Glacial Deposits Research Articles

Chronology of Late Pleistocene glacial advances in a Mount Mercedario catchment, Subtropical Andes of Argentina (32° S)

ABSTRACTGlacial fluctuations leave distinct imprints on the landscapes of mountain environments, such as moraines and outwash terraces, that allow the reconstruction of past environmental changes. Unraveling the environmental history of the valleys of the Subtropical Andes of Argentina poses challenges due to the complex interplay of various surficial processes driven by both climatic and tectonic forces, which affects the preservation of glacial deposits. Consequently, there are few studies on past glaciations in this region compared to the rest of the Andes. This study focused on the lower section of the Blanco River Basin and the piedmont of the Frontal Cordillera in the south of San Juan Province, Argentina. A comprehensive geomorphological map of glacial landforms was created, along with sedimentological studies of outwash terraces. Additionally, numerical ages were obtained for both landforms using terrestrial cosmogenic nuclides for moraine boulders and luminescence dating for sandy layers in the outwash terraces. Our findings reveal at least two glacial advances since the Last Glacial Maximum (LGM), each associated with distinct outwash levels. The Río Blanco Advance occurred during the LGM, and the Laguna Advance is assigned to the late stages of the LGM, both with their corresponding outwash terraces. Additionally, the Amarillo Advance is believed to have occurred during the Holocene period and an older Marine Istope Stage 5 d named Guanaquito Advance. The provided data add valuable numerical information about glacial fluctuations since the LGM and also reveal the impact of glacial downwasting on piedmont landforms.

Chemical succession of naphthenic acid fraction compounds in reclamation landscape mesocosms established on centrifuged and co-mixed fluid fine tailings from the Athabasca oil sands

The Athabasca oil sands region of Alberta, Canada contains one of the world's largest unconventional petroleum deposits. There is concern about residual contaminants where tailings are integrated during reclamation and the related adverse effects this may have. Some of the primary toxic organic contaminants in oilsands tailings are naphthenic acid fraction compounds (NAFCs). To plan for successful reclamation, it is imperative to understand the behaviour and fate of tailings-derived NAFCs over time where these are re-integrated into landforms. In this companion article to Degenhardt et al. (2023), we examine different reclamation integration scenarios using oil sands process-affected materials (OSPMs) at laboratory scale using wetland plants and minimal amounts of caps to explore how cap materials and thickness will affect the of NAFCs in the systems. Specifically, we examine how capping materials and thicknesses affect NAFCs adsorbed to two treated fluid fine tailings, centrifuged (CF) and co-mixed (CM) tailings over three years. Both CF and CM were placed in columns capped with peat mineral mix (PMM) and/or glacial till and planted with graminoid or woody wetland plants. Both CF and CM had considerable NAFC concentrations (CF 3717 mg/kg, CM 321 mg/kg). The O2 NAFC class was >90 % of the total adsorbed to CF and CM throughout. Relatively thin PMM caps reduced NAFC burdens in CF columns, where 10 cm of PMM resulted in the greatest reduction. Expressed water from substrate self-weight consolidation had significantly lower NAFC concentrations when capping material was present. However, NAFC oxidation (i.e., O2 to O3, O3 to O4, etc.) was limited in capped CF and CM. These results indicate that capping CF and CM with a thin (5–10 cm) layer of PMM may help reduce NAFC concentrations and limit their mobility into the cap, potentially lowering plant mortality and improving tailings reclamation success rates.

