Glass Fragments Research Articles

Distribution of bone fragments in angled shots: an experimental study conducted on composite models containing artificial bone plates.

In conventional gunshot injuries to targets containing bone the resulting osseous fragments do not precede but follow the bullet on its further way through adjacent soft tissues. The term "secondary projectiles" for the particles does not appear to be appropriate since they are not believed to have enough energy necessary for creating their own wound channels away from the temporary cavity. Former studies have shown that in angled shots to glass panes the bulk of splinters does not follow the bullet's trajectory: The majority of the glass fragments, especially the larger ones, move at right angles to the pane shot through. The aim of the presented study was to examine whether osseous fragments behave like glass splinters in angled shots to flat synthetic bone. In this context, it should also be assessed, whether the bone fragments might act as secondary projectiles in rare cases. To answer these questions, test shots were fired to composite models consisting of flat synthetic bone and ballistic gelatin. Pistol cartridges 9mm Luger were used to fire the shots which were video-documented with a high-speed camera. Afterwards, the composite models underwent CT examination and macroscopic inspection. Video-documentation revealed that the larger bone particles from the perforation site move at a roughly right angle from the osseous sheet into the gelatin, causing an eccentric bulge of the temporary cavity. The smaller bone fragments were also lodged along the bullet's path, predominantly in the cracks radiating from the permanent wound channel.

Window Glass of a Medieval Church at the Village of Veseloye Near Adler

Frequent finds from the excavations of a Christian church of the late 9th–11th century AD at the village of Veseloye (Greater Sochi) include fragments of unpainted and coloured window glass made by blowing in the disks shape, mostly, of 18 cm diameter. By the design of their edges, discs are divided into two types – one with a loop-shaped edge and one with a slightly thickened straight or slightly raised edge, and by the type of surface – smooth ones and those decorated with relief “optical” decor. A review of finds of medieval window glass over a wide area shows that finds from the Veseloye church fit into this array typologically and chronologically, which can be explained by the common technology of manufacturing this highly demanded glass product. In further research, it will be necessary to find out where window glass was produced for the churches of medieval Abkhazia and the Greater Sochi region.

Rescuing the knee: arthroscopic extraction of a long-neglected glass fragment: a case report

The knee joint frequently encounters penetrating injuries and has ample space to harbor foreign objects. While foreign bodies in the knee joint are unusual, especially those not originating from surgical procedures, extensive literature exists on the extraction of loose bodies and metallic objects from this articulation. However, documentation on uncommon intruders remains scarce. This case study delves into the experience of a 22-year-old male who suffered persistent pain due to a neglected foreign object in his knee joint. After its removal, a complete resolution of symptoms was achieved. It highlights the importance of prompt arthroscopic intervention for optimal outcomes. Here we present a unique case involving a 22-year-old male who underwent arthroscopic retrieval of a neglected glass fragment from his knee joint. The patient sought medical attention five months after the initial injury due to sudden and severe pain onset. Arthroscopy stands as the favored minimally invasive method for extracting foreign bodies from the knee joint, especially from its deeper and less accessible regions. Utilizing pre-operative radiological imaging enhances understanding of the anatomical placement, facilitates surgical orientation, and reduces operation time. A keen sense of suspicion and thorough history-taking are crucial in achieving an accurate diagnosis.

Compositional and textural evidences of Na-bentonite authigenesis in the Pellegrini lake deposit (Neuquen basin, Argentina)

Textural and compositional variations of Na-bentonites from the Pellegrini Lake deposit (Neuquén Basin) have been established, with special emphasis on petrographic features in order to better understand the genetic pathways in their formation. In this region, two bentonite beds named “white bentonite” and “green bentonite” are mined mainly for the oil and foundry industries. The genesis of these beds was studied using petrological (petrography, SEM and TEM), mineralogical (DRX, FT-IR, DTA-TGA, 27Al MAS NMR) and geochemical (ICP-AES) data from two quarries named COR and CA. The bentonites mainly consist of Na-montmorillonite, with lesser amounts of quartz, plagioclase, potassium feldspar, illite, zeolite, barite and gypsum. Mineralogical and petrographical evidence indicates that the authigenic smectite was formed by devitrification of unstable glass shards in a shallow coastal marine environment. Green bentonite would be the result of several episodes of volcanic ash-fall input from multiple eruptions with a higher degree of alteration uppermost in the bed. In this case, the alteration would have occurred in a reducing environment as evidenced by the greenish colouration of these bentonites, the Ce anomaly and the presence of pyrite. Meanwhile, white bentonite would have formed in a less restricted environment than green bentonite, as evidenced by the existence of intercalations of silt-sized grains and a higher amount of detrital grains in the clay groundmass transported probably by fresher waters. The presence of celestine, barite, halite and gypsum indicates evaporitic conditions after smectite formation. The observed secondary gypsum and iron staining of surfaces are much later processes. Green bentonite samples indicate a trachyandesite composition of the parent material, while the white bentonite suggests a parent material most related to a rhyodacite/dacite composition showing that the characteristics of the volcanism might have changed with time.

