations of heat transfer through partially glassy volcanic rocks need not consider a temperature-dependent thermal conductivity, but that decreases and increases in thermal conductivity with temperature should be expected for fully crystallised or devitrified volcanic rocks and completely glassy volcanic rocks, respectively. We highlight that more experimental studies are now required to assess the evolution of thermal conductivity as a function of temperature in a wide range of volcanic rocks with different crystallinities.

Explosive volcanic activity in Central-Southern Italy during Middle Pleistocene: A tale from tephra layers of the Acerno basin

The cored succession of the Acerno basin, a tectonic palaeolake located in the southern Apennines (Italy), represents a key point of the Italian tephrostratigraphic network for the Quaternary. Trace element and isotope (87Sr/86Sr and 143Nd/144Nd) data have been acquired on bulk rock, glassy groundmass and separated minerals (feldspar and pyroxene phenocrysts) from twenty-one tephra layers, dated between ∼570 and 470 ka, embedded in the lacustrine sediments of the basin. The already available major element compositions have been here combined with the newly acquired data. The whole dataset provides a full geochemical characterization of the tephra that strengthens and improves previous attempts to identify their volcanic sources and potential correlatives. In this context, several previously proposed correlations among distal archives have been here confuted. The geochemical fingerprints highlight that the volcanic record preserved in the Acerno lacustrine succession can be attributed to the explosive activity of the Roccamonfina, Colli Albani, Sabatini, Pontian islands (Latium region, Central Italy) and the Neapolitan Volcanic Area (Campania region, South Italy), providing new insights to enhance the current knowledge on the Middle Pleistocene volcanic record in Italy. Moreover, tephra attributions suggest still unknown eruptive activity of such volcanoes during the Quaternary. From this perspective, our study testifies how difficult it is to precisely correlate different geological archives even in a very short time interval. Such a difficulty arises from a large number of volcanic events concentrated in a relatively short time span, with products of similar chemical composition, and from the incomplete characterization of the successions in proximal outcrops. A thorough reconstruction of the eruptive history of these volcanic complexes requires a wider and denser study of distal archives, alongside further investigations in proximal areas.

Electrical properties of Lithium silicate-based glasses and their Glass-ceramics

Crystallization of lithium di- and meta-silicates were developed in the SiO2–Li2O–TiO2 glass system. Inclusion of TiO2 relatively reduced the crystallization temperature. Through the sintering process at 650 °C/2 h, lithium disilicate was devolved in the TiO2-free sample, whereas the incorporation of TiO2 catalyzed the appearance of lithium metasilicate phases. The microstructure of lithium disilicate glass-ceramics was studied using differential thermal analysis (DTA), powder X-ray diffraction (PXRD), and scanning electron microscopy (SEM). At 650 °C/2 h, the microstructure consists of spherulitic growths with reasonably sorted nanosize particles in a glassy groundmass. The electrical characteristics of lithium silicate glasses and glass-ceramics having variable concentrations of TiO2 were tested in order to explore their electronic hopping process. To clarify the effects of composition and sintering on the electrical and dielectric behavior of glasses based on lithium silicate, a Broadband Dielectric Spectroscopy (BDS) was employed. While the matching-sintered glass-ceramic exhibits like an insulator with interfacial polarization that significantly lowers the density number of free ions, bulk glass nevertheless demonstrate high conductivity. Lithium oxide considerably increases the conductivity of the composite instead of titanium oxide.

Relación entre vulcanismo dacítico monogenético y poligenético. Caso de estudio del domo Tapias (<95 ka) y volcán Cerro Machín (<50 ka), Colombia