Volcanically induced glacier collapses in southern Jan Mayen (Sør‐Jan), Norway

Jan Mayen is a small volcanic island situated in the Norwegian–Greenland Sea. The entire island was covered by a contiguous ice cap during the Last Glacial Maximum. The deglaciation of the ice cap was interrupted by a glacier advance in the southern part of the island in the Early Holocene. Today, there are no glaciers in this area, and until now it has been unknown whether any glaciers survived there into the Middle–Late Holocene. We show here that glaciers existed at several sites in the mountain areas of southern Jan Mayen. The investigations were triggered by the discovery of a relict glacier completely covered by tephra and impacted by a lava flow. Samples of ice from the glacier have 18O values that are isotopically indistinguishable from modern precipitation values and fall along the local meteoric water line trend. The lava flow in the glacier catchment and sculpted forms along the base of dry meltwater channels in bedrock show that glacier melting was abrupt and marked by sudden meltwater outbursts (jökulhlaups). Three more sites in southern Jan Mayen have meltwater channels with sculpted beds, gorges and/or sediments associated with lava flows and can be attributed to jökulhlaups caused by rapidly melting glaciers. Radiocarbon dates associated with glacial outwash sediments, cosmogenic dates of meltwater channel incisions, and cosmogenic and K‐Ar dates of lava flows associated with former periods of rapid glacier melting show that the four glaciers collapsed at different times in the Holocene. None of the glaciers reformed after their collapses despite subsequent cooling event(s). Likely, the glaciers were on the brink of existence before their sudden demise.

Hematite U-Pb dating of Snowball Earth meltwater events

The Snowball Earth hypothesis predicts global ice cover; however, previous descriptions of Cryogenian (720-635 Ma) glacial deposits are limited to continental margins and shallow marine basins. The Tavakaiv (Tava) sandstone injectites and ridges in Colorado, USA, preserve a rare terrestrial record of Cryogenian low-latitude glaciation. Injectites, ridges, and chemically weathered crystalline rock display features characteristic of fluidization and pervasive deformation in a subglacial environment due to glacial loading, fluid overpressure, and repeated sand injection during meltwater events. In situ hematite U-Pb geochronology on hematite-quartz veins, which crosscut and are cut by Tava dikes, constrain sand injection at ~690-660 Ma. We attribute early Tava sand injection episodes to basal melting associated with rifting and geothermal heating, and later injections to meltwater generation during ~661 Ma Sturtian deglaciation. A modern analog is provided by the Ross Embayment of Antarctica, where rift-related faults border sediment-filled basins, overpressurized fluids circulate in confined aquifers below ice, and extensive preglacial topography is preserved. Field evidence and geochronology in Colorado further highlight that deep chemical weathering of Proterozoic bedrock and denudation associated with the Great Unconformity predate Cryogenian injection of fluidized sand, consistent with limited glacial erosion.

Controls on regional sulphate distribution in shallow groundwater in the western Canadian Interior Plains

Sulphate (SO4), predominantly derived from sulphur (S)-bearing glacial sediments distributed widely across the Canadian Interior Plains, contributes to high groundwater salinity and can be detrimental to riparian and dry-land ecosystems, agricultural production, and water use. While previous researchers investigated SO4 distribution and dynamics in shallow groundwater at local scales (<1500 km2), we examine SO4 occurrence in groundwater at larger scales, and to depths of ∼150 m, considering variations in geology, glacial history, climate, and geochemical and hydrogeological settings in the Canadian province of Alberta. Sulphate concentrations in groundwater vary considerably, with 15 % of 139,130 samples above the 500 mg/L Canadian drinking water aesthetic objective. Analysis of δ34SSO4 and δ18OSO4 from 179 wells throughout Alberta shows SO4 is dominantly derived from oxidation of S-bearing material. At this large scale, marine shale bedrock subcrops, glacial ice flow directions, and climate control SO4 distribution. Groundwater contains less SO4 (<200 mg/L) in western Alberta compared to the east due to a lack of S-bearing bedrock, higher groundwater recharge rates, thinner glacial sediments, and increased groundwater circulation. Focusing on a region in south-central Alberta (Red Deer area), hydrogeological characteristics relating to SO4 formation, recharge, permeability, hydraulic gradient, and travel time are included in a principal component analysis to identify six groundwater groups at varying stages of evolution and SO4 concentrations depending on their hydrogeological setting. Low SO4 concentrations are associated with areas of high recharge, where SO4 has been leached from the sediments, or with more evolved bedrock groundwater where SO4 has been reduced or was recharged in pre-glacial times. High SO4 concentrations are found in areas of lower recharge and permeability, where flushing occurs more slowly. Combining the Red Deer area and province-wide analyses, we identify seven regions across Alberta with characteristic distribution and controls on SO4 occurrence in shallow groundwater.