Numerical simulation of anti-shatter films (ASF) for mechanical post-breakage analysis of retrofitted glass

Post-breakage strength and residual mechanical capacity improvements are important tasks for load-bearing structural components in general, and even more for glass elements, in order to protect people from injury in case of breakage. For this reason, among others, the design of glass components and structures is based on key concepts that are generally summarized in structural safety, robustness and redundancy. With regard to the last fundamental requirement, nowadays the use of laminated glass (LG) sections is spread for many applications and new projects, such as automotive or aircraft windshields, but especially curtain walls and many other load-bearing applications in buildings. This strategy derives from the intrinsic safety and security levels of LG sections after possible glass breakage. When LGs are not available (i.e., existing components), anti-shatter safety films (ASF) for the retrofit of monolithic glass elements are expected to provide very similar post-breakage structural performances against bending and impact actions, by reducing the possible spread of glass shards. Besides, the residual load-bearing capacity of glass components retrofitted by ASF is still challenging to quantify. In this paper, the Cohesive Zone Model (CZM) theory is considered to investigate, with the support of experiments and Finite Element (FE) numerical models, the performance of small-scale monolithic glass specimens retrofitted by ASF under bending loads. Different ageing procedures and imposed displacement-rates are considered to evaluate the influence of basic operational parameters, such as temperature and humidity, on the mechanical efficiency of common ASF layers. In doing so, the sensitivity of fundamental input parameters (i.e., maximum tensile strength of glass and fracture energy of the ASF adhesive) on the mechanical performance at pre- and post-breakage stages of retrofitted monolithic glass elements is explored.

Major Holocene cryptotephras layers identified from Jeju Island, Republic of Korea: Implications for regional volcanic eruptions and environmental changes

Cryptotephras recorded in sediments are valuable isochrons with which to reconstruct volcanic eruptive history and synchronize environmental changes across large regions. Here we identify four cryptotephras from Jeju Island, Republic of Korea, that constitute tie-points linking palaeoenvironmental records of tropical to mid-latitude east Asia. A cryptotephra of unknown source with trachytic glass compositions at around 2700 cal a BP (named M263a) can be correlated with the HGY263 recorded in the Huguangyan Maar lake in southern China, and SG14–0433 recorded in Suigetsu lake in central Japan. Another population of glass shards with basaltic andesitic to trachybasaltic composition (named M263b) represents the first cryptotephra record of a Jeju eruption. A rhyolitic cryptotephra at ∼7384 cal a BP (H53) can be correlated with the ∼7.3 ka Kikai-Akahoya eruption (specifically, the K-Ah tephra) from Kikai caldera, southern Kyushu, Japan. The cryptotephra coincides with a marked change in aquatic algae communities in Jeju sediments, possibly signifying a climate response to the eruption. Additionally, cryptotephra layers at ∼6948 cal a BP (H22) in the Hanon Maar Lake and ∼ 1030 cal a BP (M125) in Mulyoungari wetland exhibit similar glass compositions to those of the K-Ah tephra, which suggests they are the product of unknown eruptions from Kikai or a neighboring volcano. Given the widespread distributions of K-Ah and M263a tephra across east Asia, Jeju sediments can be precisely synchronized with those high-resolution sediments from southern China and Japan, providing two Holocene marker horizons for palaeoenvironmental comparisons across east Asia. Our work shows great promise for the improved chronological constraints and inter-site linkages for palaeoenvironmental sequences in the region through the application of tephrochronology.

