Efficient Generation Research Articles

Nonreciprocal magnetoacoustic waves with out-of-plane phononic angular momenta.

Surface acoustic wave (SAW) can carry phononic angular momentum, showing great potential as an energy-efficient way to control magnetism. Still, out-of-plane phononic angular momentum in SAW and its interaction with magnetism remain elusive. Here, we studied the SAW-induced magnetoacoustic waves and spin pumping in Ni-based films on LiNbO3 with selected SAW propagation direction. The crystal inversion asymmetry induces circularly polarized phonons with large out-of-plane angular momenta so that up to 60% of the SAW power attenuates nonreciprocally controlled by the out-of-plane magnetization component. The SAW propagation direction dependence of the nonreciprocity verifies the crystal origin of the phononic angular momentum, and a chiral spin pumping demonstrates that the circular polarization can control the spin current generation efficiency. These results provide an additional degree of freedom for the acoustic control of magnetism and open an avenue for applying circularly polarized phonons.

Efficient generation of a stable CHO-K1 cell line overexpressing the human water channel aquaporin-5 as tool to generate therapeutic antibodies

Aquaporins (AQPs) are a family of water permeable channels expressed on the plasma membrane with AQP5 being the major channel expressed in several human tissues including salivary and lacrimal glands. Anti-AQP5 autoantibodies have been observed in patients with Sjögren’s syndrome who are characterised by dryness of both salivary and lacrimal glands, and they have been implicated in the underlying mechanisms of glandular dysfunction. AQP5 is formed by six transmembrane helices linked with three extracellular and two intracellular loops. Develop antibodies against membrane protein extracellular loops can be a challenge due to the difficulty in maintaining these proteins as recombinant in their native form. Therefore, in this work we aimed to generate an efficient stable-transfected cell line overexpressing human AQP5 (CHO-K1/AQP5) to perform primarily cell-based phage display biopanning experiments to develop new potential recombinant antibodies targeting AQP5. We also showed that the new CHO-K1/AQP5 cell line can be used to study molecular mechanisms of AQP5 sub-cellular trafficking making these cells a useful tool for functional studies.

Electron-Withdrawing Substituents Enhance the Type I PDT and NIR-II Fluorescence of BODIPY J Aggregates for Bioimaging and Cancer Therapy.

Organic dyes with simultaneously boosted near-infrared-II (NIR-II) fluorescence, type I photodynamic therapy (PDT), and photothermal therapy (PTT) in the aggregate state are still elusive due to the unclear structure-function relationship. Herein, electron-withdrawing substituents are introduced at the 5-indolyl positions of BODIPY dyes to form tight J-aggregates for enhanced NIR-II fluorescence and type I PDT/PTT. The introduction of an electron-rich julolidine group at the meso position and an electron-withdrawing substituent (-F) at the indolyl moiety can enhance intermolecular charge transfer and the hydrogen bonding effect, contributing to the efficient generation of superoxide radicals in the aggregate state. The nanoparticles of BDP-F exhibit NIR-II fluorescence at 1000 nm, good superoxide radical generation ability, and a high photothermal conversion efficiency (50.9%), which enabled NIR-II fluorescence-guided vasculature/tumor imaging and additive PDT/PTT. This work provides a strategy for constructing phototheranostic agents with enhanced NIR-II fluorescence and type I PDT/PTT for broad biomedical applications.

A smooth method for primary frequency of wind turbine based on variable power point tracking and energy storage cooperative control

AbstractThe conventional deloading control has certain problems, such as low power generation efficiency and a small speed adjustment range. To improve the system's frequency quality and enhance the power grid's stability, this study comprehensively considers the effect of random source‐load power fluctuations on the system frequency. Moreover, this study proposes a smooth primary frequency control strategy for wind turbine based on the coordinated control of the variable power point tracking and supercapacitor energy storage. The impact of wind power fluctuations on the system frequency at different timescales for wind turbine is studied based on the historical data of wind power fluctuations in a strong wind meteorological cycle of a wind farm. The method determines the capacity of the energy storage device required for frequency smoothing at the optimal timescale. In combination with the required capacity of the wind turbine to participate in the system's primary frequency regulation, the supercapacitor energy storage device is optimally configured, and a set of supercapacitor energy storage device with the lowest cost under the highest charging/discharging efficiency is designed. Simulation and experimental results show that the primary frequency adjustment capability of the control strategy proposed in this study is significantly improved compared with the conventional primary frequency modulation control.