Uranium-series isotopes as tracers of physical and chemical weathering in glacial sediments from Taylor Valley, Antarctica

The McMurdo Dry Valleys of Antarctica formed by extensive glacial erosion, yet currently exhibit hyperarid polar conditions canonically associated with limited chemical and physical weathering. Efficient chemical weathering occurs when moisture is available, and polythermal subglacial conditions may accommodate ongoing mechanical weathering and valley incision. Taylor Valley, one of the MDV, hosts several Pleistocene glacial drift deposits that record prior expansions of Taylor Glacier and sediment redistribution, if not sediment production. We present U-series isotopics of fine-grained sediments from these drifts to assess the timescales of physical weathering and subsequent chemical alteration. The isotopes 238U, 234U, and 230Th are sensitive to both chemical and physical fractionation processes in sedimentary systems, including the physical fractionation of daughter isotopes by energetic recoil following radioactive decay. By comparing U-series isotopic measurements with models of U-series response to chemical weathering and physical fractionation processes, we show that Pleistocene drift sediments record histories of significant chemical alteration. However, fine-grained sediments entrained in the basal ice of Taylor Glacier record only minor chemical alteration and U-series fractionation, indicating comparatively recent sediment comminution and active incision of upper Taylor Valley by Taylor Glacier over the Pleistocene. In addition, the results of this study emphasize the utility of U-series isotopes as tracers of chemical and physical weathering in sedimentary and pedogenic systems, with particular sensitivity to radionuclide implantation by α-recoil from high-U authigenic phases into lower-U detrital phases. This process has occurred extensively in >200 ka drifts but to a lesser degree in younger deposits. U-series α-recoil implantation is an important physicochemical process with chronometric implications in other hyperarid and saline sedimentary systems, including analogous Martian environments.

Proglacial sediments in High Arctic glacier foreland: A case study of Werenskioldbreen, Svalbard

The glacier environment exhibits a high sensitivity to global climate change, leading to progressive deglaciation and the exposure of previously ice-covered land. The newly exposed terrain provides a valuable opportunity to observe rapid ecosystem changes, such as the accumulation of glacial sediments, the development of soil-forming and progressive alterations in water and biogeochemical cycles. While developing hydrological and hydrogeological models for the Werenskioldbreen proglacial expanding zone, we encountered a significant problem due to insufficient data for parameterizing glacial sediments, which constitute the environment for water flow and storage. This study provides detailed insight into the physicochemical parameters of glacial sediments and classifies them in terms of grain size distribution, hydraulic conductivity, pH and the content of carbon (Corg), nitrogen (Nt) and phosphorus (Pt). We found that the marginal outwash plains of Werenskioldbreen are characterised by gravelly sand, sandy gravel and silty sand (28.6%, 23.8% and 19% of the total sample contents, respectively). The lateral moraine contains sandy clayey silt, silty sandy gravel or sandy gravelly silt (7.1%, 4.8% and 2.4 % of the total sample contents, respectively). The chemical parameters of young glaciofluvial sediments have lower values than those of moraines. Corg ranged from 0.07% to 2.70%. Nt was &amp;lt; 1.00 g kg−1 for 95% of the samples and &amp;lt; 0.5 g kg−1 for 81% of them. Pt was between 0.48 and 1.18 g kg−1. In line with the studies on this subject already published, we confirm that there is clear a relationship between the type of geomorphological form, its age, and the physicochemical parameters of glacial sediments.

Deglaciation in the subtropical Andes has led to a peak in sediment delivery

Glaciers are thinning and retreating as climate warms, thus eroding less of the Earth’s surface. However, other hydrological factors in glacierized catchments are likely producing a transient increase in sediment delivery, resulting in ‘peak sediment’. Estimating the trajectory of the peak sediment is ecologically and socially important but scientifically challenging because of the delayed and non-linear response of glacier sediment export to climate forcing. This study used time series of suspended sediment concentration starting in the 1960s from 11 Andean rivers at subtropical latitudes to analyse past changes in sediment export and infer its future behaviour. The recent decade has experienced anomalously high sediment concentration in most glacierized catchments, but the 1970s experienced even higher values. Decadal variations in the relationship between sediment concentration and ice melt suggest that the magnitude of the current decade was lower due to reduced glacial sediment rather than other factors. Combining this result with the fact that glacial runoff is decreasing, it is inferred that, for most of the glacierized catchments, the peak sediment generated by the anthropogenic deglaciation started two centuries ago has already passed its maximum.