First detection in Australia of cryptotephra likely to be derived from the 25.6 ka Ōruanui supereruption in New Zealand

Cryptotephra subsampling techniques were used to identify a high concentration (c. 700 shards/g) of glass shards within the Yellow Marsh sediments in northwest Tasmania, Australia. Radiocarbon dating from the overlying sediments coupled with geochemical analysis of the glass shards indicate their similarity to the Kawakawa-Ōruanui Tephra (KOT), derived from the Ōruanui supereruption of 25,568 ± 232 cal yr BP (±2sd) from the Taupō Volcanic Zone, New Zealand. Although cryptotephra from this eruption has previously been identified in Antarctica and modelled to have been transported over parts of southern and eastern Australia, to date glass shards from this eruption have not been identified in Australia. If the correlation of the cryptotephra to the Ōruanui supereruption is correct, this finding has the potential to allow Last Glacial deposits in the SW Pacific (including those in Australia, New Zealand and Antarctica) to be irrefutably linked.

Status of needle-related injuries among nursing students at Hanoi Medical University, campus in Thanh Hoa province, in 2024

Objective: Describe the current situation of sharp object injuries among nursing students at Hanoi Medical University, campus in Thanh Hoa in 2024. Subjects and methods: A cross-sectional descriptive study was conducted involving 168 regular nursing students in their 2nd, 3rd, and 4th years. Results: Among 168 nursing students who practiced at the hospital, 117 had experienced injuries from sharp objects such as needles and glass shards, accounting for 69.6%. The majority of these injuries were among female students, accounting for 88.8%. In the past six months, the total number of sharp object injuries among the 117 students was 348, with an average of 2.1 injuries per student. Third-year students had a higher average number of injuries at 2.8 times per 6 months. The highest occurrence of sharp object injuries during clinical internships was during the day 70.1% and at night 29.9%. Most injuries occurred on daytime 81%, while weekends and holidays had a lower rate 19%. The most common activity causing injuries was breaking ampoules 45.4%, followed by administering injections 21.1%. Hands were the most commonly injured body part 87.9%. Among the students who experienced sharp object injuries: 62.6% treated their wounds correctly, 33.3% treated their wounds incorrectly and 4.1% did not treat their wounds at all. Conclusion: The proportion of nursing students who had been injured by sharp objects was 69.6%. Keywords: Sharp objects, injury, nursing students, clinical practice

Numerical and experimental blast response of multilayer laminated glass panels

Laminated glass is used in high-security buildings to mitigate the effects of blasts and ballistic loadings. The multi-layered composition of the laminated glass (LG) panels allows the glass panes to crack and undergo large deflections while preventing glass shards from spalling by mostly remaining attached to the polymeric interlayer. To characterize multilayer LG panels under blast loading, it is essential to develop their static resistance response under uniform loading. A full-scale water chamber was used to experimentally evaluate the quasistatic response to the failure of the multilayer LG panel systems under uniform pressure. The influence of different polymeric interlayer types on the response of multilayer LG panels was studied. Also, the glass breakage patterns and deflections exhibited by various multilayer glass configurations were investigated. The response of LG panels under blast was developed using ANSYS AUTODYN, which was verified using field experiments. LG panels with an Ethylene Vinyl Acetate (EVA) polymeric interlayer experienced the most dynamic deflections, whereas LG panels with an ionoplast SentryGlas® (SG) polymeric interlayer displayed the least dynamic deflections. The results indicated that multilayer LG systems provide higher blast resistance compared to double-layer systems; the additional layers can help reduce glass breakage and maintain structural integrity. Multilayer LG system’s SG interlayer enhanced blast protection by allowing load transfer and ensuring uniform load distribution between glass layers.

Radiography Ó? An effective method of detecting glass shards in wounds

Radiography Ó? An effective method of detecting glass shards in wounds

Contamination of consumer composts by metals, microplastics and other microscopic debris.