The Tapias lava dome is located ~5 km SE of the explosive, Cerro Machín polygenetic volcano, both located on the Colombian Central Cordillera. The edifices have been interpreted as generated by the same magmatic system; however, the genetic and temporal relations between both edifices have not been established. In this work, the Tapias dome is studied using petrographic characterizations, mineral-, whole-rock- and isotopic chemistry, geothermobarometric calculations, and a K/Ar radiogenic age, and subsequently it is explored the relationship with the Cerro Machín. The rocks from Tapias dome are porphyritic with phenocrysts of plagioclase (An28-48), amphibole (tschermakite and magnesiohastingsite), biotite, quartz, and Fe-Ti oxides, embedded in a glassy groundmass. Petrographically, two types of amphibole crystals were recognized: type I, which is homogeneous, and type II, which displays different rims. The composition of Tapias is dacitic (SiO2: 66.59 wt.%) with calc-alkaline affinity. Our geothermobarometric calculations indicate that type I amphibole crystallized at 871-874°C, between 10.2 and 10.4 km depth. The core of the type II amphibole crystallized at 852-920°C, between 8.5 and 12.3 km depth, while its rim did it at higher temperatures (880-973°C), but at similar depths (9.1-11.8 km). The K/Ar radiogenic age obtained for the groundmass shows an emplacement age not older than 95 ± 0.05 ka. When comparing the results to the Cerro Machín, it is noted that the mineral and compositional characteristics are nearly identical. These results suggest that indeed both volcanoes share the same magmatic system and are fed by magma hosted between ~9 and ~12 km depth. Moreover, it is proposed that the vent location of both edifices, as well as the time gap between the eruption at Tapias and the beginning of the activity at the Cerro Machín (~50 ka), are the result of crustal deformation caused by the interaction between the Otú-Pericos and Ibagué faults.

K původu analcimu v mezozoických a kenozoických vulkanitech České republiky a jeho úloze v názvosloví hornin

Magmatic origin of analcime has been discussed for decades (e. g., Karlsson and Clayton 1991, 1993; Pearce 1993). Despite the fact that analcime has been re-classified as zeolite and its secondary (post-magmatic) origin is globally accepted (e. g., Roux and Hamilton 1976, Giannetti and Masi 1989, Wilkinson and Hensel 1994), it is still commonly used in classification of alkaline rocks in the Czech Republic. In these rocks, analcime can be mostly found in the pseudomorphs after leucite (Fig. 1a; see Rapprich 2003), or as a homogeneous anhedral filling in the groundmass (Fig. 1b). In the second case, the boundaries of individual analcime crystals cannot be identified due to the isotropic optical properties of analcime. Therefore, origin and growth of analcime is difficult to reconstruct. For this contribution, we have studied samples of Mesozoic and Cenozoic alkaline rocks from three localities across the Czech Republic, where partly analcimized glass in the groundmass was preserved, with an aim to better understand the origin of analcime in alkaline rocks. Mesozoic augitite from the southwestern slope of the Petřkovice Mt. near Nový Jičín (sample TG05) displays small isometric colourless, optically isotropic domains (analcime) enclosed in originally glassy groundmass (Fig. 1c–f ). This texture suggests the analcime is replacing original glass in the groundmass, enclosing also microcrysts of the stable minerals in groundmass. Very similar texture was observed also in Oligocene augitite from Mětikalov in Doupovské hory Mts. (sample DR338, Fig. 2). In this rock, the analcime domains either mantle larger phenocrysts, or are distributed within the groundmass. The growth of the analcime domains on the edges of larger phenocrysts resembles growth of spherulites, which represent products of silica-rich glass recrystallization (e. g., Breitkreuz 2013). To further investigate this possibility, additional samples were collected from Kamenický vrch near Zákupy (Fig. 3). In individual samples, number and size of analcime domains vary, which suggests, that these domains represent various stages of a continuous growth. The X-ray elemental mapping of Al and Na (Fig. 4) then shows, that the analcime domains are represented by single grains of cubic analcime. As a result, we may conclude that analcime in groundmass of Mesozoic and Cenozoic alkaline rocks originates from devitrification of original glass. These rocks hence should not be classified as “analcimites” or “analcimic …” but rather as “analcimized …” according to Le Maitre et al. (2005).

Petrology and geochemistry of bimodal volcanic rocks of Southern Lake Hayk area, northwestern Ethiopian plateau: implication for their petrogenesis

This study presents and integrates field, petrological, and whole-rock geochemical (major and trace elements) data of the volcanic rocks from the Lake Hayk area to understand their petrogenesis. The study area's major lithological components include lower and upper basalt, rhyolitic lava, rhyolitic tuff, rhyolitic ignimbrite, and unwelded tuff. Petrographic analysis suggests that felsic rocks are dominated by quartz and well-developed sanidine (K-feldspar) phenocrysts with glassy groundmass, whereas mafic volcanic products are characterized by aphyric to porphyritic textures with the olivine and plagioclase dominant phenocryst. The area constitutes bimodal composition of flood basaltic to rhyolitic rock with scarce intermediate composition. Basalts have low Rb/Nb = 0.5-0.58, La/Nb = 0.88-1.06 and high TiO2 = 2.08-3.04, basaltic andecite have higher Rb/Nb =2.7, La/Nb = 1.81 and low TiO2= 1.96 and rhyolite Rb/Nb = 0.97-1.69, La/Nb = 0.51-1.08 and lower TiO2 = 0.41- 0.71.The positive Ba and negative K anomalies testify amphibole mantle source. The basalts are characterized by low CaO/Al2O3 ratios (0.71–0.97) and relatively less fractionated and flat hree patterns with (TbN/YbN = 1.75-2.33) chondritic values. This suggests a mantle source mostly containing spinel rather than garnet. Rhyolites are characterized by a steep negative correlation in bivariate plots of MgO, Fe2O3, TiO, and CaO against SiO2 and positive anomaly of Ta with slight Nb trough. This suggests that Fractional Crystallization is the major process for the genesis of rhyolitic rocks, rather than crustal contribution, partial melting, and assimilation, producing rhyolitic rocks.