Rb-Sr isochron method of sediment source fingerprinting reveals a fundamental shift in erosion in response to anthropogenic land use

Human alterations to landscapes can greatly influence watershed-scale sedimentary processes; therefore, in this study, we test the viability of a novel Rb-Sr isotope and elemental geochemical method for fingerprinting the impacts of human land use on sediment provenance. We analyzed a ∼1200-year sediment core record from Little Kennebago Lake, Maine, USA, that captures negligible anthropogenic activity pre-1900 CE, timber transport downstream during log drives (1900−1952 CE), and increased road construction and timber harvest (1952−2018 CE). 87Sr/86Sr data alone reveal several spikes, likely due to storm events, and variability but no systematic shift at the onset of logging. The pre-logging record Rb-Sr isotope data comprise an isochron corresponding to an age of 354 ± 16 Ma (two standard errors [2SE]; mean square of weighted deviates [MSWD] = 2.1, n = 33). None of the bedrock or glacial till sources that we analyzed fall along the pre-logging isochron, nor did any binary or ternary bulk rock mixtures. However, the linearity of all pre-logging samples and coincidence of the isochron age with Acadian metamorphism in the region suggests that sediment was derived from a single source in the undisturbed watershed, though that exact bedrock or glacial till source remains unclear. The onset of logging coincides with a shift toward generally lower sediment Rb-Sr isotope ratios that are offset from the pre-logging isochron. This logging data forms a scattered pseudo-isochron with an apparent Carboniferous age of 322 ± 32 Ma (2SE; MSWD = 4.5, n = 10). No rocks of this age exist in the region. Therefore, we interpret this age to have no geologic meaning and instead reflect the introduction of new sediment sources due to logging. Logging also coincides with subtle changes in elemental geochemistry. The Big Island Pond Pluton underlies most of the northern part of the watershed and is the only catchment lithology capable of producing each geochemical change; therefore, we conclude that it was the primary new source of sediment introduced by logging. We found little variation in sediment geochemistry between the period of early log drives and later road expansion, suggesting that sediment provenance was constant once altered by the initial onset of logging, which could reflect the same source being tapped by activities in each period. We established a framework for interpreting bulk sediment Rb-Sr isotope ratios and demonstrated their viability for identifying shifts in human impacts on geomorphic processes. Our findings suggest that relative changes in sediment Rb-Sr isotope ratios are a promising tool for investigating changes to sedimentary processes not identifiable by other commonly used fingerprints and that the method should be further tested in a range of other natural and anthropogenic settings globally.

Constraining the origin of the Norwegian strandflat – The influence of isostatic and dynamic surface changes

The Norwegian strandflat is a prominent low-relief bedrock surface found near sea level along most of the west coast of Norway. Its origin has been discussed throughout the last 130 years but is yet to be resolved. Some studies suggest that the strandflat represent a tropical weathering front of Mesozoic age that has since been buried and re-exhumed, while others relate its origin to Pleistocene periglacial and glacial processes and/or wave-induced weathering and erosion. Previous interpretations of the strandflat have considered postglacial isostatic uplift, but the impacts of isostatic changes due to glacial erosion and deposition, as well as dynamic surface changes driven by mantle convection, have been largely overlooked. Here we examine how geomorphological-driven isostatic changes and dynamic surface changes have influenced the land-surface elevation along the Norwegian coast during late Pliocene-Quaternary (the last ca. 3 million years). We employ quantitative estimates of glacial erosion and deposition to assess the flexural isostatic response from the resulting load changes. Our analyses show that patterns of geomorphic isostatic adjustments and dynamic surface changes are generally not reflected in the present elevation of the strandflat. Only the loading effect from the deposition of the North Sea Fan can clearly be correlated with the submerged strandflat found near Stad (∼62 °N). Our results imply that if the strandflat formed synchronously along the Norwegian coast as a flat surface at sea level, the strandflat we observe today must have developed after the majority of late Pliocene-Quaternary glacial erosion took place, but prior to the main deposition of the North Sea Fan. This would place strandflat formation within the last few glacial cycles, but before the Last Glacial Maximum (LGM). This inferred pre-LGM age of the strandflat is generally consistent with cosmogenic nuclide exposure ages and observed striations on the strandflat. Finally, we examine ice cover and land-surface changes relative to sea level during the last 80,000 years and find no extended periods favorable for synchronous strandflat formation across all regions along the Norwegian coast. This implies that either the strandflat is diachronous, or that the processes of formation have either been extremely fast under certain conditions or are independent of sea level, for instance related to glacial erosion.