Very little information exists on the particle and chemical contamination of consumer (horticultural) composts. In this study, anthropogenic microcellulosics (AMCs), microplastics (MPs) and other microscopic debris, along with anthropogenically impacted metals (Cu, Zn, Pb), have been determined in 12 composts (seven garden composts and five growbags) purchased at outlets in the UK. AMCs and MPs, determined microscopically, were present in all samples at up to about 1100kg-1 dw. AMCs were more abundant and were dominated by fibres constructed of rayon and cotton, while petroleum-based MPs exhibited a greater diversity in shape and polymeric construction (including polyolefins, polyethylene terephthalate, polyvinyl chloride, resins, paints and rubbers). Other microdebris, present in much smaller concentrations in the composts, consisted of fragments of glass, metal and machined wood and spherical glass beads. Concentrations of the anthropogenically impacted metals, Cu, Pb and Zn, determined directly by energy-dispersive X-ray fluorescence spectrometry, were heterogeneously distributed and averaged 52.4, 192 and 51.6mgkg-1 dw, respectively. Although concentrations of anthropogenic particles were not related to cost or type of compost, physico-chemical properties or metal concentrations, a significant relationship between Pb content and particle diversity (number of polymers and debris types) was established. This relationship might result from the general contamination of the environment by both Pb and anthropogenic particulates, or the association of the metal with various types of material (e.g. paints, polyvinyl chloride, glass). Despite the ubiquity and diversity of MPs and microdebris in consumer composts, an understanding of their impacts on plant growth, either directly or indirectly (e.g. by interacting with metals), is unknown.

The glass from the arrabal of Arrixaca (Murcia, 12th-13th centuries)

This article presents an assemblage of 36 glass samples excavated in the urban site of San Esteban, part of the arrabal of Arrixaca (Murcia) (in al-Andalus, an arrabal was a relatively dense urbanised area outside the city walls) in contexts securely dated to the 12th and early 13th century, spanning the rule of Ibn Mardanīš, and the early period of Almohad domination in the city. The samples were analysed by electron microprobe (EMPA) for major and minor elements and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) for trace elements. The results are examined within the context of glass production, circulation, and consumption in al-Andalus and the Islamicate Mediterranean more broadly. The results show that some of the glasses found in San Esteban-Arrixaca may have been imported from other Islamicate regions (Egypt and Mesopotamia), but that the vast majority can be related to previously recognised compositional Iberian glass groups. At the same time, the identification of several fragments of production waste and raw glass suggest that some glass-working facility may have existed in the vicinity of San Esteban-Arrixaca. The compositional evidence also indicates that recycling (including of imported glass objects) may have been a fairly common practice in Andalusi glassmaking, but it is suggested that some of the usual chemical markers of recycling may, in the case of al-Andalus and perhaps also elsewhere in the medieval Mediterranean, be the result of the cross-breeding of glass- and glaze-making activities.

TRPV1 corneal neuralgia mutation: Enhanced pH response, bradykinin sensitization, and capsaicin desensitization

The factors that contribute to pain after nerve injury remain incompletely understood. Laser-assisted in situ keratomileusis (LASIK) and photorefractive keratectomy (PRK) are common surgical techniques to correct refractive errors. After LASIK or PRK, a subset of patients suffers intense and persistent pain, of unknown origin, described by patients as feeling like shards of glass in their eye. Here, we evaluated a TRPV1 variant, p.V527M, found in a 49-y-old woman who developed corneal pain after LASIK and subsequent PRK enhancement, reporting an Ocular Surface Disease Index score of 100. Using patch-clamp and Ca2+ imaging, we found that the V527M mutation enhances the response to acidic pH. Increasing proton concentration induced a stronger leftward shift in the activation curve of V527M compared to WT, resulting in channel activity of the mutant in acidic pH at more physiological membrane potentials. Finally, comparing the responses to consecutive applications of different agonists, we found in V527M channels a reduced capsaicin-induced desensitization and increased sensitization by the arachidonic acid metabolite 12-hydroxyeicosatetraenoic acid (12-HETE). We hypothesize that the increased response in V527M channels to protons and enhanced sensitization by 12-HETE, two inflammatory mediators released in the cornea after tissue damage, may contribute to the pathogenesis of corneal neuralgia after refractive surgery.