The pseudotachylytes at the base of the Silvretta Nappe: A newly discovered recent generation and the tectonomometamophic evolution of the Nappe

The base of the Silvretta Nappe (Austroalpine Unit, Eastern Alps) has localized extensive deformation, including the occurrence of multiple generations of pseudotachylytes, alternating with (ultra)mylonites, in the host amphibolite and gneiss. Previous works attributed the formation of pseudotachylytes and associated ultramylonites to the Eoalpine deformation phase (mid. Cretaceous). In this work, we report the presence of a younger generation of pseudotachylytes, which overprints the previously characterized pseudotachylyte-ultramylonite association. A detailed petrographic study of selected samples from the Jamtal, Tyrol (Austria), provides further constraints on the possible tectonic evolution of the Silvretta Nappe.Contrary to the Eoalpine pseudotachylytes, the younger pseudotachylytes are not completely recrystallized, foliated, and epidotized, but rather preserve the typical features of frictional melts (e.g., microlites, glassy groundmass, evidence of melt immiscibility, etc.). This suggests formation in relatively shallow conditions, rather than under greenschist facies, as assumed for the Eoalpine pseudotachylytes. The “young” pseudotachylytes, commonly discordant to the foliation, thus likely formed during the final subduction of the Penninic Unit in the Paleogene. This occurrence lends further support to the localization of deformation at the base of the upper plate, in this case represented by the Silvretta Nappe, as observed in other portions of the Alps.

Petrological evidence of rapid evolution of the magma plumbing system of Bezymianny volcano in Kamchatka before the December 20th, 2017 eruption

We used petrological data on samples of the December 20th, 2017 eruption of the Bezymianny volcano (Kamchatka, Russia) to investigate the evolution of the magmatic system during the repose period and the following reactivation of the volcano. The eruptive products are diverse in bulk rock and matrix glass compositions, but are similar in phenocryst proportion, composition, and zoning. Three rock types are distinguished by the presence of either silica-phase (cristobalite or tridymite) or their absence. Rocks without silica phase (Silica-phase Free Host Rocks) are characterized by ~55–56 wt% bulk SiO2 content and have predominantly glassy groundmass with rare microlites in dacitic matrix glass (65.5–70.5 wt% SiO2 and 2.5–3.5 wt% K2O). Cristobalite-bearing rocks are characterized by ~56.6–57.5 wt% bulk silica content and highly crystalline groundmass with many small microlites and rhyolitic matrix glass (76.5–78 wt% SiO2 and 3.8–4.2 wt% K2O) between them. Tridymite-bearing rocks are characterized by ~58.8 wt% bulk silica content and glassy groundmass with rare microlites in rhyolitic matrix glass (77–77.5 wt% SiO2 and ~3.6 wt% K2O).Rhyolite-MELTS simulation and mineral thermobarometry indicate that silica-phase-bearing rock last equilibrated under low-pressure conditions (~15 Mpa) corresponding to the conduit depths, whereas rocks without silica phase crystallized at higher pressure corresponding to shallow magma storage depths (>40–60 Mpa). Bulk rock mass-balance calculations indicate that silica-phase-bearing magmas were produced by 15% of crystal fractionation from the magma without silica phase. Based on this petrological data, we reconstruct the evolution of the magmatic system as follows. During the volcano repose period, undisturbed magma fractionated and stratified due to buoyant ascent of fluid and melt to the chamber roof. Rejuvenation of magmatic system caused pushing the differentiated magma from the top magmatic reservoir to the conduit, where silica phases crystallized. We argue that cristobalite-bearing rocks are likely the remnants of conduit plug, whereas tridymite-bearing rocks represent magma trapped in the conduit under the plug. The renewal of explosive activity in December 2017 was triggered by magma influx from deeper levels of the plumbing system shortly before the explosion, which is supported by the presence of amphibole-bearing mafic enclaves of mid-crustal origin (520–850 Mpa).

