Accurate recognition of the concentration state of neodymium-oxide (Nd2O3) in the neodymium (Nd) molten salt electrolysis process provides crucial feedback information for online adjustment of process parameters during Nd metal batch production. This paper proposes a Nd2O3 concentration state recognition model based on flame image features. The model employs the lightweight flame segmentation algorithm (FEC-Net) to accurately segment the flame regions in the collected Nd electrolysis cell flame images. Then, using image processing techniques, geometric and color features of the flame regions are extracted. Finally, a Support Vector Machine (SVM) is used to establish a nonlinear mapping model between the flame features and Nd2O3 concentration states. This model classifies the collected flame image dataset to verify the Nd2O3 concentration state during a certain period of Nd molten salt electrolysis. Experiments demonstrate that the recognition accuracy of SVM reaches 96.09%, meeting the monitoring requirements of the Nd molten salt electrolysis process.