Integration of new zircon U–Pb ages with biostratigraphy to establish a high-precision age model of the Miocene Nakayama Formation on Sado Island in Central Japan

The most common age constraint for the diatomaceous sediments is biostratigraphy of siliceous microfossils. Although biostratigraphy is a powerful tool to establish stratigraphy and correlate with sedimentary sequences in other sites, biostratigraphy generally includes uncertainties difficult to evaluate. In this study, we measured zircon U–Pb ages of eight tuff beds intercalated with diatomaceous mudstone of the Nakayama Formation on Sado Island in Central Japan and integrated the U–Pb ages with diatom and radiolarian biostratigraphy, whose ages and errors were re-evaluated by this study, to establish an age model precisely representing the sedimentary age. Two tuff beds in the upper and middle part of the formation offered zircon U–Pb ages of 6.7 ± 0.2 Ma and 10.87 ± 0.07 Ma, which are consistent with biostratigraphy, and provided a good example of effective integration of zircon U–Pb ages with the biostratigraphy. On the other hand, zircon U–Pb ages of the other six tuff beds in the lower part are around 12 Ma and not distinguishable from each other. In addition, older zircon grains in the 6 tuff beds are assembled in the interval from 30 to 20 Ma, which is consistent with the age of the volcanic basement rocks forming most part of Sado Island. Similarities in chemical compositions of glass shards and age distributions of zircon grains indicate that the volcaniclastic components in the tuff beds should originate from single or associated magmatic activities.

Transparency at its best: neutrons probing archaeological glass finds from Romania

This paper demonstrates the suitability of Prompt Gamma Activation Analysis (PGAA) technique for the compositional study of ancient glass finds, illustrating this idea by presenting and commenting the chemical composition of 41 Roman glass fragments discovered in archaeological excavations at Tomis, Histria, and Beidaud, Romania. According to typological and stratigraphic criteria, most finds were dated to the 1st-4th centuries AD. The PGAA measurements were performed at the Budapest Neutron Centre (BNC), Hungary. Regardless of their color (or the lack of it), most of the analyzed vitreous items have compositional traits often encountered in coeval glass artefacts discovered at various sites all over the Roman Empire. The sample set turned out to include several examples of Foy Série 2.1 and a single HIMT glass item, in agreement with the later chronological attribution of the corresponding fragments. This study provides some information about the chemistry of the Roman glass finds unearthed during the archaeological research performed in the region of the western Black Sea coast.

Submarine cores record magma evolution toward a catastrophic eruption at Kikai Caldera

Magma evolution toward a caldera-forming eruption remains uncertain in many cases owing to the lack of successive volcanic records before catastrophic eruptions. Here we take an approach to this issue by analyzing a submarine core sampled near Kikai Caldera, southern Japan, which has recorded two caldera-forming eruptions at 95 and 7.3 ka and small eruptions between them. Discovery of mafic glass fragments in the submarine deposits of the 95-ka eruption, which had not been recognized in subaerial outcrops, implies the involvement of mafic magma in felsic magma-driven caldera-forming eruption. Inter-caldera volcanic activity resumed with binary mafic and felsic magma extrusions but then shifted to eruptions predominated by felsic magmas. In the final stage preceding the 7.3-ka caldera-forming eruption, the most felsic composition did not appear in glass fragments. We suggest that this period was the phase of felsic melt accumulation to grow a magma reservoir toward the next catastrophic eruption.

Detecting microfragments of glass in scar tissues

The identification of traumatic causes in the case of damage caused by sharp objects has always been one of the main issues of interest to the investigating authorities. Currently, forensic medicine allows for determining a specific acute traumatic object, including glass fragments. However, in the available literature, no information is available about the possibility of detecting microfragments of glass in the scar. Herein, the case of a man who suffered a chest wound is presented. The patient was brought to the hospital, where the wound was sutured. In the medical records, the wound was described as a stab wound and could have been caused by a knife. The accused categorically denied inflicting a knife wound on this person and argued that the victim was in a state of severe alcoholic intoxication and fell repeatedly, including on a sideboard, glass from which was found during an inspection of the scene. Four months later, the victim died from alcohol poisoning. A forensic medical examination was conducted to confirm the possibility of injury from glass fragments from the sideboard. A scar was identified on the victim’s chest. Microparticles were found in the scar tissue, and their characteristics led to the conclusion that they were microfragments of colorless, transparent glass. Determining the presence of glass microfragments in scar tissue does not require complex technical equipment and are common in wide expert practice; their use has confirmed the possibility of detecting glass microfragments not only in soft tissues along the wound channel but also in scar tissue after wound healing.