Enhancing photocatalytic hydrogen production in conjugated porous polymers through donor-π-donor fragment insertion

Recent progress in conjugated polymer photocatalysts has opened avenues for enhancing photocatalytic hydrogen production (PHP) activity through structural design. This study highlights the impact of the acceptor-to-donor feed ratio on PHP activity in copolymers, influencing their energy level structures. Five conjugated porous polymers (CPPs) were synthesized by adjusting the acceptor-to-donor molar ratio. Notably, at a 2:1 acceptor-to-donor ratio, the polymer demonstrated a high hydrogen evolution rate (HER) of 61.9 mmol g−1 h−1 under full arc irradiation without co-catalysts and an apparent quantum yield (AQY) of 7.77% at 475 nm. However, further increasing the proportion of the donor unit in the copolymers decreases their HER. Experiments and theoretical simulation characterized that the feed ratios effectively tune the polymer's molecular structure, hydrophilicity, band gap, and the generation and transport efficiency of photo-induced charge carriers, ultimately affecting the hydrogen production kinetics and efficiency. This research demonstrates that tuning the band structure and chemical compositions of CPPs through statistical copolymerization significantly impacts their PHP activity.

Highly Efficient Ultraviolet Third-Harmonic Generation in an Isolated Thin Si Meta-Structure.

Nonlinear nanophotonic devices have shown great potential for on-chip information processing, quantum source, 3D microfabrication, greatly promoting the developments of integrated optics, quantum science, nanoscience and technologies, etc. To promote the applications of nonlinear nanodevices, improving the nonlinear efficiency, expanding the spectra region of nonlinear response and reducing device thickness are three key issues. Herein, this study focuses on the nonlinear effect of third-harmonic generation (THG), and present a thin Si meta-sructure to improve the THG efficiency in the ultraviolet (UV)region. The measured THG efficiency is up to 10-5 at an emission wavelength of 309nm. Also, the THG nanosystem is only 100nm in thickness, which is two-five times thinner than previous all-dielectric nanosystems applied in THG studies. These findings not only present a powerful thin meta-structure with highly efficient THG emission in UV region, but also provide a constructive avenue for further understanding the light-matter interactions at subwavelength scales, guiding the design and fabricating of advanced photonic devices in future.

Donor-acceptor bulk-heterojunction sensitizer for efficient solid-state infrared-to-visible photon up-conversion.

Solid-state infrared-to-visible photon up-conversion is important for spectral-tailoring applications. However, existing up-conversion systems not only suffer from low efficiencies and a need for high excitation intensity, but also exhibit a limited selection of materials and complex fabrication processes. Herein, we propose a sensitizer with a bulk-heterojunction structure, comprising both an energy donor and an energy acceptor, for triplet-triplet annihilation up-conversion devices. The up-conversion occurs through charge separation at the donor-acceptor interface, followed by the formation of charge transfer state between the energy donor and annihilator following the spin statistics. The bulk-heterojunction sensitizer ensures efficient charge generation and low charge recombination. Hence, we achieve a highly efficient solid-state up-conversion device with 2.20% efficiency and low excitation intensity (10 mW cm-2) through a one-step solution method. We also demonstrate bright up-conversion devices on highly-flexible large-area substrates. This study introduces a simple and scalable platform strategy for fabricating efficient up-conversion devices.

Experimental Investigation Of The Flow-Acoustic Interaction In Human Phonation

In the human phonation process, acoustic standing waves in the vocal tract can influence the fluid flow through the glottis. To investigate the amount of two-way coupling between the flow field and the acoustics, the supraglottal flow field has been recorded via high-speed particle image velocimetry (PIV) in a synthetic larynx model for several configurations with different vocal tract lengths. Based on the obtained velocity fields, aeroacoustic source terms were computed. Furthermore, the hydrodynamic pressure in the vocal tract was recorded via wall pressure measurements. The recordings revealed that near a vocal tract resonance frequency, the focal fold oscillation frequency jumps onto the resonance. This is accompanied by a substantial relative increase in aeroacoustic sound generation efficiency. At the same time, the glottal volume flow needed for stable vocal fold oscillation decreases strongly. The pressure measurements showed that acoustic anti-resonances of the vocal tract directly dampen the harmonic content of the hydrodynamic pressure field when matching frequencies. This result shows that back-coupling of the acoustics onto the flow field does not only occur in the case where the vocal fold oscillation frequency and a resonance frequency of the vocal tract match, but also under more other conditions.