Interaction between mafic dike rocks and salt deposits in the Rhine Graben, southwest Germany

ABSTRACT Dikes of primitive olivine melilitites and monchiquites intruded into an Oligocene (Rupelian) potash salt deposit near Buggingen (SW Germany). Ocelli and amygdules reveal distinct mineral assemblages depending on whether the dike rocks are in direct contact with the potash layer or with bituminous shales (Fish Shale). Samples in contact with the potash salt layer show roundish textures that contain smectite ± talc ± chlorite, calcite, and in cases anhydrite and halite, while those close to the bituminous shale mainly comprise smectite, calcite, zeolite group minerals, and analcime. No textural or mineralogical evidence for high-temperature (magmatic) interaction between the dike rocks and the evaporites was observed. This is presumably related to (1) a very low magmatic water activity in the magma, which prevented exsolution of aqueous fluids and appreciable dissolution of the salt, and (2) fast cooling of the magmas, inhibiting melting of the salt deposits and potential liquid mingling and/or assimilation processes. Halite formation in the dike rocks is, rather, related to later, post-magmatic hydrothermal fluids that previously interacted with the salt-rich host rocks. Alteration of the initially glassy groundmass to smectites and zeolites caused an enrichment of Na in the residual fluid, but halite saturation was not attained, as indicated by the absence of groundmass halite. Only fluid–rock interaction in millimeter-sized vugs caused halite precipitation via desiccation by swelling of previously formed clay minerals. Locally, the boron silicate datolite formed in pseudomorphs after olivine. Its precipitation was controlled by the Si and B supply provided by the breakdown of serpentine and smectite.

Late Pleistocene subglacial fissure-related volcanism at Caviahue-Copahue Volcanic Complex (37° 51° S, 71° 05’ W), South Volcanic Zone

The Caviahue-Copahue Volcanic Complex (CCVC, 37° 51’ S-71° 05′ W) is located in the central segment of the South Volcanic Zone, ~30 km eastward from the main Andean volcanic arc. Within a complex tectonic setting, it has developed under the influence of the northern transtensional Liquiñe-Ofqui Fault Zone, to the south and the Copahue-Antiñir Fault Zone to the northeast. The onset of volcanic activity within Caviahue volcano-tectonic depression has been dated at Ar/Ar 125 ± 9 ka and it is represented by lava flows and ignimbrites of Las Mellizas Formation. Copahue volcano has a very well documented historical eruptive record, encompassing 13 eruptive cycles in the last 260 years. On the contrary, volcano stratigraphy during Late Pleistocene and pre-historic times is poorly constrained, mainly due to the lack of reliable radiometric data. Based on the peculiar morphology and cooling-fracture systems, lavas that crop out along Dulce, Jara and NE Agrio river valleys have been included in a new stratigraphic unit, here named as Río Dulce Formation. A subglacial emplacement is proposed taking into account the evidence of ice-confinement, provided by the flat-topped and steep-sided lava domes/flows and dammed lava flows. In addition, melt water-magma interaction is supported by conspicuous fine columnar-jointing and closely spaced curved bands with plumose structures, well-developed pseudopillow fracture systems, platy and hackly fractures and cube-jointed entablature-bearing lava flows. The basaltic andesites (SiO2= 55–57%) are porphyritic, with ~30–40% of sieved plagioclase, two pyroxenes and olivine, set in a glassy groundmass. Lava vent distribution and primary anisotropy planes orientation, in coincidence with WNW-ESE and NE-SW trending faults, lineaments and fault scarps, document a first-order structural control on the volcanic emplacement. Although undated, this study can contribute to understanding the timing of glacial fluctuations during Late Pleistocene. Furthermore, it has implications on hazard assessment since it highlights that the evolution of the CCVC has experienced alternating fissure and central eruptive style, likely related to the dynamics of the magma-plumbing system, as suggested by geophysical evidence of unrest.