Quantifying Pleistocene loess provenance in midcontinental North America using a mixing model: Implications for glacial lobe evolution along the southern Laurentide ice sheet

Quaternary glaciations have significantly impacted the midcontinental North American landscape, leaving behind a proglacial sediment record of glacial lake deposits, glacio-fluvial sand and gravel, and windblown loess. This paper aims to expand upon a previous study using detrital zircon provenance analysis to investigate midcontinental North American loess provenance in relation to the glacial history of the southern Laurentide ice sheet during the middle to late Pleistocene. The study incorporates previously published detrital zircon data from last glacial tills (representing the Huron-Erie Lobe, Lake Michigan Lobe, Green Bay Lobe, Superior Lobe, Des Moines Lobe, and James Lobe), middle to late Pleistocene loess from several sites along the Illinois and Mississippi River valleys, and suspended sediment load inputs from the Missouri River and Arkansas River. A statistical mixing model (DzMix version 2.2) was used to estimate the relative proportions of glacial and nonglacial sources to Wisconsin Episode, Illinois Episode, and pre–Illinois Episode age loess. We show that mixing models that include the modern suspended sediment loads of the Missouri and Arkansas Rivers significantly improve (up to 23% increase in cross-correlation value) the source characterization of Wisconsin Episode (last glacial) and Illinois Episode (penultimate glacial) loess deposits within the Mississippi River drainage basin. These river sources are dominant inputs for certain loess sites (as much as 51%), but their relative contributions are not static across time and space, which has implications for temporal and spatial differences in relative sediment source estimates and glacial and fluvial sediment transport evolution. Specifically, differences in relative sediment proportion estimates among Wisconsin, Illinois, and pre–Illinois Episode loess support previous evidence for the persistence of a Quebec-Labrador ice dome source through multiple glacial cycles, even with the inclusion of river sources in updated mixing models. Illinois and pre–Illinois Episode loess in the southern portion of our study area received ~20% detrital zircon input from sources similar to the present-day Missouri and Arkansas Rivers, suggesting that these river systems were contributing a significant amount of detritus to the lower Mississippi River valley region during the middle Pleistocene.

Geochronology and ice‐flow modelling of the Late Quaternary glaciers on Mt. Soğanlı, Türkiye

ABSTRACTUnderstanding Earth's climate history through the chronology and reconstruction of palaeoglaciers is a central topic of palaeoclimatology. Examining the remnants of past glaciations preserved in isolated alpine environments provides insight into critical palaeoclimatic conditions. Accurate dating techniques, such as terrestrial cosmogenic nuclides, are crucial for understanding the timing of these changes. The Anatolian Peninsula, characterized by diverse topographical and climatic factors, witnessed the presence of glaciers during the Late Pleistocene, shaping its alpine landscape significantly. While mountain ranges such as the Taurus and Pontic favoured glacier development due to their elevation and lower temperatures, isolated mountains such as Mount Soğanlı in the interior hinterland also supported significant palaeoglaciers. Despite previous studies on Anatolia's glaciers, numerical dating of glacial deposits on Mount Soğanlı has remained elusive until now, hindering precise palaeoclimatic interpretations. This study employs cosmogenic 36Cl surface exposure dating and physical‐based ice‐flow modelling using an open‐source framework, Parallel Ice Sheet Model (PISM), to determine the timing of glaciations and to reconstruct past glacier extents on Mount Soğanlı. The results reveal glacier retreat ages of 48.3 ± 13.4 and 18.3 ± 4.4 ka based on two well‐preserved moraines. Additionally, palaeoclimate simulations matched with the field observations indicate considerably colder conditions (6.65–8.15°C colder than today) necessary to sustain glaciers on Mount Soğanlı, when precipitation amounts were the same as today. These findings contribute to a better understanding of Anatolia's palaeoclimatic fluctuations and align with similar studies in neighbouring regions, enhancing our knowledge of past climate dynamics of the Eastern Mediterranean and the Middle East.

