In France, high-level nuclear wastes are confined in glass using a calcination-vitrification process. The waste can also be vitrified by liquid feeding, which imply to add directly the liquid waste. In this study, we focus on nuclear waste vitrification process by direct liquid feeding in order to decipher the dissolution kinetics of the waste in the molten glass. We propose an experimental and analytical protocol to study the dissolution in the solid glass frit of the liquid waste dried beforehand during the glass melting process. This methodology allows to: i) identify the intermediate reaction phases which formed and dissolved during the process; ii) characterizes the evolution of waste element concentrations in the dried waste as a function of time and temperature on glass obtained after cooling; iii) define kinetic parameters relative to the process of intermediate reaction phases dissolution in the molten glass. The three main intermediate reaction phases formed and dissolved in function of temperature are Ca-REE (Rare Earth Elements)- silicate, Ce- oxide and Zr- oxide. At each temperature step (800 to 1200 °C) the evolution of REE (La, Ce, Nd and Pr) and Zr concentrations in the glass samples obtained after cooling shows a fast increase followed by a stabilization in time, which reflects the fast dissolution of the dried waste in the molten glass, i.e. the fast dissolution of intermediate reaction phases. The molten glass is completely homogeneous at classical synthesis temperature (1200 °C). A parameterization methodology of element concentration evolution as a function of time and temperature is proposed here in order to define the kinetic parameters corresponding to the dried waste dissolution (i.e. concentration at a given time t, maximal concentration at a given temperature, characteristic time and activation energy). The results show that the activation related to the formation and dissolution processes of the intermediate reaction phases, i.e. whether they constitute intermediate compounds formed in temperature by the interaction between the dried waste and the glass frit, and the phases formed without reacting with the glass frit, directly in the dried waste during heat treatment.