Formation mechanisms of macroscopic globules in andesitic glasses from the Izu\u2013Bonin\u2013Mariana forearc (IODP Expedition 352)

The Izu–Bonin–Mariana volcanic arc is situated at a convergent plate margin where subduction initiation triggered the formation of MORB-like forearc basalts as a result of decompression melting and near-trench spreading. International Ocean Discovery Program (IODP) Expedition 352 recovered samples within the forearc basalt stratigraphy that contained unusual macroscopic globular textures hosted in andesitic glass (Unit 6, Hole 1440B). It is unclear how these andesites, which are unique in a stratigraphic sequence dominated by forearc basalts, and the globular textures therein may have formed. Here, we present detailed textural evidence, major and trace element analysis, as well as B and Sr isotope compositions, to investigate the genesis of these globular andesites. Samples consist of hbox {K}_2hbox {O}-rich basaltic globules set in a glassy groundmass of andesitic composition. Between these two textural domains a likely hydrated interface of devitrified glass occurs, which, based on textural evidence, seems to be genetically linked to the formation of the globules. The andesitic groundmass is Cl rich (ca. 3000, mu hbox {g/g}), whereas globules and the interface are Cl poor (ca. 300, mu hbox {g/g}). Concentrations of fluid-mobile trace elements also appear to be fractionated in that globules and show enrichments in B, K, Rb, Cs, and Tl, but not in Ba and W relative to the andesitic groundmass, whereas the interface shows depletions in the latter, but is enriched in the former. Interestingly, globules and andesitic groundmass have identical Sr isotopic composition within analytical uncertainty (^{87}hbox {Sr}/^{86}hbox {Sr} of 0.70580 pm 10), indicating that they likely formed from the same source. However, globules show high delta ^{11}B (ca. + 7permille), whereas their host andesites are isotopically lighter (ca. – 1 permille), potentially indicating that whatever process led to their formation either introduced heavier B isotopes to the globules, or induced stable isotope fractionation of B between globules and their groundmass. Based on the bulk of the textural information and geochemical data obtained from these samples, we conclude that these andesites likely formed as a result of the assimilation of shallowly altered oceanic crust (AOC) during forearc basaltic magmatism. Assimilation likely introduced radiogenic Sr, as well as heavier B isotopes to comparatively unradiogenic and low delta ^{11}hbox {B} forearc basalt parental magmas (average ^{87}hbox {Sr}/^{86}hbox {Sr} of 0.703284). Moreover, the globular textures are consistent with their formation being the result of fluid-melt immiscibility that was potentially induced by the rapid release of water from assimilated AOC whose escape likely formed the interface. If the globular textures present in these samples are indeed the result of fluid-melt immiscibility, then this process led to significant trace element and stable isotope fractionation. The textures and chemical compositions of the globules highlight the need for future experimental studies aimed at investigating the exsolution process with respect to potential trace element and isotopic fractionation in arc magmas that have perhaps not been previously considered.

Microstructure Investigation of Oil-Bearing Rhyolites: A Case Study from the Hailar Basin, NE China

Understanding the microstructure of rhyolites may greatly promote exploration efforts on rhyolitic hydrocarbon reservoirs; however, related studies are sparse. In this contribution, the microstructure and related porosity of oil-bearing rhyolitic lavas from the Hailar Basin (NE China) were investigated using a combination of optical microscopy, fluorescence image analysis, and scanning electron microscopy. The direct visual and quantitative analyses show that the rhyolites are heterogeneous and porous rocks and have complex microstructures. Phenocryst-rich rhyolitic lava, perlitic lava, and spherulitic rhyolite may be favorable targets for rhyolitic hydrocarbon exploration. For the phenocryst-rich rhyolitic lavas, embayment pores, cleavages, cavitational and shear fractures, and intracrystalline sieve pores are commonly observed in the phenocrysts; while flow-parallel laminar and micropores are ubiquitous in the groundmass. Perlitic lavas are characterized by the occurrence of numerous perlitic fractures which can also be produced in the glassy groundmass of other lavas. Spherulitic rhyolites mainly consist of small-sized (<1 mm) clustered or large-sized (>1 mm) isolated spherulites. Clustered spherulites are characterized by the development of interspherulite pores. Isolated spherulites contain numerous radiating micropores. Both types of spherulites may have water expulsion pores formed in the spherulite–glass border. The formation of the microstructure and related porosity of rhyolites is controlled by pre-, syn- (e.g., deuteric crystal dissolution, cavitation, ductile–brittle deformation, and high-T devitrification), and post-volcanic (e.g., hydration and low-T devitrification) processes. Although pores with diameters > 50 μm are often observed, small pores dominate in pore-size distribution. Small (<15 μm) and large (>300 μm) pores give the most volumetric contribution in most cases. Medium-sized pores with diameters ranging from ~150–300 μm are the least developed and contribute the least to the total volume. The results of this paper can be beneficial to further the understanding of the microstructure and pore system of rhyolites and may be applied to rhyolitic lava hydrocarbon reservoirs elsewhere.