Low-voltage ride-through strategy for an integrated permanent magnet synchronous generator in a flexible interconnected distribution network

For the permanent magnet synchronous generator (PMSG) integrated into the flexible interconnected distribution network (FIDN), its low-voltage ride-through (LVRT) strategy needs to be designed to enhance the transient operation capability of the FIDN. The design of the LVRT strategy also needs to take the fault location of the FIDN into consideration. To deal with faults occurring on the integrated feeder of the PMSG, the PMSG needs to realize successful LVRT using the hardware protection equipment. To deal with faults occurring on the feeder adjacent to the integrated feeder of the PMSG, the PMSG needs to release its stored energy to temporarily increase its active power output, which is then supplied to the loads on the faulted feeder that are isolated from the fault through the soft open point (SOP). In this paper, a novel LVRT strategy designed for the PMSG integrated into the FIDN is proposed, which includes dual operation modes that are separately applied to different fault locations. If PMSG is on the faulted feeder, the DC-link voltage of the PMSG is maintained with the controllable resistive fault current limiter (CRFCL), while the maximized stored kinetic energy is reserved to enhance the generation efficiency during the LVRT. If PMSG is on the feeder adjacent to the faulted feeder, the control strategy of the converters of the PMSG is adjusted in response to the power regulation goal at the SOP. Meanwhile, the maximum releasable kinetic energy of the PMSG is considered when increasing its active power output. The feasibility and effectiveness of the LVRT strategy for the PMSG are verified based on the numerical analysis.

Supragel-mediated efficient generation of pancreatic progenitor clusters and functional glucose-responsive islet-like clusters

Although several synthetic hydrogels with defined stiffness have been developed to facilitate the proliferation and maintenance of human pluripotent stem cells (hPSCs), the influence of biochemical cues in lineage-specific differentiation and functional cluster formation has been rarely reported. Here, we present the application of Supragel, a supramolecular hydrogel formed by synthesized biotinylated peptides, for islet-like cluster differentiation. We observed that Supragel, with a peptide concentration of 5 mg/mL promoted spontaneous hPSCs formation into uniform clusters, which is mainly attributable to a supporting stiffness of ∼1.5 kPa as provided by the Supragel matrix. Supragel was also found to interact with the hPSCs and facilitate endodermal and subsequent insulin-secreting cell differentiation, partially through its components: the sequences of RGD and YIGSR that interacts with cell membrane molecules of integrin receptor. Compared to Matrigel and suspension culturing conditions, more efficient differentiation of the hPSCs was also observed at the stages 3 and 4, as well as the final stage toward generation of insulin-secreting cells. This could be explained by 1) suitable average size of the hPSCs clusters cultured on Supragel; 2) appropriate level of cell adhesive sites provided by Supragel during differentiation. It is worth noting that the Supragel culture system was more tolerance in terms of the initial seeding densities and less demanding, since a standard static cell culture condition was sufficient for the entire differentiation process. Our observations demonstrate a positive role of Supragel for hPSCs differentiation into islet-like cells, with additional potential in facilitating germ layer differentiation.