Chemical analysis of fragments of glass and ceramic ware from Tycho Brahe’s laboratory at Uraniborg on the island of Ven (Sweden)

In addition to his astronomical observations the famous Renaissance astronomer Tycho Brahe (1546–1601) was known also for his interest in alchemy. He equipped his castle Uraniborg on the island of Ven with a state-of-the-art alchemical laboratory when it was erected around 1580. After Brahe’s death Uraniborg was demolished upon a royal decree from 1601, a process which was completed around 1650. In the present study we have analysed four glass shards and one ceramic shard most likely from the alchemical laboratory and retrieved during an archaeological excavation in 1988–90. Cross sections of the shards have been analysed for 31 trace elements by Laser Ablation Inductively Coupled Plasma with Mass Spectrometry with the aim of detecting any traces of the chemical substances on the inside or outside of the shards used in the laboratory. Four of the elements found in excess on the exterior surfaces of the shards, Cu, Sb, Au, and Hg, are in accordance with the reconstructed recipes of the three Paracelsian medicines for which Brahe was famous—Medicamenta tria. This is the first experimental data casting light on the alchemical experiments that took place at Uraniborg 1580–1599.

Blast Wave Simulator for Laminated Glass Panels Experimental Evaluation

The study of blast loads on structures is important due to the potential of significant consequences in various scenarios. From terrorist attacks to industrial accidents, comprehending how structures respond to blast waves is critical for ensuring public safety and designing resilient structures. Studying these effects typically involves two main methods: free-field tests with live explosives and shock tube tests. Although shock tube testing offers certain advantages, both approaches are costly and demand significant space. This research aims to develop a cost-effective and straightforward technique for generating stress waves that closely replicate the progressive and spatial characteristics of free-field or shock tube blast waves. This method was designed to evaluate the dynamic response of laminated glass panels. The stress wave was generated by impacting a piston on the fluid inside a tube, which was connected to a fluid chamber. This setup produced impulsive loads that were distributed across a laminated glass test panel. Moreover, it was used to simulate the shock near filed explosions for a certain part of a structure. High-speed cameras were utilized to analyze the initial velocity of flying glass fragments. The apparatus successfully produced various blast waves and impulsive profiles for different drop weight heights. The initial velocities of randomly selected flying shards ranged from 3 m/s to 4 m/s.

Effect of in-line filtration in newborns: study protocol of the Intravenous Neonatal Central Access Safety (INCAS) randomized controlled trial

BackgroundParticulate contamination due to infusion therapy (administration of parenteral nutrition and medications) carries a potential health risk for infants in neonatal intensive care units (NICUs). This particulate consists of metals, drug crystals, glass fragments, or cotton fibers and can be generated by drug packaging, incomplete reconstitution, and chemical incompatibilities. In-line filters have been shown to remove micro-organisms, endotoxin, air, and particles in critically ill adults and older infants, but its benefits in newborn remain to be demonstrated. Moreover, 50% of inflammatory episodes in the setting of NICUs are blood culture-negative. These episodes could be partly related to the presence of particles in the infusion lines.MethodsA multicenter randomized single-blind controlled trial was designed. All infants admitted to NICUs for which prolonged infusion therapy is expected will be enrolled in the study and randomized to the Filter or Control arm. All patients will be monitored until discharge, and data will be analyzed according to a “full analysis set.” The primary outcome is the frequency of patients with at least one sepsis-like event, defined by any association of suspected sepsis symptoms with a level of c-reactive protein (CRP) > 5 mg/L in a negative-culture contest. The frequency of sepsis, phlebitis, luminal obstruction, and the duration of mechanical ventilation and of catheter days will be evaluated as secondary outcomes. The sample size was calculated at 368 patients per arm.DiscussionThis is the first multicenter randomized control trial that compares in-line filtration of parenteral nutrition and other intravenous drugs to infusion without filters. Sepsis-like events are commonly diagnosed in clinical practice and are more frequent than sepsis in a positive culture contest. The risk of these episodes in the target population is estimated at 30–35%, but this data is not confirmed in the literature. If the use of in-line filters results in a significant decrease in sepsis-like events and/or in any other complications, the use of in-line filters in all intravenous administration systems may be recommended in NICUs.Trial registrationClinicalTrials.gov, NCT05537389, registered on 12 September 2022 (https://classic.clinicaltrials.gov/ct2/show/results/NCT05537389?view=results).