Ceramic-faience hybrids were used to recycle bronze in North-Western European Iron Age egg-shaped crucibles

We investigated the characteristics of a group of 13 Middle Iron Age egg-shaped crucibles and crucible fragments from Tilburg (The Netherlands). We used a combination of optical and chemical analyses, including hand-held XRF, microCT scanning and 3-D printing polarizing light microscopy and SEM-EDX. The chemical analyses confirmed that the crucibles were used for copper alloy metallurgy. Impressions in the lids of the crucibles turned out to be imprints of copper alloy scrap, including fragments of twisted wire and fibulae. Most remarkable, however, is the large proportion of sheet metal among the scrap.In order to make crucibles from the local, non-refractory clays, a hitherto unknown ceramic-faience hybrid was used: A combination of clay and halophytic plant ash was mixed with silt into a paste, and this was used to construct the crucible. During firing, the flux would promote melting of the clays and probably prevent catastrophic failure of the crucibles. The resulting glassy groundmass – in which silt grains are embedded and partially dissolved – is rich in Al2O3 as well as in Na2O, K2O, CaO, MgO and Fe2O3.It is likely that this technique of crucible manufacture was widespread in Late Prehistory in areas where no refractory clays were available.

Towards Identification of Zircon Populations in Permo-Carboniferous Rhyolites of Central Europe: Insight from Automated SEM-Mineral Liberation Analyses

Zircon is a main mineral used for dating rhyolitic magmas as well as reconstructing their differentiation. It is common that different populations of zircon grains occur in a single rhyolitic sample. The presence of both autocrystic and antecrystic zircon grains is reflected in their strongly varied chemical compositions and slight spread of ages. However, postmagmatic processes may induce lead loss, which is also recorded as a spread of zircon ages. Therefore, new approaches to identify different zircon populations in rhyolitic rocks are needed. In this study, we suggest that detailed examination of zircon positions in the thin sections of rhyolitic rocks provides valuable information on zircon sources that can be used to identify autocrystic and antecrystic zircon populations. Automated Scanning Electron Microscope (SEM) analyses are of great applicability in determining this, as they return both qualitative and quantitative information and allow for quick comparisons between different rhyolite localities. Five localities of Permo-Carboniferous rhyolites related to post-Variscan extension in Central Europe (Organy, Bieberstein, Halle, Chemnitz, Krucze) were analyzed by automated SEM (MLA-SEM). The samples covered a range of Zr whole rock contents and displayed both crystalline and glassy groundmass. Surprisingly, each locality seemed to have its own special zircon fingerprint. Based on comparisons of whole rocks, modal composition and SEM images Chemnitz ignimbrite was interpreted as containing mostly (or fully) antecrystic zircon, whereas the Bieberstein dyke was shown to possibly contain both types, with the antecrystic zircon being associated with disturbed cumulates. On the other hand, Organy was probably dominated by autocrystic zircon, and Krucze contained dismembered, subhedral zircon in its matrix, whereas Halle zircon was located partly in late veins, filling cracks in laccolith. Both localities may, therefore, contain zircon populations that represent later stages than the crystallization of the main rhyolitic body.

A new unspiked K-Ar dating approach using laser fusion on microsamples.

Issues induced by neutron irradiation makes 40 Ar/39 Ar dating inapplicable in some cases. The first issue is 37 Ar and 39 Ar recoil effects during irradiation that affect fine-grained minerals (<50 μm), such as lunar rocks, glassy groundmass, supergene minerals (e.g., illite, glauconite, Mg-oxide, etc.). The second issue from neutron irradiation is the high radioactivity gain of iron-rich samples such as pyrite, and the third is the production of interference nuclides during irradiation. The inherent drawbacks of conventional K-Ar and current unspiked K-Ar dating make it difficult to assess the reliability of age results. A new approach is proposed using well-calibrated 40 Ar/39 Ar standard minerals to directly quantify 40 Ar, 38 Ar and 36 Ar. Fish Canyon sanidine (FCs), B4M muscovite and MMhb-1 hornblende, the widely used international standard minerals, were analyzed as unknowns to test the approach. Argon isotope analyses were carried out on a noble-gas mass spectrometer using laser fusion on microsamples (n × 0.01 to n × 0.2 mg). A new isochron - an "inverse isochron" for K-Ar dating - was designed. FCs and B4M yielded apparent and inverse isochron ages of 28.1 ± 0.1 and 28.0 ± 0.3 Ma, 18.2 ± 0.1 and 18.2 ± 0.5 Ma, which are consistent with the recommended ages, while the MMhb-1 presented lower apparent and inverse isochron ages (510.8 ± 4.8 and 512.3 ± 17.0 Ma) than the recommended ones. The initial argon compositions for the three standard minerals are 299.2 ± 205.3 (FCs), 294.0 ± 16.4 (B4M) and 290.9 ± 203.1 (MMhb-1), agreeing with that of air. The proposed approach potentially overcomes the issues of 40 Ar/39 Ar rising from irradiation and the drawbacks of K-Ar. By using laser fusion on multiple microaliquots from a same sample, this approach can produce accurate and precise K-Ar ages and give an inverse isochron. This new approach may provide an alternate dating method of geochronology based on argon isotopes.