Effects of Nozzle Configuration on Efficiency of Direct-Contact Gas-Vapor Mixture Generators

Effects of Nozzle Configuration on Efficiency of Direct-Contact Gas-Vapor Mixture Generators

Efficient Poling‐Free Wavelength Conversion in Thin Film Lithium Niobate Harnessing Bound States in the Continuum

AbstractOver the past two decades, there has been a surge of interest in photonic integrated circuits (PICs) to enable low‐cost industrial mass manufacture of miniaturized optical systems while simultaneously improving performance and energy efficiency following the trajectory of electronics and large‐scale integration. An essential characteristic of any PIC lies in the ability of waveguides to efficiently confine light. The phenomenon of bound states in the continuum (BIC) shows promise in achieving confinement of light for modes that otherwise would suffer from high leakage losses, which can occur in many PIC platforms. In this contribution, the usefulness of operating near a BIC to achieve efficient second harmonic generation of ≈300% W−1 cm−2 in Silicon Nitride (SiN) loaded lithium niobate on insulator (LNOI) waveguides without needing to either pole or etch the lithium niobate is experimentally demonstrated. The guided fundamental mode is phase matched at the telecom wavelength to a higher order mode at the second harmonic wavelength that is engineered as a bound state in the continuum to mitigate leakage losses. This demonstrates the promise of using BIC in weakly confining waveguides for nonlinear optical applications all while avoiding the poling process by engineering waveguide geometry.

Optimal Oxophilicity at the Fe-Nx Interface Enhances the Generation of Singlet Oxygen for Efficient Fenton-Like Catalysis.

In the pursuit of efficient singlet oxygen generation in Fenton-like catalysis, the utilization of single-atom catalysts (SACs) emerges as a highly desired strategy. Here, a discovery is reported that the single-atom Fe coordinated with five N-atoms on N-doped porous carbon, denoted as Fe-N5/NC, outperform its counterparts, those coordinated with four (Fe-N4/NC) or six N-atoms (Fe-N6/NC), as well as state-of-the-art SACs comprising other transition metals. Thus, Fe-N5/NC exhibits exceptional efficacy in activating peroxymonosulfate for the degradation of organic pollutants. The coordination number of N-atoms can be readily adjusted by pyrolysis of pre-assembly structures consisting of Fe3+ and various isomers of phenylenediamine. Fe-N5/NC displayed outstanding tolerance to environmental disturbances and minimal iron leaching when incorporated into a membrane reactor. A mechanistic study reveals that the axial ligand N reduces the contribution of Fe-3d orbitals in LUMO and increases the LUMO energy of Fe-N5/NC. This, in turn, reduces the oxophilicity of the Fe center, promoting the reactivity of *OO intermediate-a pivotal step for yielding singlet oxygen and the rate-determining step. These findings unveil the significance of manipulating the oxophilicity of metal atoms in single-atom catalysis and highlight the potential to augment Fenton-like catalysis performance using Fe-SACs.

Fuzzy logic-based estimation model of distribution transformers aging

Currently, we are moving towards more ecological modes of transport. As a result, the demand for electric vehicles is growing exponentially, and new loads, related to charging, can negatively affect the operation of electrical grids and their elements. Concurrent and uncontrolled charging of electric vehicles can cause a blackout. Considering the stochastic nature of the additional load from electric cars, it is difficult to predict such a load by analytical methods. The fuzzy logic approach can be used to formalize the tasks with ambiguity. In this paper, a fuzzy-based block diagram of the algorithm was developed in the MATLAB-Simulink environment for evaluating the impact of the charging load of electric vehicles on the aging of transformers, as well as a model was built and the effect of various penetrations of electric cars was evaluated. The fuzzy logic-based model includes the effects of ambient temperature, power quality, and overloads. It contains a diagnostic part that warns the dispatcher of the power distribution network about possible problems, providing up-to-date information about the state of the transformer. In addition, the efficiency of photovoltaic generators to increase the service life of distribution transformers was analyzed. The results show that photovoltaic power plants are not effective enough for high levels of electric vehicle penetration, and more advanced strategies should be used.

A S-scheme 0D/2D heterojunction formed by decorating Cd0.5Zn0.5S nanoparticles on Cu2MoS4 plates for efficient photocatalytic hydrogen generation