Glacier Retreat Induces Contrasting Shifts in Bacterial Biodiversity Patterns in Glacial Lake Water and Sediment

Glacial lake ecosystems are experiencing rapid changes due to accelerated glacier retreat. As glaciers recede, their influence on downstream habitats diminishes, potentially affecting the biodiversity of glacial lake microbial communities. However, there remains a knowledge gap regarding how bacterial biodiversity patterns in glacial lakes are altered by diminishing glacial influence. Here, we investigated shifts in bacterial communities in paired water and sediment samples collected from seven glacial lakes on the Tibetan Plateau, using a space-for-time substitution approach to understand the consequences of glacier retreat. Our findings reveal that bacterial diversity in lake water increases significantly with a higher glacier index (GI), whereas sediment bacterial diversity exhibits a negative correlation with GI. Both the water and sediment bacterial communities display significant structural shifts along the GI gradient. Notably, reduced glacial influence decreases the complexity of bacterial co-occurrence networks in lake water but enhances the network complexity in sediment. This divergence in diversity and co-occurrence patterns highlights that water and sediment bacterial communities respond differently to changes in glacial influence in these lake ecosystems. This study provides insights into how diminishing glacial influence impacts the bacterial biodiversity in glacial lake water and sediments, revealing contrasting patterns between the two habitats. These findings emphasize the need for comprehensive monitoring to understand the implications of glacier retreat on these fragile ecosystems.

A comprehensive crosshole seismic experiment in glacial sediments at the ICDP DOVE site in the Tannwald Basin

Abstract. Glaciers have shaped the Alpine landscape by carving deep valleys and depositing sediments to form overdeepened basins. Understanding these processes provides information on the evolution of the climate and landscape. One such overdeepened structure is the Tannwald Basin (ICDP site 5068_1) north of Lake Constance, which was formed by the Rhine Glacier in several glacial cycles. In order to study these sediments and their seismic properties down to about 160 m depth, we conducted seismic crosshole experiments between three boreholes, obtaining compressional (P) wave data. The P-wave data are generated by a sparker source and recorded by a 24-station hydrophone string. We present the data acquisition and review our approach for future optimization, suggesting a finer time sampling interval and a separate registration of borehole and surface receivers. Travel-time tomography of the P-wave first-arrival picks under geostatistical constraints yields initial subsurface models. The tomograms correlate well with cased-hole sonic logs and the lithology derived from the core of one of the boreholes. These results will be further investigated in future research, which will include full-waveform inversion (FWI) to obtain high-resolution subsurface models.

Radiogenic Strontium‐ and Uranium‐Isotope Tracers of Water‐Rock Interactions and Hydrothermal Flow in the Upper Geyser Basin, Yellowstone Plateau Volcanic Field, USA

AbstractNatural radiogenic isotopes (primarily 87Sr/86Sr) from hot springs in the Upper Geyser Basin of the Yellowstone Plateau volcanic field and associated rocks were used to evaluate groundwater flow patterns, water‐rock reactions, and the extent of mixing between various groundwater sources. Thermal waters have very low uranium concentrations and 234U/238U activity ratios near 1.0, which limit their utility as tracers in this reducing setting. Thermal waters have higher Sr concentrations (&lt;22 ng/g) and a wide range of 87Sr/86Sr values that vary both temporally at individual discharge sites and between adjacent springs, indicating that conduits tap different subsurface reservoirs to varying degrees. Sr from local rhyolites have 87Sr/86Sr compositions that bound the range of values observed in groundwater throughout the basin. Non‐boiling springs on the west flank of the basin discharge water with low 87Sr/86Sr consistent with flow through young volcanic rocks exposed at the surface. Boiling springs in the central basin have higher 87Sr/86Sr values reflecting interactions with older, more radiogenic volcanic rocks. Variability in upwelling thermal waters requires mixing with a low 87Sr/86Sr component derived from young lava or glacial sediments, or more likely, from deeper sources of hot groundwater circulating through buried Lava Creek Tuff having intermediate 87Sr/86Sr. Isotope data constrain basin‐wide output of thermal water to 110–140 kg·s−1. Results underscore the utility of radiogenic Sr isotopes as valuable tracers of hydrothermal flow patterns and improve the understanding of temperature‐dependent water‐rock reactions in one of the largest continental hydrothermal systems on Earth.