Preparation and Electrical Characterization of Zn-Titanate / Borosilicate Glass Composites

A Composite materials from Zn-titanate/borosilicate glass of 10/0(ZT10), 9/1(ZT9), 7/3(ZT7) and 5/5(ZT5) ratios were prepared. Their XRD, SEM / EDX, electrical and dielectric properties were investigated. Willemite, rutile and Zn2TiO4 composite materials were developed through the sintering process. The incorporation of glass enhances the formation of willemite. The SEM micrographs show clear euhedral micro-size crystals of Zn2TiO4 spinel and willemite embedded in glassy groundmass. The EDX microanalysis shows the incorporation of Al- element into the structure of the formed phases. Both conductivity (σac) and dielectric constant ( $\upvarepsilon ^{\prime })$ , measured within frequency range 0.2 kHz -1 MHz, and temperature range 298- 573 (K). Glass-free sample showed the highest σac and $\upvarepsilon ^{\prime }$ . Although, 5/5 sample exhibited relative higher values than those with 9/1 and 7/3. The dielectric constant of 9/1 and 7/3 and 5/5 samples show almost an independent behavior over a wide range of temperatures which was attributed to the micro-sized grains of crystalline phases and restraining effect of rigid glassy matrix. The results of ac conductivity may indicate the dominance of electronic conduction over the ionic transfer one in the studied samples. Therefore they may present good candidates for semiconductor materials in electronic devices.

Geological evolution of Paniri volcano, Central Andes, northern Chile

Paniri volcano, in northern Chile, belongs to a volcanic chain trending across the main orientation of the Central Andean volcanic province. Field work mapping, stratigraphic sequences, and one new 40Ar/39Ar and eleven previous published 40Ar/39Ar, and K/Ar ages, indicate that the evolution of Paniri involved eruption of seven volcanic units (Malku, Los Gordos, Las Lenguas, Las Negras, Viscacha, Laguna, and Llareta) during four main stages occurring over more than 1 Myr: Plateau Shield (>800 ka); Main Edifice (800–400 ka); Old Cone (400–250 ka); and New Cone (250–100 ka). Considering glacial and fluvial action, an estimated 85.3 km3 of volcanic material were erupted during the eruptive history of Paniri volcano, giving a bulk eruption rate of 0.061 km3/ka, with major activity in the last 150 kyr (eruption rate of 0.101 km3/ka).Lava flows from Paniri show abundant plagioclase together with subordinate ortho-, and clino-pyroxene, and amphibole as main phenocrysts. Moreover, although true basalts are scarce in the Central Andes, olivine-bearing lavas were erupted at Paniri at ∼400 ka. Also, scarce phenocrysts of biotite, quartz, rutile, and opaque minerals (Fe-Ti oxides) were identified. The groundmass of these flows is composed mainly of glass along with pyroxene and plagioclase microlites. Consolidated and unconsolidated pyroclastic deposits of dacitic composition are also present. The consolidated deposits correspond to vitreous tuffs, whilst unconsolidated deposits are composed of pumice clasts up to 5 cm in diameter. Both pyroclastic deposits are composed of glassy groundmass (up to 80% vol.), and subordinated plagioclase, hornblende, and biotite phenocrysts up to 1 cm in length. Results of twenty-four new, coupled with previous published compositional analyses show that volcanic products of Paniri vary from 57% (basaltic-andesite) to 71% (rhyolite) vol. SiO2, with significant linear correlations between major element-oxide and trace-element concentrations. 87Sr/86Sr isotope ratios range from 0.7070 to 0.7075, indicating that Paniri, similar to other volcanoes of the San Pedro – Linzor volcanic chain, have undergone significant crustal contamination of its parental magmas. However, the almost constant Sr-isotope compositions of the different volcanic units defined for Paniri volcano, suggested later fractional crystallization of magmas at upper crustal levels.

