With recent progress of observational astronomy, the next generation of space telescopes (JWST, ARIEL, OST, HabEx, LUVOIR) will be able to determine the composition of exoplanetary atmospheres in the next decades. The discovery of rocky exoplanets, as potentially favorable harbors for life, finds a particularly strong echo in the scientific community and in the general audience. The interaction of the surface of a planetary body with its atmosphere is key to understanding the composition of the latter and hence to determine whether the planet may host life or not. In an effort to describe surface–atmosphere interactions on rocky planets and the heterogeneous reactions occurring on solid surfaces, in particular mineral dust grains, in such systems it is necessary to develop a systematic approach to this family of reactions. Such an approach is proposed in this Perspective on three very distinct examples of rocky planets: Earth, Mars, and Venus. These bodies have experienced very different evolutions, although they likely started from similar initial conditions; the pressure and temperature of their atmospheres cover a broad range of values, offering an invaluable set of planet-size laboratories to study the impact of physical and chemical parameters on the evolution of atmospheres. Systems that should be investigated in priority with relevance for Earth, Mars, and Venus are discussed. It is shown that a better knowledge of mineral dust supporting heterogeneous reactivity is crucial and that the impact of environmental parameters on these reactions needs to be carefully investigated. Current and future missions to Mars and Venus will require such work to better model and understand the observations. In particular, a strong effort is needed to study Venus, which has only few dedicated laboratory setups although it will be the target of exploration missions in the next decades. These studies will pave the way to build robust models of exoplanetary atmospheres, which will be crucial to account for the observations of their composition by space telescopes in the near future.