Rationally designing a Step-scheme (S-scheme) hetero-structured photocatalyst with high redox capability and separation efficiency of photoinduced carriers is considered as an attractive approach to address the shortcomings of single component and traditional hetero-structured photocatalyst. Herein, enlightened by the predictions of density functional theory (DFT), a unique S-scheme heterojunction photocatalyst was successfully fabricated by incorporating zero-dimensional (0D) Cd0.5Zn0.5S (CZS) on two-dimensional (2D) lamellar Cu2MoS4 (CMS) plates via a facile coprecipitation method, which substantially enhances the photocatalytic activity for hydrogen (H2) generation. CZS nanoparticles deposited on the surface of CMS nanoplates play a crucial role in creating highly intimate heterojunction interfaces and abundant exposed reaction sites, laying the foundation for improved photocatalytic performance. Furthermore, the significant difference in Fermi levels and band structures between CZS and CMS result in the formation of the internal electric field (IEF) and energy band bending at the interface of the heterojunction. This S-scheme charge transfer path enables 0D/2D CZS/CMS heterojunction possesses an exceptional capacity to maintain the robust redox potential and boosts the separation efficiency of light-induced carriers, as verified by DFT calculations and energy band structure analyses. As expected, the optimal heterojunction exhibits a satisfactory H2 generation rate of 13.1 mmol·g-1·h−1, which is nearly 7.7-fold higher than that of individual CZS. This study is expected to inspire the design of morphology-controlled hetero-structured photocatalyst with S-scheme charge transfer route for photocatalytic H2 generation.

A S-scheme 0D/2D heterojunction formed by decorating Cd0.5Zn0.5S nanoparticles on Cu2MoS4 plates for efficient photocatalytic hydrogen generation

Rationally designing a Step-scheme (S-scheme) hetero-structured photocatalyst with high redox capability and separation efficiency of photoinduced carriers is considered as an attractive approach to address the shortcomings of single component and traditional hetero-structured photocatalyst. Herein, enlightened by the predictions of density functional theory (DFT), a unique S-scheme heterojunction photocatalyst was successfully fabricated by incorporating zero-dimensional (0D) Cd0.5Zn0.5S (CZS) on two-dimensional (2D) lamellar Cu2MoS4 (CMS) plates via a facile coprecipitation method, which substantially enhances the photocatalytic activity for hydrogen (H2) generation. CZS nanoparticles deposited on the surface of CMS nanoplates play a crucial role in creating highly intimate heterojunction interfaces and abundant exposed reaction sites, laying the foundation for improved photocatalytic performance. Furthermore, the significant difference in Fermi levels and band structures between CZS and CMS result in the formation of the internal electric field (IEF) and energy band bending at the interface of the heterojunction. This S-scheme charge transfer path enables 0D/2D CZS/CMS heterojunction possesses an exceptional capacity to maintain the robust redox potential and boosts the separation efficiency of light-induced carriers, as verified by DFT calculations and energy band structure analyses. As expected, the optimal heterojunction exhibits a satisfactory H2 generation rate of 13.1 mmol·g-1·h−1, which is nearly 7.7-fold higher than that of individual CZS. This study is expected to inspire the design of morphology-controlled hetero-structured photocatalyst with S-scheme charge transfer route for photocatalytic H2 generation.

Galvanostatic Electroshock Synthesis of Low Loading Au-Pt Nanoalloys onto Gas Diffusion Electrodes as Multifunctional Electrocatalysts for a Glycerol-Fed Electrolyzer.

Water electrolysis is increasingly considered a viable solution for meeting the world's growing energy demands and mitigating environmental issues. An inventive strategy to mitigate the energy requirements involves substituting the energy-intensive oxygen evolution reaction (OER) with biomass-derived glycerol electrooxidation. Nonetheless, the synthesis of electrocatalysts for controlling the selectivity towards added-value chemicals at the anode and efficient H2 generation at the cathode remains a critical bottleneck. Herein, we implemented a galvanostatic electroshock synthesis approach to control the reduction kinetics of Au(III) and Pt(IV) to grow ultra-low amount of gold-platinum alloys on a gas diffusion electrode (12-26 µgmetal cm‒2) for glycerol-fed hydroxide anion exchange membrane based electrolyzer. The symmetric GDE-Au100-xPtx||GDE-Au100-xPtx systems showed a notable improvement in electrolyzer performance (GDE-Au64Pt36 = 201 mA cm-2) as compared to monometallic versions (GDE-Au100Pt0 = 18 mA cm-2, GDE-Au0Pt100 = 81 mA cm-2). Chromatography (HPLC) analysis underscores the critical importance of bulk electrolysis methodology (galvanostatic vs potentiostatic) for the efficient conversion of glycerol into high-value-added products. Regarding the electrical energy required to produce 1 kg of H2 for such an electrolyzer fed at the anode with glycerol, our results confirm a drastic decrease by a factor of at least two compared with conventional water electrolysis.