Alteration mineralogy, mineral chemistry and stable isotope geochemistry of the Eocene pillow lavas from the Trabzon area, NE Turkey

The Eocene subaqueous volcanic units in NE Turkey developed as pillow, closely packed pillow, isolated pillow, pillow breccia, hyaloclastite breccia and rare peperitic facies with red micritic limestones. They are locally set on volcaniclastic sandstone and claystone alternations and gradually pass to tuffs and volcanic breccias. The pillow lava samples generally exhibit intersertal, intergranular, microlitic porphyritic, variolitic, vesicular and glomeroporphyritic and glassy textures with clinopyroxene (Wo47-52En40-45Fs6-8), plagioclase (An10 to An96), olivine (Fo79-87) and Fe-Ti oxides (Usp0-0.27). Saponite, interlayered chlorite/saponite, rare beidellite and calcite were determined after olivine, rarely after plagioclase as well as in the glassy groundmass. Illite was restricted to plagioclase and the glassy groundmass. Na-Ca zeolites, chlorites/saponites, beidellite, dolomite and calcite occur as void infillings and in the glassy groundmass. Mineralogical, lithochemical and isotopic interpretations as well as thermometric calculations reveal a low-temperature seawater alteration in a semi-closed environment for the alteration of primary minerals and volcanic glass in addition to sealed vesicles and open systems for crosscutting veins. Due to the short exposure time intervals of seawater to rocks, the total chemistry of the rocks is not fully changed and most of the elements seem to be immobile, remaining in the system as a result of precipitation in voids and cracks. Thermometric estimations indicate that, the temperature of heated seawater is approximately 160 °C at the highest point especially in the vesicles, and decreases to approximately 85 °C due to circulation, resulting in alterations of the primary phases and volcanic glass.

Petrographic Characterization of the Different Types of Basalts of Harrat Al Fatih, Ablah Area, West Central Arabian Shield, Saudi Arabia

Harrat Al Fatih is located southwest of Ablah area, Assir terrain, southwestern Arabian Shield. It is present as black laterally extended horizontal basaltic sheet just overlying folded strata of the volcano-sedimentary succession of Ablah Formation (green mudstones, dolostones and green and red volcaniclastic red beds). These basalts are rift-related and represent part of the Oligo-Miocene basic volcanics of the western part of Saudi Arabia. The detailed field and microscopic description of these basalts enable the author to classify it into two main types: 1) Grey tuffaceous glassy basalts that present overlying the Ablah Formation. This basalt type is generally soft, bedded and intercalated with grey, green and red tuffaceous mudstones. Microscopically it composed of minute lath-like plagioclase and pyroxene crystals embedded in glassy groundmass. 2) Black olivine-rich basalts which are present in the topmost part of harrat Al Fatih are generally black, hard and contain remarkable reddish brown oxidized olivine spots and some calcite and amorphous quartz domains. Under the microscope, this basalt type is microcrystalline and composed mainly of lamellar twined Ca-plagioclase and colored olivines and pyroxenes. The olivines show different stages of oxidation and formation of amorphous blood red iron-oxyhydroxides and black hematite. The present study revealed the formation of the grey basalts at the initial stages of the volcanic eruption in ephemeral lakes and the second type of basalt was during the consolidation of proper basic magmas at the final stages of the volcanic eruption.

Sintered Mono-Cordierite Mg2Al4−xBxSi5O18 Glass-Ceramic with B/Al Replacement at the Nano- and Micro-Scale

Sintered glass-ceramics based on cordierite modified glass with partial substitution of aluminum by boron [(Mg2Al4−xBxSi5O18 (x = 1 and 3)] were prepared mainly from natural raw materials. Mono-mineralic cordierite was formed at all the sintering temperatures. The results of infrared spectra confirmed the cordierite presence. The microcrystalline structure shows scattered hexagonal cordierite crystals, either at the micro- or nano-scale, in a glassy groundmass. The microanalysis of the hexagonal crystals indicated the incorporation of some elements in the cordierite structure. The density of the sintered samples was 2.0857 and 1.4857 g/cm 3 and the coefficient of thermal expansion, from room temperature up to 500 ∘C, was in the range from 10.46 and 25.60 × 10−7∘C−1. The microhardness value was 5.64 GPa and 5.90 GPa.