First detection in Australia of cryptotephra likely to be derived from the 25.6 ka Ōruanui supereruption in New Zealand

Cryptotephra subsampling techniques were used to identify a high concentration (c. 700 shards/g) of glass shards within the Yellow Marsh sediments in northwest Tasmania, Australia. Radiocarbon dating from the overlying sediments coupled with geochemical analysis of the glass shards indicate their similarity to the Kawakawa-Ōruanui Tephra (KOT), derived from the Ōruanui supereruption of 25,568 ± 232 cal yr BP (±2sd) from the Taupō Volcanic Zone, New Zealand. Although cryptotephra from this eruption has previously been identified in Antarctica and modelled to have been transported over parts of southern and eastern Australia, to date glass shards from this eruption have not been identified in Australia. If the correlation of the cryptotephra to the Ōruanui supereruption is correct, this finding has the potential to allow Last Glacial deposits in the SW Pacific (including those in Australia, New Zealand and Antarctica) to be irrefutably linked.

Statistical characteristics of aquitard hydraulic conductivity, specific storage and porosity

Aquitard hydraulic conductivity (K), specific storage (Ss) and porosity (ϕ) are critical to the modeling of flow and mass and heat transport in groundwater systems, yet comprehensive insights into their statistical characteristics remain limited. This study compiles 456 K values from 47 studies, 202 Ss values from 49 studies and 239 ϕ values from 18 studies, followed by rigorous statistical analysis of aquitard K, Ss and ϕ with dependence on the features of test method, lithology and burial depth. Additionally, the interrelationships among K, Ss and ϕ are analyzed. A predictive model for aquitard K and Ss is developed utilizing the random forest (RF) approach. The statistical findings unearth that laboratory experiments tend to yield lower K while higher Ss, particularly when burial depths are less than 50 m. Clay, silt clay, and glacial till exhibit comparable K values, in contrast to significantly lower K values observed in shale formations. Aquitard K, Ss, and ϕ exhibit depth-decaying characteristics. Between two adjacent depth intervals, 0 – 50 m, 50 – 150 m and >150 m, there is nearly an order of magnitude difference in either K or Ss. Aquitard K tends to increase with ϕ when ϕ is below 0.25 and decreases vice versa. This phenomenon is probably attributed to the significant amount of immobile-bound water adhering to clayey particles within the aquitard with a high ϕ value, which reduces the pore space available for water flow. Elastic Ss, which indicates recoverable aquitard groundwater depletion, is about one order of magnitude lower than inelastic Ss, which indicates permanent aquitard groundwater depletion, implying that the majority of groundwater depletion from aquitards under long-term groundwater exploitation is non-recoverable. The RF-based predictive model indicates that ϕ is a highly important feature for predicting K and outperforms lithology, test method and burial depth in predicting Ss. The statistical findings of this study present a valuable basis for aquitard hydraulic parameters.

Dendrochemical Analysis as a Method to Identify Mineralized Zones: Insights from the Marathon Cu-PGE Deposit