Research on the design and optimal control of the power take-off (PTO) system for underwater eel-type power generators

Wave energy and ocean current energy are considered stable, reliable, and highly predictable renewable energy sources. The development of ocean current energy conversion technology is crucial in addressing power shortages. However, the low velocity of most ocean currents worldwide, typically less than 1.5 m/s, poses a challenge for traditional ocean current energy capture devices. Current estimations of power generation from underwater devices often significantly differ from actual results. This study presents an eel-type power generation device designed for underwater use, investigates the design and optimization of a hydraulic power take-off (PTO) system suitable for such devices, and examines key components of the hydraulic PTO system like variable hydraulic motors and generators. Analytical research was conducted to understand its operational characteristics, with a focus on components such as the accumulator, speed control valve, and energy storage flywheel. The article also delves into the hydrodynamic and energy conversion characteristics of the device under shallow water wave and current conditions, enhancing the hydraulic PTO system model and establishing an integrated calculation model for real-time data transmission during the calculation process. Through evaluations of pitch angle and power generation under varying sea conditions, the study explores the impact of hydraulic motor displacement and damping coefficient on the hydrodynamic and power generation characteristics of the device, further validated through sea trials. The study findings indicate a high level of parameter adaptation among the components of the hydraulic system. The addition of an accumulator to the system results in smoother output response curves, suggesting that the accumulator absorbs impacts and stabilizes the hydraulic power transmission system. The proposed comprehensive calculation method enables a more precise prediction of the performance of the eel power generation device in real marine environments, capturing its movement behavior and power generation characteristics. Adjusting the motor displacement or damping coefficient under specific conditions can optimize the total damping of the hydraulic PTO system for maximum power output. The optimal power point of the hydraulic power generation system varies for different sea conditions, with a potential power generation efficiency of up to 80.3% under certain circumstances.

Synergistic approach: Photocatalytic hydrogen generation for curcumin hydrogenation

Sn1-xFexO2 (x = 0, 0.1, 0.2 & 0.3) nanomaterials were successfully synthesized by co-precipitation technique and characterized by XRD, FTIR, SEM-EDAX, TG/DSC, etc. XPS revealed the presence of Fe+3 & Sn+4 ions in the SnO2 crystal lattice. Insertion of Fe shifts the absorption of SnO2 to the visible region. These synthesized nanomaterials show efficiency for hydrogen generation and degradation of organic dyes in the presence of visible light. The water splitting was performed under different conditions. A maximum hydrogen production rate of 12.8 mmol g−1h−1 was observed for Sn0.8Fe0.2O2 with glucose as a sacrificial agent. The photogenerated H2 finds application in hydrogenation of curcumin to tetrahydrocurcumin.

Improving MSME Accounting Financial Recording Skills Based on Android Applications

Purpose: This community service project aimed to enhance the financial recording skills of Micro, Small, and Medium Enterprises (MSMEs) in Desa Kapita through hands-on training with Android-based accounting applications. Research Design and Methodology: The project employed a mixed-methods approach, including pre-and post-training evaluations via questionnaires, interviews, and practical exercises. Involving 25 SME owners in Desa Kapita, Kecamatan Bangkala, and Kabupaten Jeneponto, the training focused on the Wave application for transaction recording, expense management, and financial report generation. The program featured interactive workshops, simulated business scenarios, and follow-up mentoring. Findings and Discussion: Post-training evaluations revealed significant improvements in financial recording skills. 80% of participants developed a solid understanding of basic accounting concepts, and 85% effectively utilized the Wave application for managing finances. The training enhanced the accuracy and efficiency of transaction recording and financial report generation, leading to improved financial oversight and business decision-making. Implications: The findings indicate that targeted training can effectively close the digital literacy gap among SME owners, promoting the use of modern financial tools. Future efforts should incorporate regular mentoring and the creation of local support networks to maintain and broaden the benefits of digital financial management solutions for MSMEs.