Dynamic breakthrough curves with roll-up, stepwise, and saddle-shaped structures have been commonly observed in the adsorption/separation process, but could be rarely described by the descriptive model, which limits further analysis and explanation of the breakthrough data. In this work, two new descriptive models, including a general polynomial logistic equation (GPLE) and a general polynomial Gompertz equation (GPGE) are developed to correlate these roll-up, stepwise, and saddle-shaped breakthrough curves. Their correlation coefficients (R2) between the descriptive model and breakthrough data are higher than 0.95, indicating the good applicability of the two descriptive models. Taking some difficult-to-fit literature data as an example, by adjusting these characteristic parameters, six types of breakthrough curves can be fitted by the GPLE or GPGE model. Representatively, satisfying N=2.0, a1≠a2 or b1≠b2, CN<0 or CN<1.0 (∑1NCN=1.0), various roll-up or stepwise breakthrough curves could be fitted accurately. If N=3.0, the GPGE model could explain the multiple roll-up, the multiple stepwise, and the saddle-shaped breakthrough curves. As a result, two new descriptive models can be easily used by workers in various fields to analyze and calculate breakthrough data. Although some reasonable physical explanations need to be explored in the future, they will provide a modeling basis for studying multi-component dynamic adsorption behavior.