The Marathon Cu-platinum-group element (PGE) deposit is located within the Eastern Gabbro Series of the Proterozoic Coldwell Alkalic Complex, 10 km north of Marathon, Ontario. The Cu-PGE mineralization occurs within the Two Duck Lake Gabbro, an olivine gabbro intrusion. This geochemical orientation study tested the trace element analysis of tree cores as a method of identifying mineralized versus background areas in the Marathon deposit, focusing on copper (Cu), sulfur (S), palladium (Pd), and silver (Ag). Tree core samples (n=25) were collected with an increment borer from black spruce (Picea mariana) trees and dated by counting growth rings. Fifteen cores, 12 near/overtop the deposit and three distal control samples, were analysed with Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) over a 10-year interval (1992-2002). Data normalization to 88Sr like in other dendrochemical studies corrected for tree health and growth effects. 32S, 63Cu, and 105Pd were found to have the highest concentrations at 94.198, 2.224, and 0.055 ppm, respectively, in control sample 23KPA2-3004. This tree is located beside the Pic River and receives large amounts of run-off from the entire Eastern Gabbro Series, possibly enhancing the chemical composition of the tree core. Excluding this anomalous sample, significant concentrations of Cu and Ag were found moving SSW along the deposit, aligning with the direction of movement of the Pleistocene Laurentide Ice Sheet. While this study did not clearly identify mineralized zones in the Marathon deposit, it has identified the possibility of mineralized run-off in the Pic River affecting nearshore tree chemical composition. The influence of local terrain and glacial till must be also considered when using this method. Future research will continue to study the factors influencing the uptake of elements in trees and refine methods for detecting mineralization through tree core analysis.

Deep Electrical Resistivity Tomography for Detecting Gravitational Morpho-Structures in the Becca France Area (Aosta Valley, NW Italy)

Deep-seated gravitational slope deformations (DSGSDs) consist of gravity-induced, large-scale, gradual rock mass movements. In the Aosta Valley region (Valle d’Aosta NW Italy), DSGDs affect wide valley slopes and produce several interconnected morpho-structures that involve bedrock and Quaternary cover. Some DSGSD effects are not visible at the surface because of subglacial abrasion or burial by sediments and, therefore, are difficult to map with standard geomorphological surveys. This is the case for the Pointe Leysser DSGSD in the Aosta Valley, which is heavily influenced by the historical movements of the Verrogne-Clusellaz Glacier and its tributaries. We conducted a new geological investigation, integrated with deep electrical resistivity tomography geophysical surveys (ERTs). The ERT results were initially compared with geological/geomorphological evidence at the surface to define the correlation between the values and spatial distributions of electrical resistivity and the sediments, rocks, or morpho-structures. The resistivity values at various depths were subsequently analysed, interpreted, and discussed in conjunction with geological hypotheses. The geological and geophysical survey revealed three wide buried glacial valleys filled with glacial sediments and mapped the locations of gravitational morpho-structures at depth. These new data allowed us to draw a relationship between glacialism and gravitational evolution, distinguishing between pre-singlacial movements and postglacial movements.

Soil Carbon and Nitrogen Stocks Across Hillslopes Underlain by Continuous Permafrost in the Northern Arctic Foothills, Alaska, United States

ABSTRACTConstraining the variability of soil organic carbon (SOC) and total nitrogen (TN) stocks across hillslopes in Low Arctic permafrost‐affected landscapes remains a significant challenge for improving global estimates of permafrost SOC stocks. We investigated SOC and TN stocks across hillslopes at two sites in the Arctic Foothills of Alaska, United States (Happy Valley and Sagwon Hills). Average SOC and TN stocks for the 0–1‐m depth interval were high (52.0 ± 15.1 kg C m−2 and 2.74 ± 0.82 kg N m−2) and linearly related (R2 = 0.74, p &lt; 0.0001). Unlike soils of other permafrost and nonpermafrost landscapes, variability was greatest within rather than between hillslope positions. Furthermore, SOC and TN stocks in the surface 1 m did not exhibit strong patterns by hillslope position and were only weakly associated with major geomorphic parameters that typically predict SOC and TN stocks well in other landscapes. Although sampling at upper hillslope positions was largely limited to depths of less than 1.5 m due to the presence of coarse fragments in reworked glacial till, deeper observations at lower hillslope positions (footslopes, toeslopes, and basins) revealed significantly larger SOC stocks (92.0 ± 18.0 kg C m−2 at 2 m; 117.1 ± 10.4 kg C m−2 at 3 m). The unique small‐scale variability in ice content, cryoturbation, patterned ground, and organic layer thickness on these broad, Low Arctic sites contributes to the relatively homogeneous distribution of SOC and TN stocks across hillslope positions in the top 1 m, but a future focus on deeper sampling may reveal greater differences in SOC and TN stocks.